• Energy Research

AbstractIn this work, the pyrolysis of barley straw (BS) and brown algae (BA) mixed with NaOH as a catalyst was compared. Four different catalyst‐to‐biomass mass ratios (i.e., 6:100, 8:100, 10:100, and 12:100) and five pyrolysis heating rates were examined. The kinetic parameters (e.g., the activation energy and pre‐exponential factor) were evaluated using the Friedman method and kinetic models. For noncatalytic pyrolysis, the average activation energies for BS and BA samples were 139.71 and 183.19 kJ mol−1, respectively. However, the addition of catalyst generally increased the average activation energy of BS samples but decreased that of BA samples. The enthalpy change and Gibbs free energy change revealed that both catalytic and noncatalytic pyrolysis processes were nonspontaneous and endothermic, and the inclusion of catalyst increased the average entropy change of the BS samples but decreased that of the BA samples. Char and biochar yields after pyrolysis were also analyzed quantitatively. These observations provide insight into the differences in catalytic pyrolysis between lignocellulosic and algal biomass species.

The combustion characteristics of biochar obtained from barley straw (BS) and brown algae (BA) are explored. Four different heating rates are utilized to determine the respective activation energies. A master plot analysis is used to identify the appropriate reaction model. The results show that the activation energies vary in the ranges of 6.86–48.36 and 46.34–77.51 kJ mol−1 for BS and BA biochar combustion, respectively. As the heating rate increases, most of the combustion characteristic parameters increase, while the combustion stability index decreases. These observations help provide a deeper understanding of the combustion of lignocellulosic and algal biomass-derived biochar.