- home
- Advanced Search
- Energy Research
- Energy Research
description Publicationkeyboard_double_arrow_right Article 2025 United KingdomPublisher:Royal Society of Chemistry (RSC) Funded by:UKRI | EPSRC Centre for Doctoral...UKRI| EPSRC Centre for Doctoral Training in Sustainable and Functional NanoAuthors:Lun, Z;
Merryweather, AJ;
Mahadevegowda, A; Pandurangi, SS; +8 AuthorsMerryweather, AJ
Merryweather, AJ in OpenAIRELun, Z;
Merryweather, AJ;
Mahadevegowda, A; Pandurangi, SS;Merryweather, AJ
Merryweather, AJ in OpenAIREXu, C;
Fairclough, S; Deshpande, VS; Fleck, NA; Ducati, C;Schnedermann, C;
Rao, A;Schnedermann, C
Schnedermann, C in OpenAIREGrey, CP;
Grey, CP
Grey, CP in OpenAIREUsing an operando optical scattering technique, we identify markedly asymmetric Li-ion flux in aged single crystalline NMC cathodes, primarily caused by an uneven growth of rocksalt phase across the particle surface.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d5ee00267b&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d5ee00267b&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2025 United KingdomPublisher:Royal Society of Chemistry (RSC) Funded by:UKRI | EPSRC Centre for Doctoral...UKRI| EPSRC Centre for Doctoral Training in Sustainable and Functional NanoAuthors:Lun, Z;
Merryweather, AJ;
Mahadevegowda, A; Pandurangi, SS; +8 AuthorsMerryweather, AJ
Merryweather, AJ in OpenAIRELun, Z;
Merryweather, AJ;
Mahadevegowda, A; Pandurangi, SS;Merryweather, AJ
Merryweather, AJ in OpenAIREXu, C;
Fairclough, S; Deshpande, VS; Fleck, NA; Ducati, C;Schnedermann, C;
Rao, A;Schnedermann, C
Schnedermann, C in OpenAIREGrey, CP;
Grey, CP
Grey, CP in OpenAIREUsing an operando optical scattering technique, we identify markedly asymmetric Li-ion flux in aged single crystalline NMC cathodes, primarily caused by an uneven growth of rocksalt phase across the particle surface.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d5ee00267b&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d5ee00267b&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Conference object , Preprint , Journal 2018Embargo end date: 01 Jan 2018 United KingdomPublisher:Royal Society of Chemistry (RSC) Authors:Jeongjae Lee;
Jeongjae Lee
Jeongjae Lee in OpenAIREBartomeu Monserrat;
Bartomeu Monserrat
Bartomeu Monserrat in OpenAIREIeuan D. Seymour;
Ieuan D. Seymour
Ieuan D. Seymour in OpenAIREZigeng Liu;
+2 AuthorsZigeng Liu
Zigeng Liu in OpenAIREJeongjae Lee;
Jeongjae Lee
Jeongjae Lee in OpenAIREBartomeu Monserrat;
Bartomeu Monserrat
Bartomeu Monserrat in OpenAIREIeuan D. Seymour;
Ieuan D. Seymour
Ieuan D. Seymour in OpenAIREZigeng Liu;
Zigeng Liu
Zigeng Liu in OpenAIRESiân E. Dutton;
Siân E. Dutton
Siân E. Dutton in OpenAIREClare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIREhandle: 2164/22995
We show that vacancy creation and relativistic spin–orbit coupling play a crucial role in promoting fast Mg-ion conduction of Mg3Bi2.
Journal of Materials... arrow_drop_down Journal of Materials Chemistry AArticle . 2018 . Peer-reviewedLicense: CC BYData sources: Crossrefhttps://dx.doi.org/10.48550/ar...Article . 2018License: arXiv Non-Exclusive DistributionData sources: DataciteAberdeen University Research Archive (AURA)Article . 2018Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c7ta11181a&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu25 citations 25 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert Journal of Materials... arrow_drop_down Journal of Materials Chemistry AArticle . 2018 . Peer-reviewedLicense: CC BYData sources: Crossrefhttps://dx.doi.org/10.48550/ar...Article . 2018License: arXiv Non-Exclusive DistributionData sources: DataciteAberdeen University Research Archive (AURA)Article . 2018Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c7ta11181a&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Conference object , Preprint , Journal 2018Embargo end date: 01 Jan 2018 United KingdomPublisher:Royal Society of Chemistry (RSC) Authors:Jeongjae Lee;
Jeongjae Lee
Jeongjae Lee in OpenAIREBartomeu Monserrat;
Bartomeu Monserrat
Bartomeu Monserrat in OpenAIREIeuan D. Seymour;
Ieuan D. Seymour
Ieuan D. Seymour in OpenAIREZigeng Liu;
+2 AuthorsZigeng Liu
Zigeng Liu in OpenAIREJeongjae Lee;
Jeongjae Lee
Jeongjae Lee in OpenAIREBartomeu Monserrat;
Bartomeu Monserrat
Bartomeu Monserrat in OpenAIREIeuan D. Seymour;
Ieuan D. Seymour
Ieuan D. Seymour in OpenAIREZigeng Liu;
Zigeng Liu
Zigeng Liu in OpenAIRESiân E. Dutton;
Siân E. Dutton
Siân E. Dutton in OpenAIREClare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIREhandle: 2164/22995
We show that vacancy creation and relativistic spin–orbit coupling play a crucial role in promoting fast Mg-ion conduction of Mg3Bi2.
Journal of Materials... arrow_drop_down Journal of Materials Chemistry AArticle . 2018 . Peer-reviewedLicense: CC BYData sources: Crossrefhttps://dx.doi.org/10.48550/ar...Article . 2018License: arXiv Non-Exclusive DistributionData sources: DataciteAberdeen University Research Archive (AURA)Article . 2018Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c7ta11181a&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu25 citations 25 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert Journal of Materials... arrow_drop_down Journal of Materials Chemistry AArticle . 2018 . Peer-reviewedLicense: CC BYData sources: Crossrefhttps://dx.doi.org/10.48550/ar...Article . 2018License: arXiv Non-Exclusive DistributionData sources: DataciteAberdeen University Research Archive (AURA)Article . 2018Data sources: Bielefeld Academic Search Engine (BASE)add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c7ta11181a&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2017Embargo end date: 03 Mar 2017 United KingdomPublisher:Royal Society of Chemistry (RSC) Funded by:UKRI | Energy and the Physical S...UKRI| Energy and the Physical Sciences: Advanced materials for thermo-chemical oxygen storage and productionAuthors: Cindy Y. Lau;Matthew T. Dunstan;
Matthew T. Dunstan
Matthew T. Dunstan in OpenAIREWenting Hu;
Wenting Hu
Wenting Hu in OpenAIREClare P. Grey;
+1 AuthorsClare P. Grey
Clare P. Grey in OpenAIRECindy Y. Lau;Matthew T. Dunstan;
Matthew T. Dunstan
Matthew T. Dunstan in OpenAIREWenting Hu;
Wenting Hu
Wenting Hu in OpenAIREClare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIREStuart A. Scott;
Stuart A. Scott
Stuart A. Scott in OpenAIREA combined computational and experimental methodology is developed to predict new materials that can reversibly produce oxygen for chemical looping combustion, and then promising candidates are selected for experimental validation of these predictions.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c6ee02763f&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen bronze 58 citations 58 popularity Top 10% influence Top 10% impulse Top 10% Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c6ee02763f&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2017Embargo end date: 03 Mar 2017 United KingdomPublisher:Royal Society of Chemistry (RSC) Funded by:UKRI | Energy and the Physical S...UKRI| Energy and the Physical Sciences: Advanced materials for thermo-chemical oxygen storage and productionAuthors: Cindy Y. Lau;Matthew T. Dunstan;
Matthew T. Dunstan
Matthew T. Dunstan in OpenAIREWenting Hu;
Wenting Hu
Wenting Hu in OpenAIREClare P. Grey;
+1 AuthorsClare P. Grey
Clare P. Grey in OpenAIRECindy Y. Lau;Matthew T. Dunstan;
Matthew T. Dunstan
Matthew T. Dunstan in OpenAIREWenting Hu;
Wenting Hu
Wenting Hu in OpenAIREClare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIREStuart A. Scott;
Stuart A. Scott
Stuart A. Scott in OpenAIREA combined computational and experimental methodology is developed to predict new materials that can reversibly produce oxygen for chemical looping combustion, and then promising candidates are selected for experimental validation of these predictions.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c6ee02763f&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen bronze 58 citations 58 popularity Top 10% influence Top 10% impulse Top 10% Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c6ee02763f&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 1998Publisher:Elsevier BV Lamy J Chopin; Terry Gullion; Hsien Ming Kao; Yong Ba;Clare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIREpmid: 9654474
The optimum 14N pulse lengths in the 13C-14N rotational-echo adiabatic-passage double-resonance (REAPDOR) NMR experiment are determined from calculations and from experiments on samples of glycine and L-alanine. The REAPDOR experiment utilizes the adiabatic passages that 14N spins make between the 14N Zeeman energy levels during the application of a single, short 14N radiofrequency pulse. Use of a short 14N irradiation time of less than one-quarter of a rotor period ensures that the number of 14N spins that undergo more than one passage is minimized. This simplifies calculations describing 13C dipolar dephasing and provides better agreement between calculations and experiments. Recovery of the 13C-14N dipolar couplings and 14N quadrupolar coupling constants and asymmetry parameters is described.
Journal of Magnetic ... arrow_drop_down Journal of Magnetic ResonanceArticle . 1998 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1006/jmre.1998.1422&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu58 citations 58 popularity Top 10% influence Top 10% impulse Top 10% Powered by BIP!
more_vert Journal of Magnetic ... arrow_drop_down Journal of Magnetic ResonanceArticle . 1998 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1006/jmre.1998.1422&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 1998Publisher:Elsevier BV Lamy J Chopin; Terry Gullion; Hsien Ming Kao; Yong Ba;Clare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIREpmid: 9654474
The optimum 14N pulse lengths in the 13C-14N rotational-echo adiabatic-passage double-resonance (REAPDOR) NMR experiment are determined from calculations and from experiments on samples of glycine and L-alanine. The REAPDOR experiment utilizes the adiabatic passages that 14N spins make between the 14N Zeeman energy levels during the application of a single, short 14N radiofrequency pulse. Use of a short 14N irradiation time of less than one-quarter of a rotor period ensures that the number of 14N spins that undergo more than one passage is minimized. This simplifies calculations describing 13C dipolar dephasing and provides better agreement between calculations and experiments. Recovery of the 13C-14N dipolar couplings and 14N quadrupolar coupling constants and asymmetry parameters is described.
Journal of Magnetic ... arrow_drop_down Journal of Magnetic ResonanceArticle . 1998 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1006/jmre.1998.1422&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu58 citations 58 popularity Top 10% influence Top 10% impulse Top 10% Powered by BIP!
more_vert Journal of Magnetic ... arrow_drop_down Journal of Magnetic ResonanceArticle . 1998 . Peer-reviewedLicense: Elsevier TDMData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1006/jmre.1998.1422&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Other literature type 2021 United StatesPublisher:Wiley Authors:Le Wang;
Yingge Du;
Yingge Du
Yingge Du in OpenAIREZachary W. Lebens-Higgins;
Zachary W. Lebens-Higgins
Zachary W. Lebens-Higgins in OpenAIREJatinkumar Rana;
+11 AuthorsJatinkumar Rana
Jatinkumar Rana in OpenAIRELe Wang;
Yingge Du;
Yingge Du
Yingge Du in OpenAIREZachary W. Lebens-Higgins;
Zachary W. Lebens-Higgins
Zachary W. Lebens-Higgins in OpenAIREJatinkumar Rana;
Hyeseung Chung;Jatinkumar Rana
Jatinkumar Rana in OpenAIREWanli Yang;
Wanli Yang
Wanli Yang in OpenAIRELouis F. J. Piper;
Louis F. J. Piper;Louis F. J. Piper
Louis F. J. Piper in OpenAIREMichael A. Jones;
Israel Temprano;Michael A. Jones
Michael A. Jones in OpenAIREClare P. Grey;
Carlos Mejia; Jinpeng Wu;Clare P. Grey
Clare P. Grey in OpenAIREYing Shirley Meng;
Ying Shirley Meng
Ying Shirley Meng in OpenAIREMateusz Zuba;
Mateusz Zuba
Mateusz Zuba in OpenAIREAbstractInterest in alkali‐rich oxide cathodes has grown in an effort to identify systems that provide high energy densities through reversible oxygen redox. However, some of the most promising compositions such as those based solely on earth abundant elements, e. g., iron and manganese, suffer from poor capacity retention and large hysteresis. Here, we use the disordered rocksalt cathode, Li1.3Fe0.4Nb0.3O2, as a model system to identify the underlying origin for the poor performance of Li‐rich iron‐based cathodes. Using elementally specific spectroscopic probes, we find the first charge is primarily accounted for by iron oxidation to 4+ below 4.25 V and O2 gas release beyond 4.25 V with no evidence of bulk oxygen redox. Although the Li1.3Fe0.4Nb0.3O2 is not a viable oxygen redox cathode, the iron 3+/4+ redox couple can be used reversibly during cycling.
University of Califo... arrow_drop_down University of California: eScholarshipArticle . 2021Full-Text: https://escholarship.org/uc/item/11h2x88mData sources: Bielefeld Academic Search Engine (BASE)Batteries & SupercapsArticle . 2021 . Peer-reviewedLicense: Wiley Online Library User AgreementData sources: CrossrefeScholarship - University of CaliforniaArticle . 2021Data sources: eScholarship - University of Californiaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/batt.202000318&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen hybrid 11 citations 11 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert University of Califo... arrow_drop_down University of California: eScholarshipArticle . 2021Full-Text: https://escholarship.org/uc/item/11h2x88mData sources: Bielefeld Academic Search Engine (BASE)Batteries & SupercapsArticle . 2021 . Peer-reviewedLicense: Wiley Online Library User AgreementData sources: CrossrefeScholarship - University of CaliforniaArticle . 2021Data sources: eScholarship - University of Californiaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/batt.202000318&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Other literature type 2021 United StatesPublisher:Wiley Authors:Le Wang;
Yingge Du;
Yingge Du
Yingge Du in OpenAIREZachary W. Lebens-Higgins;
Zachary W. Lebens-Higgins
Zachary W. Lebens-Higgins in OpenAIREJatinkumar Rana;
+11 AuthorsJatinkumar Rana
Jatinkumar Rana in OpenAIRELe Wang;
Yingge Du;
Yingge Du
Yingge Du in OpenAIREZachary W. Lebens-Higgins;
Zachary W. Lebens-Higgins
Zachary W. Lebens-Higgins in OpenAIREJatinkumar Rana;
Hyeseung Chung;Jatinkumar Rana
Jatinkumar Rana in OpenAIREWanli Yang;
Wanli Yang
Wanli Yang in OpenAIRELouis F. J. Piper;
Louis F. J. Piper;Louis F. J. Piper
Louis F. J. Piper in OpenAIREMichael A. Jones;
Israel Temprano;Michael A. Jones
Michael A. Jones in OpenAIREClare P. Grey;
Carlos Mejia; Jinpeng Wu;Clare P. Grey
Clare P. Grey in OpenAIREYing Shirley Meng;
Ying Shirley Meng
Ying Shirley Meng in OpenAIREMateusz Zuba;
Mateusz Zuba
Mateusz Zuba in OpenAIREAbstractInterest in alkali‐rich oxide cathodes has grown in an effort to identify systems that provide high energy densities through reversible oxygen redox. However, some of the most promising compositions such as those based solely on earth abundant elements, e. g., iron and manganese, suffer from poor capacity retention and large hysteresis. Here, we use the disordered rocksalt cathode, Li1.3Fe0.4Nb0.3O2, as a model system to identify the underlying origin for the poor performance of Li‐rich iron‐based cathodes. Using elementally specific spectroscopic probes, we find the first charge is primarily accounted for by iron oxidation to 4+ below 4.25 V and O2 gas release beyond 4.25 V with no evidence of bulk oxygen redox. Although the Li1.3Fe0.4Nb0.3O2 is not a viable oxygen redox cathode, the iron 3+/4+ redox couple can be used reversibly during cycling.
University of Califo... arrow_drop_down University of California: eScholarshipArticle . 2021Full-Text: https://escholarship.org/uc/item/11h2x88mData sources: Bielefeld Academic Search Engine (BASE)Batteries & SupercapsArticle . 2021 . Peer-reviewedLicense: Wiley Online Library User AgreementData sources: CrossrefeScholarship - University of CaliforniaArticle . 2021Data sources: eScholarship - University of Californiaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/batt.202000318&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen hybrid 11 citations 11 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert University of Califo... arrow_drop_down University of California: eScholarshipArticle . 2021Full-Text: https://escholarship.org/uc/item/11h2x88mData sources: Bielefeld Academic Search Engine (BASE)Batteries & SupercapsArticle . 2021 . Peer-reviewedLicense: Wiley Online Library User AgreementData sources: CrossrefeScholarship - University of CaliforniaArticle . 2021Data sources: eScholarship - University of Californiaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/batt.202000318&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2011Publisher:Royal Society of Chemistry (RSC) Authors:Clare P. Grey;
Clare P. Grey; Brian L. Philips;Clare P. Grey
Clare P. Grey in OpenAIREWei Li;
+3 AuthorsClare P. Grey;
Clare P. Grey; Brian L. Philips;Clare P. Grey
Clare P. Grey in OpenAIREWei Li;
Wei Li; Jongsik Kim; Jongsik Kim;doi: 10.1039/c1ee02093e
Phosphate adsorption on the surfaces of the iron oxyhydroxide polymorphs goethite, akaganeite, and lepidocrocite were studied by using 31P static spin-echo mapping NMR experiments to determine how this environmentally-important anion binds to common soil minerals. The large 31P hyperfine shifts confirm the formation of inner-sphere complexes between the phosphate anion and the iron oxyhydroxide surface, the large shifts indicating the presence of Fe3+–O–P covalent bonds. Binding was explored as a function of pH and phosphate concentrations, the phosphate ion binding via two oxygen ions to the oxyhydroxide surface under all conditions and for all the surfaces. To support our analysis of the NMR spectra, adsorption of dimethyl phosphinic acid (DPA) on iron oxyhydroxides was also investigated, since this ion can only bond via one Fe–O–P interaction to the surface. The 31P hyperfine shifts observed for this anion were 50% of those seen for the phosphate anions, confirming that the phosphate ions bind to the surface via two P–O–Fe linkages.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c1ee02093e&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu203 citations 203 popularity Top 1% influence Top 10% impulse Top 10% Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c1ee02093e&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2011Publisher:Royal Society of Chemistry (RSC) Authors:Clare P. Grey;
Clare P. Grey; Brian L. Philips;Clare P. Grey
Clare P. Grey in OpenAIREWei Li;
+3 AuthorsClare P. Grey;
Clare P. Grey; Brian L. Philips;Clare P. Grey
Clare P. Grey in OpenAIREWei Li;
Wei Li; Jongsik Kim; Jongsik Kim;doi: 10.1039/c1ee02093e
Phosphate adsorption on the surfaces of the iron oxyhydroxide polymorphs goethite, akaganeite, and lepidocrocite were studied by using 31P static spin-echo mapping NMR experiments to determine how this environmentally-important anion binds to common soil minerals. The large 31P hyperfine shifts confirm the formation of inner-sphere complexes between the phosphate anion and the iron oxyhydroxide surface, the large shifts indicating the presence of Fe3+–O–P covalent bonds. Binding was explored as a function of pH and phosphate concentrations, the phosphate ion binding via two oxygen ions to the oxyhydroxide surface under all conditions and for all the surfaces. To support our analysis of the NMR spectra, adsorption of dimethyl phosphinic acid (DPA) on iron oxyhydroxides was also investigated, since this ion can only bond via one Fe–O–P interaction to the surface. The 31P hyperfine shifts observed for this anion were 50% of those seen for the phosphate anions, confirming that the phosphate ions bind to the surface via two P–O–Fe linkages.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c1ee02093e&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu203 citations 203 popularity Top 1% influence Top 10% impulse Top 10% Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/c1ee02093e&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2021Publisher:American Chemical Society (ACS) Funded by:UKRI | Centre for Advanced Mater..., UKRI | Enabling next generation ...UKRI| Centre for Advanced Materials for Integrated Energy Systems (CAM-IES) ,UKRI| Enabling next generation lithium batteriesAuthors:Evelyna Wang;
Evelyna Wang
Evelyna Wang in OpenAIREEvan Wenbo Zhao;
Evan Wenbo Zhao
Evan Wenbo Zhao in OpenAIREClare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIRERedox-active molecules or ions are important in a variety of electrochemical energy storage systems. In lithium-air batteries (LABs), redox-active mediators are added as soluble catalysts that mitigate (dis)charge overpotentials as well as promote solution-phase reactions that improve the capacity and cycle life of a cell. Redox flow batteries (RFBs) are dependent on the dissolved species to carry and store charge. In both of these systems, crossover phenomena, whereby the redox-active species in solution diffuse from one side of the cell to the other, result in capacity loss. Here, we report a technique to monitor crossover reactions in lithium-air batteries and redox flow batteries, exploiting methodology previously developed to monitor radical formation in redox flow batteries. In this technique, radical concentrations are directly quantified operando by flowing an electrolyte solution containing 2,2,6,6-tetramethylpiperidinyloxyl (TEMPO) through nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR) spectrometers. We apply this to Li-TEMPO flow batteries and find that the Coulombic efficiency is only 50%; 50% of the oxidized TEMPO radical, TEMPO + , formed at the cathode crosses over to the anode where it is reduced, regenerating TEMPO. Numerical modeling simulations of static systems cannot capture the extent of redox shuttling seen experimentally unless extremely fast diffusion of TEMPO and TEMPO + is assumed in one-dimensional (1D) models or convection is included in two-dimensional (2D) models, confirming that redox shuttling is enhanced significantly by flow. Finally, we tested Nafion membranes in both flow cells and static LABs and found that the membrane limited crossover of TEMPO and TEMPO + by factors of ∼15× and ∼7×, respectively.
Smithsonian figshare arrow_drop_down Smithsonian figshareArticle . 1753License: CC BY NCData sources: Bielefeld Academic Search Engine (BASE)The Journal of Physical Chemistry CArticle . 2021 . Peer-reviewedLicense: STM Policy #29Data sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1021/acs.jpcc.1c07886&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu13 citations 13 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert Smithsonian figshare arrow_drop_down Smithsonian figshareArticle . 1753License: CC BY NCData sources: Bielefeld Academic Search Engine (BASE)The Journal of Physical Chemistry CArticle . 2021 . Peer-reviewedLicense: STM Policy #29Data sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1021/acs.jpcc.1c07886&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2021Publisher:American Chemical Society (ACS) Funded by:UKRI | Centre for Advanced Mater..., UKRI | Enabling next generation ...UKRI| Centre for Advanced Materials for Integrated Energy Systems (CAM-IES) ,UKRI| Enabling next generation lithium batteriesAuthors:Evelyna Wang;
Evelyna Wang
Evelyna Wang in OpenAIREEvan Wenbo Zhao;
Evan Wenbo Zhao
Evan Wenbo Zhao in OpenAIREClare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIRERedox-active molecules or ions are important in a variety of electrochemical energy storage systems. In lithium-air batteries (LABs), redox-active mediators are added as soluble catalysts that mitigate (dis)charge overpotentials as well as promote solution-phase reactions that improve the capacity and cycle life of a cell. Redox flow batteries (RFBs) are dependent on the dissolved species to carry and store charge. In both of these systems, crossover phenomena, whereby the redox-active species in solution diffuse from one side of the cell to the other, result in capacity loss. Here, we report a technique to monitor crossover reactions in lithium-air batteries and redox flow batteries, exploiting methodology previously developed to monitor radical formation in redox flow batteries. In this technique, radical concentrations are directly quantified operando by flowing an electrolyte solution containing 2,2,6,6-tetramethylpiperidinyloxyl (TEMPO) through nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR) spectrometers. We apply this to Li-TEMPO flow batteries and find that the Coulombic efficiency is only 50%; 50% of the oxidized TEMPO radical, TEMPO + , formed at the cathode crosses over to the anode where it is reduced, regenerating TEMPO. Numerical modeling simulations of static systems cannot capture the extent of redox shuttling seen experimentally unless extremely fast diffusion of TEMPO and TEMPO + is assumed in one-dimensional (1D) models or convection is included in two-dimensional (2D) models, confirming that redox shuttling is enhanced significantly by flow. Finally, we tested Nafion membranes in both flow cells and static LABs and found that the membrane limited crossover of TEMPO and TEMPO + by factors of ∼15× and ∼7×, respectively.
Smithsonian figshare arrow_drop_down Smithsonian figshareArticle . 1753License: CC BY NCData sources: Bielefeld Academic Search Engine (BASE)The Journal of Physical Chemistry CArticle . 2021 . Peer-reviewedLicense: STM Policy #29Data sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1021/acs.jpcc.1c07886&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu13 citations 13 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert Smithsonian figshare arrow_drop_down Smithsonian figshareArticle . 1753License: CC BY NCData sources: Bielefeld Academic Search Engine (BASE)The Journal of Physical Chemistry CArticle . 2021 . Peer-reviewedLicense: STM Policy #29Data sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1021/acs.jpcc.1c07886&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Review 2023Embargo end date: 14 Apr 2023 Spain, Spain, Denmark, Germany, Germany, United KingdomPublisher:Royal Society of Chemistry (RSC) Funded by:EC | E-MAGICEC| E-MAGICAuthors:Blázquez, J. Alberto;
Maça, Rudi R.;Blázquez, J. Alberto
Blázquez, J. Alberto in OpenAIRELeonet, Olatz;
Azaceta, Eneko; +27 AuthorsLeonet, Olatz
Leonet, Olatz in OpenAIREBlázquez, J. Alberto;
Maça, Rudi R.;Blázquez, J. Alberto
Blázquez, J. Alberto in OpenAIRELeonet, Olatz;
Azaceta, Eneko;Leonet, Olatz
Leonet, Olatz in OpenAIREMukherjee, Ayan;
Mukherjee, Ayan
Mukherjee, Ayan in OpenAIREZhao-Karger, Zhirong;
Zhao-Karger, Zhirong
Zhao-Karger, Zhirong in OpenAIRELi, Zhenyou;
Kovalevsky, Aleksey;Li, Zhenyou
Li, Zhenyou in OpenAIREFernández-Barquín, Ana;
Fernández-Barquín, Ana
Fernández-Barquín, Ana in OpenAIREMainar, Aroa R.;
Mainar, Aroa R.
Mainar, Aroa R. in OpenAIREJankowski, Piotr;
Rademacher, Laurin;Jankowski, Piotr
Jankowski, Piotr in OpenAIREDey, Sunita;
Dey, Sunita
Dey, Sunita in OpenAIREDutton, Siân E.;
Dutton, Siân E.
Dutton, Siân E. in OpenAIREGrey, Clare P.;
Drews, J.;Grey, Clare P.
Grey, Clare P. in OpenAIREDrews, Janina;
Drews, Janina
Drews, Janina in OpenAIREHäcker, Joachim;
Häcker, Joachim
Häcker, Joachim in OpenAIREDanner, Timo;
Danner, Timo
Danner, Timo in OpenAIRELatz, Arnulf;
Latz, Arnulf
Latz, Arnulf in OpenAIRESotta, Dane;
Palacin, M. R.;Sotta, Dane
Sotta, Dane in OpenAIREPalacin, M. Rosa;
Martin, Jean-Frédéric;Palacin, M. Rosa
Palacin, M. Rosa in OpenAIRELastra, Juan Maria García;
Lastra, Juan Maria García
Lastra, Juan Maria García in OpenAIREFichtner, Maximilian;
Fichtner, Maximilian
Fichtner, Maximilian in OpenAIREKundu, Sumana;
Kraytsberg, Alexander; Ein-Eli, Yair;Kundu, Sumana
Kundu, Sumana in OpenAIRENoked, Malachi;
Noked, Malachi
Noked, Malachi in OpenAIREAurbach, Doron;
Aurbach, Doron
Aurbach, Doron in OpenAIREhandle: 10261/334529
Emerging energy storage systems based on abundant and cost-effective materials are key to overcome the global energy and climate crisis of the 21st century.
Energy & Environment... arrow_drop_down KITopen (Karlsruhe Institute of Technologie)Article . 2023License: CC BY NCData sources: Bielefeld Academic Search Engine (BASE)Energy & Environmental ScienceArticle . 2023 . Peer-reviewedLicense: CC BY NCData sources: CrossrefRecolector de Ciencia Abierta, RECOLECTAArticle . 2023License: CC BY NC NDData sources: Recolector de Ciencia Abierta, RECOLECTARecolector de Ciencia Abierta, RECOLECTAReview . 2023 . Peer-reviewedData sources: Recolector de Ciencia Abierta, RECOLECTARecolector de Ciencia Abierta, RECOLECTA2023 . Peer-reviewedData sources: Recolector de Ciencia Abierta, RECOLECTAOnline Research Database In TechnologyArticle . 2023Data sources: Online Research Database In TechnologyARCHIVO DIGITAL PARA LA DOCENCIA Y LA INVESTIGACIONArticle . 2023Data sources: ARCHIVO DIGITAL PARA LA DOCENCIA Y LA INVESTIGACIONEnergy & Environmental ScienceArticle . 2023 . Peer-reviewedData sources: European Union Open Data Portaladd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d2ee04121a&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen hybrid 45 citations 45 popularity Top 10% influence Top 10% impulse Top 1% Powered by BIP!
more_vert Energy & Environment... arrow_drop_down KITopen (Karlsruhe Institute of Technologie)Article . 2023License: CC BY NCData sources: Bielefeld Academic Search Engine (BASE)Energy & Environmental ScienceArticle . 2023 . Peer-reviewedLicense: CC BY NCData sources: CrossrefRecolector de Ciencia Abierta, RECOLECTAArticle . 2023License: CC BY NC NDData sources: Recolector de Ciencia Abierta, RECOLECTARecolector de Ciencia Abierta, RECOLECTAReview . 2023 . Peer-reviewedData sources: Recolector de Ciencia Abierta, RECOLECTARecolector de Ciencia Abierta, RECOLECTA2023 . Peer-reviewedData sources: Recolector de Ciencia Abierta, RECOLECTAOnline Research Database In TechnologyArticle . 2023Data sources: Online Research Database In TechnologyARCHIVO DIGITAL PARA LA DOCENCIA Y LA INVESTIGACIONArticle . 2023Data sources: ARCHIVO DIGITAL PARA LA DOCENCIA Y LA INVESTIGACIONEnergy & Environmental ScienceArticle . 2023 . Peer-reviewedData sources: European Union Open Data Portaladd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d2ee04121a&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Review 2023Embargo end date: 14 Apr 2023 Spain, Spain, Denmark, Germany, Germany, United KingdomPublisher:Royal Society of Chemistry (RSC) Funded by:EC | E-MAGICEC| E-MAGICAuthors:Blázquez, J. Alberto;
Maça, Rudi R.;Blázquez, J. Alberto
Blázquez, J. Alberto in OpenAIRELeonet, Olatz;
Azaceta, Eneko; +27 AuthorsLeonet, Olatz
Leonet, Olatz in OpenAIREBlázquez, J. Alberto;
Maça, Rudi R.;Blázquez, J. Alberto
Blázquez, J. Alberto in OpenAIRELeonet, Olatz;
Azaceta, Eneko;Leonet, Olatz
Leonet, Olatz in OpenAIREMukherjee, Ayan;
Mukherjee, Ayan
Mukherjee, Ayan in OpenAIREZhao-Karger, Zhirong;
Zhao-Karger, Zhirong
Zhao-Karger, Zhirong in OpenAIRELi, Zhenyou;
Kovalevsky, Aleksey;Li, Zhenyou
Li, Zhenyou in OpenAIREFernández-Barquín, Ana;
Fernández-Barquín, Ana
Fernández-Barquín, Ana in OpenAIREMainar, Aroa R.;
Mainar, Aroa R.
Mainar, Aroa R. in OpenAIREJankowski, Piotr;
Rademacher, Laurin;Jankowski, Piotr
Jankowski, Piotr in OpenAIREDey, Sunita;
Dey, Sunita
Dey, Sunita in OpenAIREDutton, Siân E.;
Dutton, Siân E.
Dutton, Siân E. in OpenAIREGrey, Clare P.;
Drews, J.;Grey, Clare P.
Grey, Clare P. in OpenAIREDrews, Janina;
Drews, Janina
Drews, Janina in OpenAIREHäcker, Joachim;
Häcker, Joachim
Häcker, Joachim in OpenAIREDanner, Timo;
Danner, Timo
Danner, Timo in OpenAIRELatz, Arnulf;
Latz, Arnulf
Latz, Arnulf in OpenAIRESotta, Dane;
Palacin, M. R.;Sotta, Dane
Sotta, Dane in OpenAIREPalacin, M. Rosa;
Martin, Jean-Frédéric;Palacin, M. Rosa
Palacin, M. Rosa in OpenAIRELastra, Juan Maria García;
Lastra, Juan Maria García
Lastra, Juan Maria García in OpenAIREFichtner, Maximilian;
Fichtner, Maximilian
Fichtner, Maximilian in OpenAIREKundu, Sumana;
Kraytsberg, Alexander; Ein-Eli, Yair;Kundu, Sumana
Kundu, Sumana in OpenAIRENoked, Malachi;
Noked, Malachi
Noked, Malachi in OpenAIREAurbach, Doron;
Aurbach, Doron
Aurbach, Doron in OpenAIREhandle: 10261/334529
Emerging energy storage systems based on abundant and cost-effective materials are key to overcome the global energy and climate crisis of the 21st century.
Energy & Environment... arrow_drop_down KITopen (Karlsruhe Institute of Technologie)Article . 2023License: CC BY NCData sources: Bielefeld Academic Search Engine (BASE)Energy & Environmental ScienceArticle . 2023 . Peer-reviewedLicense: CC BY NCData sources: CrossrefRecolector de Ciencia Abierta, RECOLECTAArticle . 2023License: CC BY NC NDData sources: Recolector de Ciencia Abierta, RECOLECTARecolector de Ciencia Abierta, RECOLECTAReview . 2023 . Peer-reviewedData sources: Recolector de Ciencia Abierta, RECOLECTARecolector de Ciencia Abierta, RECOLECTA2023 . Peer-reviewedData sources: Recolector de Ciencia Abierta, RECOLECTAOnline Research Database In TechnologyArticle . 2023Data sources: Online Research Database In TechnologyARCHIVO DIGITAL PARA LA DOCENCIA Y LA INVESTIGACIONArticle . 2023Data sources: ARCHIVO DIGITAL PARA LA DOCENCIA Y LA INVESTIGACIONEnergy & Environmental ScienceArticle . 2023 . Peer-reviewedData sources: European Union Open Data Portaladd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d2ee04121a&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen hybrid 45 citations 45 popularity Top 10% influence Top 10% impulse Top 1% Powered by BIP!
more_vert Energy & Environment... arrow_drop_down KITopen (Karlsruhe Institute of Technologie)Article . 2023License: CC BY NCData sources: Bielefeld Academic Search Engine (BASE)Energy & Environmental ScienceArticle . 2023 . Peer-reviewedLicense: CC BY NCData sources: CrossrefRecolector de Ciencia Abierta, RECOLECTAArticle . 2023License: CC BY NC NDData sources: Recolector de Ciencia Abierta, RECOLECTARecolector de Ciencia Abierta, RECOLECTAReview . 2023 . Peer-reviewedData sources: Recolector de Ciencia Abierta, RECOLECTARecolector de Ciencia Abierta, RECOLECTA2023 . Peer-reviewedData sources: Recolector de Ciencia Abierta, RECOLECTAOnline Research Database In TechnologyArticle . 2023Data sources: Online Research Database In TechnologyARCHIVO DIGITAL PARA LA DOCENCIA Y LA INVESTIGACIONArticle . 2023Data sources: ARCHIVO DIGITAL PARA LA DOCENCIA Y LA INVESTIGACIONEnergy & Environmental ScienceArticle . 2023 . Peer-reviewedData sources: European Union Open Data Portaladd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d2ee04121a&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2001Publisher:American Chemical Society (ACS) Authors:James D. Martin;
James D. Martin
James D. Martin in OpenAIREJonathan C. Hanson;
Roger M. Sullivan;Jonathan C. Hanson
Jonathan C. Hanson in OpenAIREHaiming Liu;
+1 AuthorsHaiming Liu
Haiming Liu in OpenAIREJames D. Martin;
James D. Martin
James D. Martin in OpenAIREJonathan C. Hanson;
Roger M. Sullivan;Jonathan C. Hanson
Jonathan C. Hanson in OpenAIREHaiming Liu;
Haiming Liu
Haiming Liu in OpenAIREClare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIREdoi: 10.1021/ja010688v
pmid: 11480977
The beta and alpha phases of CuAlCl(4) have been characterized by solid-state (27)Al and (63)Cu magic angle spinning nuclear magnetic resonance. The very short spin--lattice relaxation times of the copper spins, and the sensitivity of the I = 3/2 (63)Cu nucleus to the small differences in the local structure of Cu in the two phases, allowed (63)Cu spectra to be acquired in very short time periods (1 min), in which the beta and alpha phases were clearly resolved. This time resolution was exploited to follow the phase transition from the pseudohexagonal close-packed beta-CuAlCl(4) into the pseudocubic close-packed alpha-CuAlCl(4), which occurs above 100 degrees C. In situ time-resolved (63)Cu MAS NMR and synchrotron X-ray diffraction experiments were used to measure the kinetics of this phase transition as a function of temperature. The transformation was shown to be a first-order phase transition involving no intermediate phases with an activation energy of 138 kJ/mol. The kinetic data obey a first-order Avrami--Erofe'ev rate law. A one-dimensional growth mechanism is proposed that involves a combination of Cu(+) ion self-diffusion and a translational reorganization of the close-packed anion layers imposed by the periodic rotations of [AlCl(4)](-) tetrahedra. This beta to alpha phase transformation can be induced at ambient temperatures by low partial pressures of ethylene.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1021/ja010688v&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu44 citations 44 popularity Top 10% influence Top 10% impulse Top 10% Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1021/ja010688v&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2001Publisher:American Chemical Society (ACS) Authors:James D. Martin;
James D. Martin
James D. Martin in OpenAIREJonathan C. Hanson;
Roger M. Sullivan;Jonathan C. Hanson
Jonathan C. Hanson in OpenAIREHaiming Liu;
+1 AuthorsHaiming Liu
Haiming Liu in OpenAIREJames D. Martin;
James D. Martin
James D. Martin in OpenAIREJonathan C. Hanson;
Roger M. Sullivan;Jonathan C. Hanson
Jonathan C. Hanson in OpenAIREHaiming Liu;
Haiming Liu
Haiming Liu in OpenAIREClare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIREdoi: 10.1021/ja010688v
pmid: 11480977
The beta and alpha phases of CuAlCl(4) have been characterized by solid-state (27)Al and (63)Cu magic angle spinning nuclear magnetic resonance. The very short spin--lattice relaxation times of the copper spins, and the sensitivity of the I = 3/2 (63)Cu nucleus to the small differences in the local structure of Cu in the two phases, allowed (63)Cu spectra to be acquired in very short time periods (1 min), in which the beta and alpha phases were clearly resolved. This time resolution was exploited to follow the phase transition from the pseudohexagonal close-packed beta-CuAlCl(4) into the pseudocubic close-packed alpha-CuAlCl(4), which occurs above 100 degrees C. In situ time-resolved (63)Cu MAS NMR and synchrotron X-ray diffraction experiments were used to measure the kinetics of this phase transition as a function of temperature. The transformation was shown to be a first-order phase transition involving no intermediate phases with an activation energy of 138 kJ/mol. The kinetic data obey a first-order Avrami--Erofe'ev rate law. A one-dimensional growth mechanism is proposed that involves a combination of Cu(+) ion self-diffusion and a translational reorganization of the close-packed anion layers imposed by the periodic rotations of [AlCl(4)](-) tetrahedra. This beta to alpha phase transformation can be induced at ambient temperatures by low partial pressures of ethylene.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1021/ja010688v&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu44 citations 44 popularity Top 10% influence Top 10% impulse Top 10% Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1021/ja010688v&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2025Publisher:Royal Society of Chemistry (RSC) Authors: Wenda Li;Zhaoyue Li;
Zhaoyue Li
Zhaoyue Li in OpenAIRELizhi Li;
Lizhi Li
Lizhi Li in OpenAIREAlice J. Merryweather;
+16 AuthorsAlice J. Merryweather
Alice J. Merryweather in OpenAIREWenda Li;Zhaoyue Li;
Zhaoyue Li
Zhaoyue Li in OpenAIRELizhi Li;
Lizhi Li
Lizhi Li in OpenAIREAlice J. Merryweather;
Alice J. Merryweather
Alice J. Merryweather in OpenAIREYilin Chen;
Shaoyu Yang; Hao Shi; Yang Lu; Yixiao Qiu; Guangsu Tan; Zhipeng Chen; Weiwei Wang; Yuzhu Wang; Yi-Fan Huang;Yilin Chen
Yilin Chen in OpenAIREZhengyan Lun;
Christoph Schnedermann; Xiangwen Gao;Zhengyan Lun
Zhengyan Lun in OpenAIREJingyang Wang;
Jingyang Wang
Jingyang Wang in OpenAIREClare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIREChao Xu;
Chao Xu
Chao Xu in OpenAIREdoi: 10.1039/d5ee00422e
Sodium-ion batteries (SIBs) offer a sustainable alternative to lithium-ion batteries but face cathode instability. This work emphasizes the low state of charge phase transition and shows improved cycling performance via calcium substitution.
Energy & Environment... arrow_drop_down Energy & Environmental ScienceArticle . 2025 . Peer-reviewedLicense: Royal Society of Chemistry Licence to PublishData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d5ee00422e&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eumore_vert Energy & Environment... arrow_drop_down Energy & Environmental ScienceArticle . 2025 . Peer-reviewedLicense: Royal Society of Chemistry Licence to PublishData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d5ee00422e&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2025Publisher:Royal Society of Chemistry (RSC) Authors: Wenda Li;Zhaoyue Li;
Zhaoyue Li
Zhaoyue Li in OpenAIRELizhi Li;
Lizhi Li
Lizhi Li in OpenAIREAlice J. Merryweather;
+16 AuthorsAlice J. Merryweather
Alice J. Merryweather in OpenAIREWenda Li;Zhaoyue Li;
Zhaoyue Li
Zhaoyue Li in OpenAIRELizhi Li;
Lizhi Li
Lizhi Li in OpenAIREAlice J. Merryweather;
Alice J. Merryweather
Alice J. Merryweather in OpenAIREYilin Chen;
Shaoyu Yang; Hao Shi; Yang Lu; Yixiao Qiu; Guangsu Tan; Zhipeng Chen; Weiwei Wang; Yuzhu Wang; Yi-Fan Huang;Yilin Chen
Yilin Chen in OpenAIREZhengyan Lun;
Christoph Schnedermann; Xiangwen Gao;Zhengyan Lun
Zhengyan Lun in OpenAIREJingyang Wang;
Jingyang Wang
Jingyang Wang in OpenAIREClare P. Grey;
Clare P. Grey
Clare P. Grey in OpenAIREChao Xu;
Chao Xu
Chao Xu in OpenAIREdoi: 10.1039/d5ee00422e
Sodium-ion batteries (SIBs) offer a sustainable alternative to lithium-ion batteries but face cathode instability. This work emphasizes the low state of charge phase transition and shows improved cycling performance via calcium substitution.
Energy & Environment... arrow_drop_down Energy & Environmental ScienceArticle . 2025 . Peer-reviewedLicense: Royal Society of Chemistry Licence to PublishData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d5ee00422e&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eumore_vert Energy & Environment... arrow_drop_down Energy & Environmental ScienceArticle . 2025 . Peer-reviewedLicense: Royal Society of Chemistry Licence to PublishData sources: Crossrefadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d5ee00422e&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu