• Energy Research
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Abstract The correlation between effectiveness of multiple operating parameters is a complicated issue and significant to the safe operation of solid oxide fuel cell/gas turbine (SOFC/GT) hybrid system. This paper presents a numerical analysis on biogas-fueled SOFC/GT hybrid system with a recirculation process using combustor exhaust gas. With consideration of safety constraints for critical components (fuel cell thermal crack, reformer carbon deposition, turbine blade overheat), the interaction mechanism of recirculation ratio, steam/carbon ratio and fuel/air ratio is studied from the perspective of thermodynamic analysis. Results show that the recirculation process could increase the electrical efficiency of system from 58.18% to 62.8%. However, for the safety consideration of SOFC, the acceptable recirculation ratio should be controlled between 0.17 and 0.32. Meanwhile, there exists a minimum point of turbine inlet temperature at the recirculation ratio of 0.3. With recirculation ratio switched from 0.1 to 0.3, impact of steam/carbon ratio variation on SOFC temperature gradient shrinks from 52.5% to 17.9% of the reference value. On the other hand, effect of fuel/air ratio variation on SOFC temperature gradient is promoted from 20.8% to 44.3% of the reference value, due to that oxidation reaction of biogas becomes a dominant factor. Based on these results, a parametric comparison is carried out to quantitatively describe the impact of recirculation process on the effectiveness of other parameters. Short discussion is conducted on parameter selection to acquire higher system efficiency and sufficient safety range, in which case the total output power of 176.8 kW and electrical efficiency of 61.78% could be achieved.

This paper describes the nexus of energy justice, supply and security. It advances the case that energy justice is the relatively new concept in this triangle of issues and an area requiring research. There are three central tenets of energy justice: distributional, procedural and recognition justice. Each of these tenets figures at certain stages in the energy supply chain and as a consequence there is an effect on energy supply. An example of the wind energy sector in Denmark is presented which demonstrates how the application and promotion of energy justice can enable the growth of an industry supply chain. This in turn contributes to increased energy security and national economic growth.

Abstract As interest in the distributed generation of solar power system in a building facade continues to increase, its technical performance (i.e. the amount of electricity generation) should be carefully investigated before its implementation. In this regard, this study aimed to develop the nine-node-based finite element model for estimating the technical performance of the distributed generation of solar power system in a building facade (FEM9-node), focusing on the improvement of the prediction performance. The developed model (FEM9-node) was proven to be superior to the four-node-based model (FEM4-node), which was developed in the previous study, in terms of both prediction accuracy and standard deviation. In other words, the prediction accuracy (3.55%) and standard deviation (2.93%) of the developed model (FEM9-node) was determined to be superior to those of the previous model (FEM4-node) (i.e. 4.54% and 4.39%, respectively). The practical application was carried out to enable a decision maker (e.g. construction manager, facility manager) to understand how the developed model works in a clear way. It is expected that the developed model (FEM9-node) can be used in the early design phase in an easy way within a short time. In addition, it could be extended to any other countries in a global environment.

Abstract In this study, a novel metal-foam baffle cut shell and tube heat exchanger for waste heat recovery system is presented to recover heat in the exhaust gas. A 3D numerical model is established to investigate the thermal-hydraulic performance of the metal-foam baffle heat exchangers. First, the non-baffle shell and tube heat exchangers and traditional metal baffle shell and tube heat exchangers are simulated as reference for comparison. Then, the velocity distribution, temperature distribution and pressure distribution of three different types of heat exchangers are analyzed. Afterwards, the influences of exhaust gas mass flow rate and baffle thickness on pressure drop and heat transfer performance of metal-foam baffle heat exchangers and traditional ones are evaluated. The results show that, compared with traditional metal baffle heat exchangers, all metal-foam baffle exchangers show better comprehensive performance, and the area goodness factor of metal-foam baffle heat exchangers increases by 151.89%−583.62%. Among the given heat exchangers, the metal-foam baffle heat exchanger with selected metal-foam sample (MF 40.9132) is the optimum one for waste heat recovery.

Abstract This study investigated in-situ and ex-situ biological methanation strategies for biogas upgrading potential. The addition and circulation of hydrogen with a ceramic gas diffuser unit revealed positive effects on the methanogenic process. A short-term maximum methane productivity of 2.5 L CH4 per L reactor volume per day (LVR−1 d−1) was obtained in-situ. Adverse effects of elevated dissolved hydrogen concentrations on acetogenesis became evident. Ex-situ methanation in a reactor subjected to gas recirculation for recurrent 24 h periods achieved methane formation rates of 3.7 L CH4 LVR−1 d−1. A biomethane with methane concentrations in excess of 96% successfully demonstrated the potential for gas grid injection. A theoretic model supplying gases continuously into a sequential ex-situ reactor system and steadily displacing the upgraded biogas confirmed similar methane formation performance and was advanced to a full-scale concept. Gas conversion efficiency of 95% producing biomethane at 85% methane content was attained. A hybrid model, where an in-situ grass digester is followed by an ex-situ reactor, is proposed as a novel upgrading strategy.

Abstract The preparation of a Pt–Co/C electrocatalyst for the oxygen reduction reaction in PEM fuel cells was achieved via a combined process of impregnation and seeding. The effects of initial pH of the precursor solution and Pt loading were all found to have a significant effect on both the electrocatalyst morphology and the cell performance when tested in a single PEM fuel cell. The optimum condition found for preparing the Pt–Co/C electrocatalyst was from an initial precursor solution pH of 2 at the metal loading of 23.6–30.3% (w/w). The Pt–Co/C electrocatalysts, formed under these optimal conditions, tested in a single PEM fuel cell with the carbon sub-layer, gave a cell performance of 772 mA/cm2 or 460 mW/cm2 at 0.6 V in a H2/O2 system. An electron pathway of oxygen reduction on the prepared Pt–Co/C electrocatalyst was also determined using a rotating disk electrode.

The improvement of the energy efficiency of belt conveyor systems can be achieved at equipment and operation levels. Specifically, variable speed control, an equipment level intervention, is recommended to improve operation efficiency of belt conveyors. However, the current implementations mostly focus on lower level control loops without operational considerations at the system level. This paper intends to take a model based optimization approach to improve the efficiency of belt conveyors at the operational level. An analytical energy model, originating from ISO 5048, is firstly proposed, which lumps all the parameters into four coefficients. Subsequently, both an off-line and an on-line parameter estimation schemes are applied to identify the new energy model, respectively. Simulation results are presented for the estimates of the four coefficients. Finally, optimization is done to achieve the best operation efficiency of belt conveyors under various constraints. Six optimization problems of a typical belt conveyor system are formulated, respectively, with solutions in simulation for a case study.

Abstract Considerable effort has been directed at improving the power conversion efficiency of organic photovoltaics, using oxide/metal/oxide multilayers as transparent electrodes, because of their numerous advantages including lower sheet resistance, higher transmittance, and higher flexibility in comparison to typical indium tin oxides. However, to date, most organic photovoltaics based on oxide/metal/oxide electrodes exhibit a lower conversion efficiency than indium tin oxide-based organic photovoltaics, without any clarification. In this investigation, we identify crucial factors that influence the power conversion efficiency of oxide/metal/oxide-based organic photovoltaics to fully exploit the potential of these devices, based on the correlation between the optical cavity and the transmittance. For this purpose, we fabricate five sets of inverted organic photovoltaics using poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl}) and [6,6]-Phenyl C71 butyric acid methyl ester-based active layers and ZnO/Ag/ZnO electrodes with top ZnO layers of varying thicknesses, with reference organic photovoltaics using indium tin oxides, on both rigid and flexible substrates. The highest power conversion efficiency of 8.71% and 7.53% is obtained from single-junction organic photovoltaics with 40/9/8-nm-thick ZnO/Ag/ZnO electrodes on each substrate, due to strong micro-cavity effects between the top and bottom Ag layers, despite the relatively low transmittance of the electrode. This result is supported by the relation between the electric-field intensity and the transmittance curves of the ZnO/Ag/ZnO/solution-based ZnO/active bulk optical stacks based on simulation results. Furthermore, flexible organic photovoltaics with the ZnO/Ag/ZnO electrodes demonstrate much better performance in mechanical bending tests in comparison to the performance of standard indium tin oxide-based organic photovoltaics, and the previously reported oxide/metal/oxide-based organic photovoltaics.