• Energy Research

As the world human population and industrialization keep growing, the water availability issue has forced scientists, engineers, and legislators of water supply industries to better manage water resources. Pollutant removals from wastewaters are crucial to ensure qualities of available water resources (including natural water bodies or reclaimed waters). Diverse techniques have been developed to deal with water quality concerns. Carbon based nanomaterials, especially carbon nanotubes (CNTs) with their high specific surface area and associated adsorption sites, have drawn a special focus in environmental applications, especially water and wastewater treatment. This critical review summarizes recent developments and adsorption behaviors of CNTs used to remove organics or heavy metal ions from contaminated waters via adsorption and inactivation of biological species associated with CNTs. Foci include CNTs synthesis, purification, and surface modifications or functionalization, followed by their characterization methods and the effect of water chemistry on adsorption capacities and removal mechanisms. Functionalized CNTs have been proven to be promising nanomaterials for the decontamination of waters due to their high adsorption capacity. However, most of the functional CNT applications are limited to lab-scale experiments only. Feasibility of their large-scale/industrial applications with cost-effective ways of synthesis and assessments of their toxicity with better simulating adsorption mechanisms still need to be studied.

The reuse of lignocellulosic biomaterials as a source of clean energy has been explored in recent years due to the large amount of waste that involves human activities, such as those related to agriculture and food. The anaerobic digestion (AD) of plant-based biomass for bioenergy production poses a series of challenges that new technologies are attempting to solve. An improved decomposition of recalcitrant lignocellulose together with an increase in biogas production yield are the main objectives of these new approaches, which also seek the added value of being environmentally friendly. Recent research has reported significant progress in this regard, offering promising outcomes on the degradation of lignocellulose and its subsequent transformation into biomethane by specialized anaerobic microorganisms, overcoming the drawbacks inherent to the process and improving the yield of methane production. The future of the agri–food industry seems to be heading towards the implementation of a circular economy through the introduction of strategies based on the optimized use of lignocellulosic residues as a source of clean and sustainable energy.

The global increasing food demand can be met by efficient energy utilization in mechanized agricultural productions. In this study, input–output energy flow along with CO2 emissions for different wheat production cases (C-I to C-V) were investigated to identify the one that is most energy-efficient and environment-friendly case. Data and information about input and output sources were collected from farmers through questionnaires and face-to-face interviews. Input and output sources were converted into energy units by energy equivalents while CO2 emissions were calculated by emission equivalents. Data envelopment analysis (DEA) was conducted to compare technical efficiencies of the developed cases for optimization of inputs in inefficient cases. Results revealed that case C-Ⅴ (higher inputs, larger fields, the tendency of higher fertilizer application and tillage operations) has the highest energy inputs and outputs than the rest of the cases. Moreover, it possesses the lowest energy use efficiency and energy productivity. The highest CO2 emissions (1548 kg-CO2/ha) referred to C-Ⅴ while lowest emissions per ton of grain yield were determined in C-Ⅳ (higher electricity water pumping, moderate energy input). The grain yield increases directly with input energy in most of the cases, but it does not guarantee the highest values for energy indices. C-Ⅲ (moderate irrigations, educated farmers, various fertilizer applications) was found as an optimum case because of higher energy indices like energy use efficiency of 4.4 and energy productivity of 153.94 kg/GJ. Optimum input and better management practices may enhance energy proficiency and limit the traditionally uncontrolled CO2 emissions from wheat production. Therefore, the agricultural practices performed in C-Ⅲ are recommended for efficient cultivation of wheat in the studied area.

In Pakistan, many subsurface (SS) drainage projects were launched by the Salinity Control and Reclamation Project (SCARP) to deal with twin problems (waterlogging and salinity). In some cases, sump pumps were installed for the disposal of SS effluent into surface drainage channels. Presently, sump pumps have become dysfunctional due to social and financial constraints. This study evaluates the alternate design of the Paharang drainage system that could permit the discharge of the SS drainage system in the response of gravity. The proposed design was completed after many successive trials in terms of lowering the bed level and decreasing the channel bed slope. Interconnected MS-Excel worksheets were developed to design the L-section and X-section. Design continuity of the drainage system was achieved by ensuring the bed and water levels of the receiving drain were lower than the outfalling drain. The drain cross-section was set within the present row with a few changes on the service roadside. The channel side slope was taken as 1:1.5 and the spoil bank inner and outer slopes were kept as 1:2 for the entire design. The earthwork was calculated in terms of excavation for lowering the bed level and increasing the drain section to place the excavated materials in a specific manner. The study showed that modification in the design of the Paharang drainage system is technically admissible and allows for the continuous discharge of SS drainage effluent from the area.

The present study considers evaporative cooling and desiccant unit-based air-conditioning (AC) options for livestock AC application. In this regard, proposed systems are investigated by means of experiments and thermodynamic investigations. Air-conditioning requirements for animals are theoretically investigated and temperature-humidity index (THI) is estimated. A lab-scale heat mass exchanger based on the Maisotsenko-cycle evaporative cooling conception (MEC) is set up and its performance is evaluated at different ambient air conditions. In addition, a desiccant-based air-conditioning (DAC) unit is thermodynamically evaluated using a steady-state model available in the literature. The study focuses on the ambient conditions of Multan which is the 5th largest city of Pakistan and is assumed to be a typical hot city of southern Punjab. The study proposed three kinds of AC combination i.e., (i) stand-alone MEC, (ii) stand-alone desiccant AC, and (iii) M-cycle based desiccant AC systems. Wet bulb effectiveness of the stand-alone MEC unit resulted in being from 64% to 78% whereas the coefficient of performance for stand-alone desiccant AC and M-cycle based desiccant AC system was found to be 0.51 and 0.62, respectively. Results showed that the stand-alone MEC and M-cycle based desiccant AC systems can achieve the animals’ thermal comfort for the months of March to June and March to September, respectively, whereas, stand-alone desiccant AC is not found to be feasible in any month. In addition, the ambient situations of winter months (October to February) are already within the range of animal thermal comfort.

Threats due to insufficient, inadequate and costlier methods of treating contaminants such as arsenic have emphasized the significance of optimizing and managing the processes adopted. This study was aimed at the complete elimination of arsenic from an aqueous medium with minimum energy consumption using the electrocoagulation process. Arsenic removal around 95% was rapidly attained for optimized conditions having a pH of 7, 0.46 A current intensity, 10 mg/L initial concentration and only 2 min of applied time duration using the energy of 3.1 watt-hour per gram of arsenic removed. Low values of applied current for longer durations resulted in the complete removal of arsenic with low energy consumption. Various hydroxide complexes including ferrous hydroxide and ferric hydroxide assisted in the removal of arsenic by adsorption along with co-precipitation. Surface models obtained were checked and found with a reasonably good fit having high values of coefficient of determination of 0.933 and 0.980 for removal efficiency and energy consumption, respectively. Adsorption was found to follow pseudo-first-order kinetics. Multivariate optimization proved it as a low-cost effective technology having an operational cost of 0.0974 Indian rupees (equivalent to USD 0.0013) per gram removal of arsenic. Overall, the process was well optimized using CCD based on response surface methodology.

In this study, the ideal adsorption cycle behavior of eight activated carbon and refrigerant pairs is evaluated. The selected pairs are KOH6-PR/ethanol, WPT-AC/ethanol, Maxsorb-III/methanol, Maxsorb-III/CO2, Maxsorb-III/n-butane, Maxsorb-III/R-134a, SAC-2/R32 and Maxsorb-III/R507a. The following cooling performance parameters are evaluated for all pairs: specific cooling energy (SCE), concentration difference (ΔW) and coefficient of performance (COP) of ideal adsorption cooling and refrigeration cycles. The evaporator temperatures for the applications of adsorption cooling and refrigeration are selected as 7 and −5 °C, respectively. It is found that the Maxsorb-III/methanol pair has shown the highest specific cooling energy and coefficient of performance in a wide range of desorption temperatures; i.e., for the adsorption cooling cycle it has SCE and COP of 639.83 kJ/kg and 0.803, respectively, with desorption temperatures of 80 °C. The KOH6-PR/ethanol and the WPT-AC/ethanol pairs also give good performances comparable to that of the Maxsorb-III/methanol pair. However, the SAC-2/R32 pair possesses a higher concentration difference than the Maxsorb-III/methanol, KOH6-PR/ethanol and WPT-AC/ethanol pairs but shows a lower performance. This is due to the lower isosteric heat of adsorption of SAC-2/R32 compared to these pairs. It is found that Maxsorb-III/methanol, KOH6-PR/ethanol and WPT-AC/ethanol are the most promising pairs for application in designing adsorption cooling and refrigeration systems.