• Energy Research

A novel highly compressible auxetic cementitious composite (ACC) is developed in this work. Contrary to conventional cementitious materials, such as plain concrete and fiber reinforced concrete, the ACC shows strain-hardening behavior under uniaxial compression: the stress continuously increases with strain up to approximately 40 % strain. On one hand, in the early compression stage, the ACC exhibit highly recoverable deformability of 10 % strain under cyclic loading (20 times higher than the constituent cementitious material). In addition, the ACC shows fatigue damage until the stiffness/strength and energy dissipation plateau values are reached after 500 cycles. At 2.5 % strain amplitude, the plateau stiffness/strength is approximately 120 MPa/3 MPa, while these values are only 25 MPa/1.2 MPa at 5 % strain amplitude. In contrast, the energy dissipation plateau of the ACC is independent from the amplitude and remains at 0.05 J/cm3. On the other hand, due to the strain-hardening behavior, the ACC exhibits significantly improved energy dissipation capacity compared to both the conventional cementitious materials and the auxetic frame. This behavior is achieved by a tailored composite action: integrating cementitious mortar with 3D printed thermoplastic polyurethane (TPU) auxetic frame. A rotating-square auxetic mechanism was designed for the TPU frame for the ACC to achieve the tailored cracking behavior. The horizontal ACC cells enable large deformability by enlarging the crack width under the confinement of the auxetic frame, while the vertical cells work as stiffening phase to ensure load resistance. Owing to the outstanding mechanical properties, the ACC shows great potential to be applied in engineering practice where high compressive deformability is required, for instance yielding elements for squeezing tunnel linings. ; Materials and Environment

The design of new insulating envelopes is a direct route towards energy efficient buildings. The combinations of novel materials, such as phase-change (PCM), and advanced manufacturing techniques, such as additive manufacturing, may harness important changes in the designing of building envelopes. In this work we propose a novel methodology for the design of cement-based building envelopes. Namely, we combined the use of a multiscale, multiphysical simulation framework with advanced synthesis techniques, such as the use of phase-change materials and additive manufacturing for the design of concrete envelopes with enhanced insulation properties. At the material scale, microencapsulated PCMs are added to a cementitious matrix to increase heat storage. Next, at the component level, we create novel designs for the blocks, here defined as HEXCEM, by means of additive manufacturing. The material and component design process is strongly supported on heat transfer simulations with the use of the finite element method. Effective thermal properties of the mixes can be obtained and subsequently used in macroscale simulations to account for the effect of the volume fraction of PCMs. From the experimental and numerical tests, we report an increase in the the thermal inertia, which results in thermal comfort indoors.

Abstract 3D printing is becoming increasingly popular in the construction sector. 3D printing offers the potential to reduce costs, construction time and construction waste. However, due to its high cement content, 3D printable concrete more expensive to produce. The article includes a brief literature survey on the possibility of using cement and aggregate substitutes in concrete mixtures and their impact on fresh composite properties and identifies a research gap. Herein, we propose the use of waste copper slag as a replacement for cement in 3D printable concrete. We examine the effect of replacing cement with copper slag at 5 and 10% on fresh properties of cementitious mortar. The results show that copper slag improves the workability of the mixture and lowers the design yield strength up to 44%, thereby facilitating printing. Even 30% higher fresh compressive strengths were also obtained, which suggest that the buildability of mortars containing copper slag will be improved.

The high deformation capacity of auxetic cementitious cellular composites (ACCCs) makes them promising for strain-based energy harvesting applications in infrastructure. In this study, a novel piezoelectric energy harvester (PEH) with ACCCs and surface-mounted PVDF film based on strain-induced piezoelectric mechanisms has been designed, fabricated, and experimentally tested. Furthermore, a numerical model for simulating the energy harvesting of ACCC-PVDF system undergoing repeated mechanical loading has been established and validated against the experimental data. The mechanical behavior of ACCCs was simulated by the concrete damage plasticity model during the preloading stage, which was converted to the second-elasticity model during cyclic loading stage. Based on the mechanical responses, analytical formulas for piezoelectric effects were developed to calculate the output voltage of the PVDF film. The output voltages of the ACCCs-PVDF system under different loading amplitudes and loading frequencies were assessed. The experimental results and models of the ACCCs-PVDF energy harvester lay a solid foundation for utilizing architected cementitious composites in energy harvesting applications to supply self-power electronics in infrastructure. Materials and Environment

Abstract: In the race to achieve global climate neutrality, carbon intensive industries like the clinker and cement industry are required to decarbonize rapidly. The environmental impacts related to potential transition pathways to lowcarbon systems can be evaluated using prospective life cycle assessment (pLCA). This study conducts a pLCA for future global clinker production, integrating long-term transition pathways from the IMAGE integrated assessment model (IAM) to maintain global consistency. It systematically modifies the ecoinvent v3.9.1 database using the Python library premise to create future database versions representing future clinker production embedded in a future economy according to a 3.5 degrees C-baseline, a 2 degrees C-compliant and a 1.5 degrees C-compliant scenario. Our study indicates that climate change impacts of clinker production may decrease from about 1.03 kg CO 2 -eq/kg clinker in 2020 to 0.94 (3.5 degrees C-baseline), 0.20 (2 degrees C-compliant), and 0.16 (1.5 degrees C-compliant) kg CO 2 -eq/kg clinker in 2060 for the global average. This corresponds to a 10% (3.5 degrees C-baseline), 81% (2 degrees C-compliant) and 84% (1.5 degrees C- compliant) decrease by 2060 compared to 2020. Under these scenarios, global clinker production alone would require 5% -11% of the remaining end-of-century carbon budget for the 2 degrees C and 1.5 degrees C-target, respectively. While the climate change impacts are substantially reduced, our study also indicates that the transition pathways shift the burden towards other impact categories, such as ionizing radiation, ozone depletion, material resources and land use. Developing IAM-compatible scenarios for more product groups helps to increase the coherence of pLCA studies. As this study is based on an IAM heavily reliant on carbon capture and storage and bioenergy, future research should explore the effects of different technology pathways and alternative mitigation strategies.

This paper presents a numerical investigation of thermal response of mortar panels, incorporating macro-encapsulated paraffin in different forms. Two types of macro capsules were fabricated and tested in this study using an instrumented hot plate device. The experimental results show that macro encapsulated paraffin reduced the temperature and increased time lag in the mortar panels due to the latent heat capacity of paraffin. Finite element models adopting the effective heat capacity method to model phase change effects were able to capture the overall thermal response of panels incorporated with paraffin well. Then, a parametric study was conducted using the validated finite element (FE) modelling technique to investigate the effects of different forms of macro capsules, the quantity of paraffin and the position of macro capsules. It was found that the tube and sphere macro capsules showed similar thermal responses, while the plate shaped capsules may cause a non-uniform temperature distribution in mortar panels. The quantity and position of paraffin have significant effects on the thermal response of the mortal panels. A higher paraffin content results in a significantly longer temperature lag and a lower temperature during the phase transition of paraffin. Furthermore, placing the paraffin away from the heating face can cause a longer temperature lag on the other face, which is desirable for building façade applications.

This study investigates the mechanical properties of cementitious composites with 3D-printed auxetic lattices, featuring negative Poisson’s ratios (auxetic behavior) in multiple directions. These lattices were fabricated using vat photopolymerization 3D printing, and three base materials with varying stiffness and deformation capacities were analyzed to determine their impact on the composites’ mechanical behavior. To unravel the reinforcing mechanisms of multidirectional auxetic lattices, which exhibit auxetic behavior in both planar and out-of-plane directions, X-ray computed tomography (X-ray CT) was utilized to analyze composite damage evolutions under different strain levels. The micro-CT characterization reveals that auxetic lattices more effectively constrain crack growth and dissipate energy by distributing stress evenly within the cement matrix. In contrast, due to lack of lateral confinement, the non-auxetic lattice reinforced composites primarily dissipate energy through extensive crack propagation and interfacial damage, leading to lower peak strength. When strain exceeding 5%, although the confinement from the auxetic behavior diminished with crack propagation, the lattice can still maintain the composite’s structural integrity, resulting in 1.7 times higher densification energy than conventional cement-based materials. These findings provide valuable insights for designing auxetic lattice-reinforced cementitious composites with enhanced load-bearing capacity and improved dissipation capabilities.