Aroa R. Mainar; Aroa R. Mainar
Harvested from ORCID Public Data FileAroa R. Mainar in OpenAIRE Elena Iruin; Elena Iruin
Harvested from ORCID Public Data FileElena Iruin in OpenAIRE Jose Alberto Blázquez; Jose Alberto Blázquez
Harvested from ORCID Public Data FileJose Alberto Blázquez in OpenAIREThe integration of energy storage systems into intermittent renewable energy sources in power grids ensures the continuity of the energy supply in a balanced and efficient way. Novel rechargeable zinc ion and zinc hybrid aqueous technologies constitute paradigmatic examples of promising alternative energy storage systems for large‐scale applications, due to their intrinsic low cost, environmental friendliness, safety, high power density, and ease of operation. This work evaluates the performance improvement of zinc/LiFePO4 and zinc/LiMn2O4 batteries through the incorporation of an alternative chloride‐based electrolyte formulation inspired in Leclanché battery technology and also, in recently reported secondary zinc–air batteries. The use of this alternative electrolyte shows an increased working voltage and improves capacity retention for both zinc/LiFePO4 and zinc/LiMn2O4 batteries. This work analyses for the first time the specific energy of zinc‐based hybrid aqueous batteries in a functional cell, by means of the incorporation of light zinc anode and Li+‐based cathode which comprises superior active material loading. This approach demonstrates the feasibility of reversible zinc‐based hybrid aqueous batteries with more than 90 W h kg−1Active materials as to 13 W h kg−1Active materials of the baseline technology.
8 citations 8 popularity Top 10% influence Average impulse Top 10% 
Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/ente.202000476&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu- Aroa R. Mainar;
Aroa R. Mainar
Harvested from ORCID Public Data FileAroa R. Mainar in OpenAIRE Elena Iruin; Elena Iruin
Harvested from ORCID Public Data FileElena Iruin in OpenAIRE Jose Alberto Blázquez; Jose Alberto Blázquez
Harvested from ORCID Public Data FileJose Alberto Blázquez in OpenAIREThe integration of energy storage systems into intermittent renewable energy sources in power grids ensures the continuity of the energy supply in a balanced and efficient way. Novel rechargeable zinc ion and zinc hybrid aqueous technologies constitute paradigmatic examples of promising alternative energy storage systems for large‐scale applications, due to their intrinsic low cost, environmental friendliness, safety, high power density, and ease of operation. This work evaluates the performance improvement of zinc/LiFePO4 and zinc/LiMn2O4 batteries through the incorporation of an alternative chloride‐based electrolyte formulation inspired in Leclanché battery technology and also, in recently reported secondary zinc–air batteries. The use of this alternative electrolyte shows an increased working voltage and improves capacity retention for both zinc/LiFePO4 and zinc/LiMn2O4 batteries. This work analyses for the first time the specific energy of zinc‐based hybrid aqueous batteries in a functional cell, by means of the incorporation of light zinc anode and Li+‐based cathode which comprises superior active material loading. This approach demonstrates the feasibility of reversible zinc‐based hybrid aqueous batteries with more than 90 W h kg−1Active materials as to 13 W h kg−1Active materials of the baseline technology.
8 citations 8 popularity Top 10% influence Average impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/ente.202000476&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - EC| ZABCATAroa R. Mainar; Elena Iruin; Idoia Urdampilleta; Hans-Jürgen Grande; J. Alberto Blázquez;
J. Alberto Blázquez
Harvested from ORCID Public Data FileJ. Alberto Blázquez in OpenAIREAccess Routeshybrid 6 citations 6 popularity Average influence Average impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.apenergy.2023.122049&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - EC| ZABCATAroa R. Mainar; Elena Iruin; Idoia Urdampilleta; Hans-Jürgen Grande; J. Alberto Blázquez;
J. Alberto Blázquez
Harvested from ORCID Public Data FileJ. Alberto Blázquez in OpenAIREAccess Routeshybrid 6 citations 6 popularity Average influence Average impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.apenergy.2023.122049&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - Blazquez, J. Alberto;
Blazquez, J. Alberto
Harvested from ORCID Public Data FileBlazquez, J. Alberto in OpenAIRE Iruin, Juan J.; Eceolaza, Sorkunde; Marestin, Catherine; +5 AuthorsIruin, Juan J.
Harvested from ORCID Public Data FileIruin, Juan J. in OpenAIRE Blazquez, J. Alberto; Blazquez, J. Alberto
Harvested from ORCID Public Data FileBlazquez, J. Alberto in OpenAIRE Iruin, Juan J.; Eceolaza, Sorkunde; Marestin, Catherine; Mercier, Régis;Iruin, Juan J.
Harvested from ORCID Public Data FileIruin, Juan J. in OpenAIRE Mecerreyes, David; Miguel, Oscar; Vela, Ana;Mecerreyes, David
Harvested from ORCID Public Data FileMecerreyes, David in OpenAIRE Marcilla, Rebeca; Marcilla, Rebeca
Harvested from ORCID Public Data FileMarcilla, Rebeca in OpenAIREAbstract A series of new sequenced sulfonated naphthalenic polyimides were synthesized containing a flexible aromatic–aliphatic diamine. The obtained membranes present the advantage of being soluble in N -methyl pyrrolidone (NMP) which is a less toxic solvent than the previously used m -cresol. In this work, we report on the solvent and acidification method effects on the properties of the membranes such as density, water uptake, proton conductivity as well as on the performance of these membranes in fuel cell operation. The membranes prepared from NMP solution and acidified with ion-exchange resins give the best results. They have good mechanical properties as well as high ionic conductivity (14.4 × 10 −2 S cm −1 at 80 °C) and good performances as proton exchange membrane (PEM) in fuel cell at 70 °C.
9 citations 9 popularity Average influence Average impulse Average Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.jpowsour.2005.02.082&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - Blazquez, J. Alberto;
Blazquez, J. Alberto
Harvested from ORCID Public Data FileBlazquez, J. Alberto in OpenAIRE Iruin, Juan J.; Eceolaza, Sorkunde; Marestin, Catherine; +5 AuthorsIruin, Juan J.
Harvested from ORCID Public Data FileIruin, Juan J. in OpenAIRE Blazquez, J. Alberto; Blazquez, J. Alberto
Harvested from ORCID Public Data FileBlazquez, J. Alberto in OpenAIRE Iruin, Juan J.; Eceolaza, Sorkunde; Marestin, Catherine; Mercier, Régis;Iruin, Juan J.
Harvested from ORCID Public Data FileIruin, Juan J. in OpenAIRE Mecerreyes, David; Miguel, Oscar; Vela, Ana;Mecerreyes, David
Harvested from ORCID Public Data FileMecerreyes, David in OpenAIRE Marcilla, Rebeca; Marcilla, Rebeca
Harvested from ORCID Public Data FileMarcilla, Rebeca in OpenAIREAbstract A series of new sequenced sulfonated naphthalenic polyimides were synthesized containing a flexible aromatic–aliphatic diamine. The obtained membranes present the advantage of being soluble in N -methyl pyrrolidone (NMP) which is a less toxic solvent than the previously used m -cresol. In this work, we report on the solvent and acidification method effects on the properties of the membranes such as density, water uptake, proton conductivity as well as on the performance of these membranes in fuel cell operation. The membranes prepared from NMP solution and acidified with ion-exchange resins give the best results. They have good mechanical properties as well as high ionic conductivity (14.4 × 10 −2 S cm −1 at 80 °C) and good performances as proton exchange membrane (PEM) in fuel cell at 70 °C.
9 citations 9 popularity Average influence Average impulse Average Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.jpowsour.2005.02.082&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - EC| MAT4BAT Andriy Kvasha; Idoia Urdampilleta;
Andriy Kvasha
Harvested from ORCID Public Data FileAndriy Kvasha in OpenAIRE Iratxe De Meatza; Roberta Colombo; +7 AuthorsIratxe De Meatza
Harvested from ORCID Public Data FileIratxe De Meatza in OpenAIRE Andriy Kvasha; Idoia Urdampilleta;Andriy Kvasha
Harvested from ORCID Public Data FileAndriy Kvasha in OpenAIRE Iratxe De Meatza; Roberta Colombo; Pirmin Ulmann; Michal Gulas; Cesar Gutierrez; Miguel Bengoechea;Iratxe De Meatza
Harvested from ORCID Public Data FileIratxe De Meatza in OpenAIRE Jose Alberto Blazquez; Oscar Miguel; Hans-Jurgen Grande;Jose Alberto Blazquez
Harvested from ORCID Public Data FileJose Alberto Blazquez in OpenAIREThe current lithium ion battery (LIB) technology has reached a very high degree of development and market share [1, 2]. However, several important bottlenecks still impede further spreading of lithium ion batteries into the EV market [2, 3]. Among them, their relatively high price and negative environmental impact have been addressed in this work. In particular, at the electrode manufacturing stage, the replacement of toxic and expensive N-Methyl-2-pyrrolidone (NMP) solvent by water is considered an innovative and promising approach to reduce both the environmental impact and the final price of the batteries [4] without sacrificing electrochemical performance [5]. Here, we report the development of a large format LiNixMnyCozO2 (NMC) - Graphite (C) pouch cell, with both electrodes prepared via aqueous processes using waterborne binders. The NMC-Graphite electrochemical system was chosen because it is considered as one of the most promising combinations for large format batteries for EV applications, in which both active materials are compatible with aqueous binders [6]. The positive electrode was composed of a commercial NMC (111) material. The negative electrode was prepared on the basis of C-NERGY™ ACTILION_1 graphite (IMERYS Graphite & Carbon) specially developed for better processability in aqueous slurries. Waterborne PVdF latexes (SOLVAY SPECIALTY POLYMERS ITALY) have been used as binders for both electrodes. Commercially available sodium carboxymethyl cellulose has been used as a dispersant for negative and positive electrode slurries. The formulation and design of the positive and negative electrodes was tailored to meet the MAT4BAT European project tasks and cell specifications. The negative and positive electrode slurries with elaborated formulations have been successfully scaled up to 3 and 6 kg, respectively. Then, more than 100 metres length double-side coated electrode rolls have been manufactured on a coating pilot line. Finally, several NMC/Graphite pouch cells with a stack design were assembled on automated pilot equipment. As shown in Figure 1, the manufactured NMC/C pouch cell with nominal capacity 17 Ah has demonstrated promising C-rate capability and stable long term cyclability with no negative influence of the aqueous processing. It should be noted that obtained specific energy density of 143 Wh/kg (@ 0.2C discharge) is very close to the commercial benchmark as defined within the MAT4BAT EU project. Thus, presented results allow for the conclusion that aqueous processing is a successful approach for manufacturing large format NMC-Graphite lithium ion cells for EV applications. The study has been performed within the MAT4BAT project funded by the European Community's Seventh Framework Programme (FP7/2007-2013) under grant agreement #608931. We would like to acknowledge Celaya, Emparanza y Galdós Internacional S.A. for the manufacturing of the NMC/C pouch cells. References: EUROBAT E-mobility Battery R&D Roadmap 2030, http://www.eurobat.org/sites/default/files/eurobat_emobility_roadmap_lores_2.pdf LUX Research press release: http://www.marketwired.com/press-release/next-generation-batteries-beyond-li-ion-will-be-worth-10-billion-in-2030-2078054.htm R Van Noorden, Nature 507 (7490) 26-28. D.L. Wood et al., J. Power Sources, 275 (2015) 234-242. A. Kvasha et al., C-LiFePO4 / Graphite pouch cell based on aqueous processed electrodes (P-064), in: Proceedings of the 8th International Conference on Advanced Lithium Batteries for Automobile Applications; 2015, Sept. 30 – Oct. 2; Bilbao (Spain), p. 115. N. Loeffler et al., J. Power Sources, 248 (2014) 915-922. Figure 1
5 citations 5 popularity Top 10% influence Average impulse Average Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1149/ma2016-03/2/1206&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - EC| MAT4BAT Andriy Kvasha; Idoia Urdampilleta;
Andriy Kvasha
Harvested from ORCID Public Data FileAndriy Kvasha in OpenAIRE Iratxe De Meatza; Roberta Colombo; +7 AuthorsIratxe De Meatza
Harvested from ORCID Public Data FileIratxe De Meatza in OpenAIRE Andriy Kvasha; Idoia Urdampilleta;Andriy Kvasha
Harvested from ORCID Public Data FileAndriy Kvasha in OpenAIRE Iratxe De Meatza; Roberta Colombo; Pirmin Ulmann; Michal Gulas; Cesar Gutierrez; Miguel Bengoechea;Iratxe De Meatza
Harvested from ORCID Public Data FileIratxe De Meatza in OpenAIRE Jose Alberto Blazquez; Oscar Miguel; Hans-Jurgen Grande;Jose Alberto Blazquez
Harvested from ORCID Public Data FileJose Alberto Blazquez in OpenAIREThe current lithium ion battery (LIB) technology has reached a very high degree of development and market share [1, 2]. However, several important bottlenecks still impede further spreading of lithium ion batteries into the EV market [2, 3]. Among them, their relatively high price and negative environmental impact have been addressed in this work. In particular, at the electrode manufacturing stage, the replacement of toxic and expensive N-Methyl-2-pyrrolidone (NMP) solvent by water is considered an innovative and promising approach to reduce both the environmental impact and the final price of the batteries [4] without sacrificing electrochemical performance [5]. Here, we report the development of a large format LiNixMnyCozO2 (NMC) - Graphite (C) pouch cell, with both electrodes prepared via aqueous processes using waterborne binders. The NMC-Graphite electrochemical system was chosen because it is considered as one of the most promising combinations for large format batteries for EV applications, in which both active materials are compatible with aqueous binders [6]. The positive electrode was composed of a commercial NMC (111) material. The negative electrode was prepared on the basis of C-NERGY™ ACTILION_1 graphite (IMERYS Graphite & Carbon) specially developed for better processability in aqueous slurries. Waterborne PVdF latexes (SOLVAY SPECIALTY POLYMERS ITALY) have been used as binders for both electrodes. Commercially available sodium carboxymethyl cellulose has been used as a dispersant for negative and positive electrode slurries. The formulation and design of the positive and negative electrodes was tailored to meet the MAT4BAT European project tasks and cell specifications. The negative and positive electrode slurries with elaborated formulations have been successfully scaled up to 3 and 6 kg, respectively. Then, more than 100 metres length double-side coated electrode rolls have been manufactured on a coating pilot line. Finally, several NMC/Graphite pouch cells with a stack design were assembled on automated pilot equipment. As shown in Figure 1, the manufactured NMC/C pouch cell with nominal capacity 17 Ah has demonstrated promising C-rate capability and stable long term cyclability with no negative influence of the aqueous processing. It should be noted that obtained specific energy density of 143 Wh/kg (@ 0.2C discharge) is very close to the commercial benchmark as defined within the MAT4BAT EU project. Thus, presented results allow for the conclusion that aqueous processing is a successful approach for manufacturing large format NMC-Graphite lithium ion cells for EV applications. The study has been performed within the MAT4BAT project funded by the European Community's Seventh Framework Programme (FP7/2007-2013) under grant agreement #608931. We would like to acknowledge Celaya, Emparanza y Galdós Internacional S.A. for the manufacturing of the NMC/C pouch cells. References: EUROBAT E-mobility Battery R&D Roadmap 2030, http://www.eurobat.org/sites/default/files/eurobat_emobility_roadmap_lores_2.pdf LUX Research press release: http://www.marketwired.com/press-release/next-generation-batteries-beyond-li-ion-will-be-worth-10-billion-in-2030-2078054.htm R Van Noorden, Nature 507 (7490) 26-28. D.L. Wood et al., J. Power Sources, 275 (2015) 234-242. A. Kvasha et al., C-LiFePO4 / Graphite pouch cell based on aqueous processed electrodes (P-064), in: Proceedings of the 8th International Conference on Advanced Lithium Batteries for Automobile Applications; 2015, Sept. 30 – Oct. 2; Bilbao (Spain), p. 115. N. Loeffler et al., J. Power Sources, 248 (2014) 915-922. Figure 1
5 citations 5 popularity Top 10% influence Average impulse Average Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1149/ma2016-03/2/1206&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - EC| E-MAGIC Blázquez, J. Alberto; Maça, Rudi R.;
Blázquez, J. Alberto
Harvested from ORCID Public Data FileBlázquez, J. Alberto in OpenAIRE Leonet, Olatz; Azaceta, Eneko; +27 AuthorsLeonet, Olatz
Harvested from ORCID Public Data FileLeonet, Olatz in OpenAIRE Blázquez, J. Alberto; Maça, Rudi R.;Blázquez, J. Alberto
Harvested from ORCID Public Data FileBlázquez, J. Alberto in OpenAIRE Leonet, Olatz; Azaceta, Eneko;Leonet, Olatz
Harvested from ORCID Public Data FileLeonet, Olatz in OpenAIRE Mukherjee, Ayan; Mukherjee, Ayan
Harvested from ORCID Public Data FileMukherjee, Ayan in OpenAIRE Zhao-Karger, Zhirong; Zhao-Karger, Zhirong
Harvested from ORCID Public Data FileZhao-Karger, Zhirong in OpenAIRE Li, Zhenyou; Kovalevsky, Aleksey;Li, Zhenyou
Harvested from ORCID Public Data FileLi, Zhenyou in OpenAIRE Fernández-Barquín, Ana; Fernández-Barquín, Ana
Harvested from ORCID Public Data FileFernández-Barquín, Ana in OpenAIRE Mainar, Aroa R.; Mainar, Aroa R.
Harvested from ORCID Public Data FileMainar, Aroa R. in OpenAIRE Jankowski, Piotr; Rademacher, Laurin;Jankowski, Piotr
Harvested from ORCID Public Data FileJankowski, Piotr in OpenAIRE Dey, Sunita; Dey, Sunita
Harvested from ORCID Public Data FileDey, Sunita in OpenAIRE
Dutton, Siân E.; Dutton, Siân E.
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesDutton, Siân E. in OpenAIRE Grey, Clare P.; Drews, J.;Grey, Clare P.
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesGrey, Clare P. in OpenAIRE Drews, Janina; Drews, Janina
Harvested from ORCID Public Data FileDrews, Janina in OpenAIRE Häcker, Joachim; Häcker, Joachim
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesHäcker, Joachim in OpenAIRE Danner, Timo; Danner, Timo
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesDanner, Timo in OpenAIRE Latz, Arnulf; Latz, Arnulf
Harvested from ORCID Public Data FileLatz, Arnulf in OpenAIRE Sotta, Dane; Palacin, M. R.;Sotta, Dane
Harvested from ORCID Public Data FileSotta, Dane in OpenAIRE Palacin, M. Rosa; Martin, Jean-Frédéric;Palacin, M. Rosa
Harvested from ORCID Public Data FilePalacin, M. Rosa in OpenAIRE Lastra, Juan Maria García; Lastra, Juan Maria García
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesLastra, Juan Maria García in OpenAIRE Fichtner, Maximilian; Fichtner, Maximilian
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesFichtner, Maximilian in OpenAIRE Kundu, Sumana; Kraytsberg, Alexander; Ein-Eli, Yair;Kundu, Sumana
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesKundu, Sumana in OpenAIRE Noked, Malachi; Noked, Malachi
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesNoked, Malachi in OpenAIRE Aurbach, Doron; Aurbach, Doron
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesAurbach, Doron in OpenAIREEmerging energy storage systems based on abundant and cost-effective materials are key to overcome the global energy and climate crisis of the 21st century.
Access RoutesGreen hybrid 45 citations 45 popularity Top 10% influence Top 10% impulse Top 1% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d2ee04121a&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - EC| E-MAGIC Blázquez, J. Alberto; Maça, Rudi R.;
Blázquez, J. Alberto
Harvested from ORCID Public Data FileBlázquez, J. Alberto in OpenAIRE Leonet, Olatz; Azaceta, Eneko; +27 AuthorsLeonet, Olatz
Harvested from ORCID Public Data FileLeonet, Olatz in OpenAIRE Blázquez, J. Alberto; Maça, Rudi R.;Blázquez, J. Alberto
Harvested from ORCID Public Data FileBlázquez, J. Alberto in OpenAIRE Leonet, Olatz; Azaceta, Eneko;Leonet, Olatz
Harvested from ORCID Public Data FileLeonet, Olatz in OpenAIRE Mukherjee, Ayan; Mukherjee, Ayan
Harvested from ORCID Public Data FileMukherjee, Ayan in OpenAIRE Zhao-Karger, Zhirong; Zhao-Karger, Zhirong
Harvested from ORCID Public Data FileZhao-Karger, Zhirong in OpenAIRE Li, Zhenyou; Kovalevsky, Aleksey;Li, Zhenyou
Harvested from ORCID Public Data FileLi, Zhenyou in OpenAIRE Fernández-Barquín, Ana; Fernández-Barquín, Ana
Harvested from ORCID Public Data FileFernández-Barquín, Ana in OpenAIRE Mainar, Aroa R.; Mainar, Aroa R.
Harvested from ORCID Public Data FileMainar, Aroa R. in OpenAIRE Jankowski, Piotr; Rademacher, Laurin;Jankowski, Piotr
Harvested from ORCID Public Data FileJankowski, Piotr in OpenAIRE Dey, Sunita; Dey, Sunita
Harvested from ORCID Public Data FileDey, Sunita in OpenAIRE Dutton, Siân E.; Dutton, Siân E.
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesDutton, Siân E. in OpenAIRE Grey, Clare P.; Drews, J.;Grey, Clare P.
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesGrey, Clare P. in OpenAIRE Drews, Janina; Drews, Janina
Harvested from ORCID Public Data FileDrews, Janina in OpenAIRE Häcker, Joachim; Häcker, Joachim
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesHäcker, Joachim in OpenAIRE Danner, Timo; Danner, Timo
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesDanner, Timo in OpenAIRE Latz, Arnulf; Latz, Arnulf
Harvested from ORCID Public Data FileLatz, Arnulf in OpenAIRE Sotta, Dane; Palacin, M. R.;Sotta, Dane
Harvested from ORCID Public Data FileSotta, Dane in OpenAIRE Palacin, M. Rosa; Martin, Jean-Frédéric;Palacin, M. Rosa
Harvested from ORCID Public Data FilePalacin, M. Rosa in OpenAIRE Lastra, Juan Maria García; Lastra, Juan Maria García
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesLastra, Juan Maria García in OpenAIRE Fichtner, Maximilian; Fichtner, Maximilian
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesFichtner, Maximilian in OpenAIRE Kundu, Sumana; Kraytsberg, Alexander; Ein-Eli, Yair;Kundu, Sumana
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesKundu, Sumana in OpenAIRE Noked, Malachi; Noked, Malachi
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesNoked, Malachi in OpenAIRE Aurbach, Doron; Aurbach, Doron
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesAurbach, Doron in OpenAIREEmerging energy storage systems based on abundant and cost-effective materials are key to overcome the global energy and climate crisis of the 21st century.
Access RoutesGreen hybrid 45 citations 45 popularity Top 10% influence Top 10% impulse Top 1% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1039/d2ee04121a&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - EC| ZAS Aroa R. Mainar;
Aroa R. Mainar
Harvested from ORCID Public Data FileAroa R. Mainar in OpenAIRE Elena Iruin; Elena Iruin
Harvested from ORCID Public Data FileElena Iruin in OpenAIRE Luis C. Colmenares; Luis C. Colmenares
Harvested from ORCID Public Data FileLuis C. Colmenares in OpenAIRE J. Alberto Blázquez; +1 AuthorsJ. Alberto Blázquez
Harvested from ORCID Public Data FileJ. Alberto Blázquez in OpenAIRE Aroa R. Mainar; Aroa R. Mainar
Harvested from ORCID Public Data FileAroa R. Mainar in OpenAIRE Elena Iruin; Elena Iruin
Harvested from ORCID Public Data FileElena Iruin in OpenAIRE Luis C. Colmenares; Luis C. Colmenares
Harvested from ORCID Public Data FileLuis C. Colmenares in OpenAIRE J. Alberto Blázquez; Hans‐Jürgen Grande;J. Alberto Blázquez
Harvested from ORCID Public Data FileJ. Alberto Blázquez in OpenAIREAbstractDevelopment of secondary zinc–air batteries goes through a proper specification of the electrolyte formulation adapted to extend the cycle life of the battery. However, defining an optimal formulation is not a trivial work due to the specific requirements for each electrode. At half‐cell level, it has been determined that ZnO‐saturated 4 mol L−1 KOH with 2 mol L−1 KF and 2 mol L−1 K2CO3 (4s‐2) is the most suitable formulation to increase the cycle life of secondary zinc electrode, whereas additive‐free 8 mol L−1 KOH (8‐0) formulation is more beneficial for the bifunctional air electrode (BAE). Through this systematic cycle life assessment, it has been found that the most suitable electrolyte formulation for the full cell system is a compendium for both electrodes requirements. It has determined an optimal electrolyte formulation for the full system consisting of ZnO‐saturated 7 mol L−1 KOH with 1.4 mol L−1 KF and 1.4 mol L−1 K2CO3 (7s‐1.4). This electrolyte composition increases at least 2.5 times the reversibility of the secondary zinc–air battery in comparison with that employing the traditional formulation for primary zinc–air batteries (additive‐free 8 mol L−1 KOH). In addition, the development of a proper cell design or separator is also necessary to further enhance the secondary zinc–air cycle life.
Access RoutesGreen gold 45 citations 45 popularity Top 10% influence Top 10% impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/ese3.191&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - EC| ZAS Aroa R. Mainar;
Aroa R. Mainar
Harvested from ORCID Public Data FileAroa R. Mainar in OpenAIRE Elena Iruin; Elena Iruin
Harvested from ORCID Public Data FileElena Iruin in OpenAIRE Luis C. Colmenares; Luis C. Colmenares
Harvested from ORCID Public Data FileLuis C. Colmenares in OpenAIRE J. Alberto Blázquez; +1 AuthorsJ. Alberto Blázquez
Harvested from ORCID Public Data FileJ. Alberto Blázquez in OpenAIRE Aroa R. Mainar; Aroa R. Mainar
Harvested from ORCID Public Data FileAroa R. Mainar in OpenAIRE Elena Iruin; Elena Iruin
Harvested from ORCID Public Data FileElena Iruin in OpenAIRE Luis C. Colmenares; Luis C. Colmenares
Harvested from ORCID Public Data FileLuis C. Colmenares in OpenAIRE J. Alberto Blázquez; Hans‐Jürgen Grande;J. Alberto Blázquez
Harvested from ORCID Public Data FileJ. Alberto Blázquez in OpenAIREAbstractDevelopment of secondary zinc–air batteries goes through a proper specification of the electrolyte formulation adapted to extend the cycle life of the battery. However, defining an optimal formulation is not a trivial work due to the specific requirements for each electrode. At half‐cell level, it has been determined that ZnO‐saturated 4 mol L−1 KOH with 2 mol L−1 KF and 2 mol L−1 K2CO3 (4s‐2) is the most suitable formulation to increase the cycle life of secondary zinc electrode, whereas additive‐free 8 mol L−1 KOH (8‐0) formulation is more beneficial for the bifunctional air electrode (BAE). Through this systematic cycle life assessment, it has been found that the most suitable electrolyte formulation for the full cell system is a compendium for both electrodes requirements. It has determined an optimal electrolyte formulation for the full system consisting of ZnO‐saturated 7 mol L−1 KOH with 1.4 mol L−1 KF and 1.4 mol L−1 K2CO3 (7s‐1.4). This electrolyte composition increases at least 2.5 times the reversibility of the secondary zinc–air battery in comparison with that employing the traditional formulation for primary zinc–air batteries (additive‐free 8 mol L−1 KOH). In addition, the development of a proper cell design or separator is also necessary to further enhance the secondary zinc–air cycle life.
Access RoutesGreen gold 45 citations 45 popularity Top 10% influence Top 10% impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/ese3.191&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - Andriy Kvasha; César Gutiérrez; Urtzi Osa;
Andriy Kvasha
Harvested from ORCID Public Data FileAndriy Kvasha in OpenAIRE Iratxe de Meatza; +3 AuthorsIratxe de Meatza
Harvested from ORCID Public Data FileIratxe de Meatza in OpenAIRE Andriy Kvasha; César Gutiérrez; Urtzi Osa;Andriy Kvasha
Harvested from ORCID Public Data FileAndriy Kvasha in OpenAIRE Iratxe de Meatza; Iratxe de Meatza
Harvested from ORCID Public Data FileIratxe de Meatza in OpenAIRE J. Alberto Blazquez; Haritz Macicior; Idoia Urdampilleta;J. Alberto Blazquez
Harvested from ORCID Public Data FileJ. Alberto Blazquez in OpenAIREAbstract Thermal runaway of three lithium ion cells (“A” - NCA/Graphite, “B” - LFP/Graphite, “C” - NCA/LTO) at 0%, 50%, and 100% state of charge (SOC) is studied by Accelerating Rate Calorimetry (ARC). Thermal behaviour of harvested positive and negative electrodes at three SOC (0%, 50%, and 100%) is analyzed using Differential Scanning Calorimetry (DSC). Thermal stability of recovered separators is also investigated by DSC. Harvested electrodes and separators are studied alone and in contact with a liquid electrolyte. The thermal behaviour of each component and its contribution is quantified and thoroughly discussed. A crucial negative impact of the state of charge and presence of highly flammable liquid electrolyte on the thermal instability of the investigated cells and “electrode - electrolyte” systems is clearly revealed. Among studied cells, LiFePO4/Graphite one is the safest due to intrinsic thermal stability of lithium iron phosphate LiFePO4 based cathode and despite the fact of using a microporous polyolefin separator with limited thermal stability.
113 citations 113 popularity Top 1% influence Top 10% impulse Top 1% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.energy.2018.06.173&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - Andriy Kvasha; César Gutiérrez; Urtzi Osa;
Andriy Kvasha
Harvested from ORCID Public Data FileAndriy Kvasha in OpenAIRE Iratxe de Meatza; +3 AuthorsIratxe de Meatza
Harvested from ORCID Public Data FileIratxe de Meatza in OpenAIRE Andriy Kvasha; César Gutiérrez; Urtzi Osa;Andriy Kvasha
Harvested from ORCID Public Data FileAndriy Kvasha in OpenAIRE Iratxe de Meatza; Iratxe de Meatza
Harvested from ORCID Public Data FileIratxe de Meatza in OpenAIRE J. Alberto Blazquez; Haritz Macicior; Idoia Urdampilleta;J. Alberto Blazquez
Harvested from ORCID Public Data FileJ. Alberto Blazquez in OpenAIREAbstract Thermal runaway of three lithium ion cells (“A” - NCA/Graphite, “B” - LFP/Graphite, “C” - NCA/LTO) at 0%, 50%, and 100% state of charge (SOC) is studied by Accelerating Rate Calorimetry (ARC). Thermal behaviour of harvested positive and negative electrodes at three SOC (0%, 50%, and 100%) is analyzed using Differential Scanning Calorimetry (DSC). Thermal stability of recovered separators is also investigated by DSC. Harvested electrodes and separators are studied alone and in contact with a liquid electrolyte. The thermal behaviour of each component and its contribution is quantified and thoroughly discussed. A crucial negative impact of the state of charge and presence of highly flammable liquid electrolyte on the thermal instability of the investigated cells and “electrode - electrolyte” systems is clearly revealed. Among studied cells, LiFePO4/Graphite one is the safest due to intrinsic thermal stability of lithium iron phosphate LiFePO4 based cathode and despite the fact of using a microporous polyolefin separator with limited thermal stability.
113 citations 113 popularity Top 1% influence Top 10% impulse Top 1% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.energy.2018.06.173&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - UKRI| Zinc Ion Batteries: Structural ENgineering for Severe Environment (SENSE) ,EC| POLYSTORAGE ,EC| E-MAGIC M Rosa Palacin;
M Rosa Palacin
Harvested from ORCID Public Data FileM Rosa Palacin in OpenAIRE Patrik Johansson; Patrik Johansson
Harvested from ORCID Public Data FilePatrik Johansson in OpenAIRE Robert Dominko; Ben Dlugatch; +37 AuthorsRobert Dominko
Harvested from ORCID Public Data FileRobert Dominko in OpenAIRE M Rosa Palacin; M Rosa Palacin
Harvested from ORCID Public Data FileM Rosa Palacin in OpenAIRE Patrik Johansson; Patrik Johansson
Harvested from ORCID Public Data FilePatrik Johansson in OpenAIRE Robert Dominko; Ben Dlugatch; Doron Aurbach;Robert Dominko
Harvested from ORCID Public Data FileRobert Dominko in OpenAIRE Zhenyou Li; Maximilian Fichtner;Zhenyou Li
Harvested from ORCID Public Data FileZhenyou Li in OpenAIRE Olivera Lužanin; Jan Bitenc;Olivera Lužanin
Harvested from ORCID Public Data FileOlivera Lužanin in OpenAIRE Zhixuan Wei; Zhixuan Wei
Harvested from ORCID Public Data FileZhixuan Wei in OpenAIRE Clarissa Glaser; Jürgen Janek; Ana Fernández-Barquín; Aroa R Mainar; Olatz Leonet; Idoia Urdampilleta;Clarissa Glaser
Harvested from ORCID Public Data FileClarissa Glaser in OpenAIRE J Alberto Blázquez; J Alberto Blázquez
Harvested from ORCID Public Data FileJ Alberto Blázquez in OpenAIRE Deyana S Tchitchekova; Deyana S Tchitchekova
Harvested from ORCID Public Data FileDeyana S Tchitchekova in OpenAIRE Alexandre Ponrouch; Pieremanuele Canepa; Gopalakrishnan Sai Gautam; Raúl San Román Gallego Casilda;Alexandre Ponrouch
Harvested from ORCID Public Data FileAlexandre Ponrouch in OpenAIRE Cynthia S Martinez-Cisneros; Nieves Ureña Torres; Alejandro Varez; Jean-Yves Sanchez; Kostiantyn V Kravchyk; Maksym V Kovalenko; Anastasia A Teck; Huw Shiel;Cynthia S Martinez-Cisneros
Harvested from ORCID Public Data FileCynthia S Martinez-Cisneros in OpenAIRE Ifan E L Stephens; Ifan E L Stephens
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesIfan E L Stephens in OpenAIRE Mary P Ryan; Eugen Zemlyanushin; Sonia Dsoke; Rebecca Grieco;Mary P Ryan
Harvested from ORCID Public Data FileMary P Ryan in OpenAIRE Nagaraj Patil; Rebeca Marcilla; Xuan Gao;Nagaraj Patil
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesNagaraj Patil in OpenAIRE Claire J Carmalt; Claire J Carmalt
Harvested from ORCID Public Data FileClaire J Carmalt in OpenAIRE Guanjie He; Guanjie He
Harvested from ORCID Public Data FileGuanjie He in OpenAIRE Maria-Magdalena Titirici; Maria-Magdalena Titirici
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesMaria-Magdalena Titirici in OpenAIREAbstract Battery technologies based in multivalent charge carriers with ideally two or three electrons transferred per ion exchanged between the electrodes have large promises in raw performance numbers, most often expressed as high energy density, and are also ideally based on raw materials that are widely abundant and less expensive. Yet, these are still globally in their infancy, with some concepts (e.g. Mg metal) being more technologically mature. The challenges to address are derived on one side from the highly polarizing nature of multivalent ions when compared to single valent concepts such as Li+ or Na+ present in Li-ion or Na-ion batteries, and on the other, from the difficulties in achieving efficient metal plating/stripping (which remains the holy grail for lithium). Nonetheless, research performed to date has given some fruits and a clearer view of the challenges ahead. These include technological topics (production of thin and ductile metal foil anodes) but also chemical aspects (electrolytes with high conductivity enabling efficient plating/stripping) or high-capacity cathodes with suitable kinetics (better inorganic hosts for intercalation of such highly polarizable multivalent ions). This roadmap provides an extensive review by experts in the different technologies, which exhibit similarities but also striking differences, of the current state of the art in 2023 and the research directions and strategies currently underway to develop multivalent batteries. The aim is to provide an opinion with respect to the current challenges, potential bottlenecks, and also emerging opportunities for their practical deployment.
Access RoutesGreen gold 9 citations 9 popularity Average influence Average impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1088/2515-7655/ad34fc&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - UKRI| Zinc Ion Batteries: Structural ENgineering for Severe Environment (SENSE) ,EC| POLYSTORAGE ,EC| E-MAGIC M Rosa Palacin;
M Rosa Palacin
Harvested from ORCID Public Data FileM Rosa Palacin in OpenAIRE Patrik Johansson; Patrik Johansson
Harvested from ORCID Public Data FilePatrik Johansson in OpenAIRE Robert Dominko; Ben Dlugatch; +37 AuthorsRobert Dominko
Harvested from ORCID Public Data FileRobert Dominko in OpenAIRE M Rosa Palacin; M Rosa Palacin
Harvested from ORCID Public Data FileM Rosa Palacin in OpenAIRE Patrik Johansson; Patrik Johansson
Harvested from ORCID Public Data FilePatrik Johansson in OpenAIRE Robert Dominko; Ben Dlugatch; Doron Aurbach;Robert Dominko
Harvested from ORCID Public Data FileRobert Dominko in OpenAIRE Zhenyou Li; Maximilian Fichtner;Zhenyou Li
Harvested from ORCID Public Data FileZhenyou Li in OpenAIRE Olivera Lužanin; Jan Bitenc;Olivera Lužanin
Harvested from ORCID Public Data FileOlivera Lužanin in OpenAIRE Zhixuan Wei; Zhixuan Wei
Harvested from ORCID Public Data FileZhixuan Wei in OpenAIRE Clarissa Glaser; Jürgen Janek; Ana Fernández-Barquín; Aroa R Mainar; Olatz Leonet; Idoia Urdampilleta;Clarissa Glaser
Harvested from ORCID Public Data FileClarissa Glaser in OpenAIRE J Alberto Blázquez; J Alberto Blázquez
Harvested from ORCID Public Data FileJ Alberto Blázquez in OpenAIRE Deyana S Tchitchekova; Deyana S Tchitchekova
Harvested from ORCID Public Data FileDeyana S Tchitchekova in OpenAIRE Alexandre Ponrouch; Pieremanuele Canepa; Gopalakrishnan Sai Gautam; Raúl San Román Gallego Casilda;Alexandre Ponrouch
Harvested from ORCID Public Data FileAlexandre Ponrouch in OpenAIRE Cynthia S Martinez-Cisneros; Nieves Ureña Torres; Alejandro Varez; Jean-Yves Sanchez; Kostiantyn V Kravchyk; Maksym V Kovalenko; Anastasia A Teck; Huw Shiel;Cynthia S Martinez-Cisneros
Harvested from ORCID Public Data FileCynthia S Martinez-Cisneros in OpenAIRE Ifan E L Stephens; Ifan E L Stephens
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesIfan E L Stephens in OpenAIRE Mary P Ryan; Eugen Zemlyanushin; Sonia Dsoke; Rebecca Grieco;Mary P Ryan
Harvested from ORCID Public Data FileMary P Ryan in OpenAIRE Nagaraj Patil; Rebeca Marcilla; Xuan Gao;Nagaraj Patil
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesNagaraj Patil in OpenAIRE Claire J Carmalt; Claire J Carmalt
Harvested from ORCID Public Data FileClaire J Carmalt in OpenAIRE Guanjie He; Guanjie He
Harvested from ORCID Public Data FileGuanjie He in OpenAIRE Maria-Magdalena Titirici; Maria-Magdalena Titirici
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesMaria-Magdalena Titirici in OpenAIREAbstract Battery technologies based in multivalent charge carriers with ideally two or three electrons transferred per ion exchanged between the electrodes have large promises in raw performance numbers, most often expressed as high energy density, and are also ideally based on raw materials that are widely abundant and less expensive. Yet, these are still globally in their infancy, with some concepts (e.g. Mg metal) being more technologically mature. The challenges to address are derived on one side from the highly polarizing nature of multivalent ions when compared to single valent concepts such as Li+ or Na+ present in Li-ion or Na-ion batteries, and on the other, from the difficulties in achieving efficient metal plating/stripping (which remains the holy grail for lithium). Nonetheless, research performed to date has given some fruits and a clearer view of the challenges ahead. These include technological topics (production of thin and ductile metal foil anodes) but also chemical aspects (electrolytes with high conductivity enabling efficient plating/stripping) or high-capacity cathodes with suitable kinetics (better inorganic hosts for intercalation of such highly polarizable multivalent ions). This roadmap provides an extensive review by experts in the different technologies, which exhibit similarities but also striking differences, of the current state of the art in 2023 and the research directions and strategies currently underway to develop multivalent batteries. The aim is to provide an opinion with respect to the current challenges, potential bottlenecks, and also emerging opportunities for their practical deployment.
Access RoutesGreen gold 9 citations 9 popularity Average influence Average impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1088/2515-7655/ad34fc&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - Julian Klemens;
Julian Klemens
Harvested from ORCID Public Data FileJulian Klemens in OpenAIRE Ann‐Kathrin Wurba; Ann‐Kathrin Wurba
Harvested from ORCID Public Data FileAnn‐Kathrin Wurba in OpenAIRE David Burger; David Burger
Harvested from ORCID Public Data FileDavid Burger in OpenAIRE Marcus Müller; +11 AuthorsMarcus Müller
Harvested from ORCID Public Data FileMarcus Müller in OpenAIRE Julian Klemens; Julian Klemens
Harvested from ORCID Public Data FileJulian Klemens in OpenAIRE Ann‐Kathrin Wurba; Ann‐Kathrin Wurba
Harvested from ORCID Public Data FileAnn‐Kathrin Wurba in OpenAIRE David Burger; David Burger
Harvested from ORCID Public Data FileDavid Burger in OpenAIRE Marcus Müller; Marcus Müller
Harvested from ORCID Public Data FileMarcus Müller in OpenAIRE Werner Bauer; Werner Bauer
Harvested from ORCID Public Data FileWerner Bauer in OpenAIRE Sebastian Büchele; Sebastian Büchele
Harvested from ORCID Public Data FileSebastian Büchele in OpenAIRE Olatz Leonet; Olatz Leonet
Harvested from ORCID Public Data FileOlatz Leonet in OpenAIRE J. Alberto Blázquez; J. Alberto Blázquez
Harvested from ORCID Public Data FileJ. Alberto Blázquez in OpenAIRE Iker Boyano; Iker Boyano
Harvested from ORCID Public Data FileIker Boyano in OpenAIRE Elixabete Ayerbe; Elixabete Ayerbe
Harvested from ORCID Public Data FileElixabete Ayerbe in OpenAIRE Helmut Ehrenberg; Helmut Ehrenberg
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesHelmut Ehrenberg in OpenAIRE Jürgen Fleischer; Jürgen Fleischer
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesJürgen Fleischer in OpenAIRE Anna Smith; Anna Smith
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesAnna Smith in OpenAIRE Philip Scharfer; Philip Scharfer
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesPhilip Scharfer in OpenAIRE Wilhelm Schabel; Wilhelm Schabel
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesWilhelm Schabel in OpenAIREAbstractSodium‐ion batteries are an emerging technology that is still at an early stage of development. The electrode processing for anode and cathode is expected to be similar to lithium‐ion batteries (drop‐in technology), yet a detailed comparison is not published. There are ongoing questions about the influence of the active materials on processing parameters such as slurry viscosity, coating thicknesses, drying times, and behavior during fast drying. Herein, the expected drying time for the same areal capacity of anodes (graphite vs. hard carbon) and cathodes (lithium iron phosphate vs. Prussian blue analogs) are compared based on respective specific capacities reported in the literature. Estimates are made for the materials’ impact on production speed or dryer length. Within the experimental part, water‐based slurries of the same composition are mixed using different active materials according to identical procedure and the viscosity is compared. When drying at a constant drying rate (0.75 g m−2 s−1), lithium iron phosphate electrodes with different areal capacities (1–3 mAh cm−2) are shown to have the highest adhesion. For high drying rates (3 g m−2 s−1) at constant areal capacity, especially the investigated electrodes based on hard carbon show that no binder migration occurs.
9 citations 9 popularity Average influence Average impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/batt.202300291&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - Julian Klemens;
Julian Klemens
Harvested from ORCID Public Data FileJulian Klemens in OpenAIRE Ann‐Kathrin Wurba; Ann‐Kathrin Wurba
Harvested from ORCID Public Data FileAnn‐Kathrin Wurba in OpenAIRE David Burger; David Burger
Harvested from ORCID Public Data FileDavid Burger in OpenAIRE Marcus Müller; +11 AuthorsMarcus Müller
Harvested from ORCID Public Data FileMarcus Müller in OpenAIRE Julian Klemens; Julian Klemens
Harvested from ORCID Public Data FileJulian Klemens in OpenAIRE Ann‐Kathrin Wurba; Ann‐Kathrin Wurba
Harvested from ORCID Public Data FileAnn‐Kathrin Wurba in OpenAIRE David Burger; David Burger
Harvested from ORCID Public Data FileDavid Burger in OpenAIRE Marcus Müller; Marcus Müller
Harvested from ORCID Public Data FileMarcus Müller in OpenAIRE Werner Bauer; Werner Bauer
Harvested from ORCID Public Data FileWerner Bauer in OpenAIRE Sebastian Büchele; Sebastian Büchele
Harvested from ORCID Public Data FileSebastian Büchele in OpenAIRE Olatz Leonet; Olatz Leonet
Harvested from ORCID Public Data FileOlatz Leonet in OpenAIRE J. Alberto Blázquez; J. Alberto Blázquez
Harvested from ORCID Public Data FileJ. Alberto Blázquez in OpenAIRE Iker Boyano; Iker Boyano
Harvested from ORCID Public Data FileIker Boyano in OpenAIRE Elixabete Ayerbe; Elixabete Ayerbe
Harvested from ORCID Public Data FileElixabete Ayerbe in OpenAIRE Helmut Ehrenberg; Helmut Ehrenberg
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesHelmut Ehrenberg in OpenAIRE Jürgen Fleischer; Jürgen Fleischer
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesJürgen Fleischer in OpenAIRE Anna Smith; Anna Smith
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesAnna Smith in OpenAIRE Philip Scharfer; Philip Scharfer
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesPhilip Scharfer in OpenAIRE Wilhelm Schabel; Wilhelm Schabel
Derived by OpenAIRE algorithms or harvested from 3rd party repositoriesWilhelm Schabel in OpenAIREAbstractSodium‐ion batteries are an emerging technology that is still at an early stage of development. The electrode processing for anode and cathode is expected to be similar to lithium‐ion batteries (drop‐in technology), yet a detailed comparison is not published. There are ongoing questions about the influence of the active materials on processing parameters such as slurry viscosity, coating thicknesses, drying times, and behavior during fast drying. Herein, the expected drying time for the same areal capacity of anodes (graphite vs. hard carbon) and cathodes (lithium iron phosphate vs. Prussian blue analogs) are compared based on respective specific capacities reported in the literature. Estimates are made for the materials’ impact on production speed or dryer length. Within the experimental part, water‐based slurries of the same composition are mixed using different active materials according to identical procedure and the viscosity is compared. When drying at a constant drying rate (0.75 g m−2 s−1), lithium iron phosphate electrodes with different areal capacities (1–3 mAh cm−2) are shown to have the highest adhesion. For high drying rates (3 g m−2 s−1) at constant areal capacity, especially the investigated electrodes based on hard carbon show that no binder migration occurs.
9 citations 9 popularity Average influence Average impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/batt.202300291&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - Sarai García;
Sarai García
Harvested from ORCID Public Data FileSarai García in OpenAIRE Olatz Leonet; Eneko Azaceta;Olatz Leonet
Harvested from ORCID Public Data FileOlatz Leonet in OpenAIRE Iñaki Gómez; +3 AuthorsIñaki Gómez
Harvested from ORCID Public Data FileIñaki Gómez in OpenAIRE Sarai García; Sarai García
Harvested from ORCID Public Data FileSarai García in OpenAIRE Olatz Leonet; Eneko Azaceta;Olatz Leonet
Harvested from ORCID Public Data FileOlatz Leonet in OpenAIRE Iñaki Gómez; Iñaki Gómez
Harvested from ORCID Public Data FileIñaki Gómez in OpenAIRE Antonio Reifs; Antonio Reifs
Harvested from ORCID Public Data FileAntonio Reifs in OpenAIRE J. Alberto Blázquez; J. Alberto Blázquez
Harvested from ORCID Public Data FileJ. Alberto Blázquez in OpenAIRE Mato Knez; The high capacity of sulfur makes lithium–sulfur (Li–S) batteries the most promising next‐generation battery systems. With a significantly higher theoretical specific energy than conventional lithium‐ion batteries, this technology is intensely investigated. However, currently used cathodes have some critical drawbacks which affect the performance of Li–S batteries. Atomic layer deposition (ALD) demonstrates its power for solving some emerging issues in energy‐storage systems. The application of alumina (Al2O3) to the cathode surface improves the morphology and/or chemistry, providing a solution for some of the most common issues of Li–S batteries. Herein, the cathode of Li–S batteries is coated with alumina by ALD. In addition, the optimal parameters for ALD application to sulfur‐based electrodes are reported. It is demonstrated that alumina deposition results in an improved capacity of the system. The process temperature plays an important role, in particular for few‐cycle ALD processes, aiding better cell performance. Higher numbers of ALD cycles, especially at elevated process temperatures, result in considerable sulfur loss, which significantly lowers the cell performance. Cathodes coated with alumina at low process temperatures and with low numbers of ALD cycles are promising alternatives for conventional Li–S cathodes as they increase the capacity of the system considerably.
9 citations 9 popularity Top 10% influence Average impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/ente.201901432&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu - Sarai García;
Sarai García
Harvested from ORCID Public Data FileSarai García in OpenAIRE Olatz Leonet; Eneko Azaceta;Olatz Leonet
Harvested from ORCID Public Data FileOlatz Leonet in OpenAIRE Iñaki Gómez; +3 AuthorsIñaki Gómez
Harvested from ORCID Public Data FileIñaki Gómez in OpenAIRE Sarai García; Sarai García
Harvested from ORCID Public Data FileSarai García in OpenAIRE Olatz Leonet; Eneko Azaceta;Olatz Leonet
Harvested from ORCID Public Data FileOlatz Leonet in OpenAIRE Iñaki Gómez; Iñaki Gómez
Harvested from ORCID Public Data FileIñaki Gómez in OpenAIRE Antonio Reifs; Antonio Reifs
Harvested from ORCID Public Data FileAntonio Reifs in OpenAIRE J. Alberto Blázquez; J. Alberto Blázquez
Harvested from ORCID Public Data FileJ. Alberto Blázquez in OpenAIRE Mato Knez; The high capacity of sulfur makes lithium–sulfur (Li–S) batteries the most promising next‐generation battery systems. With a significantly higher theoretical specific energy than conventional lithium‐ion batteries, this technology is intensely investigated. However, currently used cathodes have some critical drawbacks which affect the performance of Li–S batteries. Atomic layer deposition (ALD) demonstrates its power for solving some emerging issues in energy‐storage systems. The application of alumina (Al2O3) to the cathode surface improves the morphology and/or chemistry, providing a solution for some of the most common issues of Li–S batteries. Herein, the cathode of Li–S batteries is coated with alumina by ALD. In addition, the optimal parameters for ALD application to sulfur‐based electrodes are reported. It is demonstrated that alumina deposition results in an improved capacity of the system. The process temperature plays an important role, in particular for few‐cycle ALD processes, aiding better cell performance. Higher numbers of ALD cycles, especially at elevated process temperatures, result in considerable sulfur loss, which significantly lowers the cell performance. Cathodes coated with alumina at low process temperatures and with low numbers of ALD cycles are promising alternatives for conventional Li–S cathodes as they increase the capacity of the system considerably.
9 citations 9 popularity Top 10% influence Average impulse Top 10% Powered by BIP!add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.<script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1002/ente.201901432&type=result"></script>'); --> </script>For further information contact us at helpdesk@openaire.eu
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