• Energy Research

Using agricultural biomasses as solid carbon substrates in constructed wetlands (CWs) could be an effective way to achieve sustainable nitrogen removal for carbon-limited wastewater treatments. This study investigated the response of bacteria community in CWs to the addition of agricultural biomasses (wheat straw, walnut shell and apricot pit). Results indicated that the addition of different agricultural biomasses had distinct influence on bacterial communities in CWs. Both wheat straw and walnut shell increased the diversity of microbial communities and optimized the structure of microorganisms. The effect of apricot pit on the richness and evenness of microbial communities was not significant, but the composition of microorganisms was significantly affected at the phylum level, especially the relative abundance of phylum Saccharibacteria. Moreover, the addition of agricultural biomasses in CWs acclimatized more functional bacteria including nitrifier and denitrifier, which were proved to be positively correlated with the high-rate denitrification performance. The obtained results would be beneficial to understand the underlying microbial mechanism of nitrogen removal in CWs with agricultural biomass and provide some guidance on the practical application of CWs.

Effects of turbulent energy dissipation rate (increased from 1.28 × 10-6 to 1.67 × 10-5 m2 s-3) on Scenedesmus obliquus biomass and lipid accumulation at different aeration rates (0.3, 0.6, 0.9, 1.2, and 1.5 L min-1) were investigated. The turbulent energy dissipation rate was calculated by CFD model simulation. When the turbulent energy dissipation rate increased to 7.30 × 10-6 m2 s-3, the biomass and lipid productivity increased gradually, and finally reached their maximum values of 1.11 × 107 cells mL-1 and 16.0 mg L-1 day-1, respectively. When it exceeded 7.30 × 10-6 m2 s-3, the biomass and lipid productivity showed a decreasing trend. Therefore, the most favorable turbulent energy dissipation rate for S. obliquus growth and lipid accumulation was 7.30 × 10-6 m2 s-3.

Improper treatment of various wastewaters with a low C/N ratio and management of abundant agricultural wastes may pose a serious threat to bodies of water and agricultural ecosystems in rural areas, especially in developing countries. Thus, a potential alternative for simultaneous mitigation of this pollution is needed to protect rural environments. This study investigated the feasibility and enhanced performance of applying typical agricultural wastes (such as wheat straw, apricot pits, and walnut shells) as carbon sources for nitrogen removal in constructed wetlands (CWs). The leaching experiment employed fluorescence excitation-emission spectrophotometry and revealed that the wheat straw material had the highest capability of carbon release with an average dissolved organic carbon release content and rate of 27.88 mg g-1 and 5.24 mg g-1 day-1, respectively. Dissolved organic matter released from different agricultural wastes mainly consisted of humic acid-like and fulvic acid-like compounds. Long-term assessment of lab-scale intermittent aeration CWs receiving agricultural wastes revealed a high total nitrogen removal of 66.75-93.67% in low carbon/nitrogen ratio wastewaters (C/N = 3). These findings can contribute to a better understanding of the driving mechanism through which agricultural wastes enhance nitrogen removal in CW wastewater treatments.

Constructed wetlands (CWs) as a green eco-technology have been applied for treating various wastewaters for several decades. However, sustainable reclamation of the harvested wetland biomass remains a challenge. Utilization of wetland biomass for value-added activated carbon (AC) production could be a potential strategy to improve the sustainability with multi-functions such as energy storage, resource recovery and environmental remediation. This paper aims to present a comprehensive review on the recent advances in production of ACs from wetland biomass and their application for adsorption of metal ions from wastewaters. The physicochemical properties of the ACs with chemical activations and their feasibility for heavy metal ions adsorption are compared, and the adsorption mechanisms are found to be complexation, physical adsorption, ion-exchange and electrostatic interactions. The surface chemistry of ACs impacted more on the adsorption ability towards heavy metal ions than their porosity. The in-situ modification during H3PO4 activation and new phosphorus-based activation are also summarized for enhancing the surface functionality and introducing specific surface functionalities on ACs, in turn promoting their adsorption ability for heavy metal ions. The high adsorption capacity and cost-effectiveness make these ACs as economical alternatives for waste remediation, and future research on the optimization and applications of ACs was also highlighted.

Agricultural biomass waste in rural areas has been identified as an economical solid carbon sources in constructed wetlands (CWs) for treating low C/N ratio domestic sewage. However, little information is available regarding its optimal utilization as a media amendment for enhancing nitrogen removal in CWs. In this study, vertical flow CWs with different walnut peel amendment proportions (0%, 25%, 50%, 75%) were developed to explore the effects of biomass dosage on the treatment performance, nitrous oxide (N2O) emission and microbial metabolites. Results showed that the addition of biomass significantly enhanced the denitrification performance in all CWs, and the higher total nitrogen (TN) removal efficiency (91.14-97.16%) was achieved in CWs with the optimal dosage of 25%. While the addition of biomass resulted in a slight increase in N2O emission (20.56-270.13 μg m-2 h-1) compared with control systems. Additionally, the biomass addition increased the accumulation of extracellular polymeric substances (EPS) by facilitating microbial processes. Higher total EPS production was observed in CW with 25% biomass, and the proportion of tightly bound EPS (48%) dominated in the total EPS in different CWs.

Screening for highly efficient microalgae is an important technique for improving treatment efficiency. In this study, eight species of microalgae (five Scenedesmus and three Desmodesmus) were isolated from water and soil in the Hexi Corridor region, China, and identified by 18S rRNA gene sequence analysis. Scenedesmus sp. HXY2 grew well under high total organic carbon and ammonia conditions and had the highest nutrient removal efficiency (>95%). On day 12, the biomass of Scenedesmus sp. HXY2 was 7.2 × 106 cells mL-1. The lipid content and productivity of this species were 15.56% and 5.67 mg L-1 day-1, respectively. The proportion of unsaturated fatty acids (60.07%) indicated that the lipids of Scenedesmus sp. HXY2 were suitable for biodiesel production. Scenedesmus sp. HXY2 showed great potential for growth in wastewater with high ammonia and organic contents to simultaneously purify wastewater and produce lipids.

AbstractThere is no universally accepted method for evaluating cadmium (Cd) bioavailability in soil. The diffusive gradient in thin films (DGT) technique is a promising tool, but there is considerable debate about its suitability. The ability of this technique to estimate Cd bioavailability in soils was compared with the abilities of other traditional chemical extraction techniques (soil solution, ethylene diamine tetraacetic acid (EDTA), acetic acid (HAc), calcium chloride (CaCl2), and pseudo-total Cd methods) based on a greenhouse experiment using pakchoi (Brassica chinensis) grown in 15 soils from different provinces of China. In addition, we assessed whether these methods were independent of the soil properties. Correlations between the plant and soil Cd concentrations measured with the traditional extraction techniques were dependent on the pH and organic carbon (OC) content, indicating that these methods are influenced by the soil properties. In contrast, the DGT measurements were independent of the soil properties and showed a higher correlation coefficient compared to that of the traditional techniques. Hence, the DGT technique is better and should be preferable for assessing Cd biological effectiveness in different soil types.