• Energy Research

This work introduces a new method for inserting a Lithium reference electrode into commercially available 18650-type cells in order to obtain electrode potentials during cell operation. The proposed method is simple and requires limited equipment. Furthermore, electrical performance is significantly better and the cell capacity and resistance can be recorded for longer durations when compared to some of the previously used methods. Electrical performance of this new third electrode method is characterized and compared to 18650 cells with no reference electrode inserted. The capacity retention of the modified cell is more than 98% in the first 20 cycles. Harvested electrodes from a disassembled cell were also used to make coin cells that was proven to be a rather critical approach to get electrode potentials and capacities. This is an initial study that shows three-electrode performances of a commercial 18650-type cell, which suggests it could be used for understanding electrode behavior throughout a cell lifetime and for manufacturing instrumented cells.

Abstract In order to develop a deeper understanding of the behaviour of commercial automotive lithium-ion pouch cells under short-circuiting conditions, two scenarios were experimentally investigated and compared. Firstly, experiments were conducted by internally shorting 15 Ah cells by full nail penetration using three different nail materials; copper, steel and plastic. A second set of experiments involved externally shorting the cell tabs using an external circuit with a range of resistance values. In both scenarios the cell electrical and thermal response were determined by the shorting resistance. In the case of nail penetration there was a clear distinction between the outcome of the conducting and non-conducting nails, although the outcome using conducting nails suffered from poor reproducibility. The poor reproducibility was attributed to the variation in the contact resistance between the nail and the cell layers. Correlating the outcome of both tests can be used to estimate the shorting resistance and construct the current profile during nail penetration test.

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AbstractIn the quest for a sustainable society, energy storage technology is destined to play a central role in the future energy landscape. Breakthroughs in materials and methods involving sustainable resources are crucial to protect humankind from the most serious consequences of climate change. Rechargeable batteries of all forms will be required to follow the path. Elements that are eligible to harmonically contribute to the development of a sustainable ecosystem and fulfil the demands of high energy density batteries include Na, K, Ca, Mg, Zn, and Al. Numerous research efforts are underway to explore new battery chemistries based on these elements and, depending on the field of application, different elements inherit different advantages and challenges. Full sustainability implies that the environmental friendliness of these systems must be characterized by a “cradle‐to‐grave” approach. In this context, the pursuit of global environmental and economical sustainability from mass production, raw materials, and technical challenges is discussed herein for the most recent battery concepts based on monovalent and multivalent metal anodes. A perspective on strategies and opportunities particularly around the development of all‐solid‐state system configurations is provided, and the most important obstacles to overcome in search of a more sustainable future for electrochemical energy storage are addressed.