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description Publicationkeyboard_double_arrow_right Article , Journal 2021Publisher:MDPI AG Hui Khim Ooi; Xin Ning Koh; Hwai Chyuan Ong; Hwei Voon Lee; Mohd Sufri Mastuli; Yun Hin Taufiq-Yap; Fahad A. Alharthi; Abdulaziz Ali Alghamdi; Nurul Asikin Mijan;The dwindling of global petroleum deposits and worsening environmental issues have triggered researchers to find an alternative energy such as biodiesel. Biodiesel can be produced via transesterification of vegetable oil or animal fat with alcohol in the presence of a catalyst. A heterogeneous catalyst at an economical price has been studied widely for biodiesel production. It was noted that various types of natural waste shell are a potential calcium resource for generation of bio-based CaO, with comparable chemical characteristics, that greatly enhance the transesterification activity. However, CaO catalyzed transesterification is limited in its stability and studies have shown deterioration of catalytic reactivity when the catalyst is reused for several cycles. For this reason, different approaches are reviewed in the present study, which focuses on modification of waste-shell derived CaO based catalyst with the aim of better transesterification reactivity and high reusability of the catalyst for biodiesel production. The catalyst stability and leaching profile of the modified waste shell derived CaO is discussed. In addition, a critical discussion of the structure, composition of the waste shell, mechanism of CaO catalyzed reaction, recent progress in biodiesel reactor systems and challenges in the industrial sector are also included in this review.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess Routesgold 35 citations 35 popularity Top 10% influence Top 10% impulse Top 1% Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.3390/catal11020194&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal , Other literature type 2021Publisher:MDPI AG Authors: Naushad Ahmad; Abdulaziz Ali Alghamdi; Hessah A. AL-Abdulkarim; Ghulam M. Mustafa; +2 AuthorsNaushad Ahmad; Abdulaziz Ali Alghamdi; Hessah A. AL-Abdulkarim; Ghulam M. Mustafa; Neazar Baghdadi; Fahad A. Alharthi;doi: 10.3390/app11010411
The composite of ceria has been widely studied as an electrode material for supercapacitors applications due to its high energy density. Herein, we synthesize CeO2/NiO nanocomposite via a hydrothermal route and explore its different aspects using various characterization techniques. The crystal structure is investigated using X-ray diffraction, Fourier transform infrared, and Raman spectroscopy. The formation of nanoflakes which combine to form flower-like morphology is observed from scanning electron microscope images. Selected area scans confirm the presence of all elements in accordance with their stoichiometric amount and thus authenticate the elemental purity. Polycrystalline nature with crystallite size 8–10 nm having truncated octahedron shape is confirmed from tunneling electron microscope images. Using X-ray photoelectron spectroscopy the different oxidation states of Ce and Ni are observed which play the role of active sites in the electrochemical performance of this nanocomposite material. Cyclic Voltammetry(CV) measurements at different scan rates and Galvanic Charge Discharge (GCD) measurements at different current densities are performed to probe the electrochemical response which revealed the potential of CeO2/NiO nanocomposite as an electrode material for energy storage devices.
Applied Sciences arrow_drop_down Applied SciencesOther literature type . 2021License: CC BYFull-Text: http://www.mdpi.com/2076-3417/11/1/411/pdfData sources: Multidisciplinary Digital Publishing Instituteadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.3390/app11010411&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess Routesgold 34 citations 34 popularity Top 10% influence Top 10% impulse Top 1% Powered by BIP!
more_vert Applied Sciences arrow_drop_down Applied SciencesOther literature type . 2021License: CC BYFull-Text: http://www.mdpi.com/2076-3417/11/1/411/pdfData sources: Multidisciplinary Digital Publishing Instituteadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.3390/app11010411&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu
description Publicationkeyboard_double_arrow_right Article , Journal 2021Publisher:MDPI AG Hui Khim Ooi; Xin Ning Koh; Hwai Chyuan Ong; Hwei Voon Lee; Mohd Sufri Mastuli; Yun Hin Taufiq-Yap; Fahad A. Alharthi; Abdulaziz Ali Alghamdi; Nurul Asikin Mijan;The dwindling of global petroleum deposits and worsening environmental issues have triggered researchers to find an alternative energy such as biodiesel. Biodiesel can be produced via transesterification of vegetable oil or animal fat with alcohol in the presence of a catalyst. A heterogeneous catalyst at an economical price has been studied widely for biodiesel production. It was noted that various types of natural waste shell are a potential calcium resource for generation of bio-based CaO, with comparable chemical characteristics, that greatly enhance the transesterification activity. However, CaO catalyzed transesterification is limited in its stability and studies have shown deterioration of catalytic reactivity when the catalyst is reused for several cycles. For this reason, different approaches are reviewed in the present study, which focuses on modification of waste-shell derived CaO based catalyst with the aim of better transesterification reactivity and high reusability of the catalyst for biodiesel production. The catalyst stability and leaching profile of the modified waste shell derived CaO is discussed. In addition, a critical discussion of the structure, composition of the waste shell, mechanism of CaO catalyzed reaction, recent progress in biodiesel reactor systems and challenges in the industrial sector are also included in this review.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.3390/catal11020194&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess Routesgold 35 citations 35 popularity Top 10% influence Top 10% impulse Top 1% Powered by BIP!
more_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.3390/catal11020194&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal , Other literature type 2021Publisher:MDPI AG Authors: Naushad Ahmad; Abdulaziz Ali Alghamdi; Hessah A. AL-Abdulkarim; Ghulam M. Mustafa; +2 AuthorsNaushad Ahmad; Abdulaziz Ali Alghamdi; Hessah A. AL-Abdulkarim; Ghulam M. Mustafa; Neazar Baghdadi; Fahad A. Alharthi;doi: 10.3390/app11010411
The composite of ceria has been widely studied as an electrode material for supercapacitors applications due to its high energy density. Herein, we synthesize CeO2/NiO nanocomposite via a hydrothermal route and explore its different aspects using various characterization techniques. The crystal structure is investigated using X-ray diffraction, Fourier transform infrared, and Raman spectroscopy. The formation of nanoflakes which combine to form flower-like morphology is observed from scanning electron microscope images. Selected area scans confirm the presence of all elements in accordance with their stoichiometric amount and thus authenticate the elemental purity. Polycrystalline nature with crystallite size 8–10 nm having truncated octahedron shape is confirmed from tunneling electron microscope images. Using X-ray photoelectron spectroscopy the different oxidation states of Ce and Ni are observed which play the role of active sites in the electrochemical performance of this nanocomposite material. Cyclic Voltammetry(CV) measurements at different scan rates and Galvanic Charge Discharge (GCD) measurements at different current densities are performed to probe the electrochemical response which revealed the potential of CeO2/NiO nanocomposite as an electrode material for energy storage devices.
Applied Sciences arrow_drop_down Applied SciencesOther literature type . 2021License: CC BYFull-Text: http://www.mdpi.com/2076-3417/11/1/411/pdfData sources: Multidisciplinary Digital Publishing Instituteadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.3390/app11010411&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess Routesgold 34 citations 34 popularity Top 10% influence Top 10% impulse Top 1% Powered by BIP!
more_vert Applied Sciences arrow_drop_down Applied SciencesOther literature type . 2021License: CC BYFull-Text: http://www.mdpi.com/2076-3417/11/1/411/pdfData sources: Multidisciplinary Digital Publishing Instituteadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.3390/app11010411&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu