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Abstract To alleviate the shortage of natural gas resource and ease carbon emissions, a novel solar-driven combined cooling, heating and power (CCHP) system is designed and optimized using the genetic algorithm in the work. Different from the process of direct combustion in a conventional CCHP system, natural gas is firstly converted into syngas by a solar-driven natural gas reforming step, which is consumed in an efficient tri-generation system. Energy, economic and environmental evaluations on five office buildings in different climate zones in China are implemented to validate the advantages of the proposed system. Results show that the annual maximum primary energy saving, total cost saving, and CO2 emission reduction are 69.76%, 49.80%, and 71.55%, respectively. The system located in severe cold zones, where solar energy is abundant and building requires more heat load in whole year, achieves the highest benefits in comparison with separate systems. Furthermore, the sensitivities on the price fluctuations of electricity, natural gas and solar field to the system profits are investigated, which indicates that the influence of electricity price on the system performance is the most significant. Thus, a promising method for reducing the natural gas consumption and improving the utilization efficiency of solar energy is provided.

The aim of this study was to investigate the effectiveness of cultivating Parachlorella kessleri and Acutodesmus obliquus, in anaerobic digestion effluent (ADE) derived from the co-digestion of end-of-life dairy products with mixtures of agro-industrial wastes. To this end, their performance under sterile and non-sterile conditions and different ADE loadings was evaluated, in terms of biomass and lipid production, nutrient removal efficiency and vitality of the photosynthetic apparatus. 10% (v/v) ADE loading inhibited growth over 9-12days of cultivation, however biomass yields of 1.1 and 1gL-1, 22.7% and 19.5% (w/w) fatty acids concentration, as well as NH3-N assimilation of 49.7mgL-1 and 32.3mgL-1 and TP removal of 84.2% and 84% were recorded for P. kessleri and A. obliquus, respectively. Among all the ADE-based treatments tested, P. kessleri outperformed A. obliquus, with no differences observed between sterilized and non-sterilized ADE.

Bioplastics are alternatives of conventional petroleum-based plastics. Bioplastics are polymers processed from renewable sources and are biodegradable. This study aims at conducting an environmental impact assessment of the bioprocessing of agricultural wastes into bioplastics compared to petro-plastics using an LCA approach. Bioplastics were produced from potato peels in laboratory. In a biochemical reaction under heating, starch was extracted from peels and glycerin, vinegar and water were added with a range of different ratios, which resulted in producing different samples of bio-based plastics. Nevertheless, the environmental impact of the bioplastics production process was evaluated and compared to petro-plastics. A life cycle analysis of bioplastics produced in laboratory and petro-plastics was conducted. The results are presented in the form of global warming potential, and other environmental impacts including acidification potential, eutrophication potential, freshwater ecotoxicity potential, human toxicity potential, and ozone layer depletion of producing bioplastics are compared to petro-plastics. The results show that the greenhouse gases (GHG) emissions, through the different experiments to produce bioplastics, range between 0.354 and 0.623 kg CO2 eq. per kg bioplastic compared to 2.37 kg CO2 eq. per kg polypropylene as a petro-plastic. The results also showed that there are no significant potential effects for the bioplastics produced from potato peels on different environmental impacts in comparison with poly-β-hydroxybutyric acid and polypropylene. Thus, the bioplastics produced from agricultural wastes can be manufactured in industrial scale to reduce the dependence on petroleum-based plastics. This in turn will mitigate GHG emissions and reduce the negative environmental impacts on climate change.

In this study, Myriophyllum elatinoides growth under different nitrogen (N) concentrations (2, 250, 300, 350 and 400 mg L-1) and changes in rhizosphere bacterial community structure were investigated. High N (>300 mg L-1) concentrations caused reduction in M. elatinoides biomass. Growth tended to stabilize at 49 days. N concentration in roots were higher than that in stems and leaves under high N conditions. TN and NH4+ removal efficiencies reached 84.0% and 87.2%, respectively, in M. elatinoides surface flow constructed wetlands (SFCWs). Rhizosphere bacterial diversity increased over time. Proteobacteria, Firmicutes, Cyanobacteria, and Bacteroidetes dominated at the phylum level. Genera Turicibacter, Allochromatium, and Methylocystis increased at low N (<300 mg L-1) concentrations, while Pseudomonas increased at high N concentrations over the experimental period. Redundancy analysis showed that pH was strongly correlated with changes in rhizosphere bacterial community structure. These findings helped to insight into N removal mechanism in M. elatinoides.

Abstract In hot and humid climate such as in Japan and south east Asia, dehumidification in summer is really important for air conditioning. Temperature and humidity independent control (THIC) of air conditioning system can handle sensible heat and latent heat separately, and provide good indoor environment and achieve energy conservation. Desiccant air handling unit is one of the major solution for THIC of air conditioning system. It needs hot water to regenerate sorbent which absorbs moist in the air. Combined heat and power can supply hot water at almost constant temperature for desiccant air handling system and also contribute to the business continuity plan of commercial buildings. However, there are still uncertainties about the factors which affect energy performance of desiccant air handling unit and the optimum design and operations in hot and humid climate. The objectives of this paper are to prove factors which affect energy performance of desiccant air handling unit by measurement analysis and show optimum condition of the desiccant air handling unit under various room conditions by simulation. Measurement analysis shows that energy performance of desiccant air handling unit depends not only on the inlet air condition to dehumidification wheel but also on designed supply air humidity. Furthermore, simulation results show the optimum inlet air condition entering dehumidification wheel under various supply air absolute humidity which is determined by design room conditions. These results provide useful information of desiccant air handling unit during design and operation phase of buildings in hot and humid climate.

Abstract It is widely proposed that the global warming is mainly caused by the increase in of carbon dioxide (CO 2 ) content in the atmosphere, and that fossil fuels are the dominant sources of this CO 2 . Therefore, the quality of fossil fuels tends to be evaluated by amounts of CO 2 emissions. For the evaluation of an oil shale from this point, an on-line thermogravimetric-gas chromatographic system was used to measure CO 2 evolution profiles on temperature with a small oil shale sample. This method makes possible to estimate the amounts of CO 2 evolved from kerogen and carbonates in retorting and those from carbonates in combustion, respectively. These results will be basic data for a novel oil shale retorting process for the control of CO 2 emissions. The profiles for Thai and Colorado oil shales have shown CO 2 mainly evolved by the pyrolysis of kerogen below 550°C, and that evolved by the decomposition of carbonates above that temperature. On the other hand, the profile for Condor oil shale showed that most carbonates decomposed below 550°C, while only small amounts of carbonates decomposed above this temperature.

Biodiesel is a fuel generally consisting of a mixture of fatty acid methyl esters (FAMEs) which is used in alternative or in combination with petroleum diesel for its environmental benefits. Biodiesel is conveniently manufactured from vegetable oils by transesterification of triglycerides with methanol. However, the process brings about the concurrent formation of glycerol, which may become an oversupplied chemical if biodiesel production keeps growing. A novel biodiesel-like material (abbreviated as DMC-BioD) was developed by reacting soybean oil with dimethyl carbonate (DMC), which avoided the co-production of glycerol. The main difference between DMC-BioD and biodiesel produced from vegetable oil and methanol (MeOH-biodiesel) was the presence of fatty acid glycerol carbonate monoesters (FAGCs) in addition to FAMEs. In the following study, details regarding synthesis and composition of DMC-BioD are provided along with physical properties relevant for its use as a fuel. In addition, the production of potential pyrogenic contaminants was investigated by analytical pyrolysis and compared with those from MeOH-biodiesel, and the model compounds tristearin, triolein, trilinolein and oleic acid glycerol carbonate ester (OAGC). The presence of FAGCs influenced both fuel and flow properties, while the distribution of main pyrogenic compounds, including polycyclic aromatic hydrocarbons (PAHs), was little affected. Benefits and drawbacks of DMC as a candidate transmethylating reagent for producing biofuel from renewable resources and alternative co-products (glycerol carbonate and glycerol dicarbonate) are discussed.

The oxidation of water is essential to the sustainable production of fuels using sunlight or electricity, but designing active, stable and earth-abundant catalysts for the reaction is challenging. Now, a complex containing five iron atoms is shown to efficiently oxidize water by mimicking key features of the oxygen-evolving complex in green plants.

Abstract In this paper, the charging/melting of phase change materials (PCM) in thermal energy storage is discussed. An oil-driven system is considered in which oil acts as a heat-transfer fluid while solar salt (KNO3 – NaNO3) is used as a PCM. The aim of this study is to analyze the influence of increasing the number of heat transfer fluid HTF tubes during the charge cycle as a geometrical factor. The effect of changing inlet temperature is also examined. Four cases of geometric configurations are analyzed in this research in order to understand the effect of increasing the number of HTF tubes on the total melting time of PCM. Moreover, three inlet temperature conditions are considered to study their influences on melting time. Results indicate that by increasing the number of HTF tubes, total melting time of PCM decreases as it liquefies in four tube cases in almost 165 min, as compared with a single tube which took 234 min to completely melt. Furthermore, inlet temperature plays an essential role in reduction of total melting time.