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AbstractPreparation of uniform, spherical Li4Ti5O12 with high tap density is significant to achieve a high volumetric energy density in lithium‐ion batteries. Herein, Li4Ti5O12 microspheres with variable tap density and tunable size distribution were synthesized by a newly designed industrial spray‐drying approach. The slurry concentration, sintering time, sintering conditions after spraying, and the effect of lithium/titanium molar ratio on the lithium‐ion (Li+) storage capability were investigated. A narrow particle size distribution of around 10 μm and a high tap density close to 1.4 g cm−3 of the Li4Ti5O12 spheres can be obtained under the optimized conditions. The Li4Ti5O12 spheres can deliver a much higher capacity of 168 mAh g−1 at a rate of 1 C and show a high capacity retention of 97.7 % over 400 cycles. The synthetic conditions are confirmed to be critical for improving the electron conductivity and Li+ diffusivity by adjusting the crystal and spatial structures. As‐prepared high‐performance Li4Ti5O12 is an ideal electrode for lithium‐ion batteries or capacitors; meanwhile, the presented approach is also applicable for preparing other kind of spherical materials.

Abstract In the current study, a new solar-driven triple cycle is proposed to allow power generation during low insolation periods. This triple cycle integrates the solar gas-turbine top cycle, the steam Rankine cycle, and the Kalina bottom cycle. During the top cycle of the proposed system, compressed air was heated to 1000 °C or higher in the solar tower receiver. The heated compressed air was then used to drive the gas turbine to generate electricity. A Rankine cycle with a back-pressure steam turbine was utilized to recover waste heat from the gas turbine, thereby generating electricity through the steam turbine. The bottom cycle is the Kalina cycle, which comprises another back-pressure turbine and utilizes ammonia–water mixture as working fluid. After driving the steam Rankine cycle, the flue gas from the gas turbine sequentially heats the ammonia–water mixture to produce power. A new operational strategy was presented to generate electricity during low insolation period without the backup of fossil fuel. In middle insolation periods, the air is heated by the solar field and then directly drives the steam Rankine cycle, bypassing the gas turbine. In low insolation periods, the heated air directly drive the Kalina cycle, bypassing the Brayton cycle and the steam Rankine cycle. The off-design performance was investigated and the irreversibility was disclosed with the aid of the energy-utilization diagram method. Thus, the proposed system can utilize low insolation to generate electricity. This study provides a possibility to improve the solar–electric efficiency.

Cu2CdSn(S,Se)(4) is an important candidate material for thin film solar cell absorber layers. In this work, low-cost Cu2CdSnS4 nanocrytal thin film with a stannite structure has been successfully fabricated by a butyldithiocarbamate-based ethanol solution approach. The selenized Cu2CdSn(S,Se)(4) thin film shows large densely packed grains and has a suitable band gap value of 1.01 eV. The Cu2CdSn(S,Se)(4) thin film solar cell with a proof-of-concept power conversion efficiency of 3.1% was fabricated. (C) 2014 Elsevier B.V. All rights reserved.

Abstract The Renewable energy power generation capacity has been rapidly increasing in China recently. Meanwhile, the contradiction between power supply and demand is becoming increasingly more prominent due to the intermittence of renewable energies. On the other hand, on the mitigation of carbon dioxide (CO2) emissions in China needs immediate attention. Power-to-Gas (PtG), a chemical energy storage technology, can convert surplus electricity into combustible gases. Subsurface energy storage can meet the requirements of long term storage with its large capacity. This paper provides a discussion of the entire PtG energy storage technology process and the current research progress. Based on the comparative study of different geological storage schemes for synthetic methane, their respective research progress and limitations are noted. In addition, a full investigation of the distribution and implementation of global PtG and CO2 capture and storage (CCS) demonstration projects is performed. Subsequently, the opportunities and challenges of the development of this technology in China are discussed based on techno-economic and ecological effects analysis. While PtG is expected to be a revolutionary technology that will replace traditional power systems, the main issues of site selection, energy efficiency and the economy still need to be adequately addressed. Additionally, based on the comprehensive discussion of the results of the analysis, power-to-gas and subsurface energy storage implementation strategies, as well as outlook in China are presented.

Abstract Hydrothermal treatment (HT) is one of the efficient approaches for upgrading municipal solid waste (MSW). In the present study, emission characteristics of polycyclic aromatic hydrocarbons (PAHs) from hydrothermally treated municipal solid waste (H-MSW) combustion alone and H-MSW/coal co-combustion were investigated at different temperatures. The results showed that for all fuel combustion, the majority of PAHs were 3- or 4-ring PAHs. In addition, flue gas had the highest yields of PAHs followed by fly ash and bottom ash, while the ring number of dominated PAHs in fly ash was higher than those in flue gas and bottom ash. Compared to MSW, H-MSW combustion generated less PAHs at the value of 1131.95–7649.24 μg/g. The blending of H-MSW and coal reduced total PAH emissions and positive interactions were observed between H-MSW and coal during co-combustion. The toxicity equivalent quantity (TEQ) values of the PAHs from combustion were in the order MSW > H-MSW > H-MSW/coal, which was consistent with the total PAH emissions. The present study illustrated that significant reduction of PAH emissions and toxicity from combustion could be achieved by HT and the blending of H-MSW and coal.

China’s steel industry is an energy-intensive sector. Synergistic reduction of emissions of CO2 and air pollutants (SO2, NOx, and PM2.5) in the steel industry has an important practical significance for climate change and air pollution control. According to the CO2 emission reduction intensity targets (CERO) and air pollutant emission targets (PERO) for 2020 and 2030, 28 types of energy-saving and emission reduction technologies (20 types of carbon reduction technology and eight types of air pollution end-of-pipe technology) were selected for examination, and a two-stage dynamic optimization model with collaborative implementation of PERO and CERO was built to assess the near future (2015–2020) and long-term (2020–2030) implementation plans for synergistic emissions reduction of CO2 and air pollutants. The results show that in the near future, the implementation of PERO will have a greater synergistic effect on CO2 emission reduction. CO2 emission reduction under PERO in 2020 will be 97 million tons (Mt) higher than that of CERO, an increase of nearly 26%. However, the effects of implementing CERO are better in the long run. Under CERO, the emission reductions of SO2, NOx, and PM2.5 in 2030 are 2.44 Mt, 1.47 Mt, and 0.86 Mt, respectively, and 7%, 4%, and 5% higher than the implementation of PERO. As far as marginal abatement cost is concerned, in the near future, the marginal abatement costs of CO2 and air pollutant equivalents are 1.06 yuan/kgCO2 and 133 yuan/kg pollution equivalent (pe) under PERO, which are 23% and 11% lower than that of CERO, while in the long run, the marginal abatement costs of CO2 and pollutant equivalents under CERO are 0.025 yuan/kgCO2 and 2.73 yuan/kgpe, about 96% and 95% lower than that of PERO.

Robust mitigation options will play significant role in achieving the target of limiting global change to below 1.5 °C above pre-industrial levels by 2100. To support cooperation for mitigation development, we establish a real options-based model to evaluate the rational decisions of exercising the abandon option for carbon capture and storage-enhanced oil recovery (CCS-EOR) projects under oil market and geological uncertainties. Three possible cooperative mechanisms (fixed carbon dioxide (CO2) price, oil-indexed CO2 price, and joint venture contracts) among CO2-EOR stakeholders are evaluated. The results show that the conflicts in profit maximization targets for different stakeholders in cooperative mitigation are to a great extent unable to be avoided. A joint venture business model is preferred in cooperative mitigation as it can effectively weaken such conflicts. And it is more reasonable to provide incentives to the downstream of the CO2-EOR chain than compensating the adoption cost of carbon capture technologies in the upstream. From a global perspective, the inefficient cooperation can be a main barrier that hinders the development of deep-cutting options. Global mitigation strategies should not only focus on promoting technology progress but also the design of innovative business models to balance the benefits among stakeholders. A joint venture business model is recommended in both the developed and developing countries for seizing the early mitigation opportunities.

In this paper, metabolic evaluation has been employed for better understanding the trends in urban environmental changes. Due to the urban activities cause impacts not only on local level but also a broader scale, Hybrid Emergy-LCA (HEML), a combining approach of Emergy Analysis (EMA) and Life Cycle Assessment (LCA) is structured to quantitatively investigate the mechanism. For the similarity across many emerging cities in China, a large-scale sub-urban residential area named Tian Tongyuan (Try) in Beijing was chosen for testing the HEML. Objective indicators of live quality and negative impacts are both considered. Analysis indicates that the household Emergy input of TTY is 1.76E+16 sej/yr, while the prominent environmental impact is induced by Photochemical Oxidant Creation Potentials (POCP), 4.58E+05 g ethane eq./yr. The sustainable performance constructed by its live quality and environmental impacts of TTY is found as 98.80% as that of Beijing average. Mitigation polices on the building sector should be proposed because of its dominating impacts among various consuming ends of energy and materials. (C) 2009 Elsevier B.V. All rights reserved.