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Abstract Adsorbent-based carbon capture is only feasible if adsorption-desorption cycles are both fully regenerating and efficient. This work proposes a regenerative pH swing process and a pH swing regenerative adsorbent that are inspired by natural CO2 conversion by carbonic anhydrase biocatalysts found in mammalian red blood cells. The main objective is to develop, test and analyze a synthetic pH Swing Adsorption (pHSA) system as well as a pHSA compatible solid adsorbent to capture CO2 from a simulated ambient air gas stream. The lead developed adsorbent is a carbon black co-activated with potassium carbonate and nitrogenous copolymer that is impregnated with immobilized bovine carbonic anhydrase and thereby deemed “BCA/KN-CB”. BCA/KN-CB has preliminarily demonstrated both competitive CO2 adsorption capacity and limited regenerative ability under experimental pHSA conditions. In addition, BCA-based adsorbents achieved higher adsorption capacities than non-BCA adsorbent counterparts. The BCA/KN-CB adsorbent displayed both large point of zero charge (PZC) swings and regenerative stability. The proposed pHSA system requires essentially zero energy expenditure to achieve intended environments for capture and regeneration. With 1 kg of adsorbent, pHSA has the ability to capture 1 kg CO2 in less than 4 h of cycling. The tested pHSA adsorbent can also capture more than 96% of total CO2 in a given raw gas stream flowing through the capture chamber. This proof-of-concept study of a pH swing adsorption/biocatalytic adsorbent system suggests the potential to effectively operate under ambient conditions and exhibit advantageous operational efficiencies to other high-profile CO2 capture systems.

Abstract Adsorbent-based carbon capture is only feasible if adsorption-desorption cycles are both fully regenerating and efficient. This work proposes a regenerative pH swing process and a pH swing regenerative adsorbent that are inspired by natural CO2 conversion by carbonic anhydrase biocatalysts found in mammalian red blood cells. The main objective is to develop, test and analyze a synthetic pH Swing Adsorption (pHSA) system as well as a pHSA compatible solid adsorbent to capture CO2 from a simulated ambient air gas stream. The lead developed adsorbent is a carbon black co-activated with potassium carbonate and nitrogenous copolymer that is impregnated with immobilized bovine carbonic anhydrase and thereby deemed “BCA/KN-CB”. BCA/KN-CB has preliminarily demonstrated both competitive CO2 adsorption capacity and limited regenerative ability under experimental pHSA conditions. In addition, BCA-based adsorbents achieved higher adsorption capacities than non-BCA adsorbent counterparts. The BCA/KN-CB adsorbent displayed both large point of zero charge (PZC) swings and regenerative stability. The proposed pHSA system requires essentially zero energy expenditure to achieve intended environments for capture and regeneration. With 1 kg of adsorbent, pHSA has the ability to capture 1 kg CO2 in less than 4 h of cycling. The tested pHSA adsorbent can also capture more than 96% of total CO2 in a given raw gas stream flowing through the capture chamber. This proof-of-concept study of a pH swing adsorption/biocatalytic adsorbent system suggests the potential to effectively operate under ambient conditions and exhibit advantageous operational efficiencies to other high-profile CO2 capture systems.

Abstract The main hindrances to the large-scale development of renewable-energy projects are the lack of bankability and the inability to align investments and investors with suitable financial instruments or robust policy measures. To illustrate a bankable project, this paper presents a research-based case study on the installation of solar photovoltaic panels on the rooftops of 195 trains of the Indian Railways. Detailed information on the annual running hours, exposure to sunlight, efficiency of solar photovoltaic generation and electrical power demands of each rail coach is considered to conduct a quantitative measure of the tentative amount of fossil fuel savings. The purpose is to provide insight into the types of renewable-energy projects that can be highly attractive to financial institutions and promoters due to their lucrative internal return on investment. As seen in this case study, there are annual savings in diesel of 12 323 088 litres and a CO2 reduction of 32 755 tonnes, with return on investment of 1.3 years. Furthermore, this study conducts a comprehensive analysis of the limitations of existing renewable-energy project financing mechanisms in India. Subsequently, three policy measures are recommended to develop a robust financial mechanism that can effectively meet the needs of investors and investors. These measures include increasing equity injection through a buy-and-hold strategy, providing direct tax benefits to promoters and financing through real-estate investment trusts. The findings are highly relevant to address the challenges associated with bridging the financial gap between access to finance and capital investment in the renewable-energy sector, especially for Asian countries.

Abstract The main hindrances to the large-scale development of renewable-energy projects are the lack of bankability and the inability to align investments and investors with suitable financial instruments or robust policy measures. To illustrate a bankable project, this paper presents a research-based case study on the installation of solar photovoltaic panels on the rooftops of 195 trains of the Indian Railways. Detailed information on the annual running hours, exposure to sunlight, efficiency of solar photovoltaic generation and electrical power demands of each rail coach is considered to conduct a quantitative measure of the tentative amount of fossil fuel savings. The purpose is to provide insight into the types of renewable-energy projects that can be highly attractive to financial institutions and promoters due to their lucrative internal return on investment. As seen in this case study, there are annual savings in diesel of 12 323 088 litres and a CO2 reduction of 32 755 tonnes, with return on investment of 1.3 years. Furthermore, this study conducts a comprehensive analysis of the limitations of existing renewable-energy project financing mechanisms in India. Subsequently, three policy measures are recommended to develop a robust financial mechanism that can effectively meet the needs of investors and investors. These measures include increasing equity injection through a buy-and-hold strategy, providing direct tax benefits to promoters and financing through real-estate investment trusts. The findings are highly relevant to address the challenges associated with bridging the financial gap between access to finance and capital investment in the renewable-energy sector, especially for Asian countries.

Abstract In this work, energy analysis is carried out to account for inputs and outputs of energy and GHG emissions associated with the biodiesel production system. Jojoba oil is obtained by cultivation of the jojoba plant, harvesting of seeds followed by extraction of oil, which is then converted to biodiesel by the process of transesterification. Energy efficiency is expressed in terms of the net energy balance (NEB) and the net energy ratio (NER). The use of the byproducts (husk, cake or meal, waste residues and glycerin) are also included as a part of the system boundary. The results show that the NEB and NER values are calculated at 46724.1 MJ/ha (28.9 MJ/L biodiesel produced) and 2.16, respectively. At the same time, the total amount of GHG emissions are estimated at 2.28 kg-CO2eq/L biodiesel produced (66.0 g CO2eq/MJ biodiesel produced). Nevertheless, if manure is used as fertilizer for jojoba plant cultivation, the primary energy input will fall by 9.52% (to 22.49 MJ/L of biodiesel).

Abstract In this work, energy analysis is carried out to account for inputs and outputs of energy and GHG emissions associated with the biodiesel production system. Jojoba oil is obtained by cultivation of the jojoba plant, harvesting of seeds followed by extraction of oil, which is then converted to biodiesel by the process of transesterification. Energy efficiency is expressed in terms of the net energy balance (NEB) and the net energy ratio (NER). The use of the byproducts (husk, cake or meal, waste residues and glycerin) are also included as a part of the system boundary. The results show that the NEB and NER values are calculated at 46724.1 MJ/ha (28.9 MJ/L biodiesel produced) and 2.16, respectively. At the same time, the total amount of GHG emissions are estimated at 2.28 kg-CO2eq/L biodiesel produced (66.0 g CO2eq/MJ biodiesel produced). Nevertheless, if manure is used as fertilizer for jojoba plant cultivation, the primary energy input will fall by 9.52% (to 22.49 MJ/L of biodiesel).

Large amounts of CO2 from human socioeconomic activities threaten environmental sustainability. Moreover, uncontrolled resource use and lack of relevant technology exacerbate this issue. For this reason, carbon capture, utilization, and storage (CCUS) technology has gained worldwide attention. Many scholars have researched CCUS, but few have used CCUS patent bibliometric analysis from a unified perspective. This article aims to provide a conclusive analysis for CCUS researchers and policymakers, as well as summarize the innovation trends, technological distribution, and topic evolution. Based on 11,915 pieces of patent data from the Derwent Innovations Index, we used bibliometric analysis and data mining methods to conduct research on four dimensions: overall trend, geographical distribution, patentees, and patent content. The results of this article are as follows. CCUS has entered a rapid development stage since 2013. Patents are mainly distributed geographically in China, the US, and Japan, especially in heavy industries such as energy and electricity. Large enterprises hold patents with a relatively stable network of cooperators and attach great importance to international patent protection. A total of 12 topics were identified through clustering, and these topics gradually shifted from technicalities to commercialization, and from industrial production to all aspects of people’s daily lives.

Large amounts of CO2 from human socioeconomic activities threaten environmental sustainability. Moreover, uncontrolled resource use and lack of relevant technology exacerbate this issue. For this reason, carbon capture, utilization, and storage (CCUS) technology has gained worldwide attention. Many scholars have researched CCUS, but few have used CCUS patent bibliometric analysis from a unified perspective. This article aims to provide a conclusive analysis for CCUS researchers and policymakers, as well as summarize the innovation trends, technological distribution, and topic evolution. Based on 11,915 pieces of patent data from the Derwent Innovations Index, we used bibliometric analysis and data mining methods to conduct research on four dimensions: overall trend, geographical distribution, patentees, and patent content. The results of this article are as follows. CCUS has entered a rapid development stage since 2013. Patents are mainly distributed geographically in China, the US, and Japan, especially in heavy industries such as energy and electricity. Large enterprises hold patents with a relatively stable network of cooperators and attach great importance to international patent protection. A total of 12 topics were identified through clustering, and these topics gradually shifted from technicalities to commercialization, and from industrial production to all aspects of people’s daily lives.

AbstractClimate change poses new and unique challenges that threaten lives and livelihoods. Given the increasing risks and looming uncertainty of climate change, increasing attention has been directed towards adaptation, or the strategies that enable humanity to persist and thrive through climate change the best it can. Though climate change is a global problem often discussed at the national scale, urban areas are increasingly seen as having a distinct role, and distinctive motivation and capacity, for adaptation. The 12 articles in this special issue explore ways of understanding and addressing climate change impacts on urban areas. Together they reveal young but rapidly growing scholarship on how to measure, and then overcome, challenges of climate change. Two key themes emerge in this issue: 1) that we must identify and then overcome current barriers to urban adaptation and 2) frameworks/metrics are necessary to identify and track adaptation progress in urban settings. Both of these themes point to the power of indicators and other quantitative information to inform priorities and illuminate the pathway forward for adaptation. As climate change is an entirely new challenge, careful measurement that enables investment by private and public parties is necessary to provide efficient outcomes that benefit the greatest number of people.