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  • Energy Research
  • 13. Climate action
  • 11. Sustainability
  • University of North Texas

  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Ghafoori, N.;

    The overall objective of this program is to investigate the extent to which fluidized bed combustion (FBC) by-products can be properly utilized as the viable construction materials. This investigation focuses primarily on the properties of residues derived from fluidized combustion burning of Illinois high-sulfur coal. The research plan calls for evaluation of physico-chemical and engineering characteristics of the FBC-based cement and non-cement mixes. The results of this study will be used to compare the physical and mechanical properties of the FBC-based mixtures with those of conventional mixes. The suitability of using FBC residues as a filler or binder aggregate for construction applications such as structural concrete members, precast building products, and as base or surface course for gravity dams and pavements in the form of conventional and roller compacted materials will then be evaluated. During this reporting period, the literature survey, preparation of raw materials, and chemical analyses were completed. Some of the physical properties and preconditioning studies were determined and efforts are in progress to complete these tasks.

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    Authors: Xu, Tengfang;

    The objective of this project is to provide assistance in development of a standard test procedure for fan-filter units, which are gaining popularity for use in California cleanrooms. In particular, LBNL carried out collaboration with various stakeholders in the industry and took a lead in developing a draft standard method for testing the energy performance of fan-filter units, and provided assistance to California public utility companies by testing the draft method in PG&E's testing facility. Through testing more units in the future with a robust standard method, baseline performance information can be developed for use in possible energy incentive programs.

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    Authors: Torvanger, A.;

    Abstract The reduction in energy-related manufacturing carbon dioxide emissions for nine OECD countries for 1973–87 is analysed. Carbon dioxide emissions are estimated from energy use data. The emphasis is on carbon dioxide intensities, defined as emissions divided by value added. The overall manufacturing carbon dioxide intensity was reduced by 42% in the period. Four fuels are specified together with six subsectors of manufacturing. A Divisia index approach is used to evaluate the contribution to reduced carbon dioxide intensity from different components. The main contribution to reduced carbon dioxide intensity is from the general reduction in manufacturing energy intensity, most likely driven by economic growth and increased energy prices, giving incentives to invest in new technology and industrial processes. There is also a significant contribution from reduced production in the most carbon dioxide intensive subsectors, and a contribution from higher efficiency in electricity generation together with a larger nuclear power share at the expense of oil.

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    Authors: Ineel;

    An abundant and secure energy supply is critical to our country’s prosperity, and energy supply is now a central issue in global stability and security. Unfortunately, the Unites States continues to steadily increase the fraction of energy it imports from foreign sources. In May 2001, the National Energy Policy noted that this imbalance, "if allowed to continue, will inevitably undermine our economy, our standard of living, and our national security." In addition to these serious impacts, growing concern about air pollution and atmospheric carbon levels hold the potential for global climate change. According to the National Academy of Sciences, the Earth’s surface temperature has risen by about 1 degree Fahrenheit in the past century, with accelerated warming during the past two decades. The current energy supply situation clearly demands coordinated action. Nuclear energy is preeminent in its ability to deliver affordable energy today and meet the growing imperatives for clean air and energy supplies in the future.

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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ https://digital.libr...arrow_drop_down
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    Abstract The feasibility of an alternative CO 2 mitigation system and a methanol production process is investigated. The Carnol system has three components: (i) a coal-fired power plant supplying flue gas CO 2 , (ii) a process which converts the CO 2 in the presence of He from natural gas to methanol, (iii) use of methanol as a fuel component in the automotive sector. For the methanol production process alone, up to 100% CO 2 emission reduction can be achieved; for the entire system, up to 65% CO 2 emission reduction can be obtained. The Carnol system is technically feasible and economically competitive with alternative CO 2 -disposal systems for coal-fired power plants. The Carnol process is estimated to be economically attractive compared to the current market price of methanol, especially if credit can be taken for carbon as a marketable coproduct.

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    Energy
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    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Energy
    Article . 1997 . Peer-reviewed
    License: Elsevier TDM
    Data sources: Crossref
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      Energy
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Energy
      Article . 1997 . Peer-reviewed
      License: Elsevier TDM
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    Authors: Halverson, Mark A.; Liu, Bing; Richman, Eric E.; Winiarski, David W.;

    This document presents the qualitative comparison of DOE’s formal determination of energy savings of ANSI/ASHRAE/IESNA Standard 90.1-2004. The term “qualitative” is used in the sense of identifying whether or not changes have a positive, negative, or neutral impact on energy efficiency of the standard, with no attempt made to quantify that impact. A companion document will present the quantitative comparison of DOE’s determination. The quantitative comparison will be based on whole building simulation of selected building prototypes in selected climates. This document presents a comparison of the energy efficiency requirements in ANSI/ASHRAE/IESNA 90.1-1999 (herein referred to as Standard 90.1-1999) and ANSI/ASHRAE/IESNA 90.1-2004 (herein referred to as Standard 90.1-2004). The comparison was done through a thorough review of all addenda to Standard 90.1-1999 that were included in the published ANSI/ASHRAE/IESNA Standard 90.1-2001 (herein referred to as Standard 90.1-2001) and also all addenda to Standard 90.1-2001 that were included in the published Standard 90.1-2004. A summary table showing the impact of each addendum is provided. Each addendum to both Standards 90.1-1999 and 90.1-2001 was evaluated as to its impact on the energy efficiency requirements of the standard (greater efficiency, lesser efficiency) and as to significance. The final section of this document summarizes the impacts of the various addenda and proposes which addenda should be included in the companion quantitative portion of DOE’s determination. Addenda are referred to with the nomenclature addendum 90.1-xxz, where “xx” is either “99” for 1999 or “01” for 2001, and z is the ASHRAE letter designation for the addendum. Addenda names are shown in bold face in text. DOE has chosen not to prepare a separate evaluation of Standard 90.1-2001 as that standard does not appear to improve energy efficiency in commercial buildings. What this means for the determination of energy savings for Standard 90.1-2004 is that the baseline standard for comparison is Standard 90.1-1999 and all addenda to both Standards 90.1-1999 and 90.1-2001 must be considered to determine the overall change in efficiency between Standard 90.1-1999 and Standard 90.1-2004.

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    Authors: Benenson, P.;

    A residential and industrial water-conservation scenario for California is constructed in which water consumption is disaggregated by residential end use, industrial sector, and hydrologic study area (HSA). The energy use associated with this water use was estimated for surface and groundwater delivery, distribution, heating, and waste-water treatment. For each end use and sector, water-conservation measures were delineated and their potential savings in terms of both water and attendant energy use were estimated. This material is combined to estimate the total water and energy savings potential by end use, sector, and HSA. This potential is then compared with the reported water savings to date, and finally, some conclusions and policy implications are drawn from the results. The general findings are discussed first, followed by a listing of the more important detailed results.

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  • image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Authors: Christian Brannstrom; Matthew Fry;

    Abstract Beginning in the 2000s, the Dallas-Fort Worth metropolitan region became home to the world's largest and longest experiment in urban shale gas production, with 25,182 drilling permits issued from 2000 to 2016 in the Barnett Shale. Urban hydrocarbon governance centered on establishing statutory setback distances between drilling sites and nearest houses or other protected uses. Here we analyze qualitative interview data obtained with a rigorous sampling frame to examine processes and outcomes of municipal-level hydrocarbon governance. We find that early municipal responses (2001–2002) revealed lack of technical expertise to respond to unconventional drilling and production. Controversial wells, which residents considered too close to houses, focused governance debates in several municipalities. Municipal policymakers reported that protecting public health and safety were top priorities in determining setbacks. After 2003, policymakers copied ordinance language from neighboring municipalities and established task forces and working groups to reduce political tensions. The role of the hydrocarbon industry included frequent claims seeking to exploit the longstanding separation of mineral and property estates, which encouraged municipalities to reduce setbacks and lower potential exposure to regulatory takings lawsuits. Over time, municipal regulatory power in hydrocarbon governance decreased while industry power increased, offering several implications for corporate responsibility and social license debates.

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    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
    Energy Policy
    Article . 2017 . Peer-reviewed
    License: Elsevier TDM
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      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Energy Policyarrow_drop_down
      image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
      Energy Policy
      Article . 2017 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Berry, JB;

    Oak Ridge National Laboratory (ORNL) researches and develops distributed generation technology for the Department of Energy, Energy Efficiency and Renewable Energy Distributed Energy Program. This report describes installation and operation of one such distributed generation system, a United Technology Corporation fuel cell located at the National Transportation Research Center in Knoxville, Tennessee. Data collected from June 2003 to June of 2004, provides valuable insight regarding fuel cell-grid compatibility and the cost-benefit of the fuel cell operation. The NTRC fuel cell included a high-heat recovery option so that use of thermal energy improves project economics and improves system efficiency to 59% year round. During the year the fuel cell supplied a total of 834MWh to the NTRC and provided 300MBtu of hot water. Installation of the NTRC fuel cell was funded by the Distributed Energy Program with partial funding from the Department of Defense's Climate Change Fuel Cell Buy Down Program, administered by the National Energy Technology Laboratory. On-going operational expenses are funded by ORNL's utility budget and are paid from operational cost savings. Technical information and the benefit-cost of the fuel cell are both evaluated in this report and sister reports.

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    Authors: Zhu, J. H.;

    This report summarized the research efforts and major conclusions of our University Coal Research Project, which focused on developing a new class of electrically-conductive, Cr-blocking, damage-tolerant Ag-perovksite composite materials for the cathode-interconnect contact of intermediate-temperature solid oxide fuel cell (SOFC) stacks. The Ag evaporation rate increased linearly with air flow rate initially and became constant for the air flow rate {ge} {approx} 1.0 cm {center_dot} s{sup -1}. An activation energy of 280 KJ.mol{sup -1} was obtained for Ag evaporation in both air and Ar+5%H{sub 2}+3%H{sub 2}O. The exposure environment had no measurable influence on the Ag evaporation rate as well as its dependence on the gas flow rate, while different surface morphological features were developed after thermal exposure in the oxidizing and reducing environments. Pure Ag is too volatile at the SOFC operating temperature and its evaporation rate needs to be reduced to facilitate its application as the cathode-interconnect contact. Based on extensive evaporation testing, it was found that none of the alloying additions reduced the evaporation rate of Ag over the long-term exposure, except the noble metals Au, Pt, and Pd; however, these noble elements are too expensive to justify their practical use in contact materials. Furthermore, the additionmore » of La{sub 0.8}Sr{sub 0.2}MnO{sub 3} (LSM) into Ag to form a composite material also did not significantly modify the Ag evaporation rate. The Ag-perovskite composites with the perovskite being either (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.8}Fe{sub 0.2})O{sub 3} (LSCF) or LSM were systematically evaluated as the contact material between the ferritic interconnect alloy Crofer 22 APU and the LSM cathode. The area specific resistances (ASRs) of the test specimens were shown to be highly dependent on the volume percentage and the type of the perovskite present in the composite contact material as well as the amount of thermal cycling that the specimens were subjected to during testing. The Ag-LSCF composite contact materials proved more effective in trapping Cr within the contact material and preventing Cr migration into the cathode than the Ag-LSM composites. Ag-perovskite composite contact materials are promising candidates for use in intermediate-temperature SOFC stacks with ferritic stainless steel interconnects due to their ability to maintain acceptably low ASRs while reducing Cr migration into the cathode material.« less

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Ghafoori, N.;

    The overall objective of this program is to investigate the extent to which fluidized bed combustion (FBC) by-products can be properly utilized as the viable construction materials. This investigation focuses primarily on the properties of residues derived from fluidized combustion burning of Illinois high-sulfur coal. The research plan calls for evaluation of physico-chemical and engineering characteristics of the FBC-based cement and non-cement mixes. The results of this study will be used to compare the physical and mechanical properties of the FBC-based mixtures with those of conventional mixes. The suitability of using FBC residues as a filler or binder aggregate for construction applications such as structural concrete members, precast building products, and as base or surface course for gravity dams and pavements in the form of conventional and roller compacted materials will then be evaluated. During this reporting period, the literature survey, preparation of raw materials, and chemical analyses were completed. Some of the physical properties and preconditioning studies were determined and efforts are in progress to complete these tasks.

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Xu, Tengfang;

    The objective of this project is to provide assistance in development of a standard test procedure for fan-filter units, which are gaining popularity for use in California cleanrooms. In particular, LBNL carried out collaboration with various stakeholders in the industry and took a lead in developing a draft standard method for testing the energy performance of fan-filter units, and provided assistance to California public utility companies by testing the draft method in PG&E's testing facility. Through testing more units in the future with a robust standard method, baseline performance information can be developed for use in possible energy incentive programs.

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Torvanger, A.;

    Abstract The reduction in energy-related manufacturing carbon dioxide emissions for nine OECD countries for 1973–87 is analysed. Carbon dioxide emissions are estimated from energy use data. The emphasis is on carbon dioxide intensities, defined as emissions divided by value added. The overall manufacturing carbon dioxide intensity was reduced by 42% in the period. Four fuels are specified together with six subsectors of manufacturing. A Divisia index approach is used to evaluate the contribution to reduced carbon dioxide intensity from different components. The main contribution to reduced carbon dioxide intensity is from the general reduction in manufacturing energy intensity, most likely driven by economic growth and increased energy prices, giving incentives to invest in new technology and industrial processes. There is also a significant contribution from reduced production in the most carbon dioxide intensive subsectors, and a contribution from higher efficiency in electricity generation together with a larger nuclear power share at the expense of oil.

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    Authors: Ineel;

    An abundant and secure energy supply is critical to our country’s prosperity, and energy supply is now a central issue in global stability and security. Unfortunately, the Unites States continues to steadily increase the fraction of energy it imports from foreign sources. In May 2001, the National Energy Policy noted that this imbalance, "if allowed to continue, will inevitably undermine our economy, our standard of living, and our national security." In addition to these serious impacts, growing concern about air pollution and atmospheric carbon levels hold the potential for global climate change. According to the National Academy of Sciences, the Earth’s surface temperature has risen by about 1 degree Fahrenheit in the past century, with accelerated warming during the past two decades. The current energy supply situation clearly demands coordinated action. Nuclear energy is preeminent in its ability to deliver affordable energy today and meet the growing imperatives for clean air and energy supplies in the future.

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    Abstract The feasibility of an alternative CO 2 mitigation system and a methanol production process is investigated. The Carnol system has three components: (i) a coal-fired power plant supplying flue gas CO 2 , (ii) a process which converts the CO 2 in the presence of He from natural gas to methanol, (iii) use of methanol as a fuel component in the automotive sector. For the methanol production process alone, up to 100% CO 2 emission reduction can be achieved; for the entire system, up to 65% CO 2 emission reduction can be obtained. The Carnol system is technically feasible and economically competitive with alternative CO 2 -disposal systems for coal-fired power plants. The Carnol process is estimated to be economically attractive compared to the current market price of methanol, especially if credit can be taken for carbon as a marketable coproduct.

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    Energy
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    Energy
    Article . 1997 . Peer-reviewed
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      Energy
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      Energy
      Article . 1997 . Peer-reviewed
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    Authors: Halverson, Mark A.; Liu, Bing; Richman, Eric E.; Winiarski, David W.;

    This document presents the qualitative comparison of DOE’s formal determination of energy savings of ANSI/ASHRAE/IESNA Standard 90.1-2004. The term “qualitative” is used in the sense of identifying whether or not changes have a positive, negative, or neutral impact on energy efficiency of the standard, with no attempt made to quantify that impact. A companion document will present the quantitative comparison of DOE’s determination. The quantitative comparison will be based on whole building simulation of selected building prototypes in selected climates. This document presents a comparison of the energy efficiency requirements in ANSI/ASHRAE/IESNA 90.1-1999 (herein referred to as Standard 90.1-1999) and ANSI/ASHRAE/IESNA 90.1-2004 (herein referred to as Standard 90.1-2004). The comparison was done through a thorough review of all addenda to Standard 90.1-1999 that were included in the published ANSI/ASHRAE/IESNA Standard 90.1-2001 (herein referred to as Standard 90.1-2001) and also all addenda to Standard 90.1-2001 that were included in the published Standard 90.1-2004. A summary table showing the impact of each addendum is provided. Each addendum to both Standards 90.1-1999 and 90.1-2001 was evaluated as to its impact on the energy efficiency requirements of the standard (greater efficiency, lesser efficiency) and as to significance. The final section of this document summarizes the impacts of the various addenda and proposes which addenda should be included in the companion quantitative portion of DOE’s determination. Addenda are referred to with the nomenclature addendum 90.1-xxz, where “xx” is either “99” for 1999 or “01” for 2001, and z is the ASHRAE letter designation for the addendum. Addenda names are shown in bold face in text. DOE has chosen not to prepare a separate evaluation of Standard 90.1-2001 as that standard does not appear to improve energy efficiency in commercial buildings. What this means for the determination of energy savings for Standard 90.1-2004 is that the baseline standard for comparison is Standard 90.1-1999 and all addenda to both Standards 90.1-1999 and 90.1-2001 must be considered to determine the overall change in efficiency between Standard 90.1-1999 and Standard 90.1-2004.

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    Authors: Benenson, P.;

    A residential and industrial water-conservation scenario for California is constructed in which water consumption is disaggregated by residential end use, industrial sector, and hydrologic study area (HSA). The energy use associated with this water use was estimated for surface and groundwater delivery, distribution, heating, and waste-water treatment. For each end use and sector, water-conservation measures were delineated and their potential savings in terms of both water and attendant energy use were estimated. This material is combined to estimate the total water and energy savings potential by end use, sector, and HSA. This potential is then compared with the reported water savings to date, and finally, some conclusions and policy implications are drawn from the results. The general findings are discussed first, followed by a listing of the more important detailed results.

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    Authors: Christian Brannstrom; Matthew Fry;

    Abstract Beginning in the 2000s, the Dallas-Fort Worth metropolitan region became home to the world's largest and longest experiment in urban shale gas production, with 25,182 drilling permits issued from 2000 to 2016 in the Barnett Shale. Urban hydrocarbon governance centered on establishing statutory setback distances between drilling sites and nearest houses or other protected uses. Here we analyze qualitative interview data obtained with a rigorous sampling frame to examine processes and outcomes of municipal-level hydrocarbon governance. We find that early municipal responses (2001–2002) revealed lack of technical expertise to respond to unconventional drilling and production. Controversial wells, which residents considered too close to houses, focused governance debates in several municipalities. Municipal policymakers reported that protecting public health and safety were top priorities in determining setbacks. After 2003, policymakers copied ordinance language from neighboring municipalities and established task forces and working groups to reduce political tensions. The role of the hydrocarbon industry included frequent claims seeking to exploit the longstanding separation of mineral and property estates, which encouraged municipalities to reduce setbacks and lower potential exposure to regulatory takings lawsuits. Over time, municipal regulatory power in hydrocarbon governance decreased while industry power increased, offering several implications for corporate responsibility and social license debates.

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    Energy Policy
    Article . 2017 . Peer-reviewed
    License: Elsevier TDM
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      Energy Policy
      Article . 2017 . Peer-reviewed
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    Authors: Berry, JB;

    Oak Ridge National Laboratory (ORNL) researches and develops distributed generation technology for the Department of Energy, Energy Efficiency and Renewable Energy Distributed Energy Program. This report describes installation and operation of one such distributed generation system, a United Technology Corporation fuel cell located at the National Transportation Research Center in Knoxville, Tennessee. Data collected from June 2003 to June of 2004, provides valuable insight regarding fuel cell-grid compatibility and the cost-benefit of the fuel cell operation. The NTRC fuel cell included a high-heat recovery option so that use of thermal energy improves project economics and improves system efficiency to 59% year round. During the year the fuel cell supplied a total of 834MWh to the NTRC and provided 300MBtu of hot water. Installation of the NTRC fuel cell was funded by the Distributed Energy Program with partial funding from the Department of Defense's Climate Change Fuel Cell Buy Down Program, administered by the National Energy Technology Laboratory. On-going operational expenses are funded by ORNL's utility budget and are paid from operational cost savings. Technical information and the benefit-cost of the fuel cell are both evaluated in this report and sister reports.

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    Authors: Zhu, J. H.;

    This report summarized the research efforts and major conclusions of our University Coal Research Project, which focused on developing a new class of electrically-conductive, Cr-blocking, damage-tolerant Ag-perovksite composite materials for the cathode-interconnect contact of intermediate-temperature solid oxide fuel cell (SOFC) stacks. The Ag evaporation rate increased linearly with air flow rate initially and became constant for the air flow rate {ge} {approx} 1.0 cm {center_dot} s{sup -1}. An activation energy of 280 KJ.mol{sup -1} was obtained for Ag evaporation in both air and Ar+5%H{sub 2}+3%H{sub 2}O. The exposure environment had no measurable influence on the Ag evaporation rate as well as its dependence on the gas flow rate, while different surface morphological features were developed after thermal exposure in the oxidizing and reducing environments. Pure Ag is too volatile at the SOFC operating temperature and its evaporation rate needs to be reduced to facilitate its application as the cathode-interconnect contact. Based on extensive evaporation testing, it was found that none of the alloying additions reduced the evaporation rate of Ag over the long-term exposure, except the noble metals Au, Pt, and Pd; however, these noble elements are too expensive to justify their practical use in contact materials. Furthermore, the additionmore » of La{sub 0.8}Sr{sub 0.2}MnO{sub 3} (LSM) into Ag to form a composite material also did not significantly modify the Ag evaporation rate. The Ag-perovskite composites with the perovskite being either (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.8}Fe{sub 0.2})O{sub 3} (LSCF) or LSM were systematically evaluated as the contact material between the ferritic interconnect alloy Crofer 22 APU and the LSM cathode. The area specific resistances (ASRs) of the test specimens were shown to be highly dependent on the volume percentage and the type of the perovskite present in the composite contact material as well as the amount of thermal cycling that the specimens were subjected to during testing. The Ag-LSCF composite contact materials proved more effective in trapping Cr within the contact material and preventing Cr migration into the cathode than the Ag-LSM composites. Ag-perovskite composite contact materials are promising candidates for use in intermediate-temperature SOFC stacks with ferritic stainless steel interconnects due to their ability to maintain acceptably low ASRs while reducing Cr migration into the cathode material.« less

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