• Energy Research

Physical and chemical modification on biochar is an interesting approach to enhance the properties and make them potential candidates in adsorption of heavy metals from water. Studies have shown that ultrasound treatments as well as alkali activations on biochar has positive impact on adsorption behaviour of the material. Base activation on biochar derived from ultrasound pre-treated woodchips were studied to understand the influence of ultrasound pre-treatment on chemical modification of biochar and the adsorption properties emerged from it. 40 and 170 kHz ultrasound pre-treated softwood woodchips were subjected to laboratory scale pyrolysis and the resulted biochars were treated with NaOH. The physicochemical properties were examined, and the adsorption experiments revealed that ultrasound pre-treatment assisted biochars have better adsorption capacity as compared to untreated biochar samples after activation. 170 kHz pre-treated sample exhibited an equilibrium adsorption capacity of 19.99 mg/g which is almost 22 times higher than that of corresponding non-activated sample. The ultrasound pre-treated samples showed improved competitive adsorption behaviour towards copper ions in comparison with nickel or lead. The overall study suggests that ultrasound pre-treated biochars combined with alkali activation enhances the heavy metal removal efficiency and these engineered biochars can be used as an effective adsorbent in the field of wastewater treatment.

Physical and chemical modification on biochar is an interesting approach to enhance the properties and make them potential candidates in adsorption of heavy metals from water. Studies have shown that ultrasound treatments as well as alkali activations on biochar has positive impact on adsorption behaviour of the material. Base activation on biochar derived from ultrasound pre-treated woodchips were studied to understand the influence of ultrasound pre-treatment on chemical modification of biochar and the adsorption properties emerged from it. 40 and 170 kHz ultrasound pre-treated softwood woodchips were subjected to laboratory scale pyrolysis and the resulted biochars were treated with NaOH. The physicochemical properties were examined, and the adsorption experiments revealed that ultrasound pre-treatment assisted biochars have better adsorption capacity as compared to untreated biochar samples after activation. 170 kHz pre-treated sample exhibited an equilibrium adsorption capacity of 19.99 mg/g which is almost 22 times higher than that of corresponding non-activated sample. The ultrasound pre-treated samples showed improved competitive adsorption behaviour towards copper ions in comparison with nickel or lead. The overall study suggests that ultrasound pre-treated biochars combined with alkali activation enhances the heavy metal removal efficiency and these engineered biochars can be used as an effective adsorbent in the field of wastewater treatment.

Cellulose nanofibers (CNFs) and their applications have recently gained significant attention due to the attractive and unique combination of their properties including excellent mechanical properties, surface chemistry, biocompatibility, and most importantly, their abundance from sustainable and renewable resources. Although there are some commercial production plants, mostly in developed countries, the optimum CNF production is still restricted due to the expensive initial investment, high mechanical energy demand, and high relevant production cost. This paper discusses the development of the current trend and most applied methods to introduce energy-efficient approaches for the preparation of CNFs. The production of cost-effective CNFs represents a critical step for introducing bio-based materials to industrial markets and provides a platform for the development of novel high value applications. The key factor remains within the process and feedstock optimization of the production conditions to achieve high yields and quality with consistent production aimed at cost effective CNFs from different feedstock.

Cellulose nanofibers (CNFs) and their applications have recently gained significant attention due to the attractive and unique combination of their properties including excellent mechanical properties, surface chemistry, biocompatibility, and most importantly, their abundance from sustainable and renewable resources. Although there are some commercial production plants, mostly in developed countries, the optimum CNF production is still restricted due to the expensive initial investment, high mechanical energy demand, and high relevant production cost. This paper discusses the development of the current trend and most applied methods to introduce energy-efficient approaches for the preparation of CNFs. The production of cost-effective CNFs represents a critical step for introducing bio-based materials to industrial markets and provides a platform for the development of novel high value applications. The key factor remains within the process and feedstock optimization of the production conditions to achieve high yields and quality with consistent production aimed at cost effective CNFs from different feedstock.