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AbstractPreparation of uniform, spherical Li4Ti5O12 with high tap density is significant to achieve a high volumetric energy density in lithium‐ion batteries. Herein, Li4Ti5O12 microspheres with variable tap density and tunable size distribution were synthesized by a newly designed industrial spray‐drying approach. The slurry concentration, sintering time, sintering conditions after spraying, and the effect of lithium/titanium molar ratio on the lithium‐ion (Li+) storage capability were investigated. A narrow particle size distribution of around 10 μm and a high tap density close to 1.4 g cm−3 of the Li4Ti5O12 spheres can be obtained under the optimized conditions. The Li4Ti5O12 spheres can deliver a much higher capacity of 168 mAh g−1 at a rate of 1 C and show a high capacity retention of 97.7 % over 400 cycles. The synthetic conditions are confirmed to be critical for improving the electron conductivity and Li+ diffusivity by adjusting the crystal and spatial structures. As‐prepared high‐performance Li4Ti5O12 is an ideal electrode for lithium‐ion batteries or capacitors; meanwhile, the presented approach is also applicable for preparing other kind of spherical materials.

Abstract In the current study, a new solar-driven triple cycle is proposed to allow power generation during low insolation periods. This triple cycle integrates the solar gas-turbine top cycle, the steam Rankine cycle, and the Kalina bottom cycle. During the top cycle of the proposed system, compressed air was heated to 1000 °C or higher in the solar tower receiver. The heated compressed air was then used to drive the gas turbine to generate electricity. A Rankine cycle with a back-pressure steam turbine was utilized to recover waste heat from the gas turbine, thereby generating electricity through the steam turbine. The bottom cycle is the Kalina cycle, which comprises another back-pressure turbine and utilizes ammonia–water mixture as working fluid. After driving the steam Rankine cycle, the flue gas from the gas turbine sequentially heats the ammonia–water mixture to produce power. A new operational strategy was presented to generate electricity during low insolation period without the backup of fossil fuel. In middle insolation periods, the air is heated by the solar field and then directly drives the steam Rankine cycle, bypassing the gas turbine. In low insolation periods, the heated air directly drive the Kalina cycle, bypassing the Brayton cycle and the steam Rankine cycle. The off-design performance was investigated and the irreversibility was disclosed with the aid of the energy-utilization diagram method. Thus, the proposed system can utilize low insolation to generate electricity. This study provides a possibility to improve the solar–electric efficiency.

Cu2CdSn(S,Se)(4) is an important candidate material for thin film solar cell absorber layers. In this work, low-cost Cu2CdSnS4 nanocrytal thin film with a stannite structure has been successfully fabricated by a butyldithiocarbamate-based ethanol solution approach. The selenized Cu2CdSn(S,Se)(4) thin film shows large densely packed grains and has a suitable band gap value of 1.01 eV. The Cu2CdSn(S,Se)(4) thin film solar cell with a proof-of-concept power conversion efficiency of 3.1% was fabricated. (C) 2014 Elsevier B.V. All rights reserved.

Исследование ландшафтов всегда было традиционным научным направлением географии. В России подобная направленность исследований остаётся актуальной, несмотря на то, что термины «геоэкология» и «ландшафтная экология» сегодня более распространены в англоязычном научном сообществе. Наш краткий обзор показывает значительное ускорение антропогенных ландшафтных изменений в Европе, Центральной Азии и азиатской части России за последние пять десятилетий. Ландшафтные исследования в антропоцене должны быть направлены на достижение и сохранение устойчивости ландшафта при его высокой производительности, что включает в себя прекращение деградации ландшафтов, развитие культурных и сохранение природных ландшафтов. Чистая вода и чистый воздух, плодородные и здоровые почвы для производства продуктов питания и других экосистемных услуг, а также биологически разнообразная зеленая среда являются атрибутами ландшафтов, обеспечивающих выживание и благополучие населения. Дисциплинарные и междисциплинарные исследования должны генерировать знания, инновации и правила принятия действенных решений. Генерация знаний в глобализованном мире основана на сборе больших массивов данных и моделировании сценариев. Международные длительные полевые опыты и системы агроэкологического мониторинга будут предоставлять данные для экосистемных моделей и систем поддержки принимаемых решений. Landscape research has been a traditional scientific discipline of geography. This is still the case in Russia, whilst the terms geo-ecology and landscape ecology have become established in the English speaking scientific community. Our short review reveals huge and accelerating anthropogenic landscape transformations in Europe, Central Asia and Asian Russia since the end the 1960s. Landscape research in the Anthropocene has to focus on achieving landscape sustainability at high productivity. This includes halting landscape degradation, developing cultural landscapes, and maintaining semi-natural landscapes. Clean water and air, fertile and healthy soils for food and other ecosystem services and a green and bio-diverse environment are attributes of landscapes for the survival and well-being of humans. Research has to generate knowledge, innovations and decision rules by disciplinary, interdisciplinary and trans-disciplinary work. Knowledge generation in a globalized world is based on big data gathering and scenario modelling. International long-term experiments and agri-environmental monitoring systems will deliver data for ecosystem models and decision support systems.

Abstract The Renewable energy power generation capacity has been rapidly increasing in China recently. Meanwhile, the contradiction between power supply and demand is becoming increasingly more prominent due to the intermittence of renewable energies. On the other hand, on the mitigation of carbon dioxide (CO2) emissions in China needs immediate attention. Power-to-Gas (PtG), a chemical energy storage technology, can convert surplus electricity into combustible gases. Subsurface energy storage can meet the requirements of long term storage with its large capacity. This paper provides a discussion of the entire PtG energy storage technology process and the current research progress. Based on the comparative study of different geological storage schemes for synthetic methane, their respective research progress and limitations are noted. In addition, a full investigation of the distribution and implementation of global PtG and CO2 capture and storage (CCS) demonstration projects is performed. Subsequently, the opportunities and challenges of the development of this technology in China are discussed based on techno-economic and ecological effects analysis. While PtG is expected to be a revolutionary technology that will replace traditional power systems, the main issues of site selection, energy efficiency and the economy still need to be adequately addressed. Additionally, based on the comprehensive discussion of the results of the analysis, power-to-gas and subsurface energy storage implementation strategies, as well as outlook in China are presented.

Most of the world’s mountain glaciers have been retreating for more than a century in response to climate change. Glacier retreat is evident on all continents, and the rate of retreat has accelerated during recent decades. Accurate, spatially explicit information on the position of glacier margins over time is useful for analyzing patterns of glacier retreat and measuring reductions in glacier surface area. This information is also essential for evaluating how mountain ecosystems are evolving due to climate warming and the attendant glacier retreat. Here, we present a non-comprehensive spatially explicit dataset showing multiple positions of glacier fronts since the Little Ice Age (LIA) maxima, including many data from the pre-satellite era. The dataset is based on multiple historical archival records including topographical maps; repeated photographs, paintings, and aerial or satellite images with a supplement of geochronology; and own field data. We provide ESRI shapefiles showing 728 past positions of 94 glacier fronts from all continents, except Antarctica, covering the period between the Little Ice Age maxima and the present. On average, the time series span the past 190 years. From 2 to 46 past positions per glacier are depicted (on average: 7.8).

Abstract Hydrothermal treatment (HT) is one of the efficient approaches for upgrading municipal solid waste (MSW). In the present study, emission characteristics of polycyclic aromatic hydrocarbons (PAHs) from hydrothermally treated municipal solid waste (H-MSW) combustion alone and H-MSW/coal co-combustion were investigated at different temperatures. The results showed that for all fuel combustion, the majority of PAHs were 3- or 4-ring PAHs. In addition, flue gas had the highest yields of PAHs followed by fly ash and bottom ash, while the ring number of dominated PAHs in fly ash was higher than those in flue gas and bottom ash. Compared to MSW, H-MSW combustion generated less PAHs at the value of 1131.95–7649.24 μg/g. The blending of H-MSW and coal reduced total PAH emissions and positive interactions were observed between H-MSW and coal during co-combustion. The toxicity equivalent quantity (TEQ) values of the PAHs from combustion were in the order MSW > H-MSW > H-MSW/coal, which was consistent with the total PAH emissions. The present study illustrated that significant reduction of PAH emissions and toxicity from combustion could be achieved by HT and the blending of H-MSW and coal.