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AbstractEarthworms may promote the biodegradation of polycyclic aromatic hydrocarbons (PAHs) in soil, but the mechanism through which they exert such influence is still unknown. To determine if the stimulation of PAH degradation by earthworms is related to changes in microbial communities, a microcosm experiment was conducted consisting of columns with natural uncontaminated soil covered with PAH‐contaminated dredge sediment. Columns without and with low and high Eisenia andrei densities were prepared. Organic matter and PAH content, microbial biomass, and dehydrogenase activity (DHA) were measured in soil and sediment over time. Biolog Ecoplate™ and polymerase chain reaction using denaturing gradient gel electrophoresis were used to evaluate changes in metabolic and structural diversity of the microbial community, respectively. Earthworm activity promoted PAH degradation in soil, which was significant for biphenyl, benzo[a]pyrene, and benzo[e]pyrene. Microbial biomass and DHA activity generally did not change over the experiment. Earthworm activity did change microbial community structure, but this did not affect its functioning in terms of carbon substrate consumption. Results suggest no relationship between changes in the microbial community by earthworm activity and increased PAH disappearance. The role of shifts in soil microbial community structure induced by earthworms in PAH removal needs further investigation. Environ. Toxicol. Chem. 2012;31:794–803. © 2011 SETAC

A methodology for the sizing of domestic hot water heating and storage systems is defined, by assuming an extreme operating condition cycle composed of only two parts, a water consumption period and a system repositioning period. In both parts to respond to the extreme hot water demanding conditions, the heating is always on. The subsequent exergy analysis of this domestic hot water production system compares the irreversibility and the exergy efficiency of the water storage and the tankless situation. To carry out such analysis, some basic assumptions were made: a constant temperature heat source, a short duration operating cycle and a constant thermal energy supply. Under these circumstances it is shown that the hot water storage system leads to lower exergy losses while the tankless system is more exergy efficient, but requiring a higher instantaneous thermal power input. The use of the joule effect electricity, as the system heat source, be it a water storage one or a tankless one, maximizes the system irreversibility losses and minimizes the system exergy efficiency. The tankless system, with the joule effect electricity heat source is the worst situation.

This paper aims to correlate the in-cylinder soot formation and the exhaust particle emissions for different methods of gasoline/ethanol fueling in spark ignition engine. In particular, the engine was fueled with gasoline and ethanol separately and not, in this latter case both blended (E30) and dual fueled (EDF). For E30 the bend was direct injected and for EDF, the ethanol was injected in the combustion chamber and the gasoline into the intake duct. For both the injection configurations, the same percentage of ethanol in gasoline was supplied: 30%v/v. The measurements were carried out at 2000 and 4000 rpm, under full load, and stoichiometric condition, in small single cylinder optical engine. 2D-digital imaging was performed to follow the combustion process with a high spatial and temporal resolution through a full-bore optical piston. The two-color pyrometry was applied for the analysis of the in cylinder soot formation in the combustion chamber. Particle mass concentration was evaluated at the exhaust by means of a smoke meter. The particle size distribution function was measured in the range from 5.6 to 560 nm by an Engine Exhaust Particle Sizer (EEPS). It was observed that the use of ethanol allows the reduction of soot formation and particles emission in DI configuration. However, for E30 the in-cylinder soot formation and emissions are larger than EDF. This result is mainly due to the different contribution of gasoline. Optical analysis shows that in E30 the direct injected gasoline causes wide diffusive flames where soot formation is promoted; whereas for EDF the better evaporation and mixing of gasoline, typical of PFI configuration, results in few, small, and localized diffusive flames producing smaller particle emissions.

The use of methane as supplement to liquid fuel is one of the solution proposed for the reduction of the internal combustion engine pollutant emissions. Its intrinsic properties as the high knocking resistance and the low carbon content makes methane the most promising clean fuel. The dual fuel combustion mode allows improving the methane combustion acting mainly on the methane slow burning velocity and allowing lean burn combustion mode. An experimental investigation was carried out to study the methane-gasoline dual fuel combustion. Methane was injected in combustion chamber (DI fuel) while gasoline was injected in the intake manifold (PFI fuel). The measurements were carried out in an optically accessible small single-cylinder four-stroke engine. It was equipped with the cylinder head of a commercial 250 cc motorcycles engine representative of the most popular two-wheel vehicles in Europe. UV-visible spectroscopy measurements were performed to analyze the combustion process with high spatial and temporal resolution. In particular, UV-visible spectroscopy allows detecting the chemical markers of combustion process such as the radicals OH* and CH*. The in-cylinder lambda spatial and temporal evolution was evaluated. The combustion evolution is characterized by means of a high speed cycle resolved camera. The exhaust emissions were characterized by means of gaseous analyzers. The measurements were performed under steady state conditions at different engine operating conditions.

A new concept of a system for Combined Heat and Power generation is presented. The concept is based on hybrid use of two renewable energy sources, direct solar (thermodynamic solar) and biomass (indirect solar energy). Biomass combustion is conducted using a fluidized bed combustor. A second source of energy, given by the direct irradiation of the bed with a concentrated solar radiation, is integrated in the same system, using the fluidized bed as solar receiver. A Stirling engine converts heat into mechanical power. A Scheffler type mirror is adopted to allow irradiation of the system in a fixed focal point. Advantages of the proposed solution are illustrated and some preliminary results on the performance of the system, obtained with a simple model, are presented. The principal improvements with respect to existing systems of similar size and primary energy source are illustrated. The most important are the enhanced heat transfer processes that are realized with the help of the fluidized bed, and the possibility of continuous cogeneration during the day. Different working conditions are considered to estimate the contribution given by the burning of fuel, in presence as well as in absence of sun irradiation (as during the night). The distribution of energy shares among the different flux contributes is reported versus the amount of biomass burned per unit time. The results clearly demonstrate the advantage of coupling, in the same system, two sources for heat generation, thus maintaining the option of producing electricity without the supply of biomass fuel.

In this study we show that a chemical ferricyanide cathode can be replaced by a biological oxygen reducing cathode in a plant microbial fuel cell (PMFC) with a new record power output. A biocathode was successfully integrated in a PMFC and operated for 151 days. Plants growth continued and the power density increased reaching a maximum power output of 679 mW/m2 plant growth area (PGA) in a 10 min polarization. The two week record average power densities was 240 mW/m2 PGA. The new records were reached due to the high redox potential of oxygen reduction which was effectively catalyzed by microorganisms in the cathode. This resulted in a 127 mV higher cathode potential of the PMFC with a biocathode than a PMFC with a ferricyanide cathode. We also found that substrate availability in the anode likely limits the current generation. This work is crucial for PMFC application as it shows that PMFC can be a completely sustainable biotechnology with an improved power output.

Distributed power generation and cogeneration of heat and power is an attractive way toward a more rational conversion of fossil and bio fuels. Solid oxide fuel cell (SOFC) – gas turbine (GT) hybrid systems are emerging as the most promising candidates enabling the achievement of a cleaner and more efficient conversion of a large variety of resources across a broad power range covering from small to medium scale applications. This thesis introduces an innovative concept of SOFC-GT hybrid system that allows reaching efficiencies higher than the state of the art while enabling the carbon dioxide separation and avoiding fuel cell pressurisation technical issues. Several hybrid system design alternatives based on this concept are analysed through a thermodynamic optimisation approach combining process modelling, advanced process integration techniques and multi-objective optimisation. A number of optimal hybrid system configurations are determined for different design targets. The results consistently demonstrate the higher energy conversion performance and flexibility enabled with respect to the state of the art. The innovative concept analysis is extended to two applications for which SOFC-GT hybrid cycles are expected to provide the most significant impact toward sustainability: the small scale distributed generation and the conversion of renewable resources. A simplified version of the new hybrid system layout is especially developed for small scale distributed generation, typical of residential building applications (5-10 kWel). Experimental data are used to prove the technical feasibility of the system and to assess the performance potentially achievable with currently feasible technologies. The results of the analysis underline that energy conversion efficiencies higher than traditional centralised power generation can be achieved even at such a small scale. A systematic process integration and optimisation approach is used to assess the energy conversion performance of the original SOFC-GT hybrid cycle fuelled with hydrothermally gasified wet waste biomass. The analysis highlights the considerable potential of the integrated system that allows for converting wet waste biomass into electricity with First Law efficiency higher than 60% while simultaneously enabling the separation of the biogenic carbon dioxide.

Hot water heat stores with stratification are a common technology used in solar energy systems and reuse of waste heat. Adding a PCM module at the top of the water tank would give the system higher storage density, and compensate heat loss in the top layer. The work presented here includes experimental results and numerical simulation of the system using an explicit finite-difference method. Experiments and simulations were carried out using different cylindrical PCM modules. With only 1/16 of the volume of the store being PCM, 3/16 of water at the top of the store was held warm for 50% to 200% longer and the average energy density was increased by 20% to 45%. Furthermore, these 3/16 of water were reheated by the heat from the module after being cooled down in only 20 min.

In the last years, even more attention was paid to the alternative fuels that allow both reducing the fossil fuel consumption and the pollutant emissions. Gaseous fuels like methane and hydrogen are the most interesting in terms of engine application. This paper reports a comparison between methane and different methane/hydrogen mixtures in a single-cylinder Port Fuel/Direct Injection spark ignition (PFI/DI SI) engine operating under steady state conditions. It is representative of the gasoline engine for automotive application. Engine performance and exhaust emissions were evaluated. Moreover, 2D-digital cycle resolved imaging was performed with high spatial and temporal resolution in the combustion chamber. In particular, it allows characterizing the combustion by means of the flame propagation in terms of mean radius and velocity. Moreover, the interaction of turbulence with the local flame was evaluated. For both the engine configurations, it was observed that the addition of hydrogen results in a more efficient combustion, even though the engine configuration plays an important role. In PFI mode, the lower density of hydrogen causes a lower energy input. In DI mode, instead, the larger hydrogen diffusivity counteracts the charge stratification especially for larger hydrogen content. © 2016 Elsevier Ltd. All