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This work evaluates, for the first time, the possibility of producing multifunctional alkali-activated composites combining ultra-low density, low thermal conductivity, high acoustic absorption, and good moisture buffering capacity. The composites were prepared using cork as a lightweight aggregate. This novel material might promote energy savings and tackle the CO2 emissions of the building sector, while simultaneously improve the comfort for inhabitants (e.g. humidity levels regulation and sound pollution reduction). The composites apparent density (as low as 168 kg/m3) and thermal conductivity (as low as 68 mW/m K) are amongst the lowest ever reported for alkali-activated materials (AAM) composites and foams, while their sound absorption ability is comparable to the best performing AAM foams reported to date, but in addition these eco-friendly composites also show good ability to passively adjust the humidity levels inside buildings. The multifunctional properties shown by the cork – AAM composites set them apart from other conventional building materials and might contribute to the global sustainability of the construction sector. Peer Reviewed

This work evaluates, for the first time, the possibility of producing multifunctional alkali-activated composites combining ultra-low density, low thermal conductivity, high acoustic absorption, and good moisture buffering capacity. The composites were prepared using cork as a lightweight aggregate. This novel material might promote energy savings and tackle the CO2 emissions of the building sector, while simultaneously improve the comfort for inhabitants (e.g. humidity levels regulation and sound pollution reduction). The composites apparent density (as low as 168 kg/m3) and thermal conductivity (as low as 68 mW/m K) are amongst the lowest ever reported for alkali-activated materials (AAM) composites and foams, while their sound absorption ability is comparable to the best performing AAM foams reported to date, but in addition these eco-friendly composites also show good ability to passively adjust the humidity levels inside buildings. The multifunctional properties shown by the cork – AAM composites set them apart from other conventional building materials and might contribute to the global sustainability of the construction sector. Peer Reviewed

Beyond the anticipated experience associated with tourism destinations, the United Nations World Tourism Organization (UNWTO) has further tasked (especially the destination countries) on the importance of tourism to achieving the 2030 Sustainable Development Goals (SDGs). From this dimension, this study employed the ecological footprint of the 10 most visited countries (France, Spain, United States, China, Italy, Mexico, United Kingdom, Turkey, Germany, and Thailand) over the period 1995-2016. Specifically, the study employed an econometric approach and found that increase in tourism arrivals and globalization is detrimental to the attainment of sustainable environmental quality in a long term. Precisely, a 1% increase in international arrivals and globalization is responsible for a 0.18 and 0.89% increase in ecological footprint in the long-run. These impacts of tourism activities and globalization are detrimental to the environmental quality of the destination countries. Meanwhile, the real income per capita and biocapacity in the destination countries improve the environmental quality of the panel of destination countries in the long-run. In addition, the study found significant evidence of Granger causality from tourism and real income to ecological footprint without feedback, the globalization-ecological footprint Granger causality nexus is with feedback. Moreover, potentially effective policies for government and other stakeholders especially toward attaining Global goals were proffered in the study.

Beyond the anticipated experience associated with tourism destinations, the United Nations World Tourism Organization (UNWTO) has further tasked (especially the destination countries) on the importance of tourism to achieving the 2030 Sustainable Development Goals (SDGs). From this dimension, this study employed the ecological footprint of the 10 most visited countries (France, Spain, United States, China, Italy, Mexico, United Kingdom, Turkey, Germany, and Thailand) over the period 1995-2016. Specifically, the study employed an econometric approach and found that increase in tourism arrivals and globalization is detrimental to the attainment of sustainable environmental quality in a long term. Precisely, a 1% increase in international arrivals and globalization is responsible for a 0.18 and 0.89% increase in ecological footprint in the long-run. These impacts of tourism activities and globalization are detrimental to the environmental quality of the destination countries. Meanwhile, the real income per capita and biocapacity in the destination countries improve the environmental quality of the panel of destination countries in the long-run. In addition, the study found significant evidence of Granger causality from tourism and real income to ecological footprint without feedback, the globalization-ecological footprint Granger causality nexus is with feedback. Moreover, potentially effective policies for government and other stakeholders especially toward attaining Global goals were proffered in the study.

The pyrolysis of waste disposable paper cups (WDPCs) was investigated using a thermogravimetric analyser coupled with a Fourier transform infrared spectrometer. The activation energies of the pyrolysis reactions were obtained by the Flynn–Wall–Ozawa (FWO) and Kissinger–Akahira–Sunose (KAS) methods respectively. The kinetic model was determined by the master plots method. Thermogravimetric results showed that the highest weight loss rate occurred from 345 to 365 °C as the heating rate was increased from 10 to 30 °C min−1, indicating the pyrolysis of cellulosic material in the WDPC. The weight loss between 400 and 500 °C can be attributed to the decomposition of polyethylene. By analysing the FTIR spectra, it was found that the absorbance of all the evolved gaseous products had peaks at 360 °C due to the decomposition of cellulose fibres and the cracking of polyethylene at 485 °C led to the emergence of a second hydrocarbon peak. Ketones were the most abundant condensable organic products and CO2 was the dominating gaseous product, which can also be produced via secondary cracking of the small molecule organics above 400 °C. Kinetic analysis revealed that the average activation energy of the pyrolysis of the WDPC was 153.75 kJ mol−1 from the FWO method and 151.43 kJ mol−1 from the KAS method. The reaction mechanism can be described by the R3 model.

The pyrolysis of waste disposable paper cups (WDPCs) was investigated using a thermogravimetric analyser coupled with a Fourier transform infrared spectrometer. The activation energies of the pyrolysis reactions were obtained by the Flynn–Wall–Ozawa (FWO) and Kissinger–Akahira–Sunose (KAS) methods respectively. The kinetic model was determined by the master plots method. Thermogravimetric results showed that the highest weight loss rate occurred from 345 to 365 °C as the heating rate was increased from 10 to 30 °C min−1, indicating the pyrolysis of cellulosic material in the WDPC. The weight loss between 400 and 500 °C can be attributed to the decomposition of polyethylene. By analysing the FTIR spectra, it was found that the absorbance of all the evolved gaseous products had peaks at 360 °C due to the decomposition of cellulose fibres and the cracking of polyethylene at 485 °C led to the emergence of a second hydrocarbon peak. Ketones were the most abundant condensable organic products and CO2 was the dominating gaseous product, which can also be produced via secondary cracking of the small molecule organics above 400 °C. Kinetic analysis revealed that the average activation energy of the pyrolysis of the WDPC was 153.75 kJ mol−1 from the FWO method and 151.43 kJ mol−1 from the KAS method. The reaction mechanism can be described by the R3 model.

Coal power plants have been a major source of undesirable emissions. Despite the technological advancements in renewable energies, coal units are still in-service in many developed and developing countries due to their reliability, adequacy, and flexibility for power delivery. There are some promising technologies for cleaner operation during power production from coal, including supercritical boiler (SC) design and carbon capture and storage (CCS), however, the challenging in innovating effective methods is still open to expand the boundary of knowledge in this speciality. This paper introduces a novel and simple method for reducing CO2 emissions and improving the dynamic responses of a 600 MW SC coal power plant by Artificial Neural Network (ANN) technique. A wide-range data-driven feedforward ANN model has been identified and verified for the various operations recorded as closed-loop data-sets, which covers all situations of startup, once-through mode, and even emergency shutdown of the unit. The closed-loop SC plant model has been augmented with an inverse multivariable coordinate NN controller, developed by analogous learning algorithm to improve the plant automation. With precisely selected setpoints, as operational rules, of temperature, pressure, and earliest possible power demand signals, the automated SC plant has been capable to operate with lower coal consumption - and thus lower emissions – than the existing operation strategy during startup, normal operation, and emergency shutdown modes. The improvement in dynamic responses have been quantified through simulations with comparison with existing performance, which have resulted in an overall average reduction of 2.143 Kg/s in coal consumption.