• Energy Research

Organic solar cells utilize an energy-level offset to generate free charge carriers. Although a very small energy-level offset increases the open-circuit voltage, it remains unclear how exactly charge generation is affected. Here we investigate organic solar cell blends with highest occupied molecular orbital energy-level offsets (∆EHOMO) between the donor and acceptor that range from 0 to 300 meV. We demonstrate that exciton quenching at a negligible ∆EHOMO takes place on timescales that approach the exciton lifetime of the pristine materials, which drastically limits the external quantum efficiency. We quantitatively describe this finding via the Boltzmann stationary-state equilibrium between charge-transfer states and excitons and further reveal a long exciton lifetime to be decisive in maintaining an efficient charge generation at a negligible ∆EHOMO. Moreover, the Boltzmann equilibrium quantitatively describes the major reduction in non-radiative voltage losses at a very small ∆EHOMO. Ultimately, highly luminescent near-infrared emitters with very long exciton lifetimes are suggested to enable highly efficient organic solar cells. Donor–acceptor systems with low energy-level offset enable high power efficiency in organic solar cells yet it is unclear what drives charge generation. Classen et al. show that long exciton lifetimes enable efficient exciton splitting and thus generation of free charges while also suppressing voltage losses.

Magnetic refrigeration is an upcoming technology that could be an alternative to the more than 100‐year‐old conventional gas–vapor compression cooling. Magnetic refrigeration might answer some of the global challenges linked with the increasing demands for readily available cooling in almost every region of the world and the global‐warming potential of conventional refrigerants. Important issues to be solved are, for example, the required mass and the ecological footprint of the rare‐earth permanent magnets and the magnetocaloric material, which are key parts of the magnetic cooling device. The majority of existing demonstrators use Nd–Fe–B permanent magnets, which account for more than 50% of the ecological footprint, and Gd, which is a critical raw material. This work shows a solution to these problems by demonstrating the world's first magnetocaloric demonstrator that uses recycled Nd–Fe–B magnets as the magnetic field source, and, as a Gd replacement material, La–Fe–Mn–Si for the magnetocaloric heat exchanger. These solutions show that it is possible to reduce the ecological footprint of magnetic cooling devices and provides magnetic cooling as a green solid‐state technology that has the potential to satisfy the rapidly growing global demands.