• Energy Research

(1) Background: sewage sludge is a by-product of wastewater treatment, which needs to be managed appropriately, e.g., in composting processes. The application of municipal sewage sludge composts (MSSCs) as a soil amendment is a potential way to effectively manage sewage sludge. (2) Methods: this paper presents the results of a vegetation pot experiment undertaken to assess the suitability of Dactylis glomerata L. and MSSC in the aided phytostabilization technique when applied on soils from an area effected by industrial pressure; this is characterized by high levels of heavy metal (HM). The contents of HMs in the test plant (the roots and above-ground parts), as well as in the soil and MSSC, were determined via an atomic spectrometry method. (3) Results: the application of MSSC positively contributed to an increased production of plant biomass and an increase in the pH in the soil. Concentrations of Cu, Cd, Pb, Zn, and Cr were higher in the roots than in the above-ground parts of Dactylis glomerata L. The addition of MSSC contributed most significantly to the considerable reduction in Ni, Pb, and Zn contents in the soil after the experiment. (4) Conclusions: MSSC can support the phytostabilization of soils contaminated with high levels of HMs.

One of crucial waste management problems is the management of organic waste. This activity employs the composting. In case of green waste, its application seems reasonable, whereas the use of selected mixed waste raises problems related to the compost quality. Across countries, the non-sterile organic fraction of municipal solid waste is being separated through the mechanical-biological treatment. The technology is a solution of waste treatment and meets objectives set out in the Landfill Directive. There are many problems associated with the use of output products. The use of compost as a fertilizer requires determination of its impact on the environment. Compost quality can be assessed using analytical methods and phytotoxicity tests. Therefore, the aim of this study was to describe changes in physico-chemical, enzymatic, phytotoxicity and vegetation parameters occurring in composts from two systems - a prismatic installation for green waste, and a mechanical-biological treatment installation. The compost from green waste exhibited greater stability. Values of dehydrogenase activity were lower if compared with the mechanically and biologically treated compost, which indicates lower compost maturity. The biomass production of Brassica napus L. and Fetuca rubra L. was higher in the variant with the application of green compost. The influence on Hordeum vulgare L., Cannabis sativa L., and Sinapis alba L. depended on the plant type and the compost used. Nevertheless, the compost from green waste was less toxic. The evidence from this study suggests that the mechanical-biological treatment had problems associated with the maturation and quality of the final product.

The experiment was carried out in order to evaluate the effects of trace element immobilizing soil amendments, i.e., chalcedonite, dolomite, halloysite, and diatomite on the chemical characteristics of soil contaminated with Cr and the uptake of metals by plants. The study utilized analysis of variance (ANOVA), principal component analysis (PCA) and Factor Analysis (FA). The content of trace elements in plants, pseudo-total and extracted by 0.01 M CaCl2, were determined using the method of spectrophotometry. All of the investigated element contents in the tested parts of Indian mustard (Brassica juncea L.) differed significantly in the case of applying amendments to the soil, as well as Cr contamination. The greatest average above-ground biomass was observed when halloysite and dolomite were amended to the soil. Halloysite caused significant increases of Cr concentrations in the roots. The obtained values of bioconcentration and translocation factors observed for halloysite treatment indicate the effectiveness of using Indian mustard in phytostabilization techniques. The addition of diatomite significantly increased soil pH. Halloysite and chalcedonite were shown to be the most effective and decreased the average Cr, Cu and Zn contents in soil.

(1) Background: The growing demand for developing new methods of degraded land remediation is linked to the need to improve the soil environment, including post-industrial soils. Biological methods such as the aided phytostabilisation technique are the most common methods applied to achieve effective remediation. This study aimed to determine the technical potential of methods using novel or yet not used soil amendments, such as blast furnace slag (BFS) and coal slag (CS), with Dactylis glomerata L. as a test plant. (2) Methods: The experiment was conducted on post-industrial area soil with high concentrations of Cu (761 mg/kg), Cd (23.9 mg/kg), Pb (13,539 mg/kg) and Zn (8683 mg/kg). The heavy metal content in roots and the above-ground parts of plants and soil was determined by flame atomic absorption spectrometry. (3) Results: The addition of BFS to the soil was the most effective in increasing Dactylis glomerata L. biomass yield. The Cu, Cd, Pb, and Zn concentrations were higher in the roots than in the above-ground parts of the plants. BFS and CS induced a considerable increase in soil pH, compared to the control treatment. The addition of BFS also produced the greatest significant decrease in the Pb content in soil following the phytostabilisation process. (4) Conclusions: In view of the above, the use of BFS in the aided phytostabilisation in soils contaminated with high levels of Cu, Cd, Pb, and Zn can be recommended for larger-scale in situ projects.

Due to the presence of toxic pollutants, soils in former military areas need remedial actions with environmentally friendly methods. Greenhouse experiments were conducted to investigate the aided phytostabilization of multi-heavy metals (HMs), i.e. Cd, Cr, Cu, Ni, Pb, Zn, in post-military soil by Festuca rubra and three mineral amendments (diatomite, dolomite and halloysite). The amendments were applied at 0 and 3.0% to each pot filled with 5 kg of polluted soil. After seven weeks of the phytostabilization, selected soil properties, biomass yield of F. rubra and immobilization of HMs by their accumulation in plant and redistribution among individual fractions in soil were determined. In addition, ecotoxicology parameters of non-amended and amended soil were established using Phytotoxkit (Sinapsis alba) and Ostracodtoxkit (Heterocypris incongruens) tests. The addition of halloysite significantly increased F. rubra biomass. Diatomite significantly increased both the Cd, Cu, Pb and Cr concentrations in the roots and the pH of the soil. The application of halloysite significantly decreased the Cd and Zn contents of the soil after the completion of the experiment. Dolomite and halloysite were more effective in HM immobilization in soil by decreasing their content in an exchangeable fraction than diatomite. These soil amendments significantly differentiated the length of S. alba roots and had a positive effect on the development of H. incongruens.

Contamination of soil by copper (Cu) has become a serious problem throughout the world, causing the reduction of agricultural yield and harmful effects on human health by entering the food chain. A glasshouse pot experiment was designed to evaluate the potential use of halloysite as an immobilizing agent in the aided phytostabilization of Cu-contaminated soil, using Festuca rubra L. The content of Cu in plants, i.e., total and extracted by 0.01 M CaCl2, was determined using the method of spectrophotometry. Cu content in the tested parts of F. rubra differed significantly when halloysite was applied to the soil, as well as with increasing concentrations of Cu. The addition of halloysite significantly increased plant biomass. Cu accumulated in the roots, thereby reducing its toxicity to the aerial parts of the plant. The obtained values of bioconcentration and translocation factors observed for halloysite treatment indicate the effectiveness of using F. rubra in phytostabilization techniques.

The presence of potentially toxic elements (PTEs) in soils can upset the natural balance and increase the risk of PTE incorporation into the food chain. The use of composite biochar with municipal sewage sludge compost (MSSC/C) can be an effective way of both managing waste, such as sewage sludge, and providing an effective additive-supporting phytostabilization processes. The effectiveness of D. glomerata and MSSC/C in the technique of assisted phytostabilization of industrially contaminated soils was determined under the pot experiment conditions. The PTE contents in D. glomerata and the soil were determined using the spectrophotometric method. The addition of MSSC/C to PTE-contaminated soil contributed to an 18% increase in plant biomass and increased the soil pH by 1.67 units, with the PTE concentration being higher in the roots than in the above-ground parts of D. glomerata. The MSSC/C addition had the strongest effect on the reduction in Cd, Cr, and Ni contents in the soil following the completion of the experiment. The current study confirmed the effectiveness of MSSC/C in aiding the phytostabilization processes in PTE-contaminated soils.