• Energy Research
• Closed Access close
• Open Source close
• Embargo close
• Karlsruhe Institute of Technology close

Atmospheric concentrations of the greenhouse gas nitrous oxide (N(2)O) have increased significantly since pre-industrial times owing to anthropogenic perturbation of the global nitrogen cycle, with animal production being one of the main contributors. Grasslands cover about 20 per cent of the temperate land surface of the Earth and are widely used as pasture. It has been suggested that high animal stocking rates and the resulting elevated nitrogen input increase N(2)O emissions. Internationally agreed methods to upscale the effect of increased livestock numbers on N(2)O emissions are based directly on per capita nitrogen inputs. However, measurements of grassland N(2)O fluxes are often performed over short time periods, with low time resolution and mostly during the growing season. In consequence, our understanding of the daily and seasonal dynamics of grassland N(2)O fluxes remains limited. Here we report year-round N(2)O flux measurements with high and low temporal resolution at ten steppe grassland sites in Inner Mongolia, China. We show that short-lived pulses of N(2)O emission during spring thaw dominate the annual N(2)O budget at our study sites. The N(2)O emission pulses are highest in ungrazed steppe and decrease with increasing stocking rate, suggesting that grazing decreases rather than increases N(2)O emissions. Our results show that the stimulatory effect of higher stocking rates on nitrogen cycling and, hence, on N(2)O emission is more than offset by the effects of a parallel reduction in microbial biomass, inorganic nitrogen production and wintertime water retention. By neglecting these freeze-thaw interactions, existing approaches may have systematically overestimated N(2)O emissions over the last century for semi-arid, cool temperate grasslands by up to 72 per cent.

Abstract Every day and innumerably, road vehicles of different types pass flat roadside-placed elements like stable or temporary traffic signs, noise barriers, charge devices, etc. The elements are exposed to a vehicle-specific flow and pressure field, i.e. to transient loads. In order to quantify the involved phenomena, full-scale experiments were performed for six different vehicle types and three sizes of square plates, which were aligned in three different configurations with respect to the vehicle׳s track. For the measurement of loads effecting the plate, the pressure multi-tapping technique was implemented with high temporal and spatial resolution. The experiments delivered a broad database for the proper quantification of vehicle induced loads on flat elements as a function of vehicle type, vehicle velocity and passing distance to the plate, element size as well as spatial plate alignment with respect to the vehicle.

This study is to our knowledge the first to describe the effect of a Gas-Gas Heater (GGH) of a coal fired power plant's has on (i) the H2SO4 concentration and (ii) the particle/aerosol number concentration and particle size distribution present in the flue gas. In the absence of a GGH, homogenous nucleation takes places inside the Wet Flue Gas Desulphurisation (WFGD) converting the gaseous H2SO4 into aerosol H2SO4. This leads to a high aerosol number concentration behind the WFGD with 80% of the aerosols being smaller than 0.02 μm. This implies that an amine based carbon capture (CC) installation treating this flue gas can suffer from amine mist formation due to the high amount of available nuclei (i.e., H2SO4 aerosols) resulting in high amine emissions. In contrast, in the presence of a GGH not only 70% of the H2SO4 is removed from the flue gas (measured at the Nijmegen powerplant), but also homogenous nucleation in the WFGD is prevented resulting in low particle number concentrations. The flue gas leaving the GGH will not create any mist formation issues in an amine based CC installation due to the low amount of nuclei present in the flue gas. It is not the reduction in H2SO4 concentration by 70% inside the GGH as such that prevents mist formation but absence of H2SO4 in its aerosol form. These results are most likely quite widely transformable to other power plants that burn low sulfur coal i.e., around 0.7 weight%. This information will serve future pilot and demo CC installation around the world; in particular when retrofitted on power plants that have a GGH.

Abstract In this study, voltage relaxation and impedance spectroscopy are introduced as in-operando methods for detecting lithium plating in commercial lithium-ion cells with graphitic anodes. Voltage relaxation is monitored subsequent to defined charge steps of variable amplitudes, charge throughputs, termination criteria and at different ambient temperatures yielding dependencies over a wide experimental parameter range. An adapted differential voltage analysis is presented to resolve the characteristic mixed potential evolving in case of plating. Impedance spectroscopy is applied in parallel to the relaxation phase to trace a possible alteration of the cell's impedance due to the concurrent depletion of reversibly deposited lithium. The introduced voltage differentials are shown to resolve the mixed potential with restrictions only for little charge throughputs. The comparison of voltage relaxation and already established stripping discharge reveals similarities of the underlying physicochemical processes and allows an estimate of the amount of deposited lithium in case of relaxation. In the evolution of the cell's impedance, a reversible shrinkage of the high frequency intersection resistance and the arc representing the anodic charge transfer process are identified as indicators towards plating. The presented methods solely rely on non-destructive measurement quantities and thus are fully suitable for the application in battery management systems.

A fixed-bed reactor was used to pyrolyse small samples of oil shale particles under an inert gas flow (argon). A special sampling technique was used for collecting organic products eluted from the reactor at different temperatures and time intervals. The pyrolysis products were analysed by capillary gas chromatography and the total product evolution rate was investigated as a function of temperature and time. The maximum volatile product evolution temperature was ∼440°C. The aliphatic hydrocarbon content of the pyrolysis products was characterized and classified by carbon number. In addition, the performance of the experimental system was assessed by a carbon balance. The recovery of total organic carbon as organic volatile products, CO2 and coke was determined.

Abstract Despite the comparatively limited stock of vehicles, heavy-duty road transport is responsible for a major share of CO2 emissions from the European transport sector. Electric trucks powered by overhead lines, so-called trolley trucks or catenary hybrid trucks, have been proposed as a potential GHG mitigation option. However, from the perspective of the energy system, trolley trucks constitute an additional and inflexible electricity demand. Here, we analyse scenarios with an ambitious European market diffusion of trolley trucks and their impact on the electricity system and CO2 emissions. Our results show that trolley trucks can noteworthily reduce the CO2 emissions from heavy road transport even when the additional CO2 emissions from electricity generation are taken into account. Furthermore, the actual impact of the additional load from trolley trucks on the total energy system is limited. Compared to the anticipated electricity demand from passenger cars in 2030, trolley trucks require less energy and the load is more equally distributed over daytime. Our findings thus show that electric trucks are an interesting option for CO2 mitigation in heavy road transport.

The average antimony concentration in municipal solid waste is estimated to be about 10-60 ppm. Thermodynamical models predict a volatile behavior for antimony compounds, yet literature mass balances show that about 50% of the antimony input remains in the grate ashes. This fact can be explained by the formation of thermally stable antimonates in the fuel bed due to interactions with alkali or earth-alkali metals. Thermogravimetric experiments revealed an increased thermal stability for antimony oxide in presence of oxygen and calcium oxide. Spiking experiments on the test incinerator TAMARA showed that chlorination processes have a strong effect on antimony volatilization whereas high fuel-bed temperatures and addition of antimony oxide only have a moderate effect. In the grate ashes, antimony shows a pH-depending leaching property, which is typical for anionic species. This fact supports the thesis that antimony is present in the grate ashes in an anionic speciation.

Abstract Two full continuous countercurrent processes for the recovery of trivalent actinides (An(III)) from a simulated PUREX raffinate solution (HAR) were developed and demonstrated using miniature laboratory-scale centrifugal contactors: the innovative SANEX and the 1-cycle SANEX processes. The innovative SANEX process was successfully demonstrated in a 16 + 16 stage flow sheet. In the first 16 stages, Am(III), Cm(III), and Ln(III) were quantitatively co-extracted from the HAR by a TODGA-based extractant. The decontamination factors (DFs) for the major non-lanthanide fission products were >103. The loaded extractant was then subjected to two stripping steps using the second 16 stages of the flow sheet. The first stripping step concerned the selective stripping of Am(III) + Cm(III) at fairly high acidity (0.35 ML−1 HNO3) with the new hydrophilic N-chelating selective ligand SO3-Ph-BTP. High An(III) recoveries >99.8% were achieved with high decontamination factors toward the trivalent lanthanides. In the second step, the residual stripping of Ln(III) from loaded organic phase was carried out quantitatively using 0.5 ML−1 citric acid solution at pH 3. However, Ru proved to be the only exception and remained to a large extent (12.8%) in the spent extractant. A more challenging route also studied at our laboratories is the 1-cycle SANEX process, i.e. direct An(III) separation from HAR using an extractant mixture of CyMe4BTBP and TODGA in 1-octanol/TPH diluent. A demonstration process was also successfully implemented using a 16 + 16 stage flow sheet on the above-mentioned laboratory-scale centrifugal contactor rig. It was demonstrated that a selective extraction and high recovery of >99.8% of Am(III) and >99.4% Cm(III) was achieved with low contamination of fission products. Both new processes are major contributions to the field of partitioning and important steps forward toward the industrial implementation of MA partitioning.

Abstract Experimental and theoretical investigations have been performed on critical heat flux ( CHF ) and turbulent mixing in tight, hexagonal, 7-rod bundles. Freon-12 was used as working fluid due to its low latent heat, low critical pressure and well known properties. It has been found that the two-phase mixing coefficient depends mainly on mass flux. It increases with decreasing mass flux and ranges from 0.01 to 0.04 for the test conditions considered. More than 900 CHF data points have been obtained in a large range of parameters: pressure 1.0–3.0 MPa and mass flux 1.0–6.0 Mg/m 2 s. The effect of different parameters on CHF has been analysed. It has been found that the effect of pressure, mass flux and vapour quality on CHF is similar to that observed in circular tubes. Nevertheless, the CHF in the tight rod bundle is much lower than that in a circular tube of the same equivalent hydraulic diameters. The effect of wire wraps on CHF is mainly dependent on local vapour qualities and subsequently on flow regimes. Based on subchannel flow conditions, the effect of radial power distribution on CHF is small. Comparison of the test results with CHF prediction methods underlines the need for further work.