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  • Authors: Sergio Mario Camporeale; Gianluigi Brunetti; Francesco Fornarelli; Antonio M. Pantaleo; +2 Authors

    In this paper different gas-steam combined-cycles fueled by syngas produced in a local downdraft gasifier, are analyzed. At first, the downdraft gasifier model is briefly described, where waste biomass is transformed into syngas, which can be used more efficiently than the original solid biomass to generate useful power, and can be transported much more easily. The gasifier model is able to estimate, with good approximation, the composition of the produced syngas, taking separately into account the biomass drying and the pyrolysis, oxidation and reduction processes. The gasifier operates at ambient pressure using air as gasification agent and biomass as input. Among others, pomace has been considered, since, in Italy (where the plant is supposed to be located) there are many regions, like Apulia, where this biomass is largely available. Three different plant configurations have been proposed and compared in terms of overall performance. The first two, named REXC (Regenerative cycle with EXternal Combustor) and CR (Conventional Regenerative cycle), burn the syngas in an internal combustor, whereas the third one, named SyEXC (Syngas External Combustion), considers an externally fired configuration for the syngas combustion. In the REXC cycle, a secondary external combustion system, fed by cellulosic biomass, is connected to a heat exchanger in order to increase the air temperature, as in a regenerative cycle. The combustion products pass through a primary heat exchanger placed in the external combustion system, heating the compressed air, which flows into the primary internal combustion chamber, where a defined quantity of syngas reacts with the compressed air. The turbine exhaust gas (TEG), before going back into the external combustion, partially transfers its enthalpy content to a Heat Recovery Steam Generator (HRSG) of a bottoming Rankine cycle. The second plant configuration (CR cycle) is characterized by a main internal combustor fueled by the produced syngas and implements a conventional regenerative process. The TEG is reheated by an externally fired combustion before flowing in the HRSG of a bottoming Rankine cycle. The last plant configuration (SyEXC) differs from the CR one only for the main externally fired gas turbine fueled by syngas, thus avoiding any costly cleanup operation and cooling.

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: El Nemr, A; Hassaan, MA; Elkatory, MR; Ragab, S; +4 Authors

    This paper proposes the use of modified biochar, derived from Sawdust (SD) biomass using sonication (SSDB) and Ozonation (OSDB) processes, as an additive for biogas production from green algae Cheatomorpha linum (C. linum) either individually or co-digested with natural diet for rotifer culture (S. parkel). Brunauer-Emmett-Teller (BET), Fourier-Transform Infrared (FTIR), thermal-gravimetric (TGA), and X-ray diffraction (XRD) analyses were used to characterize the generated biochar. Ultrasound (US) specific energy, dose, intensity and dissolved ozone (O3) concentration were also calculated. FTIR analyses proved the capability of US and ozonation treatment of biochar to enhance the biogas production process. The kinetic model proposed fits successfully with the data of the experimental work and the modified Gompertz models that had the maximum R2 value of 0.993 for 150 mg/L of OSDB. The results of this work confirmed the significant impact of US and ozonation processes on the use of biochar as an additive in biogas production. The highest biogas outputs 1059 mL/g VS and 1054 mL/g VS) were achieved when 50 mg of SSDB and 150 mg of OSDB were added to C. linum co-digested with S. parkle.

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    Ultrasonics Sonochemistry
    Article . 2022 . Peer-reviewed
    License: CC BY NC ND
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    Ultrasonics Sonochemistry
    Article . 2022
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Imperial College Lon...arrow_drop_down
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      Ultrasonics Sonochemistry
      Article . 2022 . Peer-reviewed
      License: CC BY NC ND
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Ultrasonics Sonochemistry
      Article . 2022
      Data sources: DOAJ
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Sara Giarola; Antonio M. Pantaleo; Antonio M. Pantaleo; Nilay Shah; +1 Authors

    The paper presents a mixed integer linear programming (MILP) approach to optimize multi-biomass and natural gas supply chain strategic design for heat and power generation in urban areas. The focus is on spatial and temporal allocation of biomass supply, storage, processing, transport and energy conversion (heat and CHP) to match the heat demand of residential end users. The main aim lies on the representation of the relationships between the biomass processing and biofuel energy conversion steps, and on the trade-offs between centralized district heating plants and local heat generation systems. After a description of state of the art and research trends in urban energy systems and bioenergy modelling, an application of the methodology to a generic case study is proposed. With the assumed techno-economic parameters, biomass based thermal energy generation results competitive with natural gas, while district heating network results the main option for urban areas with high thermal energy demand density. Potential further applications of this model are also described, together with main barriers for development of bioenergy routes for urban areas.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Energy Conversion an...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Energy Conversion and Management
    Article . 2014 . Peer-reviewed
    License: Elsevier TDM
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Energy Conversion an...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Energy Conversion and Management
      Article . 2014 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Oyeniyi A. Oyewunmi; Antonio M. Pantaleo; Antonio M. Pantaleo; P. De Palma; +5 Authors

    Abstract The high cost of organic Rankine cycle (ORC) systems is a key barrier to their implementation in waste-heat recovery (WHR) applications. In particular, the choice of the expansion device has a significant influence on this cost, strongly affecting the economic viability of an installation. In this work, numerical simulations and optimisation strategies are used to compare the performance and profitability of small-scale ORC systems using reciprocating-piston or single/two-stage screw expanders when recovering heat from the exhaust gases of a 185-kW internal combustion engine operating in baseload mode. The study goes beyond previous work by directly comparing these small-scale expanders for a broad range of working fluids, and by exploring the sensitivity of project viability to key parameters such as electricity price and onsite heat demand. For the piston expander, a lumped-mass model and optimisation based on artificial neural networks are used to generate performance maps, while performance and cost correlations from the literature are used for the screw expanders. The thermodynamic analysis shows that two-stage screw expanders typically deliver more power than either single-stage screw or piston expanders due to their higher conversion efficiency at the required pressure ratios. The best fluids for the proposed application are acetone and ethanol, as these provide a compromise between the exergy losses in the condenser and in the evaporator. The maximum net power output is found to be 17.7 kW, from an ORC engine operating with acetone and a two-stage screw expander. On the other hand, the thermoeconomic optimisation shows that reciprocating-piston expanders show a potential for lower specific costs, and since piston-expander technology is not mature, especially at these scales, this finding motivates further consideration of this component. A minimum specific investment cost of 1630 €/kW is observed for an ORC engine with a piston expander, again with acetone as the working fluid. This system, optimised for minimum cost, gives the shortest payback time of 4 years at an avoided electricity cost of 0.13 €/kWh. Finally, financial appraisals show a high sensitivity of the investment profitability to the value of produced electricity and to the heat-demand intensity.

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    Energy Conversion and Management
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    Energy Conversion and Management
    Article . 2019 . Peer-reviewed
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    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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      Energy Conversion and Management
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      Energy Conversion and Management
      Article . 2019 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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    Authors: Antonio M. Pantaleo; Antonio M. Pantaleo; Kai Wang; María Herrando; +2 Authors

    This paper presents a thermoeconomic analysis of a solar combined heating and power (S-CHP) system based on hybrid photovoltaic-thermal (PV/T) collectors for the University Sport Centre (USC) of Bari, Italy. Hourly demand data for space heating, swimming pool heating, hot water and electricity provision as well as the local weather data are used as inputs to a transient model developed in TRNSYS. Economic performance is evaluated by considering the investment costs and the cost savings due to the reduced electricity and natural gas consumptions. The results show that 38.2% of the electricity demand can be satisfied by the PV/T S-CHP system based on an installation area of 4, 000 m 2 . The coverage increases to 81.3% if the excess electricity is fed to the grid. In addition, the system can cover 23.7% of the space heating demand and 53.8% of the demand for the swimming pool and hot water heating. A comparison with an equivalent gas-fired internal combustion engine (ICE) CHP system shows that the PV/T system has a longer payback time, i.e., 11.6 years vs. 3 years, but significantly outperforms the ICE solution in terms of CO2 emission reduction, i.e., 435 tons CO2/year vs. 164 tons CO2/year. These findings suggest that even though the economic competitiveness of the proposed PV/T S-CHP system is not yet favourable when compared to the alternative gas-fired ICE-based system, the S-CHP solution has an excellent decarbonisation potential, and that if this is of importance in the wider sense of energy-system decarbonisation, it is necessary to consider how the higher upfront costs can be addressed.

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    Energy Procedia
    Article . 2019 . Peer-reviewed
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      Energy Procedia
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    Authors: Michele Faccia; Kai Wang; Kai Wang; Christos N. Markides; +5 Authors

    Dairy farming is one of the most energy- and emission-intensive industrial sectors, and offers noteworthy opportunities for displacing conventional fossil-fuel consumption both in terms of cost saving and decarbonisation. In this paper, a solar-combined heat and power (S–CHP) system is proposed for dairy-farm applications based on spectral-splitting parabolic-trough hybrid photovoltaic-thermal (PVT) collectors, which is capable of providing simultaneous electricity, steam and hot water for processing milk products. A transient numerical model is developed and validated against experimental data to predict the dynamic thermal and electrical characteristics and to assess the thermoeconomic performance of the S–CHP system. A dairy farm in Bari (Italy), with annual thermal and electrical demands of 6000 MWh and 3500 MWh respectively, is considered as a case study for assessing the energetic and economic potential of the proposed S–CHP system. Hourly simulations are performed over a year using real-time local weather and measured demand-data inputs. The results show that the optical characteristic of the spectrum splitter has a significant influence on the system''s thermoeconomic performance. This is therefore optimised to reflect the solar region between 550 nm and 1000 nm to PV cells for electricity generation and (low-temperature) hot-water production, while directing the rest to solar receivers for (higher-temperature) steam generation. Based on a 10000-m2 installed area, it is found that 52% of the demand for steam generation and 40% of the hot water demand can be satisfied by the PVT S–CHP system, along with a net electrical output amounting to 14% of the farm''s demand. Economic analyses show that the proposed system is economically viable if the investment cost of the spectrum splitter is lower than 75% of the cost of the parabolic trough concentrator (i.e., <1950 €/m2 spectrum splitter) in this application. The influence of utility prices on the system''s economics is also analysed and it is found to be significant. An environmental assessment shows that the system has excellent decarbonisation potential (890 tCO2/year) relative to conventional solutions. Further research efforts should be directed towards the spectrum splitter, and in particular on achieving reductions to the cost of this component, as this leads directly to an increased financial competitiveness of the proposed system.

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    Renewable Energy
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    Renewable Energy
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      Renewable Energy
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      Renewable Energy
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    Authors: Sergio Mario Camporeale; Antonio M. Pantaleo; Antonio M. Pantaleo; Nilay Shah;

    Abstract This paper compares different operating strategies for small scale (100 kWe) combined heat and power (CHP) plants fired by natural gas and solid biomass to serve a residential energy demand. The focus is on a dual fuel micro gas turbine (MGT) cycle. Various biomass/natural gas energy input ratios are modelled, in order to assess the trade-offs between: (i) lower energy conversion efficiency and higher investment cost when increasing the biomass input rate; (ii) higher primary energy savings and revenues from feed-in tariff available for biomass electricity fed into the grid. The strategies of baseload (BL), heat driven (HD) and electricity driven (ED) plant operation are compared, for an aggregate of residential end-users in cold, average and mild climate conditions. On the basis of the results from thermodynamic assessment and simulation at partial load operation, CAPEX and OPEX estimates, and Italian energy policy scenario (incentives available for biomass electricity, on-site and high efficiency CHP), the maximum global energy efficiency, primary energy savings and investment profitability is found, as a function of biomass/natural gas ratio, plant operating strategy and energy demand typology. The thermal and electric conversion efficiency ranged respectively between 46 and 38% and 30 and 19% for the natural gas and biomass fired case studies. The IRR of the investment was highly influenced by the load/CHP thermal power ratio and by the operation mode. The availability of high heat demand levels was also a key factor, to avoid wasted cogenerated heat and maximize CHP sales revenues. BL operation presented the highest profitability because of the higher revenues from electricity sales. Climate area was another important factor, mainly in case of low load/CHP ratios. Moreover, at low load/CHP power ratio and for the BL operation mode, the dual fuel option presented the highest profitability. This is due to the lower cost of biomass fuel in comparison to natural gas and the high subsidies available for biomass electricity by feed-in tariffs. The results show that dual fuel MT can be an interesting option to increase efficiencies, flexibility and plant reliability at low cost in comparison to only biomass systems, facilitating an integration of renewable and fossil fuel systems.

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    Applied Thermal Engineering
    Article . 2014 . Peer-reviewed
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      Applied Thermal Engineering
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    Authors: Maria Anna Chatzopoulou; Christos N. Markides; Martin T. White; Andrew J. Haslam; +3 Authors

    The successful commercialisation of organic Rankine cycle (ORC) systems across a range of power outputs and heat-source temperatures demands step-changes in both improved thermodynamic performance and reduced investment costs. The former can be achieved through high-performance components and optimised system architectures operating with novel working-fluids, whilst the latter requires careful component-technology selection, economies of scale, learning curves and a proper selection of materials and cycle configurations. In this context, thermoeconomic optimisation of the whole power-system should be completed aimed at maximising profitability. This paper couples the computer-aided molecular design (CAMD) of the working-fluid with ORC thermodynamic models, including recuperated and other alternative (e.g., partial evaporation or trilateral) cycles, and a thermoeconomic system assessment. The developed CAMD-ORC framework integrates an advanced molecular-based group-contribution equation of state, SAFT-γ Mie, with a thermodynamic description of the system, and is capable of simultaneously optimising the working-fluid structure, and the thermodynamic system. The advantage of the proposed CAMD-ORC methodology is that it removes subjective and pre-emptive screening criteria that would otherwise exist in conventional working-fluid selection studies. The framework is used to optimise hydrocarbon working-fluids for three different heat sources (150, 250 and 350 °C, each with mcp = 4.2 kW/K). In each case, the optimal combination of working-fluid and ORC system architecture is identified, and system investment costs are evaluated through component sizing models. It is observed that optimal working fluids that minimise the specific investment cost (SIC) are not the same as those that maximise power output. For the three heat sources the optimal working-fluids that minimise the SIC are isobutane, 2-pentene and 2-heptene, with SICs of 4.03, 2.22 and 1.84 £/W respectively.

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    Energy Procedia
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      Energy Procedia
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    Authors: Marko Aunedi; Andreas V. Olympios; Antonio M. Pantaleo; Christos N. Markides; +1 Authors

    This research explores various combinations of electric heat pumps (EHPs), hydrogen boilers (HBs), electric boilers (EBs), hydrogen absorption heat pumps (AHPs) and thermal energy storage (TES) to assess their potential for delivering cost-efficient low-carbon heat supply. The proposed technology-to-systems approach is based on comprehensive thermodynamic and component-costing models of various heating technologies, which are integrated into a whole-energy system optimisation model to determine cost-effective configurations of heating systems that minimise the overall cost for both the system and the end-user. Case studies presented in the study focus on two archetypal systems: (i) the North system, which is characterised by colder climate conditions and abundant wind resource; and (ii) the South system, which is characterised by a milder climate and higher solar energy potential. The results indicate a preference for a portfolio of low-carbon heating technologies including EHPs, EBs and HBs, coupled with a sizable amount of TES, while AHPs are not chosen, since, for the investigated conditions, their efficiency does not outweigh the high investment cost. Capacities of heat technologies are found to vary significantly depending on system properties such as the volume and diversity of heat demand and the availability profiles of renewable generation. The bulk of heat (83–97%) is delivered through EHPs, while the remainder is supplied by a mix of EBs and HBs. The results also suggest a strong impact of heat demand diversity on the cost-efficient mix of heating technologies, with higher diversity penalizing EHP relatively more than other, less capital-intensive heating options.

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    Renewable and Sustainable Energy Reviews
    Article . 2023 . Peer-reviewed
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      Renewable and Sustainable Energy Reviews
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    Authors: Ahmed El Nemr; Mohamed A. Hassaan; Marwa R. Elkatory; Safaa Ragab; +1 Authors

    In this work, different pretreatment methods for algae proved to be very effective in improving cell wall dissociation for biogas production. In this study, the Ulva intestinalis Linnaeus (U. intestinalis) has been exposed to individual pretreatments of (ultrasonic, ozone, microwave, and green synthesized Fe3O4) and in a combination of the first three mentioned pretreatments methods with magnetite (Fe3O4) NPs, (ultrasonic-Fe3O4, ozone-Fe3O4 and microwave-Fe3O4) in different treatment times. Moreover, the green synthesized Fe3O4 NPs has been confirmed by FTIR, TEM, XRD, SEM, EDEX, PSA and BET. The maximum biogas production of 179 and 206 mL/g VS have been attained when U. intestinalis has been treated with ultrasonic only and when combined microwave with Fe3O4 respectively, where sediment were used as inoculum in all pretreatments. From the obtained results, green Fe3O4 NPs enhanced the microwave (MW) treatment to produce a higher biogas yield (206 mL/g VS) when compared with individual MW (84 mL/g VS). The modified Gompertz model (R2 = 0.996 was appropriate model to match the calculated biogas production and could be used more practically to distinguish the kinetics of the anaerobic digestion (AD) period. The assessment of XRD, SEM and FTIR discovered the influence of different treatment techniques on the cell wall structure of U. intestinalis.

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    Molecules
    Article . 2021 . Peer-reviewed
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      Molecules
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36 Research products
  • Authors: Sergio Mario Camporeale; Gianluigi Brunetti; Francesco Fornarelli; Antonio M. Pantaleo; +2 Authors

    In this paper different gas-steam combined-cycles fueled by syngas produced in a local downdraft gasifier, are analyzed. At first, the downdraft gasifier model is briefly described, where waste biomass is transformed into syngas, which can be used more efficiently than the original solid biomass to generate useful power, and can be transported much more easily. The gasifier model is able to estimate, with good approximation, the composition of the produced syngas, taking separately into account the biomass drying and the pyrolysis, oxidation and reduction processes. The gasifier operates at ambient pressure using air as gasification agent and biomass as input. Among others, pomace has been considered, since, in Italy (where the plant is supposed to be located) there are many regions, like Apulia, where this biomass is largely available. Three different plant configurations have been proposed and compared in terms of overall performance. The first two, named REXC (Regenerative cycle with EXternal Combustor) and CR (Conventional Regenerative cycle), burn the syngas in an internal combustor, whereas the third one, named SyEXC (Syngas External Combustion), considers an externally fired configuration for the syngas combustion. In the REXC cycle, a secondary external combustion system, fed by cellulosic biomass, is connected to a heat exchanger in order to increase the air temperature, as in a regenerative cycle. The combustion products pass through a primary heat exchanger placed in the external combustion system, heating the compressed air, which flows into the primary internal combustion chamber, where a defined quantity of syngas reacts with the compressed air. The turbine exhaust gas (TEG), before going back into the external combustion, partially transfers its enthalpy content to a Heat Recovery Steam Generator (HRSG) of a bottoming Rankine cycle. The second plant configuration (CR cycle) is characterized by a main internal combustor fueled by the produced syngas and implements a conventional regenerative process. The TEG is reheated by an externally fired combustion before flowing in the HRSG of a bottoming Rankine cycle. The last plant configuration (SyEXC) differs from the CR one only for the main externally fired gas turbine fueled by syngas, thus avoiding any costly cleanup operation and cooling.

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: El Nemr, A; Hassaan, MA; Elkatory, MR; Ragab, S; +4 Authors

    This paper proposes the use of modified biochar, derived from Sawdust (SD) biomass using sonication (SSDB) and Ozonation (OSDB) processes, as an additive for biogas production from green algae Cheatomorpha linum (C. linum) either individually or co-digested with natural diet for rotifer culture (S. parkel). Brunauer-Emmett-Teller (BET), Fourier-Transform Infrared (FTIR), thermal-gravimetric (TGA), and X-ray diffraction (XRD) analyses were used to characterize the generated biochar. Ultrasound (US) specific energy, dose, intensity and dissolved ozone (O3) concentration were also calculated. FTIR analyses proved the capability of US and ozonation treatment of biochar to enhance the biogas production process. The kinetic model proposed fits successfully with the data of the experimental work and the modified Gompertz models that had the maximum R2 value of 0.993 for 150 mg/L of OSDB. The results of this work confirmed the significant impact of US and ozonation processes on the use of biochar as an additive in biogas production. The highest biogas outputs 1059 mL/g VS and 1054 mL/g VS) were achieved when 50 mg of SSDB and 150 mg of OSDB were added to C. linum co-digested with S. parkle.

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    Ultrasonics Sonochemistry
    Article . 2022 . Peer-reviewed
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    Ultrasonics Sonochemistry
    Article . 2022
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Imperial College Lon...arrow_drop_down
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      Ultrasonics Sonochemistry
      Article . 2022 . Peer-reviewed
      License: CC BY NC ND
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      Ultrasonics Sonochemistry
      Article . 2022
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Sara Giarola; Antonio M. Pantaleo; Antonio M. Pantaleo; Nilay Shah; +1 Authors

    The paper presents a mixed integer linear programming (MILP) approach to optimize multi-biomass and natural gas supply chain strategic design for heat and power generation in urban areas. The focus is on spatial and temporal allocation of biomass supply, storage, processing, transport and energy conversion (heat and CHP) to match the heat demand of residential end users. The main aim lies on the representation of the relationships between the biomass processing and biofuel energy conversion steps, and on the trade-offs between centralized district heating plants and local heat generation systems. After a description of state of the art and research trends in urban energy systems and bioenergy modelling, an application of the methodology to a generic case study is proposed. With the assumed techno-economic parameters, biomass based thermal energy generation results competitive with natural gas, while district heating network results the main option for urban areas with high thermal energy demand density. Potential further applications of this model are also described, together with main barriers for development of bioenergy routes for urban areas.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Energy Conversion an...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Energy Conversion and Management
    Article . 2014 . Peer-reviewed
    License: Elsevier TDM
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Energy Conversion an...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Energy Conversion and Management
      Article . 2014 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Oyeniyi A. Oyewunmi; Antonio M. Pantaleo; Antonio M. Pantaleo; P. De Palma; +5 Authors

    Abstract The high cost of organic Rankine cycle (ORC) systems is a key barrier to their implementation in waste-heat recovery (WHR) applications. In particular, the choice of the expansion device has a significant influence on this cost, strongly affecting the economic viability of an installation. In this work, numerical simulations and optimisation strategies are used to compare the performance and profitability of small-scale ORC systems using reciprocating-piston or single/two-stage screw expanders when recovering heat from the exhaust gases of a 185-kW internal combustion engine operating in baseload mode. The study goes beyond previous work by directly comparing these small-scale expanders for a broad range of working fluids, and by exploring the sensitivity of project viability to key parameters such as electricity price and onsite heat demand. For the piston expander, a lumped-mass model and optimisation based on artificial neural networks are used to generate performance maps, while performance and cost correlations from the literature are used for the screw expanders. The thermodynamic analysis shows that two-stage screw expanders typically deliver more power than either single-stage screw or piston expanders due to their higher conversion efficiency at the required pressure ratios. The best fluids for the proposed application are acetone and ethanol, as these provide a compromise between the exergy losses in the condenser and in the evaporator. The maximum net power output is found to be 17.7 kW, from an ORC engine operating with acetone and a two-stage screw expander. On the other hand, the thermoeconomic optimisation shows that reciprocating-piston expanders show a potential for lower specific costs, and since piston-expander technology is not mature, especially at these scales, this finding motivates further consideration of this component. A minimum specific investment cost of 1630 €/kW is observed for an ORC engine with a piston expander, again with acetone as the working fluid. This system, optimised for minimum cost, gives the shortest payback time of 4 years at an avoided electricity cost of 0.13 €/kWh. Finally, financial appraisals show a high sensitivity of the investment profitability to the value of produced electricity and to the heat-demand intensity.

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    Energy Conversion and Management
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    Energy Conversion and Management
    Article . 2019 . Peer-reviewed
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    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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    Authors: Antonio M. Pantaleo; Antonio M. Pantaleo; Kai Wang; María Herrando; +2 Authors

    This paper presents a thermoeconomic analysis of a solar combined heating and power (S-CHP) system based on hybrid photovoltaic-thermal (PV/T) collectors for the University Sport Centre (USC) of Bari, Italy. Hourly demand data for space heating, swimming pool heating, hot water and electricity provision as well as the local weather data are used as inputs to a transient model developed in TRNSYS. Economic performance is evaluated by considering the investment costs and the cost savings due to the reduced electricity and natural gas consumptions. The results show that 38.2% of the electricity demand can be satisfied by the PV/T S-CHP system based on an installation area of 4, 000 m 2 . The coverage increases to 81.3% if the excess electricity is fed to the grid. In addition, the system can cover 23.7% of the space heating demand and 53.8% of the demand for the swimming pool and hot water heating. A comparison with an equivalent gas-fired internal combustion engine (ICE) CHP system shows that the PV/T system has a longer payback time, i.e., 11.6 years vs. 3 years, but significantly outperforms the ICE solution in terms of CO2 emission reduction, i.e., 435 tons CO2/year vs. 164 tons CO2/year. These findings suggest that even though the economic competitiveness of the proposed PV/T S-CHP system is not yet favourable when compared to the alternative gas-fired ICE-based system, the S-CHP solution has an excellent decarbonisation potential, and that if this is of importance in the wider sense of energy-system decarbonisation, it is necessary to consider how the higher upfront costs can be addressed.

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    Energy Procedia
    Article . 2019 . Peer-reviewed
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      Energy Procedia
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    Authors: Michele Faccia; Kai Wang; Kai Wang; Christos N. Markides; +5 Authors

    Dairy farming is one of the most energy- and emission-intensive industrial sectors, and offers noteworthy opportunities for displacing conventional fossil-fuel consumption both in terms of cost saving and decarbonisation. In this paper, a solar-combined heat and power (S–CHP) system is proposed for dairy-farm applications based on spectral-splitting parabolic-trough hybrid photovoltaic-thermal (PVT) collectors, which is capable of providing simultaneous electricity, steam and hot water for processing milk products. A transient numerical model is developed and validated against experimental data to predict the dynamic thermal and electrical characteristics and to assess the thermoeconomic performance of the S–CHP system. A dairy farm in Bari (Italy), with annual thermal and electrical demands of 6000 MWh and 3500 MWh respectively, is considered as a case study for assessing the energetic and economic potential of the proposed S–CHP system. Hourly simulations are performed over a year using real-time local weather and measured demand-data inputs. The results show that the optical characteristic of the spectrum splitter has a significant influence on the system''s thermoeconomic performance. This is therefore optimised to reflect the solar region between 550 nm and 1000 nm to PV cells for electricity generation and (low-temperature) hot-water production, while directing the rest to solar receivers for (higher-temperature) steam generation. Based on a 10000-m2 installed area, it is found that 52% of the demand for steam generation and 40% of the hot water demand can be satisfied by the PVT S–CHP system, along with a net electrical output amounting to 14% of the farm''s demand. Economic analyses show that the proposed system is economically viable if the investment cost of the spectrum splitter is lower than 75% of the cost of the parabolic trough concentrator (i.e., <1950 €/m2 spectrum splitter) in this application. The influence of utility prices on the system''s economics is also analysed and it is found to be significant. An environmental assessment shows that the system has excellent decarbonisation potential (890 tCO2/year) relative to conventional solutions. Further research efforts should be directed towards the spectrum splitter, and in particular on achieving reductions to the cost of this component, as this leads directly to an increased financial competitiveness of the proposed system.

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    Renewable Energy
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    Renewable Energy
    Article . 2020 . Peer-reviewed
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      Renewable Energy
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      Renewable Energy
      Article . 2020 . Peer-reviewed
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    Authors: Sergio Mario Camporeale; Antonio M. Pantaleo; Antonio M. Pantaleo; Nilay Shah;

    Abstract This paper compares different operating strategies for small scale (100 kWe) combined heat and power (CHP) plants fired by natural gas and solid biomass to serve a residential energy demand. The focus is on a dual fuel micro gas turbine (MGT) cycle. Various biomass/natural gas energy input ratios are modelled, in order to assess the trade-offs between: (i) lower energy conversion efficiency and higher investment cost when increasing the biomass input rate; (ii) higher primary energy savings and revenues from feed-in tariff available for biomass electricity fed into the grid. The strategies of baseload (BL), heat driven (HD) and electricity driven (ED) plant operation are compared, for an aggregate of residential end-users in cold, average and mild climate conditions. On the basis of the results from thermodynamic assessment and simulation at partial load operation, CAPEX and OPEX estimates, and Italian energy policy scenario (incentives available for biomass electricity, on-site and high efficiency CHP), the maximum global energy efficiency, primary energy savings and investment profitability is found, as a function of biomass/natural gas ratio, plant operating strategy and energy demand typology. The thermal and electric conversion efficiency ranged respectively between 46 and 38% and 30 and 19% for the natural gas and biomass fired case studies. The IRR of the investment was highly influenced by the load/CHP thermal power ratio and by the operation mode. The availability of high heat demand levels was also a key factor, to avoid wasted cogenerated heat and maximize CHP sales revenues. BL operation presented the highest profitability because of the higher revenues from electricity sales. Climate area was another important factor, mainly in case of low load/CHP ratios. Moreover, at low load/CHP power ratio and for the BL operation mode, the dual fuel option presented the highest profitability. This is due to the lower cost of biomass fuel in comparison to natural gas and the high subsidies available for biomass electricity by feed-in tariffs. The results show that dual fuel MT can be an interesting option to increase efficiencies, flexibility and plant reliability at low cost in comparison to only biomass systems, facilitating an integration of renewable and fossil fuel systems.

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    Applied Thermal Engineering
    Article . 2014 . Peer-reviewed
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      Applied Thermal Engineering
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    Authors: Maria Anna Chatzopoulou; Christos N. Markides; Martin T. White; Andrew J. Haslam; +3 Authors

    The successful commercialisation of organic Rankine cycle (ORC) systems across a range of power outputs and heat-source temperatures demands step-changes in both improved thermodynamic performance and reduced investment costs. The former can be achieved through high-performance components and optimised system architectures operating with novel working-fluids, whilst the latter requires careful component-technology selection, economies of scale, learning curves and a proper selection of materials and cycle configurations. In this context, thermoeconomic optimisation of the whole power-system should be completed aimed at maximising profitability. This paper couples the computer-aided molecular design (CAMD) of the working-fluid with ORC thermodynamic models, including recuperated and other alternative (e.g., partial evaporation or trilateral) cycles, and a thermoeconomic system assessment. The developed CAMD-ORC framework integrates an advanced molecular-based group-contribution equation of state, SAFT-γ Mie, with a thermodynamic description of the system, and is capable of simultaneously optimising the working-fluid structure, and the thermodynamic system. The advantage of the proposed CAMD-ORC methodology is that it removes subjective and pre-emptive screening criteria that would otherwise exist in conventional working-fluid selection studies. The framework is used to optimise hydrocarbon working-fluids for three different heat sources (150, 250 and 350 °C, each with mcp = 4.2 kW/K). In each case, the optimal combination of working-fluid and ORC system architecture is identified, and system investment costs are evaluated through component sizing models. It is observed that optimal working fluids that minimise the specific investment cost (SIC) are not the same as those that maximise power output. For the three heat sources the optimal working-fluids that minimise the SIC are isobutane, 2-pentene and 2-heptene, with SICs of 4.03, 2.22 and 1.84 £/W respectively.

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    Energy Procedia
    Article . 2017 . Peer-reviewed
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      Energy Procedia
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    Authors: Marko Aunedi; Andreas V. Olympios; Antonio M. Pantaleo; Christos N. Markides; +1 Authors

    This research explores various combinations of electric heat pumps (EHPs), hydrogen boilers (HBs), electric boilers (EBs), hydrogen absorption heat pumps (AHPs) and thermal energy storage (TES) to assess their potential for delivering cost-efficient low-carbon heat supply. The proposed technology-to-systems approach is based on comprehensive thermodynamic and component-costing models of various heating technologies, which are integrated into a whole-energy system optimisation model to determine cost-effective configurations of heating systems that minimise the overall cost for both the system and the end-user. Case studies presented in the study focus on two archetypal systems: (i) the North system, which is characterised by colder climate conditions and abundant wind resource; and (ii) the South system, which is characterised by a milder climate and higher solar energy potential. The results indicate a preference for a portfolio of low-carbon heating technologies including EHPs, EBs and HBs, coupled with a sizable amount of TES, while AHPs are not chosen, since, for the investigated conditions, their efficiency does not outweigh the high investment cost. Capacities of heat technologies are found to vary significantly depending on system properties such as the volume and diversity of heat demand and the availability profiles of renewable generation. The bulk of heat (83–97%) is delivered through EHPs, while the remainder is supplied by a mix of EBs and HBs. The results also suggest a strong impact of heat demand diversity on the cost-efficient mix of heating technologies, with higher diversity penalizing EHP relatively more than other, less capital-intensive heating options.

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    Renewable and Sustainable Energy Reviews
    Article . 2023 . Peer-reviewed
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      Renewable and Sustainable Energy Reviews
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    Authors: Ahmed El Nemr; Mohamed A. Hassaan; Marwa R. Elkatory; Safaa Ragab; +1 Authors

    In this work, different pretreatment methods for algae proved to be very effective in improving cell wall dissociation for biogas production. In this study, the Ulva intestinalis Linnaeus (U. intestinalis) has been exposed to individual pretreatments of (ultrasonic, ozone, microwave, and green synthesized Fe3O4) and in a combination of the first three mentioned pretreatments methods with magnetite (Fe3O4) NPs, (ultrasonic-Fe3O4, ozone-Fe3O4 and microwave-Fe3O4) in different treatment times. Moreover, the green synthesized Fe3O4 NPs has been confirmed by FTIR, TEM, XRD, SEM, EDEX, PSA and BET. The maximum biogas production of 179 and 206 mL/g VS have been attained when U. intestinalis has been treated with ultrasonic only and when combined microwave with Fe3O4 respectively, where sediment were used as inoculum in all pretreatments. From the obtained results, green Fe3O4 NPs enhanced the microwave (MW) treatment to produce a higher biogas yield (206 mL/g VS) when compared with individual MW (84 mL/g VS). The modified Gompertz model (R2 = 0.996 was appropriate model to match the calculated biogas production and could be used more practically to distinguish the kinetics of the anaerobic digestion (AD) period. The assessment of XRD, SEM and FTIR discovered the influence of different treatment techniques on the cell wall structure of U. intestinalis.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Moleculesarrow_drop_down
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    Molecules
    Article . 2021 . Peer-reviewed
    License: CC BY
    Data sources: Crossref
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    Molecules
    Article
    License: CC BY
    Data sources: UnpayWall
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    Molecules
    Article . 2021
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Molecules
    Article . 2021
    Data sources: DOAJ
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Moleculesarrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Molecules
      Article . 2021 . Peer-reviewed
      License: CC BY
      Data sources: Crossref
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Molecules
      Article
      License: CC BY
      Data sources: UnpayWall
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Molecules
      Article . 2021
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Molecules
      Article . 2021
      Data sources: DOAJ
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      This Research product is the result of merged Research products in OpenAIRE.

      You have already added works in your ORCID record related to the merged Research product.
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