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The oil industry is extremely important to China's overall economic growth, fiscal stability and international trade. But oil industry reforms have been undertaken slowly and gradually. In 1994 the government reimposed central control over its oil industry by fixing the price of crude and petroleum products, and channelling virtually all sales through state agencies. This move marks a temporary retreat from the ongoing experiment with oil deregulation, which picked up speed since 1992. For as long as it lasts, this renewed central recontrol over oil prices and distribution will create increased uncertainty for foreign participation.

It is now recognized that analytical chemistry must also be a target for green principles, in particular chromatographic methods which typically use relatively large volumes of hazardous organic solvents. More generally, high performance liquid chromatography (HPLC) is employed routinely for quality control of complex mixtures in various industries. Acetonitrile and methanol are the most commonly used organic solvents in HPLC, but they generate an impact on the environment and can have a negative effect on the health of analysts. Ethanol offers an exciting alternative as a less toxic, biodegradable solvent for HPLC. In this work we demonstrate that replacement of acetonitrile with ethanol as the organic modifier for HPLC can be achieved without significantly compromising analytical performance. This general approach is demonstrated through the specific example analysis of a complex plant extract. A benchmark method employing acetonitrile for the analysis of Bidens pilosa extract was statistically optimized using the Green Chromatographic Fingerprinting Response (GCFR) which includes factors relating to separation performance and environmental parameters. Methods employing ethanol at 30 and 80°C were developed and compared with the reference method regarding their performance of separation (GCFR) as well as by a new metric, Comprehensive Metric to Compare Liquid Chromatography Methods (CM). The fingerprint with ethanol at 80°C was similar to or better than that with MeCN according to GCFR and CM. This demonstrates that temperature may be used to replace harmful solvents with greener ones in HPLC, including for solvents with significantly different physiochemical properties and without loss in separation performance. This work offers a general approach for the chromatographic analysis of complex samples without compromising green analytical chemistry principles.

Abstract This paper aims to investigate sustainable waste management solutions for the city of Rio de Janeiro in Brazil, based on a life cycle approach. The Life Cycle Assessment (LCA) was performed by using the LCA-IWM methodology. The model was adapted to the Brazilian solid waste context and to the local characteristics, including waste composition, electricity mix and regulations. The annual amount of waste generated was the functional unit adopted. Eight municipal solid waste management strategies were evaluated. Scenarios including mixed waste collection and source separated collection as well as materials recovery and energy from waste were investigated. Scenarios were ranked based on the LCA results. Sensitivity analysis was carried out by varying the electricity mix. The results indicate that the current situation of municipal solid waste (MSW) in Rio de Janeiro presents the worst performance in terms of aggregated environmental burdens, indicating the urgency for implement new strategies toward a more environmentally friendly and sustainable MSW management system. It is noted that the better LCA performances were obtained in scenarios with high separately collection rates. Among them, the scenario based on recyclables recovery and anaerobic digestion shows to be a promising strategy to improve environmental sustainability. Sensitivity analysis demonstrates that the ranking of scenarios was not affected by changes in the electricity mix. From the results, the investment in source separated waste collection and materials recovery is the most environmentally friendly MSW strategy for Rio de Janeiro. In addition, scenarios with an emphasis in materials recovery presented higher environmental benefits than the alternatives focused on energy generation.

Following the environmental crises of recent decades, a turning point in the awareness of the fragility of ecosystems has been marked, i.e., environmental awareness. This has contributed to the development of various environmental laws and regulations such as the “Waste Electrical and Electronic Equipment,” the “Restriction of Hazardous Substances,” and the “Registration, Evaluation, Authorization and Restriction of Chemicals” regulations and the “Energy Using Products” Directives. Our work contributes to the development of eco-friendly product manufacturing processes. In order to estimate and optimize the environmental impacts of a product, most of the methodologies, concepts, and tools that integrate computer-aided design (CAD) and life cycle assessment systems generally exploit the feature technology at the level of each feature independently of the others, i.e., “microplanning.” The feature interaction technology (FIT) is treated only in few studies, but it is pivotal in the eco-manufacturing process. In this paper, we propose a new manufacturing-scenarios-based methodology by using FIT and a Multi-criteria Decision Support Method (MCDSM), which helps manufacturers maintain their marketplaces by producing goods in an eco-friendly way. In fact, this methodology helps designers choose from the CAD design phase the most ecological manufacturing process from possible existent scenarios in real time.

Abstract This study develops a novel sustainability assessment methodology for energy systems using life-cycle emission factors and sustainability indicators. Here, the global warming and environmental impact dimensions of the sustainability assessment methodology are examined in detail. A comparative analysis shows that a wind-battery system produces fewer potential global warming, stratospheric ozone depletion, air pollution, and water pollution impacts compared to a gas-fired system. The wind-battery system generates 13% of the life-cycle GHG emissions and 22% of the life-cycle ozone-depleting substance emissions of a gas-fired power plant. Nitrous oxide contributes more than 90% of the stratospheric ozone depletion potential of gas-fired and wind-battery systems.

Abstract Vapour absorption heat transformers are thermodynamic cycles which are capable of upgrading the temperature of waste heat energy using only negligible quantities of electrical energy. Although marked as a future technology by the IEA (International Energy Agency), as being important for energy utilization in the 21st century, industrial applications of heat transformers are still very limited. This paper presents a comprehensive review of heat transformer research over the past two decades. Emphasis is placed upon optimisation studies, alternate cycle configurations, working fluids comparisons and industrial application case studies.

Abstract A forecast of transport activity, energy consumption and carbon dioxide emissions from transportation, carried out under ‘business as usual’ economic assumptions, is presented for the 10 countries of Central and Eastern Europe that have acquired the status of ‘accession countries’ to the European Union. Energy demand is projected under considerations of the dynamic evolution of transport modes and their use, the evolution of automotive fuel prices, which are assumed to gradually converge with Western European price levels within the current decade, and assumptions on efficiency improvements in all transport modes according to current technological trends and European regulations. The results, showing transportation energy demand to double and CO2 emissions to be 70% higher in 2030 compared to 2000, are compared with other published forecasts and discussed with a view to potential future energy and environmental impacts in these countries, outlining major policy implications.

It has been known for a very long time that chemical energy may be converted into electrical energy by using biomass, considered a renewable energy source. In the study that is being presented here, an explanation and a presentation are offered on a one-of-a-kind hybrid system that generates dependable power and cooling by harnessing the chemical energy of biomass. An anaerobic digester takes in organic material and converts it into biomass by using the high-energy content of cow manure as fuel. The Rankin cycle is the primary engine that drives the system that produces energy, and its combustion-based byproducts are routed to an ammonia absorption refrigeration system in order to provide sufficient cooling for the process of pasteurizing and drying the milk. It is expected that solar panels might contribute to the production of sufficient amounts of power for necessary activities. The technical and financial facets of the system are both being investigated at the moment. In addition, the optimal working conditions are determined by employing a forward-thinking multi-objective optimization strategy. This method simultaneously raises the operational effectiveness to the greatest extent that is practically possible while simultaneously lowering both expenses and emissions. The findings indicate that under ideal conditions, the levelized cost of the product (LCOP), efficiency, and emission of the system are, respectively, 0.087 $/kWh, 38.2%, and 0.249 kg/kWh. The digester and the combustion chamber both have very high exergy destruction rates, with the digester having the highest rate and the combustion chamber having the second-highest rate among all of the system's components. This assertion is supported by every one of these components.

Abstract An international workshop was held in Richland, Washington, United States of America, in October, 1980 to discuss progress on development of the acid digestion process for treating combustible nuclear waste. The workshop was attended by participants from nine member countries of the Nuclear Energy Agency of the Organization for Economic Cooperation and Development (OECD/NEA). The status of the acid digestion development programs of various countries is discussed in this paper. The acid digestion process has been developed and demonstrated on an engineering scale in several countries and appears to be especially applicable to treatment of combustible wastes containing high levels of transuranic contamination, where there is potential for recovering the transuranic radionuclides. Because the process takes place at a relatively low temperature, the plutonium contained in the residue is in a form that can be readily recovered using standard leaching techniques. The process is adaptable to a wide variety of combustible wastes, such as cellulosics, plastics, rubber materials, and ion exchange resin. While the process has been developed and demonstrated on an engineering scale primarily for transuranic contaminated wastes, the process is also adaptable to beta-gamma wastes such as reactor ion exchange resins.