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AbstractPreparation of uniform, spherical Li4Ti5O12 with high tap density is significant to achieve a high volumetric energy density in lithium‐ion batteries. Herein, Li4Ti5O12 microspheres with variable tap density and tunable size distribution were synthesized by a newly designed industrial spray‐drying approach. The slurry concentration, sintering time, sintering conditions after spraying, and the effect of lithium/titanium molar ratio on the lithium‐ion (Li+) storage capability were investigated. A narrow particle size distribution of around 10 μm and a high tap density close to 1.4 g cm−3 of the Li4Ti5O12 spheres can be obtained under the optimized conditions. The Li4Ti5O12 spheres can deliver a much higher capacity of 168 mAh g−1 at a rate of 1 C and show a high capacity retention of 97.7 % over 400 cycles. The synthetic conditions are confirmed to be critical for improving the electron conductivity and Li+ diffusivity by adjusting the crystal and spatial structures. As‐prepared high‐performance Li4Ti5O12 is an ideal electrode for lithium‐ion batteries or capacitors; meanwhile, the presented approach is also applicable for preparing other kind of spherical materials.

AbstractPreparation of uniform, spherical Li4Ti5O12 with high tap density is significant to achieve a high volumetric energy density in lithium‐ion batteries. Herein, Li4Ti5O12 microspheres with variable tap density and tunable size distribution were synthesized by a newly designed industrial spray‐drying approach. The slurry concentration, sintering time, sintering conditions after spraying, and the effect of lithium/titanium molar ratio on the lithium‐ion (Li+) storage capability were investigated. A narrow particle size distribution of around 10 μm and a high tap density close to 1.4 g cm−3 of the Li4Ti5O12 spheres can be obtained under the optimized conditions. The Li4Ti5O12 spheres can deliver a much higher capacity of 168 mAh g−1 at a rate of 1 C and show a high capacity retention of 97.7 % over 400 cycles. The synthetic conditions are confirmed to be critical for improving the electron conductivity and Li+ diffusivity by adjusting the crystal and spatial structures. As‐prepared high‐performance Li4Ti5O12 is an ideal electrode for lithium‐ion batteries or capacitors; meanwhile, the presented approach is also applicable for preparing other kind of spherical materials.

Abstract In the current study, a new solar-driven triple cycle is proposed to allow power generation during low insolation periods. This triple cycle integrates the solar gas-turbine top cycle, the steam Rankine cycle, and the Kalina bottom cycle. During the top cycle of the proposed system, compressed air was heated to 1000 °C or higher in the solar tower receiver. The heated compressed air was then used to drive the gas turbine to generate electricity. A Rankine cycle with a back-pressure steam turbine was utilized to recover waste heat from the gas turbine, thereby generating electricity through the steam turbine. The bottom cycle is the Kalina cycle, which comprises another back-pressure turbine and utilizes ammonia–water mixture as working fluid. After driving the steam Rankine cycle, the flue gas from the gas turbine sequentially heats the ammonia–water mixture to produce power. A new operational strategy was presented to generate electricity during low insolation period without the backup of fossil fuel. In middle insolation periods, the air is heated by the solar field and then directly drives the steam Rankine cycle, bypassing the gas turbine. In low insolation periods, the heated air directly drive the Kalina cycle, bypassing the Brayton cycle and the steam Rankine cycle. The off-design performance was investigated and the irreversibility was disclosed with the aid of the energy-utilization diagram method. Thus, the proposed system can utilize low insolation to generate electricity. This study provides a possibility to improve the solar–electric efficiency.

Abstract In the current study, a new solar-driven triple cycle is proposed to allow power generation during low insolation periods. This triple cycle integrates the solar gas-turbine top cycle, the steam Rankine cycle, and the Kalina bottom cycle. During the top cycle of the proposed system, compressed air was heated to 1000 °C or higher in the solar tower receiver. The heated compressed air was then used to drive the gas turbine to generate electricity. A Rankine cycle with a back-pressure steam turbine was utilized to recover waste heat from the gas turbine, thereby generating electricity through the steam turbine. The bottom cycle is the Kalina cycle, which comprises another back-pressure turbine and utilizes ammonia–water mixture as working fluid. After driving the steam Rankine cycle, the flue gas from the gas turbine sequentially heats the ammonia–water mixture to produce power. A new operational strategy was presented to generate electricity during low insolation period without the backup of fossil fuel. In middle insolation periods, the air is heated by the solar field and then directly drives the steam Rankine cycle, bypassing the gas turbine. In low insolation periods, the heated air directly drive the Kalina cycle, bypassing the Brayton cycle and the steam Rankine cycle. The off-design performance was investigated and the irreversibility was disclosed with the aid of the energy-utilization diagram method. Thus, the proposed system can utilize low insolation to generate electricity. This study provides a possibility to improve the solar–electric efficiency.

Cu2CdSn(S,Se)(4) is an important candidate material for thin film solar cell absorber layers. In this work, low-cost Cu2CdSnS4 nanocrytal thin film with a stannite structure has been successfully fabricated by a butyldithiocarbamate-based ethanol solution approach. The selenized Cu2CdSn(S,Se)(4) thin film shows large densely packed grains and has a suitable band gap value of 1.01 eV. The Cu2CdSn(S,Se)(4) thin film solar cell with a proof-of-concept power conversion efficiency of 3.1% was fabricated. (C) 2014 Elsevier B.V. All rights reserved.

Cu2CdSn(S,Se)(4) is an important candidate material for thin film solar cell absorber layers. In this work, low-cost Cu2CdSnS4 nanocrytal thin film with a stannite structure has been successfully fabricated by a butyldithiocarbamate-based ethanol solution approach. The selenized Cu2CdSn(S,Se)(4) thin film shows large densely packed grains and has a suitable band gap value of 1.01 eV. The Cu2CdSn(S,Se)(4) thin film solar cell with a proof-of-concept power conversion efficiency of 3.1% was fabricated. (C) 2014 Elsevier B.V. All rights reserved.

Abstract The Renewable energy power generation capacity has been rapidly increasing in China recently. Meanwhile, the contradiction between power supply and demand is becoming increasingly more prominent due to the intermittence of renewable energies. On the other hand, on the mitigation of carbon dioxide (CO2) emissions in China needs immediate attention. Power-to-Gas (PtG), a chemical energy storage technology, can convert surplus electricity into combustible gases. Subsurface energy storage can meet the requirements of long term storage with its large capacity. This paper provides a discussion of the entire PtG energy storage technology process and the current research progress. Based on the comparative study of different geological storage schemes for synthetic methane, their respective research progress and limitations are noted. In addition, a full investigation of the distribution and implementation of global PtG and CO2 capture and storage (CCS) demonstration projects is performed. Subsequently, the opportunities and challenges of the development of this technology in China are discussed based on techno-economic and ecological effects analysis. While PtG is expected to be a revolutionary technology that will replace traditional power systems, the main issues of site selection, energy efficiency and the economy still need to be adequately addressed. Additionally, based on the comprehensive discussion of the results of the analysis, power-to-gas and subsurface energy storage implementation strategies, as well as outlook in China are presented.

Abstract The Renewable energy power generation capacity has been rapidly increasing in China recently. Meanwhile, the contradiction between power supply and demand is becoming increasingly more prominent due to the intermittence of renewable energies. On the other hand, on the mitigation of carbon dioxide (CO2) emissions in China needs immediate attention. Power-to-Gas (PtG), a chemical energy storage technology, can convert surplus electricity into combustible gases. Subsurface energy storage can meet the requirements of long term storage with its large capacity. This paper provides a discussion of the entire PtG energy storage technology process and the current research progress. Based on the comparative study of different geological storage schemes for synthetic methane, their respective research progress and limitations are noted. In addition, a full investigation of the distribution and implementation of global PtG and CO2 capture and storage (CCS) demonstration projects is performed. Subsequently, the opportunities and challenges of the development of this technology in China are discussed based on techno-economic and ecological effects analysis. While PtG is expected to be a revolutionary technology that will replace traditional power systems, the main issues of site selection, energy efficiency and the economy still need to be adequately addressed. Additionally, based on the comprehensive discussion of the results of the analysis, power-to-gas and subsurface energy storage implementation strategies, as well as outlook in China are presented.