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It is now recognized that analytical chemistry must also be a target for green principles, in particular chromatographic methods which typically use relatively large volumes of hazardous organic solvents. More generally, high performance liquid chromatography (HPLC) is employed routinely for quality control of complex mixtures in various industries. Acetonitrile and methanol are the most commonly used organic solvents in HPLC, but they generate an impact on the environment and can have a negative effect on the health of analysts. Ethanol offers an exciting alternative as a less toxic, biodegradable solvent for HPLC. In this work we demonstrate that replacement of acetonitrile with ethanol as the organic modifier for HPLC can be achieved without significantly compromising analytical performance. This general approach is demonstrated through the specific example analysis of a complex plant extract. A benchmark method employing acetonitrile for the analysis of Bidens pilosa extract was statistically optimized using the Green Chromatographic Fingerprinting Response (GCFR) which includes factors relating to separation performance and environmental parameters. Methods employing ethanol at 30 and 80°C were developed and compared with the reference method regarding their performance of separation (GCFR) as well as by a new metric, Comprehensive Metric to Compare Liquid Chromatography Methods (CM). The fingerprint with ethanol at 80°C was similar to or better than that with MeCN according to GCFR and CM. This demonstrates that temperature may be used to replace harmful solvents with greener ones in HPLC, including for solvents with significantly different physiochemical properties and without loss in separation performance. This work offers a general approach for the chromatographic analysis of complex samples without compromising green analytical chemistry principles.

Abstract This paper aims to investigate sustainable waste management solutions for the city of Rio de Janeiro in Brazil, based on a life cycle approach. The Life Cycle Assessment (LCA) was performed by using the LCA-IWM methodology. The model was adapted to the Brazilian solid waste context and to the local characteristics, including waste composition, electricity mix and regulations. The annual amount of waste generated was the functional unit adopted. Eight municipal solid waste management strategies were evaluated. Scenarios including mixed waste collection and source separated collection as well as materials recovery and energy from waste were investigated. Scenarios were ranked based on the LCA results. Sensitivity analysis was carried out by varying the electricity mix. The results indicate that the current situation of municipal solid waste (MSW) in Rio de Janeiro presents the worst performance in terms of aggregated environmental burdens, indicating the urgency for implement new strategies toward a more environmentally friendly and sustainable MSW management system. It is noted that the better LCA performances were obtained in scenarios with high separately collection rates. Among them, the scenario based on recyclables recovery and anaerobic digestion shows to be a promising strategy to improve environmental sustainability. Sensitivity analysis demonstrates that the ranking of scenarios was not affected by changes in the electricity mix. From the results, the investment in source separated waste collection and materials recovery is the most environmentally friendly MSW strategy for Rio de Janeiro. In addition, scenarios with an emphasis in materials recovery presented higher environmental benefits than the alternatives focused on energy generation.

Following the environmental crises of recent decades, a turning point in the awareness of the fragility of ecosystems has been marked, i.e., environmental awareness. This has contributed to the development of various environmental laws and regulations such as the “Waste Electrical and Electronic Equipment,” the “Restriction of Hazardous Substances,” and the “Registration, Evaluation, Authorization and Restriction of Chemicals” regulations and the “Energy Using Products” Directives. Our work contributes to the development of eco-friendly product manufacturing processes. In order to estimate and optimize the environmental impacts of a product, most of the methodologies, concepts, and tools that integrate computer-aided design (CAD) and life cycle assessment systems generally exploit the feature technology at the level of each feature independently of the others, i.e., “microplanning.” The feature interaction technology (FIT) is treated only in few studies, but it is pivotal in the eco-manufacturing process. In this paper, we propose a new manufacturing-scenarios-based methodology by using FIT and a Multi-criteria Decision Support Method (MCDSM), which helps manufacturers maintain their marketplaces by producing goods in an eco-friendly way. In fact, this methodology helps designers choose from the CAD design phase the most ecological manufacturing process from possible existent scenarios in real time.

Abstract This study develops a novel sustainability assessment methodology for energy systems using life-cycle emission factors and sustainability indicators. Here, the global warming and environmental impact dimensions of the sustainability assessment methodology are examined in detail. A comparative analysis shows that a wind-battery system produces fewer potential global warming, stratospheric ozone depletion, air pollution, and water pollution impacts compared to a gas-fired system. The wind-battery system generates 13% of the life-cycle GHG emissions and 22% of the life-cycle ozone-depleting substance emissions of a gas-fired power plant. Nitrous oxide contributes more than 90% of the stratospheric ozone depletion potential of gas-fired and wind-battery systems.

Abstract Vapour absorption heat transformers are thermodynamic cycles which are capable of upgrading the temperature of waste heat energy using only negligible quantities of electrical energy. Although marked as a future technology by the IEA (International Energy Agency), as being important for energy utilization in the 21st century, industrial applications of heat transformers are still very limited. This paper presents a comprehensive review of heat transformer research over the past two decades. Emphasis is placed upon optimisation studies, alternate cycle configurations, working fluids comparisons and industrial application case studies.

The present study is motivated by the need to decouple economic growth from environmental degradation given the new wave of chase for higher economic growth trajectories comes with its environmental cost implications, especially among developing blocs like the Emerging 7 (E7) countries. There is a consistent trade-off between economic growth versus environmental quality. Government apparatus are perpetually on the chase for low-carbon emission policies via the pursuit for green economy. To this end, this present study extends the conventional environmental Kuznets curve (EKC) argument by incorporating the role of institution in emerging industrialized economies (E7) and using second-generation panel analysis methods like mean group (MG), augmented mean group (AMG), common correlated effects mean group (CCEMG), and the Dumitrescu and Hurlin causality test for more robust estimates and inferences. To this end, we explore the long-run and causality relationship between economic growth, quadratic form of economic growth, institutional quality, trade flow, investment in energy sector, and financial development in an EKC environment. Empirical analysis established a long-run equilibrium relationship among the outlined variables over the study period. The long-run regression shows the presence of EKC in the E7. Thus, suggesting the preference for GDP growth over environmental quality at the earlier stage of growth curve. Interestingly, investment in energy, trade flow dynamics across the blocs, and financial development dampens the detrimental effect of environmental pollution as we observed negative relationship with the ecological footprint. On the contrary, quality of institution is weak as institutional quality increase (worsen) the quality of environment in the E7 economies. From a policy perspective, this current study proposed the need for more stringent environmental treaties and regulations and promotion of green economy without compromising economic growth. In the conclusion part of the study, more details and specifics about the policy blueprint are presented.

Abstract A forecast of transport activity, energy consumption and carbon dioxide emissions from transportation, carried out under ‘business as usual’ economic assumptions, is presented for the 10 countries of Central and Eastern Europe that have acquired the status of ‘accession countries’ to the European Union. Energy demand is projected under considerations of the dynamic evolution of transport modes and their use, the evolution of automotive fuel prices, which are assumed to gradually converge with Western European price levels within the current decade, and assumptions on efficiency improvements in all transport modes according to current technological trends and European regulations. The results, showing transportation energy demand to double and CO2 emissions to be 70% higher in 2030 compared to 2000, are compared with other published forecasts and discussed with a view to potential future energy and environmental impacts in these countries, outlining major policy implications.

Abstract Social acceptance of innovative technologies is a key element of an effective transition towards more sustainable energy economies. However, innovative technologies like genetic modification also tend to spark controversy and backlash. So far, efforts to inform the public about any risks and benefits of novel technologies not only have struggled to foster acceptance but also neglect the interdependent foundations of consumer decision-making. Through a controlled experiment with German consumers (N = 322), we examine whether consumer support and rejection of genetic modification in bioenergy crops is influenced by the statements and actions of actors throughout the supply chain. In specific, we show that the decision of energy companies to sell and support GM bioenergy positively impacts consumer decisions to support. To ensure that decision outcomes were specifically impacted by the expressions of corporate actors, we controlled for the content and valence of information by random assignment to one of three treatments in which participants received positive, negative, or balanced (risks and benefits) information. We find that negative messaging diminished support and increased rejection relative to the other treatments. Lastly, the statements and actions of corporate actors also exerted an indirect influence on consumer decisions through their interactions with social trust and labels, e.g. greater support by farmers had a positive influence only for those who are more generally trustworthy. Given these results, we anticipate more attention to the importance of actors such as farmers and energy companies for the social acceptance of novel technologies in the energy sphere.

It has been known for a very long time that chemical energy may be converted into electrical energy by using biomass, considered a renewable energy source. In the study that is being presented here, an explanation and a presentation are offered on a one-of-a-kind hybrid system that generates dependable power and cooling by harnessing the chemical energy of biomass. An anaerobic digester takes in organic material and converts it into biomass by using the high-energy content of cow manure as fuel. The Rankin cycle is the primary engine that drives the system that produces energy, and its combustion-based byproducts are routed to an ammonia absorption refrigeration system in order to provide sufficient cooling for the process of pasteurizing and drying the milk. It is expected that solar panels might contribute to the production of sufficient amounts of power for necessary activities. The technical and financial facets of the system are both being investigated at the moment. In addition, the optimal working conditions are determined by employing a forward-thinking multi-objective optimization strategy. This method simultaneously raises the operational effectiveness to the greatest extent that is practically possible while simultaneously lowering both expenses and emissions. The findings indicate that under ideal conditions, the levelized cost of the product (LCOP), efficiency, and emission of the system are, respectively, 0.087 $/kWh, 38.2%, and 0.249 kg/kWh. The digester and the combustion chamber both have very high exergy destruction rates, with the digester having the highest rate and the combustion chamber having the second-highest rate among all of the system's components. This assertion is supported by every one of these components.