• Energy Research
• 2021-2025close
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• 7. Clean energy close

Cities are progressively heightening their climate aspirations to curtail urban carbon emis- sions and establish a future where economies and communities can flourish within the Earth’s eco- logical limits. Consequently, numerous climate initiatives are being launched to control urban car- bon emissions, targeting various sectors, including transport, residential, agricultural, and energy. However, recent scientific literature underscores the disproportionate distribution of climate poli- cies. While cities in the Global North have witnessed several initiatives to combat climate change, cities in the Global South remain uncovered and highly vulnerable to climate hazards. To address this disparity, we employed the Balanced Iterative Reducing and Clustering using the Hierarchies (BRICH) algorithm to cluster cities from diverse geographical areas that exhibit comparable socio- economic profiles. This clustering strives to foster enhanced cooperation and collaboration among cities globally, with the goal of addressing climate change in a comprehensive manner. In summary, we identified similarities, pa􏰀erns, and clusters among peer cities, enabling mutual and generaliza- ble learning among worldwide peer-cities regarding urban climate policy exchange. This exchange occurs through three approaches: (i) inner-mutual learning, (ii) cross-mutual learning, and (iii) outer-mutual learning. Our findings mark a pivotal stride towards a􏰀aining worldwide climate ob- jectives through a shared responsibility approach. Furthermore, they provide preliminary insights into the implementation of “urban climate policy exchange” among peer cities on a global scale.

Abstract Energy storage systems (ESS) are widely used in active distribution networks (ADN) to smoothen the drastic fluctuation of renewable energy sources (RES). In order to enhance the scalability and flexibility of ESS, a virtual energy storage system (VESS), which is composed of battery energy storage system (BESS), RES as well as flexible loads (FL), is developed in this paper to realize the functionalities of ESS in more cost-effective way in ADN. Aiming at achieving voltage regulation, dynamic pricing strategies based on system voltage condition are designed for VESS. A distributed real-time power management model containing dynamic pricing strategies is proposed to accomplish the voltage regulation and economic power sharing in VESS. Moreover, a set of distributed algorithms, over time-varying unbalanced directed networks, are designed for dynamic pricing strategies and optimal power management model. Furthermore, the convergence property, optimality and system voltage stability are explained by detailed mathematical analysis. Three various case studies which were ran on a real time digital simulator (OPAL-RT OP5600) were designed to validate the effectiveness of the strategy. Finally, simulation results show that the economic power dispatch and voltage regulation are achieved among VESS simultaneously, even in the presence of time-varying directed and unbalanced communication networks.

Wide‐bandgap (WBG) perovskite solar cells (PSCs) are acknowledged as promising candidates for tandem solar cells and building photovoltaics. It is well known that cesium‐based all‐inorganic halide WBG perovskites possess the comparable optoelectronic properties as the organic–inorganic counterparts, but exhibit superior thermal stability. Among them, CsPbIBr2 is considered a feasible material for tandem solar cells after balancing the bandgap and stability of the inorganic perovskite. However, CsPbIBr2 PSCs are often subjected to drastic interfacial charge recombination especially in carbon‐based device structure derived from the chemical bonding defects (i.e., uncoordinated Pb2+) naked on CsPbIBr2 soft lattice, which dramatically limits overall efficiency of CsPbIBr2 WBG PSCs. Herein, a trimethyl ammonium salt hexyltrimethylammonium bromide is presented for CsPbIBr2/carbon interfacial modification. Benefiting from the −N+(CH3)3 passivation effect and −C6H13 hydrophobic alkyl chain, the optimal device with highly smooth morphology and sufficient charge extraction exhibits a champion power conversion efficiency of 11.24% and improved long‐term stability with 99.7% and 79.7% efficiency retention under dry air atmosphere and continuous 85 °C thermal stress, indicating the valuable potential application of the lattice solidified CsPbIBr2 WBG PSCs.

The use of superconducting magnetic energy storage (SMES) has been widely reported in the literature to mitigate various load frequency control (LFC) issues in a multi-area power system. Most of these are thyristor based SMES, employing proportional type controllers. In this paper, a supervisory adaptive model predictive control scheme (AMPC) is proposed for a voltage source converter based relatively small rating SMES for LFC application. The reference power command for the SMES is derived from the AMPC in such a manner that it effectively handles the operational constraints of the SMES system. A representative first-order system emulating the inner loop dynamics of the SMES chopper system, is tuned offline via genetic algorithm (GA) and is used to derive dynamic constraints for the cost function in AMPC. The effectiveness of the scheme is demonstrated through simulations.

Interfacial resistance at electrode‐high Li+ conductive solid electrolytes must be reduced well to develop high‐power all‐solid‐state batteries using oxide‐based solid electrolytes (Ox‐SSBs). Herein, crystalline electrode films of LiCoO2 (LCO) are formed on a high Li+ conductive crystalline‐glass solid electrolyte sheet, Li1.3Al0.3Ti2(PO4)3 (LATP) (σ25 °C = 1 × 10−4 S cm−1), at room temperature by aerosol deposition (AD), and the effects of the annealing temperature on the interfacial resistivities (Rint) at the LCO/LATP are investigated. The Rint visibly increases by annealing over 500 °C with the growth of Co3O4 as a reactant. In contrast, Rint is reduced to ≈100 Ω cm2 by low‐temperature annealing at 250–350 °C due to superior contact through the structural rearrangement of an artificial metastable interface formed by the AD. These results are applied to bulk‐type Ox‐SSB, Li/Li7La3Zr2O12(LLZ)/LCO–LATP, and our best Ox‐SSB delivers a discharge capacity of 100 mA cm−2 at 100 °C.

Abstract The prime purpose of this work is to prepare a novel kind of Pickering interfacial solid catalysts for biodiesel production to meet the requirements of highly efficiency and environmental benign. To achieve this goal, the core–shell P[xSPA-yDABCO]@SiO2@Fe3O4 composite materials with a shell of photo-responsive and base catalytic sites were manufactured by means of layer-by-layer fabrication method. The modified materials, entirely characterized by transmission electron microscopy (TEM), scanning electron microscope (SEM), Fourier transform infrared (FT-IR) spectra, X-ray powder diffraction (XRD) and magnetization versus magnetic (VSM) techniques, demonstrated sufficient catalytic active sites and photo-responsive sites. Among all the so-prepared catalysts, P[3SPA-2DABCO]@SiO2@Fe3O4 performs extremely well and can stabilize soybean oil-in-methanol Pickering emulsion for 24 h, achieving a biodiesel yield up to 98.2% at a catalyst dosage of 5 wt% after the reaction time of 5 h at 60 °C. Furthermore, the double responsive solid catalyst can be readily separated from the mixture of reaction by an external magnet and UV irradiation, and still presented superior catalytic activity after 6 cycles.

Plastic film mulching (FM) became a general practice to enhance crop productivity and its net primary production (NPP), but it can increase greenhouse gas (GHG) emissions. The proper addition of organic amendments might effectively decrease the impact of FM on global warming. To evaluate the feasibility of biomass addition on decreasing this negative influence, cover crop biomass as a green manure was incorporated with different recycling levels (0-100% of aboveground biomass) under FM and no-mulching. The net global warming potential (GWP) which integrated with soil C stock change and GHG (N2O and CH4) fluxes with CO2-equivalent was evaluated during maize cultivation. Under the same biomass incorporation, FM significantly enhanced the grain productivity and NPP of maize by 22-61 and 18-58% over no-mulching, respectively. In contrast, FM also highly increased the respired C loss, which was 11-95% higher than NPP increase, over no-mulching. Irrespective with biomass recycling ratio and mulching system, negative NECB which indicates the decrease of soil C stock was observed, mainly due to big harvest removal. FM decreased more soil C stock by 57-158% over no-mulching, but its C stock was clearly increased with increasing biomass addition. FM significantly increased total N2O and CH4 fluxes by 4-61 and 140-600% over no-mulching, respectively. Soil C stock changes mainly decided net GWP scale, but N2O and CH4 fluxes negligibly influenced. As a result, FM highly increased net GWP over no-mulching, while this net GWP was clearly decreased with increasing biomass application. However, cover cropping, and its biomass recycling was not enough to compensate the negative impact of FM on global warming. Therefore, more biomass incorporation might be essential to compensate this negative effect of FM.

Abstract In a passive nuclear plant, the main control room must provide self-support functions for 72 h after an accident occurs. In this isolation mode, the heat generated by indoor occupants and equipment should be removed by using concrete walls that are 610 mm thick, and the finned ceiling made of concrete should maintain thermal habitability. However, the finned ceiling design has not been studied in normal buildings, and the cooling storage effect of plate-shaped fins is usually ignored during the design phase. In this study, a novel parametric resistance–capacitance thermal network is proposed to simulate the thermal performance of different fin-plate layout forms in the case of an accident. An experiment was conducted on a 1200 mm × 1200 mm × 610 mm fin-concrete module for 72 h to validate the model under constant air temperature conditions. Based on the model, multi-objective optimization was conducted to obtain optimal solution sets by using a radial basis function approximation model. The results show that the optimal performance indicators can be classified into unsteady and quasi-steady states, in which the dominant factors for heat transfer include the heat transfer area and the thickness of the finned plate, respectively. Further, the optimal solution sets for different convection and heating conditions obtained through an optimization process are used to design a fin layout based on actual temperature control demands and cooling storage.

Abstract AP1000® Generation III+ reactor bases its safety concept on passive systems, differently from the previous Generation II reactors. This fact has led the approximations and methodologies previously used for modeling active safety systems to be reviewed and adapted to simulate the physics of passive systems. Diverse studies about the AP1000 containment have demonstrated the difficulty to correctly model the occurring phenomenology. In this paper, an integral AP1000 3D containment GOTHIC model is presented, including the Passive Containment Cooling System (PCCS). The model includes the compartments inside and outside the metallic containment liner that influence the thermal–hydraulic behavior. The model is tested against a Large Break Loss of Coolant Accident (LBLOCA) to assess its thermal–hydraulic performance, assuming a PCS tank malfunction, what is a conservative hypothesis. The pressure and temperature evolution predicted by the 3D containment model is analyzed and compared with a single node Lumped Parameters model, allowing to evaluate some preliminary benefits of 3D modeling for containment safety analysis. The 3D containment model allows to predict the thermal evolution in each containment compartment capturing the heterogeneity of this phenomenon, with higher resolution than the lumped parameters models traditionally used in this kind of analyses. It allows to observe the thermohydraulic conditions locally at any time during the transient.