• Energy Research

Three-dimensional numerical simulations of electron-beam-induced current (EBIC) near a vertical silicon grain boundary are demonstrated. They are compared with an analytical model which excludes the effect of carrier generation other than in the bulk base region of a solar cell structure. We demonstrate that in a wide range of solar cell structures recombination in the space charge region (SCR) significantly affects the EBIC results and hence needs to be included in the data evaluation. Apart from these findings, simulations of a realistic silicon solar cell structure (thick emitter, field-dependent mobility, etc.) are demonstrated.

Solar photovoltaics (PV) has emerged as one of the world’s most promising power-generation technologies, and it is essential to assess its applications from the perspective of a material-energy-water (MEW) nexus. We performed a life cycle assessment of the cradle-to-grave MEW for single-crystalline silicon (s-Si) and CdTe PV technologies by assuming both PV systems are recycled at end of life. We found that the MEW network was dominated by energy flows (>95%), while only minor impacts of materials and water flows were observed. Also, these MEW flows have pyramid-like distributions between the three tiers (i.e., primary, secondary/sub-secondary, and tertiary levels), with greater flows at the primary and lower flows at the tertiary levels. A more detailed analysis of materials’ circularity showed that glass layers are the most impactful component of recycling due to their considerable weight in both technologies. Our analysis also emphasized the positive impacts that increased power-conversion efficiency and the use of recycled feedstock have on the PV industry’s circularity rates. We found that a 25% increase in power-conversion efficiency and the use of fully recycled materials in PV panel feedstocks resulted in 91% and 86% material circularity for CdTe and s-Si PV systems, respectively.

A survey has been carried out of graduates and employers working in the sustainable energy (SE) industry in Australia. The aims were to identify the key areas of content to be included in University level SE training and the type of degree structures that are most appropriate for SE professionals. Attention was also directed to the mode of instruction (online, blended or face-to-face) and the role of work-integrated learning (WIL). This paper presents the results of the survey, which provide guidance to Universities seeking to develop new, or revise existing, SE education offerings. The results of the survey clearly indicate that responding students and employers prefer a generalist degree in engineering, with a stream in sustainable energy as the initial qualification for professionals in this field. Specialist degrees at postgraduate level were also considered appropriate for continuing professional education (CPE). Both graduates and employers agreed on key areas to be included in the SE courses. These key areas are generic skills (research methods, team work, report writing), generation technologies (especially PV, wind and biomass), and enablers (such as economics, policy and project management). The graduates, many of whom came from overseas countries, generally agreed about the course content and its relevance to employment in their countries. Face-to-face or blended learning was preferred by both groups as the mode of instruction for the first degree. Online learning was considered a valuable adjunct in the undergraduate course and more suitable for CPE in postgraduate courses. WIL and more practical work were considered important, especially in the first degree. There was some disagreement about the appropriate length of work placements, with graduates preferring 6–8 weeks and employers 10–12 weeks. This work should provide a basis for further course development and curriculum reform for sustainable energy education.

AbstractStuart Wenham was not only an outstanding researcher and inventor and mentor but also an outstanding educator. This paper documents some of the major aspects of his educational contributions and legacy, especially through the creation of the first specialised Bachelor of Engineering degree in photovoltaics at The University of New South Wales.

ISES Asia-Pacific Conference; Beijing, China

Recent work has indicated that a significant number of electrons and holes remain in the free-exciton form in silicon at room temperature, a finding which, if supportable by experimental evidence, requires the inclusion of excitons in diode and solar cell theory. Excitons, although neutral, may contribute to device currents by diffusing to the junction region where they may be dissociated by the field. A generalized three-particle theory of transport in semiconductors is presented. The results of application of the theory to silicon devices indicate a decrease in the dark saturation current as well as an increase in light-generated current when excitons are incorporated in the theory so long as exciton diffusion length exceeds that of the minority carriers. The work includes suggestions for experimental methods to confirm exciton involvement and to estimate the value of the exciton-binding parameter from spectral response measurements on solar cells.

Abstract Tandem technologies offer potential price reductions and higher efficiencies of PV modules. The high band gap nature of chalcogenides like CIGS, CZTS and AZTS makes them excellent materials for use on top of a Si base tandem cells. Nevertheless, along with the search for new technologies, there is also the concern about the environmental impact that its lifetime can cause. A comprehensive life cycle assessment for CIGS/Si, CZTS/Si and AZTS/Si tandem solar modules was not reported to date. This work compares the environmental impacts of Si and chalcogenide/Si tandem solar modules, assessing global warming potential, human toxicity potential (cancer and non-cancer effects), freshwater eutrophication potential, freshwater ecotoxicity potential, abiotic depletion potential and the energy payback time of these technologies. The results of this study show that compared with Si, CIGS/Si presents worse environmental impacts for most of the categories but, on the other hand, CZTS/Si and AZTS/Si present better outcomes for most of the impacts categories. We can also say that higher efficiency of these tandem technologies could potentially reverse that result. This LCA provides design advice for the R&D community, showing which structure has the best environmental outcomes and which processes should be optimized to achieve better results.