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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: orcid Marta Otero;
    Marta Otero
    ORCID
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    Marta Otero in OpenAIRE
    A. Aller; orcid J. Cara;
    J. Cara
    ORCID
    Harvested from ORCID Public Data File

    J. Cara in OpenAIRE
    orcid Antonio Morán;
    Antonio Morán
    ORCID
    Harvested from ORCID Public Data File

    Antonio Morán in OpenAIRE

    Column biodesulphurization of coal is at the experimental stage and is influenced by many variables including temperature, pH, particle size, concentration of iron in solution, among others. Idle time in the washing process and the concentration of dissolved iron in the purged leachate are two variables with a definite effect on the yield of the desulphurization system. In the laboratory, several trials were run with columns packed with coal for different idle times: 1, 2, 3, 5, 6 and 7 days, and for different concentrations of iron in the purged leachate: 500 to 4,000 mg/l. The optimal values for the two variables; that is, those allowing for the highest desulphurization yields, were idle times of 3 and 5 days, which give an elimination of 56% and 49% of pyritic sulphur, respectively, and 3,000 mg/l of iron concentration in the purged leachate, giving a decrease in pyritic sulphur in coal of 57%.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Applied Microbiology...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Applied Microbiology and Biotechnology
    Article . 2001 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Applied Microbiology...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Applied Microbiology and Biotechnology
      Article . 2001 . Peer-reviewed
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: orcid Marta Otero;
    Marta Otero
    ORCID
    Harvested from ORCID Public Data File

    Marta Otero in OpenAIRE
    A. Aller; orcid J. Cara;
    J. Cara
    ORCID
    Harvested from ORCID Public Data File

    J. Cara in OpenAIRE
    orcid Antonio Morán;
    Antonio Morán
    ORCID
    Harvested from ORCID Public Data File

    Antonio Morán in OpenAIRE

    Column biodesulphurization of coal is at the experimental stage and is influenced by many variables including temperature, pH, particle size, concentration of iron in solution, among others. Idle time in the washing process and the concentration of dissolved iron in the purged leachate are two variables with a definite effect on the yield of the desulphurization system. In the laboratory, several trials were run with columns packed with coal for different idle times: 1, 2, 3, 5, 6 and 7 days, and for different concentrations of iron in the purged leachate: 500 to 4,000 mg/l. The optimal values for the two variables; that is, those allowing for the highest desulphurization yields, were idle times of 3 and 5 days, which give an elimination of 56% and 49% of pyritic sulphur, respectively, and 3,000 mg/l of iron concentration in the purged leachate, giving a decrease in pyritic sulphur in coal of 57%.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Applied Microbiology...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Applied Microbiology and Biotechnology
    Article . 2001 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Applied Microbiology...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Applied Microbiology and Biotechnology
      Article . 2001 . Peer-reviewed
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: orcid Marta Otero;
    Marta Otero
    ORCID
    Harvested from ORCID Public Data File

    Marta Otero in OpenAIRE
    orcid Antonio Morán;
    Antonio Morán
    ORCID
    Harvested from ORCID Public Data File

    Antonio Morán in OpenAIRE
    orcid A.I. García;
    A.I. García
    ORCID
    Harvested from ORCID Public Data File

    A.I. García in OpenAIRE
    Marta Elena Sánchez;

    Abstract To combust coal together with a small percentage (<10%) of sewage sludge may be an option for the management of these wastes. Combustion of two different sewage sludge, one semianthracite coal and several sludges-coal blends (containing different dried mass% of each of the two sewage sludges) were studied by simultaneous TG/MS dynamic runs carried out at 5C min–1 in the temperature range 100–800C. No interactions have been observed between coal and sludge during the blends combustion. Neither the combustion process, neither the studied emissions have changed appreciably for the mass% of sludge in the blends considered in this work.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Thermal A...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Journal of Thermal Analysis and Calorimetry
    Article . 2006 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Thermal A...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Journal of Thermal Analysis and Calorimetry
      Article . 2006 . Peer-reviewed
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: orcid Marta Otero;
    Marta Otero
    ORCID
    Harvested from ORCID Public Data File

    Marta Otero in OpenAIRE
    orcid Antonio Morán;
    Antonio Morán
    ORCID
    Harvested from ORCID Public Data File

    Antonio Morán in OpenAIRE
    orcid A.I. García;
    A.I. García
    ORCID
    Harvested from ORCID Public Data File

    A.I. García in OpenAIRE
    Marta Elena Sánchez;

    Abstract To combust coal together with a small percentage (<10%) of sewage sludge may be an option for the management of these wastes. Combustion of two different sewage sludge, one semianthracite coal and several sludges-coal blends (containing different dried mass% of each of the two sewage sludges) were studied by simultaneous TG/MS dynamic runs carried out at 5C min–1 in the temperature range 100–800C. No interactions have been observed between coal and sludge during the blends combustion. Neither the combustion process, neither the studied emissions have changed appreciably for the mass% of sludge in the blends considered in this work.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Thermal A...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Journal of Thermal Analysis and Calorimetry
    Article . 2006 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Thermal A...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Journal of Thermal Analysis and Calorimetry
      Article . 2006 . Peer-reviewed
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: orcid Marta Otero;
    Marta Otero
    ORCID
    Harvested from ORCID Public Data File

    Marta Otero in OpenAIRE
    orcid Antonio Morán;
    Antonio Morán
    ORCID
    Harvested from ORCID Public Data File

    Antonio Morán in OpenAIRE
    orcid María Victoria Gil;
    María Victoria Gil
    ORCID
    Harvested from ORCID Public Data File

    María Victoria Gil in OpenAIRE
    L.F. Calvo; +1 Authors

    The kinetics of the combustion of coal, two different sewage sludge and their blends (containing different dried weight percentages of sewage sludge) was studied by simultaneous thermogravimetric analysis. Once the weight percentage of sludge in the blend was 10%, the effects on the combustion of coal were hardly noticeable in terms of weight loss. The Arrhenius activation energy corresponding to the co-combustion of the blends was evaluated by non-isothermal kinetic analysis. This showed that, though differences between coal and sewage sludge, the combustion of their blends kept kinetically alike to that of the coal. This work illustrates how thermogravimetric analysis may be used as an easy rapid tool to asses, not only mass loss, but also kinetics of the co-combustion of sewage sludge and coal blends.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Bioresource Technolo...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Bioresource Technology
    Article . 2008 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Bioresource Technolo...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Bioresource Technology
      Article . 2008 . Peer-reviewed
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: orcid Marta Otero;
    Marta Otero
    ORCID
    Harvested from ORCID Public Data File

    Marta Otero in OpenAIRE
    orcid Antonio Morán;
    Antonio Morán
    ORCID
    Harvested from ORCID Public Data File

    Antonio Morán in OpenAIRE
    orcid María Victoria Gil;
    María Victoria Gil
    ORCID
    Harvested from ORCID Public Data File

    María Victoria Gil in OpenAIRE
    L.F. Calvo; +1 Authors

    The kinetics of the combustion of coal, two different sewage sludge and their blends (containing different dried weight percentages of sewage sludge) was studied by simultaneous thermogravimetric analysis. Once the weight percentage of sludge in the blend was 10%, the effects on the combustion of coal were hardly noticeable in terms of weight loss. The Arrhenius activation energy corresponding to the co-combustion of the blends was evaluated by non-isothermal kinetic analysis. This showed that, though differences between coal and sewage sludge, the combustion of their blends kept kinetically alike to that of the coal. This work illustrates how thermogravimetric analysis may be used as an easy rapid tool to asses, not only mass loss, but also kinetics of the co-combustion of sewage sludge and coal blends.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Bioresource Technolo...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Bioresource Technology
    Article . 2008 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Bioresource Technolo...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Bioresource Technology
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: orcid Marta Otero;
    Marta Otero
    ORCID
    Harvested from ORCID Public Data File

    Marta Otero in OpenAIRE
    C. Dı́ez; orcid Antonio Morán;
    Antonio Morán
    ORCID
    Harvested from ORCID Public Data File

    Antonio Morán in OpenAIRE
    orcid A.I. García;
    A.I. García
    ORCID
    Harvested from ORCID Public Data File

    A.I. García in OpenAIRE
    +1 Authors

    Combustion of sewage sludge may be a viable solution for its management in some cases and so is its co-combustion with coal. The aim of the present paper is to study the behavior of three different sludges during combustion and the modifications of combustion parameters that take place when sludges are mixed with coal, all measurements being done by thermogravimetry. The combustion of pyrolyzed sewage sludges has also been studied, related to the possibility of combining combustion with pyrolysis when trying to valorize sludges by producing active carbon. From the burning profile data it has been possible to observe that a rapid devolatilization occurs during sludge combustion compared to coal and previously pyrolyzed sludge. The exact temperatures of devolatilization and of maximum speed of weight loss have also been ascertained together with differential thermal analysis and measurements of gas emissions during combustion. The behavior of the sludges tested is qualitatively similar but quantitatively different, so tests have to be carried out before they are put in the furnace.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Biomass and Bioenerg...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Biomass and Bioenergy
    Article . 2002 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Biomass and Bioenerg...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Biomass and Bioenergy
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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: orcid Marta Otero;
    Marta Otero
    ORCID
    Harvested from ORCID Public Data File

    Marta Otero in OpenAIRE
    C. Dı́ez; orcid Antonio Morán;
    Antonio Morán
    ORCID
    Harvested from ORCID Public Data File

    Antonio Morán in OpenAIRE
    orcid A.I. García;
    A.I. García
    ORCID
    Harvested from ORCID Public Data File

    A.I. García in OpenAIRE
    +1 Authors

    Combustion of sewage sludge may be a viable solution for its management in some cases and so is its co-combustion with coal. The aim of the present paper is to study the behavior of three different sludges during combustion and the modifications of combustion parameters that take place when sludges are mixed with coal, all measurements being done by thermogravimetry. The combustion of pyrolyzed sewage sludges has also been studied, related to the possibility of combining combustion with pyrolysis when trying to valorize sludges by producing active carbon. From the burning profile data it has been possible to observe that a rapid devolatilization occurs during sludge combustion compared to coal and previously pyrolyzed sludge. The exact temperatures of devolatilization and of maximum speed of weight loss have also been ascertained together with differential thermal analysis and measurements of gas emissions during combustion. The behavior of the sludges tested is qualitatively similar but quantitatively different, so tests have to be carried out before they are put in the furnace.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Biomass and Bioenerg...arrow_drop_down
    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Biomass and Bioenergy
    Article . 2002 . Peer-reviewed
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Biomass and Bioenerg...arrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Biomass and Bioenergy
      Article . 2002 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: orcid M.J. Cuetos;
    M.J. Cuetos
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    M.J. Cuetos in OpenAIRE
    orcid E. Judith Martínez;
    E. Judith Martínez
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    E. Judith Martínez in OpenAIRE
    orcid Marta Otero;
    Marta Otero
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    Marta Otero in OpenAIRE
    orcid Rubén González;
    Rubén González
    ORCID
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    Rubén González in OpenAIRE
    +2 Authors

    The potential of using anaerobic digestion for the treatment of poultry blood has been evaluated in batch assays at the laboratory scale and in a mesophilic semi-continuous reactor. The biodegradability test performed on residual poultry blood was carried out in spite of high inhibitory levels of acid intermediaries. The use of activated carbon as a way to prevent inhibitory conditions demonstrated the feasibility of attaining anaerobic digestion under extreme ammonium and acid conditions. Batch assays with higher carbon content presented higher methane production rates, although the difference in the final cumulative biogas production was not as sharp. The digestion of residual blood was also studied under semi-continuous operation using granular and powdered activated carbon. The average specific methane production was 216 ± 12 mL CH4/g VS. This result was obtained in spite of a strong volatile fatty acid (VFA) accumulation, reaching values around 6 g/L, along with high ammonium concentrations (in the range of 6-8 g/L). The use of powdered activated carbon resulted in a better assimilation of C3-C5 acid forms, indicating that an enhancement in syntrophic metabolism may have taken place. Thermal analysis and scanning electron microscopy (SEM) were applied as analytical tools for measuring the presence of organic material in the final digestate and evidencing modifications on the carbon surface. The addition of activated carbon for the digestion of residual blood highly improved the digestion process. The adsorption capacity of ammonium, the protection this carrier may offer by limiting mass transfer of toxic compounds, and its capacity to act as a conductive material may explain the successful digestion of residual blood as the sole substrate.

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    Authors: orcid M.J. Cuetos;
    M.J. Cuetos
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    M.J. Cuetos in OpenAIRE
    orcid E. Judith Martínez;
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    E. Judith Martínez in OpenAIRE
    orcid Marta Otero;
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    Marta Otero in OpenAIRE
    orcid Rubén González;
    Rubén González
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    Rubén González in OpenAIRE
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    The potential of using anaerobic digestion for the treatment of poultry blood has been evaluated in batch assays at the laboratory scale and in a mesophilic semi-continuous reactor. The biodegradability test performed on residual poultry blood was carried out in spite of high inhibitory levels of acid intermediaries. The use of activated carbon as a way to prevent inhibitory conditions demonstrated the feasibility of attaining anaerobic digestion under extreme ammonium and acid conditions. Batch assays with higher carbon content presented higher methane production rates, although the difference in the final cumulative biogas production was not as sharp. The digestion of residual blood was also studied under semi-continuous operation using granular and powdered activated carbon. The average specific methane production was 216 ± 12 mL CH4/g VS. This result was obtained in spite of a strong volatile fatty acid (VFA) accumulation, reaching values around 6 g/L, along with high ammonium concentrations (in the range of 6-8 g/L). The use of powdered activated carbon resulted in a better assimilation of C3-C5 acid forms, indicating that an enhancement in syntrophic metabolism may have taken place. Thermal analysis and scanning electron microscopy (SEM) were applied as analytical tools for measuring the presence of organic material in the final digestate and evidencing modifications on the carbon surface. The addition of activated carbon for the digestion of residual blood highly improved the digestion process. The adsorption capacity of ammonium, the protection this carrier may offer by limiting mass transfer of toxic compounds, and its capacity to act as a conductive material may explain the successful digestion of residual blood as the sole substrate.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Journal of Advanced ...arrow_drop_down
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    Authors: orcid Marta Otero;
    Marta Otero
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    Marta Otero in OpenAIRE
    Carla Escapa; orcid Sergio A. Paniagua;
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    Sergio A. Paniagua in OpenAIRE
    orcid Ricardo N. Coimbra;
    Ricardo N. Coimbra
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    Ricardo N. Coimbra in OpenAIRE
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    This work aimed to study both the removal of nutrients and pharmaceuticals, namely salicylic acid or paracetamol, from water by the culture of Chlorella sorokiniana. The removal of nutrients was nearly complete at the end of the batch culture; above 70% for nitrates and 89% for phosphates in the semicontinuous culture. The pharmaceuticals removal kinetics were 2.3 times greater for the salicylic acid than paracetamol, reaching volumetric efficiencies above 93% for salicylic acid in the semicontinuous culture. Finally, to separate the microalgae biomass from treated water, metal salts, synthetic polyelectrolytes and a biopolymer were tested as coagulants-flocculants. The best flocculation results were achieved with AlCl3 (95.23% with 200mgg(-1), 1min incubation time). However, given that resulting flocs had different characteristics, flocculants must be chosen on the basis of the subsequent use of the biomass.

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    Bioresource Technology
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    Authors: orcid Marta Otero;
    Marta Otero
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    Carla Escapa; orcid Sergio A. Paniagua;
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    Sergio A. Paniagua in OpenAIRE
    orcid Ricardo N. Coimbra;
    Ricardo N. Coimbra
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    Harvested from ORCID Public Data File

    Ricardo N. Coimbra in OpenAIRE
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    This work aimed to study both the removal of nutrients and pharmaceuticals, namely salicylic acid or paracetamol, from water by the culture of Chlorella sorokiniana. The removal of nutrients was nearly complete at the end of the batch culture; above 70% for nitrates and 89% for phosphates in the semicontinuous culture. The pharmaceuticals removal kinetics were 2.3 times greater for the salicylic acid than paracetamol, reaching volumetric efficiencies above 93% for salicylic acid in the semicontinuous culture. Finally, to separate the microalgae biomass from treated water, metal salts, synthetic polyelectrolytes and a biopolymer were tested as coagulants-flocculants. The best flocculation results were achieved with AlCl3 (95.23% with 200mgg(-1), 1min incubation time). However, given that resulting flocs had different characteristics, flocculants must be chosen on the basis of the subsequent use of the biomass.

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    Bioresource Technology
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    Authors: L.F. Calvo; orcid Sergio A. Paniagua;
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    orcid Ricardo N. Coimbra;
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    orcid Marta Otero;
    Marta Otero
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    Marta Otero in OpenAIRE
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    Properties of primary and secondary pulp mill sludge are unalike and are also very different from those of coal. Thermogravimetric analysis was used to assess the separate combustion of coal, primary and secondary pulp mill sludge. Then, the co-combustion of coal with primary and with secondary pulp mill sludge was studied under identical experimental conditions. Both Differential Thermogravimetry burning profiles (DTG) and Differential Scanning Calorimetric analysis (DSC) showed remarkable differences between the combustion of coal, primary and secondary paper mill sludge. However, compared with the combustion of coal, the effects of adding a 10 wt.% of either primary or secondary paper mill sludge were not relevant in terms of weight loss or heat release. This was further proved by non-isothermal kinetic analysis, which was used to evaluate the apparent activation energy corresponding to the single combustions and to the co-combustion of blends.

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      Renewable Energy
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    Authors: L.F. Calvo; orcid Sergio A. Paniagua;
    Sergio A. Paniagua
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    orcid Marta Otero;
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    Properties of primary and secondary pulp mill sludge are unalike and are also very different from those of coal. Thermogravimetric analysis was used to assess the separate combustion of coal, primary and secondary pulp mill sludge. Then, the co-combustion of coal with primary and with secondary pulp mill sludge was studied under identical experimental conditions. Both Differential Thermogravimetry burning profiles (DTG) and Differential Scanning Calorimetric analysis (DSC) showed remarkable differences between the combustion of coal, primary and secondary paper mill sludge. However, compared with the combustion of coal, the effects of adding a 10 wt.% of either primary or secondary paper mill sludge were not relevant in terms of weight loss or heat release. This was further proved by non-isothermal kinetic analysis, which was used to evaluate the apparent activation energy corresponding to the single combustions and to the co-combustion of blends.

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    Renewable Energy
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    Authors: orcid Marta Otero;
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    Sandra I.M. Carvalho; orcid Eduarda B.H. Santos;
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    The pulp and paper industry generates large volume of wastewater that adversely affects water resources. Lignin derived macromolecular compounds, similar to natural humic substances, are the main waste products in the pulp mill effluents. The UV-Vis and fluorescence spectroscopies were used to assess the effect of solar exposition on fulvic acids from a kraft pulp mill effluent. Solar irradiation of the solutions of these fulvic acids caused solution acidification and decay both in the UV-Vis absorbance and in the fluorescence. This decay was not the same for the whole spectra but pointed to the selective photodegradation of lignin typical structures. Furthermore, by sequential ultrafiltration it was found that during irradiation, the high-molecular weight fractions were destroyed and low-molecular-weight constituents, potentially more able to penetrate the cell membranes of living organisms were formed. Photodegradation of macromolecular organic matter from a kraft pulp mill effluent may be a key process occurring in natural waters that modifies the physicochemical properties of such effluents.

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    Chemosphere
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    Authors: orcid Marta Otero;
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    The pulp and paper industry generates large volume of wastewater that adversely affects water resources. Lignin derived macromolecular compounds, similar to natural humic substances, are the main waste products in the pulp mill effluents. The UV-Vis and fluorescence spectroscopies were used to assess the effect of solar exposition on fulvic acids from a kraft pulp mill effluent. Solar irradiation of the solutions of these fulvic acids caused solution acidification and decay both in the UV-Vis absorbance and in the fluorescence. This decay was not the same for the whole spectra but pointed to the selective photodegradation of lignin typical structures. Furthermore, by sequential ultrafiltration it was found that during irradiation, the high-molecular weight fractions were destroyed and low-molecular-weight constituents, potentially more able to penetrate the cell membranes of living organisms were formed. Photodegradation of macromolecular organic matter from a kraft pulp mill effluent may be a key process occurring in natural waters that modifies the physicochemical properties of such effluents.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Chemospherearrow_drop_down
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    Chemosphere
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    Authors: Ferreira, Catarina I. A.; orcid Calisto, Vania;
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    Abstract This work aims to test the adsorption process for the removal of the fish anaesthetic MS-222 from water using biochars obtained from agricultural biowastes ( Eucalyptus bark, peanut shells, walnut shells, peach stones, grape seeds and olive waste) as adsorbents. An industrial residue (primary paper mill sludge) and a commercial activated carbon were tested for comparison purposes. The starting materials and the resulting biochars were characterized by elemental and proximate analyses, total organic carbon, FTIR, 13 C and 1 H solid state NMR, and SEM. Also, specific surface area and porosity of biochars were determined. Then, batch kinetic and equilibrium experiments were performed on the adsorption of MS-222 onto the different produced biochars. The fastest kinetic was obtained using primary sludge pyrolysed (30 min to equilibrium attainment) and the highest biochars adsorption capacity was obtained using peanut shells (34 mg g −1 of maximum adsorption capacity, predicted by the Langmuir–Freundlich model). Commercial activated carbon reaches 349 mg g −1 of maximum adsorption capacity, as predicted by Langmuir model.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Analytica...arrow_drop_down
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    Journal of Analytical and Applied Pyrolysis
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    Authors: Ferreira, Catarina I. A.; orcid Calisto, Vania;
    Calisto, Vania
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    Calisto, Vania in OpenAIRE
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    Santos, Sergio M.
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    Cuerda-Correa, Eduardo M.
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    Abstract This work aims to test the adsorption process for the removal of the fish anaesthetic MS-222 from water using biochars obtained from agricultural biowastes ( Eucalyptus bark, peanut shells, walnut shells, peach stones, grape seeds and olive waste) as adsorbents. An industrial residue (primary paper mill sludge) and a commercial activated carbon were tested for comparison purposes. The starting materials and the resulting biochars were characterized by elemental and proximate analyses, total organic carbon, FTIR, 13 C and 1 H solid state NMR, and SEM. Also, specific surface area and porosity of biochars were determined. Then, batch kinetic and equilibrium experiments were performed on the adsorption of MS-222 onto the different produced biochars. The fastest kinetic was obtained using primary sludge pyrolysed (30 min to equilibrium attainment) and the highest biochars adsorption capacity was obtained using peanut shells (34 mg g −1 of maximum adsorption capacity, predicted by the Langmuir–Freundlich model). Commercial activated carbon reaches 349 mg g −1 of maximum adsorption capacity, as predicted by Langmuir model.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Analytica...arrow_drop_down
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    Journal of Analytical and Applied Pyrolysis
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      Journal of Analytical and Applied Pyrolysis
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    Authors: orcid Ricardo N. Coimbra;
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    In this work, thermogravimetric analysis (TGA), differential thermogravimetry (DTG), and differential scanning calorimetric (DSC) were used to assess the combustion of microalgae biomass, a bituminous coal, and their blend. Furthermore, different correlations were tested for estimating the high heating value of microalgae biomass and coal, with both materials possessing similar values. TGA evidenced differences between the combustion of the studied fuels, but no relevant interaction occurred during their co-combustion, as shown by the DTG and DSC curves. These curves also indicated that the combustion of the blend mostly resembled that of coal in terms of weight loss and heat release. Moreover, non-isothermal kinetic analysis revealed that the apparent activation energies corresponding to the combustion of the blend and coal were quite close. Overall, the obtained results indicated that co-combustion with coal might be a feasible waste to energy management option for the valorization of microalgae biomass resulting from wastewater treatment.

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    Energies
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      Energies
      Article . 2019
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    Authors: orcid Ricardo N. Coimbra;
    Ricardo N. Coimbra
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    Ricardo N. Coimbra in OpenAIRE
    orcid Carla Escapa;
    Carla Escapa
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    Carla Escapa in OpenAIRE
    orcid Marta Otero;
    Marta Otero
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    Marta Otero in OpenAIRE

    In this work, thermogravimetric analysis (TGA), differential thermogravimetry (DTG), and differential scanning calorimetric (DSC) were used to assess the combustion of microalgae biomass, a bituminous coal, and their blend. Furthermore, different correlations were tested for estimating the high heating value of microalgae biomass and coal, with both materials possessing similar values. TGA evidenced differences between the combustion of the studied fuels, but no relevant interaction occurred during their co-combustion, as shown by the DTG and DSC curves. These curves also indicated that the combustion of the blend mostly resembled that of coal in terms of weight loss and heat release. Moreover, non-isothermal kinetic analysis revealed that the apparent activation energies corresponding to the combustion of the blend and coal were quite close. Overall, the obtained results indicated that co-combustion with coal might be a feasible waste to energy management option for the valorization of microalgae biomass resulting from wastewater treatment.

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    Energies
    Article . 2019 . Peer-reviewed
    License: CC BY
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    Energies
    Article
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    Energies
    Article . 2019
    Data sources: DOAJ
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      Energies
      Article . 2019 . Peer-reviewed
      License: CC BY
      Data sources: Crossref
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article
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      Data sources: UnpayWall
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      Energies
      Article . 2019
      Data sources: DOAJ
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