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Abstract In case of a core melt-down accident in a light water nuclear reactor, hydrogen is produced during reactor core degradation and released into the reactor building. This subsequently creates a combustion hazard. A local ignition of the combustible mixture may generate standing flames or initially slow propagating flames. Depending on geometry, mixture composition and turbulence level, the flame can accelerate or be quenched after a certain distance. The loads generated by the combustion process (increase of the containment atmosphere pressure and temperature) may threaten the integrity of the containment building and of internal walls and equipment. Turbulent deflagration flames may generate high pressure pulses, temperature peaks, shock waves and large pressure gradients which could severely damage specific containment components, internal walls and/or safety equipment. The evaluation of such loads requires validated codes which can be used with a high level of confidence. Currently, turbulence and steam effect on flame acceleration, flame deceleration and flame quenching mechanisms are not well reproduced by combustion models usually implemented in safety tools and further model enhancement and validation are still needed. For this purpose, two hydrogen deflagration benchmark exercises have been organised in the framework of the SARNET network. The first benchmark was focused on turbulence effect on flame propagation. For this purpose, three tests performed in the ENACCEF facility were considered. They concern vertical flame propagation in an initially homogenous mixture with 13 vol.% hydrogen content and different geometrical configurations. Three blockage ratios of 0, 0.33 and 0.6 were considered to generate different levels of turbulence. The second benchmark objective was the investigation of the diluting effect on flame propagation. Thus, three tests performed in the ENACCEF facility using the same blockage ratio of 0.63 and three different initial gas compositions (with 10, 20 and 30 vol.% diluents) have been considered. Since ENACCEF runs at ambient temperature, a surrogate to steam was used consisting of a mixture of 0.6He + 0.4CO 2 on molar basis. This paper aims to present the benchmarks conclusions regarding the ability of LP and CFD combustion models to predict the effect of turbulence and diluent on flame propagation.

Abstract In case of a core melt-down accident in a light water nuclear reactor, hydrogen is produced during reactor core degradation and released into the reactor building. This subsequently creates a combustion hazard. A local ignition of the combustible mixture may generate standing flames or initially slow propagating flames. Depending on geometry, mixture composition and turbulence level, the flame can accelerate or be quenched after a certain distance. The loads generated by the combustion process (increase of the containment atmosphere pressure and temperature) may threaten the integrity of the containment building and of internal walls and equipment. Turbulent deflagration flames may generate high pressure pulses, temperature peaks, shock waves and large pressure gradients which could severely damage specific containment components, internal walls and/or safety equipment. The evaluation of such loads requires validated codes which can be used with a high level of confidence. Currently, turbulence and steam effect on flame acceleration, flame deceleration and flame quenching mechanisms are not well reproduced by combustion models usually implemented in safety tools and further model enhancement and validation are still needed. For this purpose, two hydrogen deflagration benchmark exercises have been organised in the framework of the SARNET network. The first benchmark was focused on turbulence effect on flame propagation. For this purpose, three tests performed in the ENACCEF facility were considered. They concern vertical flame propagation in an initially homogenous mixture with 13 vol.% hydrogen content and different geometrical configurations. Three blockage ratios of 0, 0.33 and 0.6 were considered to generate different levels of turbulence. The second benchmark objective was the investigation of the diluting effect on flame propagation. Thus, three tests performed in the ENACCEF facility using the same blockage ratio of 0.63 and three different initial gas compositions (with 10, 20 and 30 vol.% diluents) have been considered. Since ENACCEF runs at ambient temperature, a surrogate to steam was used consisting of a mixture of 0.6He + 0.4CO 2 on molar basis. This paper aims to present the benchmarks conclusions regarding the ability of LP and CFD combustion models to predict the effect of turbulence and diluent on flame propagation.

Received 4 September 2013 Received in revised form 21 November 2013 Accepted 28 November 2013 Available online 31 December 2013 Keywords: Anisole Pyrolysis Oxidation Tars Biomass Kinetic modeling 1. Introduction Environmental concerns such as the control of greenhouse gas emissions have led to an increased interest in the use of renewable energy. Biomass is widely used in combustion but can also be uti- lized in more advanced applications such as the production of a synthesis gas (syngas, a mixture of CO and H2), which can be used for the production of liquid fuels such as Fisher-Tropsch or meth- anol. Lignocellulosic biomass may be a promising feedstock through the gasification processes [1,2], but tar is also formed dur- ing gasification [3]. The tar content in the product gas is the major cumbersome and problematic parameter in the gasification pro- cesses [4]. Tar represents a complex mixture of over 100 com- pounds [5,6]. It leads to fouling, coke deposition, and catalyst deactivation. Hence, tar conversion or removal is one of the main challenges for the successful development of commercial gasifica- tion technologies and has been extensively studied [7,8]. Evans and Milne [5] defined three main classes of tars: primary tars (low temperature, oxygenated) and secondary and tertiary tars (benzene, polycyclic aromatic hydrocarbons--PAHs, etc.). In com- bustion and gasification reactors, the heaviest (tertiary) tars are ⇑ Corresponding author. Fax: +33 3 83 37 81 20. E-mail address: pierre-alexandre.glaude@univ-lorraine.fr (P.-A. Glaude). abstract Anisole was chosen as the simplest surrogate for primary tar from lignin pyrolysis to study the gas-phase chemistry of methoxyphenol conversion. Methoxyphenols are one of the main precursors of PAH and soot in biomass combustion and gasification. These reactions are of paramount importance for the atmospheric environment, to mitigate emissions from wood combustion, and for reducing tar formation during gasification. Anisole pyrolysis and stoichiometric oxidation were studied in a jet-stirred reactor (673-1173 K, residence time 2 s, 800 Torr (106.7 kPa), under dilute conditions) coupled with gas chromatography-flame ionization detector and mass spectrometry. Decomposition of anisole starts at 750 K and a conversion degree of 50% is obtained at about 850 K under both studied conditions. The main products of reaction vary with temperature and are phenol, methane, carbon monoxide, benzene, and hydrogen. A detailed kinetic model (303 species, 1922 reactions) based on a combustion model for light aromatic compounds has been extended to anisole. The model predicts the conversion of anisole and the formation of the main products well. The reaction flux analyses show that anisole decomposes mainly to phenoxy and methyl radicals in both pyrolysis and oxidation conditions. The decomposition of phenoxy radicals is the main source of cyclopentadienyl radicals, which are the main precursor of naphthalene and heavier PAH in these conditions.

Received 4 September 2013 Received in revised form 21 November 2013 Accepted 28 November 2013 Available online 31 December 2013 Keywords: Anisole Pyrolysis Oxidation Tars Biomass Kinetic modeling 1. Introduction Environmental concerns such as the control of greenhouse gas emissions have led to an increased interest in the use of renewable energy. Biomass is widely used in combustion but can also be uti- lized in more advanced applications such as the production of a synthesis gas (syngas, a mixture of CO and H2), which can be used for the production of liquid fuels such as Fisher-Tropsch or meth- anol. Lignocellulosic biomass may be a promising feedstock through the gasification processes [1,2], but tar is also formed dur- ing gasification [3]. The tar content in the product gas is the major cumbersome and problematic parameter in the gasification pro- cesses [4]. Tar represents a complex mixture of over 100 com- pounds [5,6]. It leads to fouling, coke deposition, and catalyst deactivation. Hence, tar conversion or removal is one of the main challenges for the successful development of commercial gasifica- tion technologies and has been extensively studied [7,8]. Evans and Milne [5] defined three main classes of tars: primary tars (low temperature, oxygenated) and secondary and tertiary tars (benzene, polycyclic aromatic hydrocarbons--PAHs, etc.). In com- bustion and gasification reactors, the heaviest (tertiary) tars are ⇑ Corresponding author. Fax: +33 3 83 37 81 20. E-mail address: pierre-alexandre.glaude@univ-lorraine.fr (P.-A. Glaude). abstract Anisole was chosen as the simplest surrogate for primary tar from lignin pyrolysis to study the gas-phase chemistry of methoxyphenol conversion. Methoxyphenols are one of the main precursors of PAH and soot in biomass combustion and gasification. These reactions are of paramount importance for the atmospheric environment, to mitigate emissions from wood combustion, and for reducing tar formation during gasification. Anisole pyrolysis and stoichiometric oxidation were studied in a jet-stirred reactor (673-1173 K, residence time 2 s, 800 Torr (106.7 kPa), under dilute conditions) coupled with gas chromatography-flame ionization detector and mass spectrometry. Decomposition of anisole starts at 750 K and a conversion degree of 50% is obtained at about 850 K under both studied conditions. The main products of reaction vary with temperature and are phenol, methane, carbon monoxide, benzene, and hydrogen. A detailed kinetic model (303 species, 1922 reactions) based on a combustion model for light aromatic compounds has been extended to anisole. The model predicts the conversion of anisole and the formation of the main products well. The reaction flux analyses show that anisole decomposes mainly to phenoxy and methyl radicals in both pyrolysis and oxidation conditions. The decomposition of phenoxy radicals is the main source of cyclopentadienyl radicals, which are the main precursor of naphthalene and heavier PAH in these conditions.

In this paper a survey of solar-based driven thermoelectric technologies and their applications is presented. Initially, a brief analysis of the environmental problems related to the use of conventional technologies and energy sources is presented and the benefits offered by thermoelectric technologies and renewable energy systems are outlined. The development history of solar-based thermoelectric technologies is introduced together with the discussion of the existing drawbacks of current systems. Typical applications of the solar-driven thermoelectric refrigeration and the solar-driven thermoelectric power generation are presented in order to show to the reader the extent of their applicability. The application areas described in this paper show that solar-driven thermoelectric technologies could be used in a wide variety of fields. They are attractive technologies that not only can serve the needs for refrigeration, air-conditioning applications and power generation, but also can meet demand for energy conservation and environment protection.

In this paper a survey of solar-based driven thermoelectric technologies and their applications is presented. Initially, a brief analysis of the environmental problems related to the use of conventional technologies and energy sources is presented and the benefits offered by thermoelectric technologies and renewable energy systems are outlined. The development history of solar-based thermoelectric technologies is introduced together with the discussion of the existing drawbacks of current systems. Typical applications of the solar-driven thermoelectric refrigeration and the solar-driven thermoelectric power generation are presented in order to show to the reader the extent of their applicability. The application areas described in this paper show that solar-driven thermoelectric technologies could be used in a wide variety of fields. They are attractive technologies that not only can serve the needs for refrigeration, air-conditioning applications and power generation, but also can meet demand for energy conservation and environment protection.

We develop an open-source Python software integrating flexibility needs from Variable Renewable Energies (VREs) in the development of regional energy mixes. It provides a flexible and extensible tool to researchers/engineers, and for education/outreach. It aims at evaluating and optimizing energy deployment strategies with higher shares of VRE, assessing the impact of new technologies and of climate variability and conducting sensitivity studies. Specifically, to limit the algorithm’s complexity, we avoid solving a full-mix cost-minimization problem by taking the mean and variance of the renewable production–demand ratio as proxies to balance services. Second, observations of VRE technologies being typically too short or nonexistent, the hourly demand and production are estimated from climate time series and fitted to available observations. We illustrate e4clim’s potential with an optimal recommissioning-study of the 2015 Italian PV-wind mix testing different climate data sources and strategies and assessing the impact of climate variability and the robustness of the results.