• Energy Research
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Abstract The automotive operating protocols is a comprehensive expression of a country or a region’s road, climatic environment and driving habits. It is the foundation of energy consumption, test method and limit method for automobile products. It has direct impact on R & D, production and government access management of enterprises. For fuel cells vehicles, the lifetime is one of the main factors restricting their commercialization. Furthermore, the lifetime evaluation methods and its standard specifications of vehicular proton exchange membrane fuel cell are the critical factors to its technological development, but there is no authoritative recognized life evaluation method and test protocols so far. A logical fuel cell durability test protocol is the fundamental for developing the fuel cell life evaluation methods. A review on the state-of-art in the world for fuel cell accelerated test protocols was given, the research circumstances of different universities and research institutions in China, America, the European Union, Japan and so on are analyzed and summarized in detail. Then the essential characteristics and applicable environments of a comprehensive and effective durability test protocol are summarized based on the analysis and demonstration of the existing durability test protocols in literature. The work in this paper focuses on the research of durability test protocols of the fuel cell stack for the first time. The final conclusion will provide theoretical basis for establishing fuel cell durability test specifications and proposing life evaluation methods, and make a contribution to the long life research of vehicular fuel cells.

Abstract Microalgae have reported to be one of the most promising feedstock for biofuel production. However, microalgal cultivation for biofuel production is a costly process due to the large amounts of water, inorganic nutrients (mainly N and phosphate (P)), and CO2 needed. In this study, we evaluated whether the nutrient-rich ash and flue gas generated in biomass power plants could serve as a nutrient source for Chlorella sp. C2 cultivation to produce biolipids in a cost-efficient manner. When ash was incorporated in the culture medium and photosynthesis was enhanced by CO2 from flue gas, Chlorella cultures produced a lipid productivity of 99.11 mg L−1 d−1 and a biomass productivity of 0.31 g L−1 d−1, which are 39% and 35% more than the control cultures grown in BG11 medium. Additionally, the cultures reduced the nitrogen oxide (NOx) present in the flue gas and sequestered CO2, with a maximum ash denutrition rate of 13.33 g L−1 d−1, a NOx reduction (DeNOx) efficiency of ∼ 100%, and a CO2 sequestration rate of 0.46 g L−1 d−1. The residual medium was almost nutrient-free and suitable for recycling for continuous microalgal cultivation or farmland watering, or safely disposed off. Based on these results, we propose a technical strategy for biomass power plants in which the industrial wastes released during power generation nourish the microorganisms used to produce biofuel. Implementation of this strategy would enable carbon negative bioenergy production and impart significant environmental benefits.

As one of the three high-energy consumption sectors (industry, building, and transportation) in China, the transport sector faced a devastating resource and environment challenge. The transport sector was reportedly responsible for about 15.9% of the country’s total final energy consumption in 2008. This paper investigates the energy consumption and efficiency of China’s transport sector from 2003 to 2009. The transport energy data of 30 China administrative regions were divided into “three-belts” (Eastern, Western, and Central areas), and the corresponding turnovers were reported and analyzed using an index decomposition analysis (Logarithmic Mean Divisia Index). The energy data and turnover of the transport sector indicated that the high growth rate of turnover results is attributed to the high growth rate of diesel, assuming that diesel is the major fuel for freight transport. The growth of diesel is the main contributor to the overall growth of energy consumption. The growth rate of gasoline has become minimal since 2006. Since 2005, all three-belt areas, with regard to the effectiveness of energy conservation policies, have continuously improved their energy efficiencies based on the results of decomposition analysis. The energy intensity effect shows that the energy conservation and efficiency policies were more effective in the Central and Western areas than that in the Eastern area. On the other hand, the regional shift effect indicates that the policies favor to the Eastern area since only its regional shift effect contributes energy savings since 2008. The energy-mix effect is insignificant, which indicates that it is not necessary to conduct CO2 emission decomposition analysis due to the redundant observations. At last, the activity effect dominates the energy consumption increase (98.05% of the accumulated total energy increase) from 2003 to 2009, which is consistent with the rapid development of transportation in China. That is, the policies in the transport sector mainly focused on the economic development but the energy efficiencies in the study period.

Abstract In-situ CO2 biomethanisation offers a means to combine biogas upgrading with increased methane productivity, but its potential contribution to power-to-gas is often ignored due to concerns over process stability and control. The research presents an equation derived from fundamental chemical equilibria which predicts the relationship between partial CO2 pressure and digester pH, and allows estimation of the maximum achievable biogas methane content compatible with stable operation. A rapid experimental determination was also developed to support these predictions. The results were validated by long-term experiments using synthetic feedstock with different ammonia concentrations (2 and 3 g N L-1). Further trials carried out using food waste and sewage sludge as substrates showed stable operation at biogas methane contents of 92 and 90% CH4 and pH 8.5 and 7.9, respectively. CO2 biomethanisation was successfully demonstrated in a food waste digester with a total ammoniacal nitrogen of 4.8 g N L-1 with volumetric methane production enhanced by more than 2 times, from 2.29 to 5.01 L CH4 per L digester per day. The predictive approach used is applicable to digesters fed on different feedstocks and to hybrid systems with biomethanisation of both endogenous and exogenous CO2; and offers a basis for both process design guidelines and operational control. The output from the work thus provides engineers, operators and plant designers with a valuable tool for the successful implementation of in-situ biomethanisation in anaerobic digesters.

An ever more environmentally conscious society demands the use of green, sustainable and high-efficiency renewable energy resources. However, large-scale energy storage remains a challenge for a deep penetration of power produced from renewables into the grid. The Calcium-Looping (CaL) process, based on the reversible carbonation/calcination of CaO, is a promising technology for thermochemical energy storage (TCES) in Concentrated Solar Power (CSP) plants. Natural limestone to be used as CaO precursor is cheap, non-toxic and abundant. Nevertheless, recent works have shown that carbonation of CaO derived limestone at optimum conditions for TCES is limited by pore-plugging, which leads to severe deactivation for large enough particles to be employed in practice. In our work, we have synthesized inexpensive CaO/SiO composites by means of a biotemplate method using rice husk as support. The morphological and compositional features of the biomorphic materials synthesized help improve the CaO multicycle activity under optimum CSP storage conditions and for particles sufficiently large to be managed in practical processes. Peer Reviewed

Abstract Reducing a building’s energy consumption and providing better indoor environmental quality (IEQ) are the two major issues that building professionals are facing all over the world. It is not easy, however, to simultaneously address both issues. Therefore, this study aimed to establish the optimal occupant behavior that can simultaneously reduce total energy consumption and improve the IEQ, using an energy simulation and optimization tool. This study also developed an integrated IEQ score by combining three different IEQ indices (i.e., thermal comfort, indoor air quality (IAQ), and visual comfort) for building users to easily understand the IEQ condition. To analyze the effects of occupant behavior by region, the education facility was selected as the target facility, and five target regions were selected considering the Koppen climate classification system and the C40 Cities Climate Leadership Group. Finally, a total of 5 × 1.01 × 1022 occupant behavior combinations can be generated in the five target regions. As a result, among the four target variables (i.e., total energy consumption, thermal comfort, IAQ, and visual comfort), the total energy consumption of the optimal solution was found to have changed most dramatically compared to that of the basic condition in terms of percentage (94.7%), due to its strong correlation with the overall occupant behavior (the highest correlation coefficient: 0.879). Therefore, it is shown that occupant behavior has more influence on the total energy consumption than on the three IEQ indices. Among the three IEQ indices, the IAQ of the optimal solution decreased most significantly compared to that of the basic condition (the highest reduction ratio: 4.04% in Ulsan), which indicates that the IAQ has more influences on the integrated IEQ score than thermal and visual comfort. The facility manager and the building user can operate the building for reducing total energy consumption and improving the IEQ considering occupant behavior, which can be used as the building management guideline in various regions.

Abstract Carbon intensity is a valuable indicator for balancing economic growth and environmental pollution, and plays an important role in mitigating global climate change and promoting environmental sustainability. This study attempts to examine the impacts of export on carbon intensity by proposing a novel framework that targeting at the gap between export aggregate carbon intensity (EACI) and self aggregate carbon intensity (SACI) which constitute the total carbon intensity to reveal export effects. Multi-region input-output model was used to calculate EACI and SACI in 44 world regions in 2014. LMDI approach was further adopted to decompose the gap between EACI and SACI from sectoral perspective. Some main results are concluded. (1) On global scale, exports increased 7.2% in carbon intensity. On national scale, exports showed increased effects on most countries (42/44). The regional EACI/SACI ranged from 0.79 to 3.53. (2) Sectoral aggregate carbon intensity (ACI) of export decreased EACI by 51 g/$, while sectoral aggregate structure (AS) of export increased EACI by 186 g/$, resulting in 135 g/$ increase in EACI globally. (3) For most regions, although ACI of carbon-intensive sectors (Elec., Metal, Nonmetal, Trans., Chem. and Coke&petrol.) in exports was lower than that in self, the high AS of these sectors in exports resulted in EACI higher than SACI, causing pulling force of export on global carbon intensity. Thus reducing carbon-intensive industries’ weights in exports would have great effects on global and national carbon intensity mitigation.

Abstract The deep decarbonisation of the power sector coupled with electrification of end-use sectors will be crucial towards a carbon neutral economy, as required to achieve the Paris Agreement's goal. Several studies have highlighted the relevance of electrification under deep decarbonisation. However, previous work does not explore what would be the major shifts towards electrification, i.e., in what economic activities it will likely occur and when up to 2050 considering gradually stricter GHG emissions constraints. This is of upmost relevance since relatively small variations in emission caps may trigger substantial modifications in specific components of the energy system, namely the shift for the electrification of a particular energy end-use, with impacts on the power sector’s portfolio. In this paper, we analyse the extension of the electrification of the energy system as a cost-effective strategy for deep decarbonisation. We set a large number of increasingly stringent mitigation caps to assess: (i) the degree of electrification of different energy end-uses across all economic activities, (ii) the impact in power sector portfolio and costs and (iii) investment needs. The novelty of this paper relies on the anticipation of electrification of activities traditionally supplied by non-electricity energy carriers, by exploring when and how such transformation may occur in the future, and how much it would cost. We assess the case of Portugal till 2050 by using the TIMES_PT model to generate 50 increasingly stricter decarbonisation scenarios. In the long term, incremental changes (+1%) in more aggressive decarbonisation targets (beyond −70% reduction) induce substantial increase in the share of electrification growth rates. Electric private vehicles, electricity-based steam and heat production in ceramic industrial sector and heat pumps in buildings are the most cost-effective electric technologies. We found that a decarbonisation up to near −80% of 1990′s levels of the Portuguese energy system does not have a significant impact on the power sector unit costs, and does not surpass historic values for some years. However, it should be noted that incremental changes (+1%) in more aggressive decarbonisation targets may increase sharply electricity costs in 2050 (+9%). Thus, focusing in only few scenarios may narrow the role of electrification (or other mitigation options) and its associated costs for deep decarbonisation. This paper allows researchers, planners and decision makers to enhance awareness regarding the relevance and cost-effectiveness of electrification under decarbonisation, namely its feasibility and affordability, providing fruitful insights.