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Abstract This paper examines the effects of foreign trade and foreign direct investment (FDI) on CO 2 emissions in Turkey. We consider linear and nonlinear ARDL models and find significant asymmetric effects of exports, imports and FDI on CO 2 emissions per capita. However, FDI has no statistically significant long-run effects. In the long run, decreases in exports reduce CO 2 emissions per capita but increases in exports have no statistically significant effects. Increases in imports push up CO 2 emissions per capita, while decreases in imports have no long-run effects. On the other hand, CO 2 intensity, which measures CO 2 emissions per unit of energy, is not influenced by exports and imports, nor by FDI. Instead, it is affected positively by financial development and urbanization. Also, we find that an environmental Kuznets curve is present for both CO 2 measures so that increases in real GDP per capita have led to reductions in CO 2 emissions for at least the most recent decade, controlling for other confounding factors. Furthermore, the sectoral shares of CO 2 emissions in total CO 2 emissions change asymmetrically with foreign trade for two of four sectors, with export increases leading to lower CO 2 shares and imports having the opposite effect.

In industrialized countries, large amounts of mineral wastes are produced. They are re-used in various ways, particularly in road and earth constructions, substituting primary resources such as gravel. However, they may also contain pollutants, such as heavy metals, which may be leached to the groundwater. The toxic impacts of these emissions are so far often neglected within Life Cycle Assessments (LCA) of products or waste treatment services and thus, potentially large environmental impacts are currently missed. This study aims at closing this gap by assessing the ecotoxic impacts of heavy metal leaching from industrial mineral wastes in road and earth constructions. The flows of metals such as Sb, As, Pb, Cd, Cr, Cu, Mo, Ni, V and Zn originating from three typical constructions to the environment are quantified, their fate in the environment is assessed and potential ecotoxic effects evaluated. For our reference country, Germany, the industrial wastes that are applied as Granular Secondary Construction Material (GSCM) carry more than 45,000 t of diverse heavy metals per year. Depending on the material quality and construction type applied, up to 150 t of heavy metals may leach to the environment within the first 100 years after construction. Heavy metal retardation in subsoil can potentially reduce the fate to groundwater by up to 100%. One major challenge of integrating leaching from constructions into macro-scale LCA frameworks is the high variability in micro-scale technical and geographical factors, such as material qualities, construction types and soil types. In our work, we consider a broad range of parameter values in the modeling of leaching and fate. This allows distinguishing between the impacts of various road constructions, as well as sites with different soil properties. The findings of this study promote the quantitative consideration of environmental impacts of long-term leaching in Life Cycle Assessment, complementing site-specific risk assessment, for the design of waste management strategies, particularly in the construction sector.

According to the second law of thermodynamics, all human activities cause exergy destructions, adding to additional root causes for carbon dioxide emissions responsibility. It means that current carbon dioxide concentrations are accurately observed, but the root causes and their potential solutions against global warming fall short of achieving the goals of the Paris agreement by almost 45% in terms of decarbonization efforts, as shown in this paper. This result applies to all activities, including the green facility concept. In this respect, the primary aim of this paper is to raise awareness about the essence of the Second Law of Thermodynamics in expanding the green facility concept to reach more effective and sustainable rating methodologies concerning the climate crisis. A new evaluating and rating model with a set of exergy-based green building metrics that relate additional carbon dioxide emissions to irreversible exergy destructions has been developed. Examples about apparently green buildings according to the First Law of Thermodynamics are given by showing that these buildings are not green due to additional carbon dioxide emissions responsibility due to exergy destructions. An airport terminal building case is elaborated. It has been shown that although part of the electricity comes from a third-party wind energy provider, it ends up with carbon dioxide emissions responsibility because it is not entirely used in exergy-rational demand points and compares less favorably with an on-site cogeneration system using natural gas by about 30% more emissions responsibility. The results and derivations of new metrics are discussed, which shed light on adding new criteria to existing green building certification programs.

Abstract As main contributors to greenhouse gas emissions, power and transportation are crucial sectors for energy system decarbonization. Their interaction is expected to increase significantly: plug-in electric vehicles add a new electric load, increasing grid demand and potentially requiring substantial grid upgrade; hydrogen production for fuel cell electric vehicles or for clean fuels synthesis could exploit the projected massive power overgeneration by intermittent and seasonally-dependent renewable sources via Power-to-Hydrogen. This work investigates the infrastructural needs involved with a broad diffusion of clean mobility, adopting a sector integration perspective at the national scale. The analysis combines a multi-node energy system balance simulation and a techno-economic assessment of the infrastructure to deliver energy vectors for mobility. The article explores the long-term case of Italy, considering a massive increase of renewable power generation capacity and investigating different mobility scenarios, where low-emission vehicles account for 50% of the stock. First, the model solves the energy balances, integrating the consumption related to mobility energy vectors and taking into account power grid constraints. Then, an optimal infrastructure is identified, composed of both a hydrogen delivery network and a widespread installation of charging points. Results show that the infrastructural requirements bring about investment costs in the range of 43–63 G€. Lower specific costs are associated with the exclusive presence of FCEVs, whereas the full reliance on BEVs leads to the most significant costs. Scenarios that combine FCEVs and BEVs lie in between, suggesting that the overall power + mobility system benefits from the presence of both drivetrain options.

AbstractThis study compared the economic and environmental impacts of torrefaction on bioenergy supply chains against conventional pellets for scenarios where biomass is produced in Mozambique, and undergoes pre‐processing before shipment to Rotterdam for conversion to power and Fischer‐Tropsch (FT) fuels. We also compared the impacts of using different land quality (productive and marginal) for feedstock production, feedstocks (eucalyptus and switchgrass), final conversion technologies (XtY and CXtY) and markets (the Netherlands and Mozambique). At current conditions, the torrefied pellets (TOPs) are delivered in Rotterdam at higher cost (7.3–7.5 $/GJ) than pellets (5.1–5.3 $/GJ). In the long term, TOPs costs could decline (4.7–5.8 $/GJ) and converge with pellets. TOPs supply chains also incur 20% lower greenhouse gas (GHG) emissions than pellets. Due to improved logistics and lower conversion investment, fuel production costs from TOPs are lower (12.8–16.9 $/GJFT) than from pellets (12.9–18.7 $/GJFT). Co‐firing scenarios (CXtY) result in lower cost fuel (but a higher environmental penalty) than 100% biomass fired scenarios (XtY). In most cases, switchgrass and the productive region of Nampula provide the lowest fuel production cost compared to eucalyptus and the marginally productive Gaza region. Both FT and ion in Mozambique are more costly than in Rotterdam. For the Netherlands, both FT and power production are competitive against average energy costs in Western Europe. The analysis shows that large‐scale bioenergy production can become competitive against fossil fuels. While the benefits of TOPs are apparent in logistics and conversion, the current higher torrefaction costs contribute to higher biofuel costs. Improvements in torrefaction technology can result in significant performance improvements over the future chain. © 2013 Society of Chemical Industry and John Wiley & Sons, Ltd

This article searches the effects of tourism development onemission pollutants in Malta using (1) the autoregressivedistributed lag approach and (2) two datasets which are annualdata from 1971 to 2018 and quarterly data from 1990Q1 tı2018Q4 as per data availability. Findings confirm that tourism,energy usage, and carbon dioxide emissions are in a long-termequilibrium relationship; carbon emissions converge rapidlytowards the long-term equilibrium path through tourism andenergy consumption channels. Findings also reveal that growthin tourism results in significant changes in energy consumptionand, therefore, in CO2emissions. Tourism has positive effects oncarbon emissions in shorter periods. Still, these effects turn out tobe harmful in the more extended periods beyond the peak pointof carbon emissions which correspond to 1,063,213 milliontourists. Therefore, this study strongly confirms the existence ofan inverted U-shaped Environmental Kuznets Curve hypothesisfor Malta.

Fossil fuel substitution with biomass is one of the measures to reduce carbon dioxide (CO2) emissions. This paper estimates the cost-effectiveness of raising industrial steam and producing materials (i.e. chemicals, polymers) from biomass. We quantify their long-term global potentials in terms of energy saving, CO2 emission reduction, cost and resource availability. Technically, biomass can replace all fossil fuels used for the production of materials and for generating low and medium temperature steam. Cost-effective opportunities exist for steam production from biomass residues and by substitution of high value petrochemicals which would together require more than 20 exajoules (EJ) of biomass worldwide in addition to baseline by 2030. Potentials could double in 2050 and reach 38-45 EJ (25% of the total industrial energy use), with most demand in Asia, other developing countries and economies in transition. The economic potential of using biomass as chemical feedstock is nearly as high as for steam production, indicating its importance. The exploitation of these potentials depends on energy prices and industry's access to biomass supply. Given the increasing competition for biomass from several economic sectors, more resource efficient materials need to be developed while steam production is already attractive due to its high effectiveness for reducing CO2 emissions per unit of biomass.

National net zero emission targets could, if fully implemented, reduce best estimates of projected global average temperature increase to 2.0–2.4 °C by 2100, bringing the Paris Agreement temperature goal within reach. A total of 131 countries are discussing, have announced or have adopted net zero targets, covering 72% of global emissions. These targets could substantially lower projected warming as compared to currently implemented policies (2.9–3.2 °C) or pledges submitted to the Paris Agreement (2.4–2.9 °C). Current pledges for emissions cuts are insufficient to meet the Paris Agreement temperature goal. The wave of net zero targets being discussed and adopted could make the Paris goal possible if further countries follow suit.