• Energy Research

Photosynthetic microbial fuel cells (pMFCs) are hybrid systems that enable simultaneous wastewater treatment under anaerobic conditions and the generation of electricity by utilizing the potential difference in the anaerobic anode chamber and the oxygenated cathode chamber. Dairy wastewater with a concentration of 2000 mg COD/L was treated in the anode of a batch pMFC. In the cathode chamber, Chlorella vulgaris or Arthrospira platensis was cultivated in synthetic medium, and next in diluted effluent from the anode chamber. The highest power density of 91 mW/m2 was generated by the pMFC with the cultivation of Arthrospira platensis. Higher values of dissolved oxygen remained during the dark phase in the cathodic medium with Arthrospira platensis cultivation than with Chlorella vulgaris. This depletion of oxygen significantly decreased voltage generation, which during the light phase increased again to the maximum values. The COD removal achieved in the anodic chamber was 87%. The efficiency of nitrogen removal in the cathode chamber during the cultivation of Arthrospira platensis and Chlorella vulgaris was about 78% and 69%, respectively. The efficiency of phosphorus removal in the cathode chamber with the cultivation of Arthrospira plantensis and Chlorella vulgaris was 58% and 43%, respectively. This study has shown that the introduction of Arthrospira platensis into the cathode chamber is more effective than that of Chlorella vulgaris.

The conversion of chemical energy contained in organic matter into electricity has become an object of interest for many scientists worldwide. This technology is used in microbial fuel cells (MFC). Apart from generating electrical energy, these cells can be used simultaneously for wastewater treatment. Although the technology is constantly being improved, currently functioning microbial fuel cells cannot provide appropriate output parameters to use on an industrial scale. One of the barriers is so-called extracellular electron transfer, which in turn depends on the electrode type used, its material, shape, and size. According to current literature, carbon, graphite, stainless steel, and ceramics are the most frequently used electrode materials. However, more and more often, scientists are turning to other, unusual materials, the production of which uses the newest technologies, and one of them is graphene. This material is modified in different ways and connected with other materials, and the results of this seem to be very promising. Scientists manage to get a higher level of extracellular electron transfer and, hence, higher output parameters of the whole system. This article describes chosen technologies and attempts made by scientists worldwide to use graphene in MFC and their results.