• Energy Research

European regions are facing many important challenges, as the need to recover from the pandemic coincides with the need to carry out the green and digital transitions foreseen in the European Green Deal, making the task harder, especially for less-developed regions. The paper considers making use of regional intellectual capital in the context of smart specialisation strategies (S3) as the most effective way to address these challenges and achieve smart, sustainable and inclusive growth. This is viewed through a closer look at two specific cases of Greek regions that are behind the EU mean in terms of development and innovation: Central Macedonia and Western Macedonia. Development trends, available intellectual capital and current smart specialisation strategies in these regions are examined. These result in concrete, evidence-based suggestions on how they can make maximum use of intellectual capital for the next generation of smart specialisation strategies to achieve growth via a focus on more innovative and sustainable activities.

The torrefaction process represents a thermal conversion technique conducted at relatively low temperatures ranging between 200 to 300 °C. Its objective is to produce fuel with a higher energy density by decomposing the reactive portion of hemicellulose. In this study, the kinetics of mass loss during torrefaction were investigated for willow. The experiments were carried out under isothermal conditions using thermogravimetric analysis. Batch torrefaction reactor designs were conducted and explained in detail. Co-combustion of willow with hard coal (origin: Katowice mine) in different mass ratios (25% biomass + 75% coal, 50% biomass + 50% coal, and 75% biomass + 25% coal) was conducted in addition to raw biomass torrefaction. TG/MS analysis (a combination of thermogravimetric analysis with mass spectrometry analysis) was performed in the research. The optimal torrefaction conditions for willow were identified as an average temperature of 245 °C and a residence time of 14 min, resulting in the lowest mass loss (30.15%). However, it was noted that the composition of torgas, a by-product of torrefaction, presents challenges in providing a combustible gas with sufficient heat flux to meet the energy needs of the process. Prolonged residence times over 15 min and higher average temperatures above 250 °C lead to excessive energy losses from volatile torrefaction products, making them suboptimal for willow. On the other hand, the co-combustion of torrefied biomass with hard coal offers advantages in reduced sulfur emissions but can lead to increased NOx emissions when biomass with a higher nitrogen content is co-combusted in proportions exceeding 50% biomass. This paper summarizes findings related to optimizing torrefaction conditions, challenges in torgas composition, and the emissions implications of co-combustion.

The effective operation of machinery in agricultural processes is crucial in terms of energy efficiency, economic consequences, and environmental footprint. The agricultural sector provides many opportunities to bring biomass to the market. An interesting option is to collect the branches after a regular pruning of apple orchards in the winter-spring season. As the harvesting of pruning residues in apple orchards for energy purposes demands additional primary energy, any measures that increase the amount of collected biomass are desirable. In this study, the influence of pruning harvesting using a baler with and without windrowers on pruning biomass yield, energy input and output flow, energy balance, CO2 emission reduction, and costs of that operation in apple orchards was investigated. The performed analysis, based on the results from two apple orchards, revealed that the energy balance was positive for both variants. However, in comparison with the harvesting process without windrowers, the use of windrowers in these two orchards caused an increase in pruning biomass yield by 0.45 tDM·ha−1 per year (25%) and 0.54 tDM·ha−1 per year (33%), respectively. The energy balance increased up by ca. 0.8–1.0 GJ·ha−1, although the fuel consumption by the tractor was higher. The use of windrowers did not significantly increase the costs, but resulted in remarkably better income from biomass selling (ca. €30–40 ha−1). Finally, the increase in the mass of harvested biomass led to a higher potential CO2 emission reduction. As a result, pruning biomass is an attractive source of energy, especially for local markets.

Different approach to valorise the sweet sorghum using pyrolysis process to obtain valuable resources for energy production: bio-char, bio-oil and syngas are presented in the paper. In this study the influence of process parameters of slow pyrolysis on sorghum and straw were analysed. Temperatures used in the process varied from 400 to 800�C and heating rate parameter varied from 10�C . min-1 to 65�C . min-1. The experiments were conducted using a lab scale slow pyrolysis reactor with electric heaters, equipped with a thermo balance analyzer to collect data of pyrolysis process. The achieved product yield can vary significantly according to the slow pyrolysis parameters. The temperature influenced more on the bio-char yield compared to the heating rate parameter. The highest bio-char yield (over 35% weight,) was obtained at 400�C and heating rate of 10�C . min-1.

The paper presents the results of research aimed at evaluating the possibility of using selected tree leaf species to produce solid biofuels. The possibility of production of qualitative solid biofuels from urban tree leaves meets the expectations of the municipal sector. Collection of tree leaves in urban areas is very often necessary for road safety reasons, the need to collect biomass rich in dust and pollution as well as biomass infested with pests. The production of solid biofuels from tree leaves allows for effective management of this raw material with energy recovery. The performed research indicates such a possibility, and the obtained ash is used as a soil improver. The conducted research showed that the biomass of leaves of five tree species used in the experiment can be a source of raw materials for production of qualitative biofuels. The obtained pellets were characterized by properties comparable to those of classical wood pellets. The lower heating value of the obtained pellets ranged from 14.5 to 15.5 MJ∙kg−1. Physical properties of the obtained pellets described by bulk density (BD 600–660 kg∙m−3), mechanical durability (DU 90–96%), moisture (Mar 10–12.5%) indicate that these products can be used in existing combustion equipment. Preliminary analysis of the obtained ashes (determination of ash melting point, bulk density) indicates that they should not cause difficulties in ash removal systems from the combustion chamber.

The annual potential of waste biomass production from food processing in Europe is 16.9 million tonnes. Unfortunately, most of these organic wastes are utilized without the energy gain, mainly due to the high moisture content and the ability to the fast rotting and decomposition. One of the options to increase its value in terms of energy applications is to valorize its properties. Torrefaction process is one of the pre-treatment technology of raw biomass that increases the quality of the fuel, especially in the context of resistance to moisture absorption. However, little is known about the influence of torrefaction temperature on the degree of valorization of some specific waste biomass. The aim of this paper was to analyze the influence of the temperature of the torrefaction on the hydrophobic properties of waste biomass, such as black currant pomace, apple pomace, orange peels, walnut shells, and pumpkin seeds. The torrefaction process was carried out at temperatures of 200 °C, 220 °C, 240 °C, 260 °C, 280 °C, and 300 °C. The hydrophobic properties were analyzed using the water drop penetration time (WDPT) test. The torrefied waste biomass was compared with the raw material dried at 105 °C. The obtained results revealed that subjecting the biomass to the torrefaction process improved its hydrophobic properties. Biomass samples changed their hydrophobic properties from hydrophilic to extremely hydrophobic depending on the temperature of the process. Apple pomace was the most hydrophilic sample; its water drop penetration was under 60 s. Black currant and apple pomaces reached extremely hydrophobic properties at a temperature of 300 °C, only. In the case of orange peels, walnut shells, and pumpkin seeds, already at the temperature of 220 °C, the samples were characterized by severely hydrophobic properties with a penetration time over 1000 s. At the temperature of 260 °C, orange peels, walnut shells, and pumpkin seeds reached extremely hydrophobic properties. Furthermore, in most cases, the increase of torrefaction temperature improved the resistance to moisture absorption, which is probably related to the removal of hydroxyl groups and structural changes occurring during this thermal process.

This paper presents a series of economic efficiency studies comparing three different investment variants: without energy storage, with energy stored in batteries and hydrogen installation with a PEM fuel cell stack for a location in Poland. To reach a target, the current solar potential in Poland, the photovoltaic (PV) productivity, the capacity of the energy storage in batteries as well as the size of the hydrogen production system were calculated. The solar potential was determined using archival meteorological data and the Krieg estimation method. A laboratory scale PV system (1 kW) was used to estimate the decrease in real solar installation power during the last 10 years of operation. All analyses were made for a 100 kW photovoltaic array located in Poland using static and dynamic methods of investment project assessment, such as Simply Bay Back Period (SPBP) or Net Present Value (NPV). The results showed that the SPBP amounted to 8.8 years and NPV 54,896 € for non-storage systems. Whereas, for systems with energy stored the economic indexes were, as follow: SPBP = never, NPV = 183,428 € for batteries and SPBP = 14.74 years, NPV = 22,639 € for hydrogen/fuel cell installation. Storage in hydrogen is more advantageous than batteries due to the smaller investment outlays.

Due to the tendency for excessive moisture adsorption by raw, unprocessed biomass, various methods of biomass valorization are in use, allowing for the improvement of physical–chemical biomass properties, including hydrophobicity. One of the methods is torrefaction, which changes the hydrophilic properties of the biomass to hydrophobic. Therefore, in this study, the influence of the torrefaction temperature and the exposure time to moisture adsorption conditions on the hydrophobic properties of waste biomass from the agri-food industry (lemon peel, mandarin peel, grapefruit peel, and butternut-squash peel) were analyzed. The torrefaction was carried out at the following temperatures: 200, 220, 240, 260, 280, 300, and 320 °C. The hydrophobic properties were determined by using the EMC (Equilibrium Moisture Content) method, conducting an experiment in the climatic chamber at atmospheric pressure, a temperature of 25 °C, and relative humidity of 80%. The total residence time of the material in the climate chamber was 24 h. It was shown that the torrefaction process significantly improves the hydrophobic properties of waste biomass. Concerning dried raw (unprocessed) material, the EMC (24 h) coefficient was 0.202 ± 0.004 for lemon peels, 0.223 ± 0.001 for grapefruit peels, 0.237 ± 0.004 for mandarin peels, and 0.232 ± 0.004 for butternut squash, respectively. After the torrefaction process, the EMC value decreased by 24.14–56.96% in relation to the dried raw material, depending on the type of organic waste. However, no correlation between the improvement of hydrophobic properties and increasing the torrefaction temperature was observed. The lowest values of the EMC coefficient were determined for the temperatures of 260 °C (for lemon peel, EMC = 0.108 ± 0.001; for mandarin peel, EMC = 0.102 ± 0.001), 240 °C (for butternut-squash peel, EMC = 0.176 ± 0.002), and 220 °C (for grapefruit peel, EMC = 0.114 ± 0.008). The experiment also showed a significant logarithmic trend in the dependence of the EMC coefficient on the operating time of the climatic chamber. It suggests that there is a limit of water adsorption by the material and that a further increase of the exposure time does not change this balance.