• Energy Research

Waste heat recovery can apply to a wide range of applications, from transportation, or industries to domestic appliances. Thermoelectric generation technology applied to those cases could produce electrical energy and thus improve their efficiency. A validated computational methodology, which simulates the behavior of any thermoelectric generator and calculates the energy consumption of the auxiliary equipment involved, has been used to determine the potential of waste heat harvesting. The usable energy, the net energy, generated has to be maximized, not only the thermoelectric generation has to be maximized, but also the consumption of the auxiliary equipment has to be minimized, or if possible eliminated. Heat exchangers with a liquid as the heat carrier procure high thermoelectric generations, as their thermal resistances are very low, nevertheless when the consumption of their auxiliary consumption is borne in mind, their use is not that promising. The optimal thermoelectric energy obtained from the flue gases of a real industry using these dissipation systems is 119 MWh/year, while the maximum net energy is 73 MWh/year due to the consumption of the auxiliary equipment. The latest scenario does not only represent a 40% reduction from the optimal thermoelectric generation but also a different optimal working point. The complete elimination of the auxiliary equipment using novel biphasic thermosyphons with free convection at the same application produces a net energy of 128 MWh/year. This novel dissipation technology presents an increase on the thermoelectric generation due to its low thermal resistances, but above all due to the elimination of the auxiliary consumption. The authors are indebted to the Spanish Ministry of Economy and Competitiveness for the economic support to this work, included in the DPI2014-53158-R research project.

One of the measures to fight against the current energy situation and reduce the energy consumption at an industrial process is to recover waste heat and transform it into electric power. Thermoelectric generators can be used for that purpose but there is a lack of experimental studies that can bring this technology closer to reality. This work presents the design, optimizations and development of two devices that are experimented and compared under the same working conditions. The hot side heat exchanger of both generators has been designed using a computational fluid dynamics software and for the cold side of the generators two technologies have been analysed: a finned dissipater that uses a fan and free convection biphasic thermosyphon. The results obtained show a maximum net generation of 6.9W in the thermoelectric generator with the finned dissipater; and 10.6W of power output in the generator with the biphasic thermosyphon. These results remark the importance of a proper design of the heat exchangers, trying to get low thermal resistances at both sides of the thermoelectric modules, as well as, the necessity of considering the auxiliary consumption of the equipment employed.

Abstract Thermoelectric refrigeration (TEC) exhibits several advantages compared to vapour-compression, since this technology presents accurate temperature control systems and higher levels of compactness, robustness and noiselessness. However, its low efficiency is acting as a deterrent for it to spread in the refrigeration market. One of the factors determining the efficiency of a thermoelectric refrigerator is the temperature difference between the hot and cold sides of the thermoelectric modules (TEMs). This is dependent on the thermal resistances of the heat exchangers used. This paper discusses the results of an experimental study of different types of heat exchangers for the thermoelectric module hot side: a water–air system comprising a cold plate, pump and fan coil; a finned heat sink with fan; a heat pipe with fan. Expressions of thermal resistance have been obtained for these three types as a function of the air and water mass flows and the number of TEMs per unit of surface area of heat exchanger (occupancy ratio, δ), as well as expressions of the power consumed by the fans and the pump. Finally, a computational study has been carried out on a thermoelectric refrigerator of 15 m3 of interior volume, in order to obtain the influence of the heat exchanger studied, on the total consumption of the refrigerator and its efficiency. The results have demonstrated that relevant improvements can be made in TEC efficiency by the proper optimisation of the heat exchangers.

The need to reach a full energy decarbonisation is well known. Heating and cooling consumption is almost half of the global energy end-use. Thus, development of low-carbon and highly efficient power-to-heat technologies must be developed. In this work, the use of thermoelectric technology working as a heat pump is proposed to heat up an airflow of 38 m3/h. Two different prototypes of multistage thermoelectric heat pumps have been developed and compared based on monophasic and phase-change intermediate heat exchangers. The reduced thermal resistance obtained for the novel phase-change heat exchanger increases the heat flux supplied to the airflow and reduces the consumed power of the system, outperforming the operation of the monophasic thermoelectric heat pump between a 30 and a 67 %. The novel multistage phase-change heat pump obtains experimental COP values between 3.25 and 1.26 when the airflow rises its temperature from 3.5 °C to 23.5 °C. Additionally, this experimental study proves a new methodology to calculate the supplied heat flux to the airflow. The validation of this technology proves a discrepancy of ± 9 % when this novel technology is compared to the conventional one based on the airflow temperature rise. The authors would like to acknowledge the support of the Government of Navarre, as part of the “Grants to SINAI agents for the realization of collaborative R&D projects” under the PC066-067-068 FlexORCStorage projects and PC116-117-118 MASS-STORAGE projects. Open access funding provided by Universidad Pública de Navarra.

The inclusion of a thermoelectric subcooler as an alternative to increment the performance of a vapour compression cycle has been proved promising when properly designed and operated for low-medium power units. In this work, a computational model that simulates the behaviour of a carbon dioxide transcritical vapour compression cycle in conjunction with a thermoelectric subcooler system is presented. The computational tool is coded in Matlab and uses Refprop V9.1 to calculate the properties of the refrigerant at each point of the refrigeration cycle. Working conditions, effect of the heat exchangers of the subcooling system, temperature dependent thermoelectric properties, thermal contact resistances and the four thermoelectric effects are taken into account to increment its accuracy. The model has been validated using experimental data to prove the reliability and accuracy of the results obtained and shows deviations between the ±7% for the most relevant outputs. Using the validated computational tool a 13.6 % COP improvement is predicted when optimizing the total number of thermoelectric modules of the subcooling system. The computational experimentally validated tool is properly fit to aid in the design and operation of thermoelectric subcooling systems, being able to predict the optimal configuration and operation settings for the whole refrigeration plant. The authors would like to acknowledge the support of the Spanish Ministry of Science, Innovation and Universities , and European Regional Development Fund , for the funding under the RTI2018-093501-B-C21 and RTI2018-093501-B-C22 research projects. We would also like to acknowledge the support from the Education Department of the Government of Navarra, Spain with the Predoctoral Grants for Phd programs of Interest to Navarra and the Official School of Industrial Engineers of Navarre with the scholarship, Spain Fuentes Dutor.

An important issue in thermoelectric generators is the thermal design of the heat exchangers since it can improve their performance by increasing the heat absorbed or dissipated by the thermoelectric modules. Due to its several advantages, compared to conventional dissipation systems, a thermosyphon heat exchanger with phase change is proposed to be placed on the cold side of thermoelectric generators. Some of these advantages are: high heat-transfer rates; absence of moving parts and lack of auxiliary con- sumption (because fans or pumps are not required); and the fact that these systems are wickless. A com- putational model is developed to design and predict the behaviour of this heat exchangers. Furthermore, a prototype has been built and tested in order to demonstrate its performance and validate the compu- tational model. The model predicts the thermal resistance of the heat exchanger with a relative error in the interval [?8.09;7.83] in the 95% of the cases. Finally, the use of thermosyphons with phase change in thermoelectric generators has been studied in a waste-heat recovery application, stating that including them on the cold side of the generators improves the net thermoelectric production by 36% compared to that obtained with finned dissipators under forced convection. The authors are indebted to the Ministry of Economy, Industry and Competitiveness-Government of Spain and FEDER Funds for economic support of this work, included in the DPI2014-53158-R Research Project.

The use of thermoelectric generators with phase change heat exchangers has demonstrated to be an interesting and environmentally friendly alternative to enhanced geothermal systems (EGS) in shallow hot dry rock fields (HDR), since rock fracture is avoided. The present paper studies the possibilities of the former proposal in a real location: Timanfaya National Park (Canary Islands, Spain), one of the greatest shallow HDR fields in the world, with 5000 m2 of characterized geothermal anomalies presenting temperatures up to 500 °C at only 2 m deep. For this purpose, a computational model based on the thermal-electrical analogy has been developed and validated thanks to a real prototype, leading to a relative error of less than 8%. Based on this model, two prototypes have been designed and studied for two different areas within the park, varying the size of the heat exchangers and the number of thermoelectric modules installed. As a result, the potential of the solution is demonstrated, leading to an annual electricity generation of 681.53 MWh thanks to the scalability of thermoelectric generators. This generation is obtained without moving parts nor auxiliary consumption, thus increasing the robustness of the device and removing maintenance requirements. The authors would like to acknowledge the support of the Spanish State Research Agency and FEDER–UE under the grant RTC-2017-6628-3; as well as the FPU Program of the Spanish Ministry of Science, Innovation, and Universities (FPU16/05203).