• Energy Research

This research aimed to evaluate the comparative biogas yields of waste (peels) of selected fibrous materials from the West African region: cassava, plantain, a mixture of cassava, plantain and yam. Three models: The Boyle model, the Modified Boyle’s model, and the Buswell and Müller’s model were used to determine the theoretical maximum biomethane potential (TBMP), while the Hohenheim Biogas Yield test (D-HBT) was used to undertake a batch test of anaerobic digestion. The samples were co-digested with digested sewage sludge (DSS) for 39 days, with an operating temperature of 37 ± 0.5 °C. The study draws comparisons between the TBMPs and the experimental results, the experimental results of the different substrates, and the experimental results and figures reported in the literature. From the experimental results, plantain peels had the highest biogas yield (468 ± 72 mL/g oTS), followed by a mixture of yam, cassava and plantain peels (362 ± 31 mL/g oTS) and cassava peels obtained the least biogas yield (218 ± 19 mL/g oTS). TBMPS of 204.04, 209.03 and 217.45 CH4 mL/g oTS were obtained for plantain peels, a mixture of yam, cassava and plantain peels and cassava peels, respectively, evaluated using Boyle’s model. For all the samples, the TBMPS (205.56, 209.03 and 218.45 CH4 mL/g oTS, respectively) obtained using the Buswell and Mueller model were slightly higher than those obtained by both the Boyle and the modified Boyle’s model (163.23, 167.22 and 174.76 CH4 mL/g oTS, respectively). While the study result is sufficient to imply that generating biogas from fibrous waste materials in its mixture form is a valuable approach, it is not sufficient to conclude that the use of these waste materials in its naturally occurring mixture form has a technical added advantage in co-digestion over their individual potential. However, future studies could explore this possibility with different fractions of the mixture with a view to optimising generation. The study finds that theoretically modelling the biogas potential of fibrous materials is a good method for biogas evaluation despite having overestimation tendencies, as this challenge could be corrected by applying factors that result in these tendencies, biodegradability indices. The data can, therefore, find use in fibrous waste treatment and waste-to-energy technologies, especially in Africa. This application will not be negatively affected by whether single waste streams are used or their mixture.

Hydrothermal treatment (HTT) offers the potential to upgrade low-value biomass such as digestate (DG) or forest residue (FR) by producing solids and liquids for material use or energetic utilization. In this study, microwave-assisted HTT experiments with DG and FR as feedstocks were executed at different temperatures (130, 150, 170 °C) and with different holding times (30, 60, 90 min) to determine the influences on product properties (ash and elemental concentrations, calorific values and chemical compounds). In general, DG and FR reacted differently to HTT. For the DG solids, for instance, the ash concentration was reduced to 8.68%DM at 130 °C (initially 27.67%DM), and the higher heating value increased from 16.55 MJ/kgDM to 20.82 MJ/kgDM at 170 °C, while the FR solids were affected only marginally. Elements with importance for emissions in combustion were leached out in both HTT solids. The DG and FR liquids contained different chemical compounds, and the temperature or holding time affected their formation. Depending on the designated application of HTT, less severe conditions can deliver better results. It was demonstrated that different low-temperature HTT conditions already induce strong changes in the product qualities of DG and FR. Optimized interactions between process parameters (temperature, holding time and feedstock) might lead to better cost–benefit effects in HTT.

Anaerobic digestion has the potential to convert organic waste materials into valuable energy. At the same time, using press water from biomass materials for energy generation while taking advantage of the resulting cake for other purposes is an emerging approach. Therefore, this study aimed to investigate the residual potential expected from a typical biogas feedstock after it has been mechanically separated into liquid and solid phases. Hence, in this study, the rumen contents of ruminants (cow, goat, and sheep) and their proportionate ratios were obtained from an abattoir in Ghana. Resource characterization of the waste samples was carried out in the central laboratory of the HFR, Germany. Anaerobic batch tests for biogas (biomethane) yield determination were set up using the Hohenheim Biogas Yield Test (HBT). The inoculum used was obtained from an inoculum production unit at the Hohenheim University biogas laboratory. The trial involved two different forms of the sample: mixture of rumen contents, press water, and inoculum, each in four (4) replicates. The trial was carried out at a mesophilic temperature of 37 °C. Results obtained over a seventy (70) day period were transformed into biogas yields. Overall, the results show that the current contents are suitable for biogas generation as an option as opposed to the current form of disposal at a refuse dump. However, using these mixtures in their original forms is more technically viable than using press water without further treatment.