• Energy Research

AbstractCurrently the use of solar energy for heating and cooling isn’t widespread. In order to reduce primary energy consumption in the built environment along with improving the thermal performance of the current building stock, retrofit solutions are required to utilise renewable energy. Using solar energy to reduce primary energy consumption is seen as a possible solution. With the precipitous fall in the prices of crystalline solar photovoltaic modules, utilising this technology to reduce electrical energy consumption for cooling is an attractive solution. Recently, a sorption module integrated collector has been developed in order to improve cost-effectiveness and simplify solar thermal heating and cooling systems. A techno-economic analysis has been performed to evaluate solar photovoltaic cooling and solar thermal cooling systems for residential renewable energy retrofit. The analysis is based on potential energy and cost savings according to simulated heating and cooling loads under climatic conditions of Madrid, Spain. Simplified models were used to determine heating and cooling demands and the solar energy contribution to heating and cooling loads. Additionally, given the sorption collector's unique capacity to store solar energy thermally and provide cooling at night an analysis has been carried out to identify the combined benefit of solar-assisted heating and cooling via photovoltaics during the day and solar sorption at night. For system sizes between 5m2 and 20m2 solar fractions between 16% and 64% could be achieved which translated to annual energy cost savings between €153 to €615.

Abstract A straightforward thermodynamic model is developed in this work to analyze the efficiency limit of diverse sorption systems. A method is presented to quantify the dead thermal mass of heat exchangers. Solid and liquid sorbents based on chemisorption or physical adsorption are accommodated. Four possible single-effect configurations are considered: basic absorption or adsorption (separate desorber, absorber, condenser, and evaporator); separate condenser/evaporator (two identical sorbent-containing reactors with a condenser and a separate direct expansion evaporator); combined condenser/evaporator (one salt-containing reactor with a combined condenser/evaporator module); and resorption (two sorbent-containing reactors, each with a different sorbent). The analytical model was verified against an empirical heat and mass transfer model derived from component experimental results. It was then used to evaluate and determine the optimal design for an ammoniate salt-based solid/gas sorption heat pump for a space heating application. The effects on system performance were evaluated with respect to different working pairs, dead thermal mass factors, and system operating temperatures. The effect of reactor dead mass as well as heat recovery on system performance was also studied for each configuration. Based on the analysis in this work, an ammonia resorption cycle using LiCl/NaBr as the working pair was found to be the most suitable single-effect cycle for space heating applications. The maximum cycle heating coefficient of performance for the design conditions was 1.50 with 50% heat recovery and 1.34 without heat recovery.

The thermal masses of components influence the performance of many adsorption heat pump systems. However, typically when experimental adsorption systems are reported, data on thermal mass are missing or incomplete. This work provides original measurements of the thermal masses for experimental sorption heat exchanger hardware. Much of this hardware was previously reported in the literature, but without detailed thermal mass data. The data reported in this work are the first values reported in the literature to thoroughly account for all thermal masses, including heat transfer fluid. The impact of thermal mass on system performance is also discussed, with detailed calculation left for future work. The degree to which heat transfer fluid contributes to overall effective thermal mass is also discussed, with detailed calculation left for future work. This work provides a framework for future reporting of experimental thermal masses. The utilization of this framework will enrich the data available for model validation and provide a more thorough accounting of adsorption heat pumps.