• Energy Research

Abstract In salt gradient solar ponds, the clarity of water and absorptivity of the bottom are important concerns. However, both are practically difficult to maintain beyond a certain limit. The reflectivity of the bottom causes the loss of a fraction of the incident radiation flux, resulting in lower absorption of flux in the pond. Turbidity hinders the propagation of radiation. Thereby it decreases the flux reaching the storage zone. Both these factors lower the efficiency of the pond significantly. However, the same turbidity also prevents the loss of radiation reflected from the bottom. Hence, the combined effect is compensatory to some extent. The present work is an analysis of the combined effect of the bottom’s reflectivity and water turbidity on the steady state efficiency of solar ponds. It is found that in the case of a reflective bottom, turbidity, within certain limits, improves the efficiency of pond. This is apparently contradictory to the conventional beliefs about the pond. Nevertheless, this conclusion is of practical importance for design and maintenance of solar ponds.

The salt gradient solar pond is a long-term heat storage system with a considerable warm-up time. A pond is efficient when it reaches the desired temperature quickly and maximum heat is subsequently retrieved at steady state. This requires optimum sizing of the non-convective zone. In the present work, the optimum size of the non-convective zone for fast warm-up is determined. This is found to differ considerably from the optimum size of the steady state criterion. The possibility of achieving both performance parameters, i.e. fast warm-up and maximum heat collection later on, is analyzed. It is suggested that when commissioning a pond, the size of the non-convective zone should at first be the optimum value from the warm-up rate criterion, but may later be changed to the optimum size from the steady state criterion.

Abstract Two simple formulations for estimation of net available radiation at a depth in solar pond are proposed. The first formulation uses the correlation of Bryant and Colbeck [Solar Energy 19 (1977) 321] and extends the same to incorporate the reflected part of radiation coming from bottom and surface of the pond. The other formulation is an empirical fourth order polynomial function. The universal functions of Hull [Solar Energy 29 (5) (1982) 385] are taken as a base line for comparison of accuracy in estimation of radiation flux. The proposed formulations provide a substantial saving of computational time, much simplicity in analytical calculations, and reasonably good accuracy in estimation of radiation flux at a depth in solar pond. Their impact of these formulations is also analyzed on accuracy in prediction of pond’s long-term thermal behavior and gain in terms of computational speed. It provides a 20–25% saving in computational time as compared to Hull’s method with comparable accuracy.

AbstractThe fluorescence quenching spectrum of bovine serum albumin (BSA) was investigated in the presence of felodipine (FLD) by spectroscopic methods including fluorescence spectroscopy and UV–Vis absorption spectroscopy. Stern–Volmer quenching was successfully applied and the corresponding thermodynamic parameters, namely enthalpy change (ΔH), free energy change (ΔG) and entropy change (ΔS) at different temperatures (304, 314 and 324 K) were calculated according to the Van't Hoff relation. This revealed that the hydrophobic interaction plays a major role in stabilizing the complex. The fluorescence spectrum of BSA was studied in presence of various concentrations of SDS surfactant. The distance (r) between donor (BSA) and acceptor (FLD) was obtained according to fluorescence resonance energy transfer (FRET). The synchronous fluorescence spectroscopy was used to investigate the effect of FLD on BSA molecule. The result shows that the conformation of BSA was changed in the presence of felodipine. Copyright © 2009 John Wiley & Sons, Ltd.

Abstract This paper investigates a few mathematical aspects of computer simulation of salt gradient solar pond’s thermal behavior. The basic equation governing heat flow in the non-convective zone of solar pond is solved by finite difference approach using the Crank–Nicholsen method. Stability and convergence of the method, specifically for the case of solar pond, is examined over a wide range of depth difference (Δx) and time difference (Δt). It is observed that the mesh ratio parameter ( r = K Δ t / ρ C p Δ x 2 ) which is used to define the stability and convergence of the method does not have an absolute value, rather its value varies with Δx. While using an actual set of Δx and Δt, the stability must be tested with reference to the set being used. Few other mathematical aspects pertaining to the actual application of the method are also investigated. Also, the effect of fineness of ambient input data on long term performance of the pond is investigated. It is observed that the diurnal variation of ambient input data yields the same accuracy as the hourly variation. Different approaches of calculating the heat losses from upper convective zone are compared for long term performance of the pond. A simple method is suggested to calculate the radiation flux at a depth which results due to multiple reflections between bottom and surface of the pond. The method saves computational time when used for simulation and is also suitable for hand calculations.