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description Publicationkeyboard_double_arrow_right Article , Journal 2019 TurkeyPublisher:Elsevier BV Authors: Haug, Alfred Albert;Ucal, Meltem Şengün;
Ucal, Meltem Şengün
Ucal, Meltem Şengün in OpenAIREAbstract This paper examines the effects of foreign trade and foreign direct investment (FDI) on CO 2 emissions in Turkey. We consider linear and nonlinear ARDL models and find significant asymmetric effects of exports, imports and FDI on CO 2 emissions per capita. However, FDI has no statistically significant long-run effects. In the long run, decreases in exports reduce CO 2 emissions per capita but increases in exports have no statistically significant effects. Increases in imports push up CO 2 emissions per capita, while decreases in imports have no long-run effects. On the other hand, CO 2 intensity, which measures CO 2 emissions per unit of energy, is not influenced by exports and imports, nor by FDI. Instead, it is affected positively by financial development and urbanization. Also, we find that an environmental Kuznets curve is present for both CO 2 measures so that increases in real GDP per capita have led to reductions in CO 2 emissions for at least the most recent decade, controlling for other confounding factors. Furthermore, the sectoral shares of CO 2 emissions in total CO 2 emissions change asymmetrically with foreign trade for two of four sectors, with export increases leading to lower CO 2 shares and imports having the opposite effect.
Kadir Has University... arrow_drop_down Kadir Has University Academic RepositoryArticle . 2019Data sources: Kadir Has University Academic RepositoryKadir Has University Academic RepositoryArticle . 2019Data sources: Kadir Has University Academic Repositoryadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 254 citations 254 popularity Top 0.1% influence Top 10% impulse Top 0.1% Powered by BIP!
more_vert Kadir Has University... arrow_drop_down Kadir Has University Academic RepositoryArticle . 2019Data sources: Kadir Has University Academic RepositoryKadir Has University Academic RepositoryArticle . 2019Data sources: Kadir Has University Academic Repositoryadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2019 TurkeyPublisher:Elsevier BV Authors: Haug, Alfred Albert;Ucal, Meltem Şengün;
Ucal, Meltem Şengün
Ucal, Meltem Şengün in OpenAIREAbstract This paper examines the effects of foreign trade and foreign direct investment (FDI) on CO 2 emissions in Turkey. We consider linear and nonlinear ARDL models and find significant asymmetric effects of exports, imports and FDI on CO 2 emissions per capita. However, FDI has no statistically significant long-run effects. In the long run, decreases in exports reduce CO 2 emissions per capita but increases in exports have no statistically significant effects. Increases in imports push up CO 2 emissions per capita, while decreases in imports have no long-run effects. On the other hand, CO 2 intensity, which measures CO 2 emissions per unit of energy, is not influenced by exports and imports, nor by FDI. Instead, it is affected positively by financial development and urbanization. Also, we find that an environmental Kuznets curve is present for both CO 2 measures so that increases in real GDP per capita have led to reductions in CO 2 emissions for at least the most recent decade, controlling for other confounding factors. Furthermore, the sectoral shares of CO 2 emissions in total CO 2 emissions change asymmetrically with foreign trade for two of four sectors, with export increases leading to lower CO 2 shares and imports having the opposite effect.
Kadir Has University... arrow_drop_down Kadir Has University Academic RepositoryArticle . 2019Data sources: Kadir Has University Academic RepositoryKadir Has University Academic RepositoryArticle . 2019Data sources: Kadir Has University Academic Repositoryadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 254 citations 254 popularity Top 0.1% influence Top 10% impulse Top 0.1% Powered by BIP!
more_vert Kadir Has University... arrow_drop_down Kadir Has University Academic RepositoryArticle . 2019Data sources: Kadir Has University Academic RepositoryKadir Has University Academic RepositoryArticle . 2019Data sources: Kadir Has University Academic Repositoryadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Doctoral thesis 2022 CanadaPublisher:University of Windsor Authors: Adesina, Adeyemi;Engineered cementitious composites (ECCs) are special types of fibre-reinforced cementitious composites (FRCC) with higher strain capacity which can be achieved with low fibre volume as low as 2% and total elimination of coarse aggregates. Due to the outstanding performance of ECCs, they are suitable for various construction and repair applications. However, in order for ECCs to achieve their properties; a high amount of binder which is primarily composed of Portland cement (PC) is used alongside a special type of ultrafine silica sand (USS) which is different from the conventional natural fine aggregates. The production of PC is known to be detrimental to the environment due to its high carbon dioxide emissions coupled with the high consumption of natural resources. Thus, the high use of PC content in ECCs posed a sustainability threat. Similarly, the USS used in ECCs are not readily available everywhere and are expensive. The processing of the USS coupled with its transportation over long distances would also increase the cost and embodied carbon of ECCs. Hence, in order to promote more development and applications of ECCs for various applications; this dissertation aims to provide innovative ways to improve the sustainability of ECCs and their performances. This dissertation offers four solutions to improve the sustainability of ECCs which are (i) use of unconventional industrial by-products as partial replacement of PC (ii) total replacement of PC in ECCs with alternative sustainable binders (iii) replacement of USS in ECCs with recycled materials and (iv) the use of supplementary cementitious materials to replace a high volume of PC. The findings from this study revealed sustainable ECCs with acceptable mechanical and durability performance can be achieved with the use of alternative binders or replacement of the conventional USS used in ECC mixtures. The sustainability and cost assessment of the ECCs indicated that the incorporation of industrial by-products such as blast furnace slag (BFS) especially at higher content is beneficial to reducing the negative environmental impact and economic burden associated with ECCs compared to the conventional ECC. The sustainability index and cost index of the ECCs further showed that the use of BFS is more beneficial when the sustainability and cost of the ECCs are compared with the corresponding performance. Similarly, the use of recycled materials as an alternative to USS was found to result in a significant reduction in the embodied carbon and cost of ECCs. The use of recycled materials such as expanded glass (EG) as aggregates in ECCs was also found to improve the thermal insulation properties of ECCs making such ECC suitable for the production of building envelope elements.
Scholarship at UWind... arrow_drop_down Scholarship at UWindsorDoctoral thesis . 2022License: CC BY NC NDData sources: Scholarship at UWindsoradd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert Scholarship at UWind... arrow_drop_down Scholarship at UWindsorDoctoral thesis . 2022License: CC BY NC NDData sources: Scholarship at UWindsoradd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=od______2870::42c956dbdad7d50f52da74a508071486&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Doctoral thesis 2022 CanadaPublisher:University of Windsor Authors: Adesina, Adeyemi;Engineered cementitious composites (ECCs) are special types of fibre-reinforced cementitious composites (FRCC) with higher strain capacity which can be achieved with low fibre volume as low as 2% and total elimination of coarse aggregates. Due to the outstanding performance of ECCs, they are suitable for various construction and repair applications. However, in order for ECCs to achieve their properties; a high amount of binder which is primarily composed of Portland cement (PC) is used alongside a special type of ultrafine silica sand (USS) which is different from the conventional natural fine aggregates. The production of PC is known to be detrimental to the environment due to its high carbon dioxide emissions coupled with the high consumption of natural resources. Thus, the high use of PC content in ECCs posed a sustainability threat. Similarly, the USS used in ECCs are not readily available everywhere and are expensive. The processing of the USS coupled with its transportation over long distances would also increase the cost and embodied carbon of ECCs. Hence, in order to promote more development and applications of ECCs for various applications; this dissertation aims to provide innovative ways to improve the sustainability of ECCs and their performances. This dissertation offers four solutions to improve the sustainability of ECCs which are (i) use of unconventional industrial by-products as partial replacement of PC (ii) total replacement of PC in ECCs with alternative sustainable binders (iii) replacement of USS in ECCs with recycled materials and (iv) the use of supplementary cementitious materials to replace a high volume of PC. The findings from this study revealed sustainable ECCs with acceptable mechanical and durability performance can be achieved with the use of alternative binders or replacement of the conventional USS used in ECC mixtures. The sustainability and cost assessment of the ECCs indicated that the incorporation of industrial by-products such as blast furnace slag (BFS) especially at higher content is beneficial to reducing the negative environmental impact and economic burden associated with ECCs compared to the conventional ECC. The sustainability index and cost index of the ECCs further showed that the use of BFS is more beneficial when the sustainability and cost of the ECCs are compared with the corresponding performance. Similarly, the use of recycled materials as an alternative to USS was found to result in a significant reduction in the embodied carbon and cost of ECCs. The use of recycled materials such as expanded glass (EG) as aggregates in ECCs was also found to improve the thermal insulation properties of ECCs making such ECC suitable for the production of building envelope elements.
Scholarship at UWind... arrow_drop_down Scholarship at UWindsorDoctoral thesis . 2022License: CC BY NC NDData sources: Scholarship at UWindsoradd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
more_vert Scholarship at UWind... arrow_drop_down Scholarship at UWindsorDoctoral thesis . 2022License: CC BY NC NDData sources: Scholarship at UWindsoradd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Master thesis 2021Publisher:Fen Bilimleri Enstitüsü Authors: İmal, Muharrem;THERMODYNAMIC AND ECONOMIC ANALYSIS OF COMBINED HEAT AND POWER (COGENERATION) STEAM CYCLES SUMMARY Thermodynamic models for twoprocess heating, cogeneration steam cycles were developed in this study. These cycles are an extraction-condensing turbine cycle and a back pressure turbine cycle. Heat and electric outputs were calculated for inlet conditions ranging from 3 MPa, 250 C to 12 MPa, 535 C and process heat supply temperatures ranging from 80 C to 160 C. Furthermore, the performance of these cycles at 0 to 100 percent of their maximum heat outputs were examined. A simple method of economic analysis based on the annual costs was developed. This method can take part load into consideration. An extraction-condensing system and a back pressure system were compared by using this method. Process heating with cogeneration is a thermodinamically effective way of supplying heat and power to the industry. In a central plant, fuel can be burned more efficently, environmental controls can be applied more easily and economies of scale can be used to advantage. Furthermore, producing electricity as a byproduct in such plants is less expensive than producing electricity in power stations. In the extraction-condensing type, steam is expanded to condenser pressure and an extraction is made at the saturation pressure corresponding to the process heat supply temperature. In the back pressure type, steam is expanded only to the saturation pressure correspoding to the process heat supply temperature. The extraction-condensing turbines have the advantage that the electric output can be increased at partial heat loads. On the other hand, back- pressure turbines have a simpler mechanism of load control and lower initial costs. Detailed thermodynamic analysis of these systems appears to be lacking [14]-. For example, information on the variation of heat and electric outputs and thermal efficiencies of different configurations with changes in load and inlet steam conditions is essantial for the initial planning stage. viIn this study, computer modelling and simulation of two steam turbine based cogeneration cycles is made. Nu merical experiments were performed for various steam inlet conditions. Heat and electric outputs of cycles, heat input to the cycles and various parameters based on these thermodynamic quantities were calculated at full load and part load conditions. Partial loads ranging from 0 to 100 percent of full load were considered for the extraction-condensing cycle and partial loads of 37.5 to 100 percent were considered for the back pressure cycle. Thermodynamic Analysis The extraction-condensing turbine cycle consists of steam generator, turbine, condenser, heating condenser, feedwater heaters and pumps. The following assumptions are made regarding this cycle: The condenser is assumed to operate at 10 kPa. Extractions from the turbine to the feedwater heaters, heating condenser and the condenser is assumed to occur with a pressure loss equal to 5 persent of the exraction pressure. Pressure loss in the steam generator is assumed to be 25 percent of the turbine inlet pressure. Enthalpy rise of the feedwater is taken as 70 percent of the theoretically optimum value [13- This value is given by Ahopt = n/n+1 (hab - he) (1) where: n is the number of feedwater heaters, hs*> is the boiler drum satureted liquid enthalpy he is the enthalpy of satureted liquid leaving the condenser The loses in the expansion process through the turbine are accounted for by using an isentropic efficiency, r/, defined as : hi- ho r, = - t- r (2) h>- - hos where : hi is the enthalpy before expansion ho is the enthalpy after expansion hos is the enthalpy after an isentropic expansion This value is taken as 0.8 for the high pressure section of the turbine. The isentropic expansion efficiency for the flow between the heating condenser extraction and the turbine exhaust decreases linearly from 0.8 to 0.5 as the flow to the condenser decreases. Isentropic efficiency or compression in all of the pumps is asumed to be 0.7. viiThe calculations performed in the computer program are summarized in the block diagram of figure 1. Application of the first law of thermodynamics and the conservation of mass to each of the components of the cycle yield the exraction mass flows, work in the turbines and in the pumps, heat transfer in the boiler, heating condenser and in the condenser. Heat output is assumed to be primary output from the cycle. Electric output is considered to be a byproduct. Variation of the heat output is achieved by controlling the flow passing through the condenser. At 100 percent heat output, only the cooling steam flows to the condenser. At no heat output, there is no flow through the heating condenser. Cycle calculations have been performed for 100, 75, 50, 25, and 0 percent of the maximum heat output. Assumptions calculation procedures outlined above for the extraction-condensing cycle also apply for back- pressure cycle. The control of heat output, however, is different. The heat output of the back pressure cycle is varied by changing the mass flow rate through the turbine. Calculations have been performed for 100 to 37.5 percent of the maximum heat output. Properties of water required in the computer programs were computed using the equation and procedures given in [3]- Economic Analysis It is the economic consideration which will determine whether or not a cogeneration plant should be built. A simple method is presented here for determining the economic feasibility of a cogeneration plant. In this method all costs and revenues are expressed on an annual basis for comparison. Two assumption are made. First the heat demand is assumed to be supplied by other means if a cogeneration plant is not built. Therefore only the additional or incremental cost is considered. This includes the turbo generator set, condensers, feedwater heaters, steam generators, additional piping, fuel handling, exhaust cleaning measures, building and consruction costs as well as engineering cost. The second assumption is that all of the byproduct electricity produced can be utilised. A numerical example using this method shows that an extinction condensing cycle should bepreferred if the system is to operate at partial heat loads for long periods of time. Back-pressure cycle will be economically feasible only if the system operates at full load more than 90 percent of the time. However the most economic operation for the extraction-condensing cycle is also realized at full load. vmResults Results of the computer simulation of the two cycles discussed above. The key parameters on which the results are based, are explained below. Heat output per unit mass of steam entering the turbine has a maximum value for a given throttle condition and process heat supply temperature. Heat output from the cycle for a given set of turbine inlet conditions was varied as explained in the thermodinamic a na lysis. It was also found that the thermal efficiency of these cycles, defined as net work output over the heat input. Increasing the process heat supply temperature decreases the electric to heat ratio and the electric out put, increases the heat output. IXEnter the type of the system Turbine inlet pressure and temperature Process heat supply temperature Deter mine feedwater enthalpy rise and Turbine exraetion pressure Determine for the case of no heat output mass flow to the feed water heaters and the condenser r* Select a heat load as a percent of full load L-. Determine mass flows to the feedwater heaters, process heating condenser, condenser, net work, electric output heat output, heat input Figure 1. Block diagram of calculation procedure xi ÖZET Birleşik ısı ve güç çevrimlerinin endüstride kullanımının yaygınlaşması bu konudaki araştırmalara yeni boyutlar kazandırmaktadır. Bu durum göz ününe alınarak endüstride kullanılan buharlı birleşik ısı -güç çevrimleri ne ait termodinamik ve ekonomik çözümlemelerin yapıldığı bu çalışmada beş bölüm bulunmaktadır. Birinci bölümde, yapılan çalışmanın amacı açıklanmış, literatürdeki yerine ve önemine değinilmiştir. Konu ile ilgili kabullerden bahsedilmiştir. ikinci bölümde, buharlı güç çevrimleri hakkında genel bilgi verilmiştir. Çevrimlere ait T-s ve akis diyagramlarının yer aldığı bu bölümde çalışmada dikkate alınan değişkenlerin değişim aralığından bahsedilmiştir. Uçüncü bölümde, termodinamik çözümleme yapılarak, kısmi ve tam yükte ısı ve elektirik enerjisinin değişimi ile proses için gereken ısı enerjisi değeri hesaplanmıştır Dördüncü bölümde yakıt fi ati arı ve yakıt türleri yanısıra isletmelerin ihtiyaç duyduğu güç değerleri ve çalışma süreleri esas alınarak bu çevrimlerin ekonomik analizi yapılmıştır. Son bölümde sonuçların grafiklerle kıyaslama ve tartışması yapılarak her iki çevrime ait değişik değerlerin irdelemesi yapılmıştır. 69
YÖK Açık Bilim - CoH... arrow_drop_down YÖK Açık Bilim - CoHE Open ScienceMaster thesis . 2021License: CC BYData sources: YÖK Açık Bilim - CoHE Open Scienceadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eu0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Master thesis 2021Publisher:Fen Bilimleri Enstitüsü Authors: İmal, Muharrem;THERMODYNAMIC AND ECONOMIC ANALYSIS OF COMBINED HEAT AND POWER (COGENERATION) STEAM CYCLES SUMMARY Thermodynamic models for twoprocess heating, cogeneration steam cycles were developed in this study. These cycles are an extraction-condensing turbine cycle and a back pressure turbine cycle. Heat and electric outputs were calculated for inlet conditions ranging from 3 MPa, 250 C to 12 MPa, 535 C and process heat supply temperatures ranging from 80 C to 160 C. Furthermore, the performance of these cycles at 0 to 100 percent of their maximum heat outputs were examined. A simple method of economic analysis based on the annual costs was developed. This method can take part load into consideration. An extraction-condensing system and a back pressure system were compared by using this method. Process heating with cogeneration is a thermodinamically effective way of supplying heat and power to the industry. In a central plant, fuel can be burned more efficently, environmental controls can be applied more easily and economies of scale can be used to advantage. Furthermore, producing electricity as a byproduct in such plants is less expensive than producing electricity in power stations. In the extraction-condensing type, steam is expanded to condenser pressure and an extraction is made at the saturation pressure corresponding to the process heat supply temperature. In the back pressure type, steam is expanded only to the saturation pressure correspoding to the process heat supply temperature. The extraction-condensing turbines have the advantage that the electric output can be increased at partial heat loads. On the other hand, back- pressure turbines have a simpler mechanism of load control and lower initial costs. Detailed thermodynamic analysis of these systems appears to be lacking [14]-. For example, information on the variation of heat and electric outputs and thermal efficiencies of different configurations with changes in load and inlet steam conditions is essantial for the initial planning stage. viIn this study, computer modelling and simulation of two steam turbine based cogeneration cycles is made. Nu merical experiments were performed for various steam inlet conditions. Heat and electric outputs of cycles, heat input to the cycles and various parameters based on these thermodynamic quantities were calculated at full load and part load conditions. Partial loads ranging from 0 to 100 percent of full load were considered for the extraction-condensing cycle and partial loads of 37.5 to 100 percent were considered for the back pressure cycle. Thermodynamic Analysis The extraction-condensing turbine cycle consists of steam generator, turbine, condenser, heating condenser, feedwater heaters and pumps. The following assumptions are made regarding this cycle: The condenser is assumed to operate at 10 kPa. Extractions from the turbine to the feedwater heaters, heating condenser and the condenser is assumed to occur with a pressure loss equal to 5 persent of the exraction pressure. Pressure loss in the steam generator is assumed to be 25 percent of the turbine inlet pressure. Enthalpy rise of the feedwater is taken as 70 percent of the theoretically optimum value [13- This value is given by Ahopt = n/n+1 (hab - he) (1) where: n is the number of feedwater heaters, hs*> is the boiler drum satureted liquid enthalpy he is the enthalpy of satureted liquid leaving the condenser The loses in the expansion process through the turbine are accounted for by using an isentropic efficiency, r/, defined as : hi- ho r, = - t- r (2) h>- - hos where : hi is the enthalpy before expansion ho is the enthalpy after expansion hos is the enthalpy after an isentropic expansion This value is taken as 0.8 for the high pressure section of the turbine. The isentropic expansion efficiency for the flow between the heating condenser extraction and the turbine exhaust decreases linearly from 0.8 to 0.5 as the flow to the condenser decreases. Isentropic efficiency or compression in all of the pumps is asumed to be 0.7. viiThe calculations performed in the computer program are summarized in the block diagram of figure 1. Application of the first law of thermodynamics and the conservation of mass to each of the components of the cycle yield the exraction mass flows, work in the turbines and in the pumps, heat transfer in the boiler, heating condenser and in the condenser. Heat output is assumed to be primary output from the cycle. Electric output is considered to be a byproduct. Variation of the heat output is achieved by controlling the flow passing through the condenser. At 100 percent heat output, only the cooling steam flows to the condenser. At no heat output, there is no flow through the heating condenser. Cycle calculations have been performed for 100, 75, 50, 25, and 0 percent of the maximum heat output. Assumptions calculation procedures outlined above for the extraction-condensing cycle also apply for back- pressure cycle. The control of heat output, however, is different. The heat output of the back pressure cycle is varied by changing the mass flow rate through the turbine. Calculations have been performed for 100 to 37.5 percent of the maximum heat output. Properties of water required in the computer programs were computed using the equation and procedures given in [3]- Economic Analysis It is the economic consideration which will determine whether or not a cogeneration plant should be built. A simple method is presented here for determining the economic feasibility of a cogeneration plant. In this method all costs and revenues are expressed on an annual basis for comparison. Two assumption are made. First the heat demand is assumed to be supplied by other means if a cogeneration plant is not built. Therefore only the additional or incremental cost is considered. This includes the turbo generator set, condensers, feedwater heaters, steam generators, additional piping, fuel handling, exhaust cleaning measures, building and consruction costs as well as engineering cost. The second assumption is that all of the byproduct electricity produced can be utilised. A numerical example using this method shows that an extinction condensing cycle should bepreferred if the system is to operate at partial heat loads for long periods of time. Back-pressure cycle will be economically feasible only if the system operates at full load more than 90 percent of the time. However the most economic operation for the extraction-condensing cycle is also realized at full load. vmResults Results of the computer simulation of the two cycles discussed above. The key parameters on which the results are based, are explained below. Heat output per unit mass of steam entering the turbine has a maximum value for a given throttle condition and process heat supply temperature. Heat output from the cycle for a given set of turbine inlet conditions was varied as explained in the thermodinamic a na lysis. It was also found that the thermal efficiency of these cycles, defined as net work output over the heat input. Increasing the process heat supply temperature decreases the electric to heat ratio and the electric out put, increases the heat output. IXEnter the type of the system Turbine inlet pressure and temperature Process heat supply temperature Deter mine feedwater enthalpy rise and Turbine exraetion pressure Determine for the case of no heat output mass flow to the feed water heaters and the condenser r* Select a heat load as a percent of full load L-. Determine mass flows to the feedwater heaters, process heating condenser, condenser, net work, electric output heat output, heat input Figure 1. Block diagram of calculation procedure xi ÖZET Birleşik ısı ve güç çevrimlerinin endüstride kullanımının yaygınlaşması bu konudaki araştırmalara yeni boyutlar kazandırmaktadır. Bu durum göz ününe alınarak endüstride kullanılan buharlı birleşik ısı -güç çevrimleri ne ait termodinamik ve ekonomik çözümlemelerin yapıldığı bu çalışmada beş bölüm bulunmaktadır. Birinci bölümde, yapılan çalışmanın amacı açıklanmış, literatürdeki yerine ve önemine değinilmiştir. Konu ile ilgili kabullerden bahsedilmiştir. ikinci bölümde, buharlı güç çevrimleri hakkında genel bilgi verilmiştir. Çevrimlere ait T-s ve akis diyagramlarının yer aldığı bu bölümde çalışmada dikkate alınan değişkenlerin değişim aralığından bahsedilmiştir. Uçüncü bölümde, termodinamik çözümleme yapılarak, kısmi ve tam yükte ısı ve elektirik enerjisinin değişimi ile proses için gereken ısı enerjisi değeri hesaplanmıştır Dördüncü bölümde yakıt fi ati arı ve yakıt türleri yanısıra isletmelerin ihtiyaç duyduğu güç değerleri ve çalışma süreleri esas alınarak bu çevrimlerin ekonomik analizi yapılmıştır. Son bölümde sonuçların grafiklerle kıyaslama ve tartışması yapılarak her iki çevrime ait değişik değerlerin irdelemesi yapılmıştır. 69
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Doctoral thesis 2021Publisher:Fen Bilimleri Enstitüsü Authors: Elagöz, Ayşe;SUMMARY A NEW METHOD FOR THE ORIENTATION AND DESIGN OF A BUILDING OF MINIMAL ENERGY CONSUMPTION Substitution of passive solar systems for the `dirty` combustion of fossil fuels for energy use in buildings to keep the environment biologically clean, can make important contributions to the health, both of individuals and of the global ecosystem, as well as contributing to the energy economy. Local outdoor chemical pollution, with all the damage it causes, can also be reduced with energy-cone ious design. A new method for design and orientation of an energy conservative building is presented for the use of architectural, urban planning, and energy engineering purposes. The precedure of the thesis is explained in five chapters. The concept of the energy conservative building is given in passive systems' methodology in Chapter 1. Also in the same chapter, the climatological effects on the building envelope and a review of current calculation procedures and computer programs with solar heating and cooling system capabilities are included. Successful passive solar architecture integrates energy conservation with passive solar heating, natural cooling and day lighting. The result can be a comfortable and economic building that uses 50%-90% less operating energy than most contemporary buildings. A world wide interest in passive solar architecture has developed since last five years because it provides an alternative to the trend toward an overdependence on lighting, heating, ventilating, and air conditioning equipment to maintain a livable and productive indoor environment in modern building. Building practitioners in many devoloping countries are interested in passive solar methods which may be integrated into the building design using familiar and readily available materials. Passive solar architecture has emphasized heating of residences in temperate climates; however, passive strategies have now spread to nearly all building types and most climates. The process is more complex for institutional and commercial buildings than for residential, but the same concepts always apply. viiiHour-by-hour simulation provides the backbone for design analysis. For smaller or simpler buildings simplified methods are usually based on monthly analysis. For larger or more complex buildings, the trend is to take full advantage of the inceased computing power of the current generation of powerful microcomputers in order to use simulation directly for design. Convenient design tools based on simulation are becoming available. The entire area of design tools appropriate to passive solar architecture needs much additional effort. Rasearch in the software design area, with powerful microcomputers, expert systems, and computer aided design techniques, promises to aid greatly in the spread of passive solar strategies. The second chapter is a review of the methods of estimation of hourly beam, diffuse and reflected solar radiation data for vertical and horizontal surfaces; whereas in this chapter Liu-Jordan's equations have a significant emphasis and are explained in full detail. There is evidence with the increasing emphasis on the use of solar energy in buildings, that much of the past solar radiation data will be rehabiliated and additional data will be collected in the future; however, it is unlikely that the hourly data to be taken will be extended to cover surfaces other than the horizontal for the majority of the stations. Liu and Jordan conducted extensive analyses during the early I960' s on the available solar radiation data and developed several emperical correlations that can be used to estimate the available solar radiation on `average` days for each month of the year and for a larger number of locations in the United States and Canada. Using the correlations, it is possible to take the monthly average daily total radiation on a horizontal surface, divide the daily total into direct and diffuse components, convert each component into hourly values, and then compute the hourly value of either component on a surface of any orientation desired. In the third chapter shadow analysis techniques for window and building energy studies are examined in detail. These techniques are examined under two parallel groups of classification. In the first group, roughly, the methods deal either with the building as a whole or only with the windows. In the second group, however, the methods are classified according to the first or second position of the observer. ixShading and solar influences on a building can be understood from two different observer positions. At the first position the observer stands at the ground or the building element and looks toward the Sun. The entire yearly movements of the Sun and relationship to the modifying intermediate conditions are seen at one time j thus, from the single station point, the observer has a yearly picture of solar movement. The disadavantage of this technique is that every position of the subject surface must be seperately analysed with a a new drawing and accompanying calculations. For a total analysis, a continious three-dimentional site volume must necessarily be broken into discrete representative points each of which is seperately analysed. Without intermediate obstructions any point on a site is equivalent in a solar analysis, since solar rays are parellel. However when the obstruction is large or close, its influence on different station points may be quite varied, such as on an urban. Since the proximity of the obstruction determines the the degree of variation in complex situations, differences may be considerable. Therefore, the movement or location of shadows is impossible to analyze, for only by accident can one determine whether the discrete object point is at a shadow edge. The crucial issue of total overshadowing effects and shadow patterns cannot be seen, nor can the entire building be examined at one time. In the second position, as used in the new method, the observer is located at a spot between the Sun and the building. By considering both the Sun and the entire building at once, all surfaces in any orientation can be observed under solar illumination. In this position, the relationship of of one portion of the site can be understood acting on another portion of the site. It is clearly seen from the examples that in the methods dealing only with the windows, the observer is, generally, in the first position, whereas in the methods which consider the building as a whole, the observer is in the latter position. The method is explained in details and step by step with a set of examples in Chapter 4. The method is an optimisation of the total percent of the sunlit area and the thermal effect due to the beam component of total solar energy on the vertical exterior surfaces of a building of minimal energy consumption, in Olgyay's bioclimatic chart which considers temperature, solar energy, wind, precipitation, relative humidity and vapor pressure. In other words, the method is a new and comprehensive interpretation of Olgyay's well known Overheated period charts. By replacing the secondposition of the observer in hourly simulation by the original gnomonic diagrams based on the first position of the observer, the metod gets closer to the aims of Olgyays' in the interpretation of architectural principles, site selection, sol-air orientation, solar control, environment and building forms, wind effects and air-flow patterns, and finally the thermal effects of materials. The method assumes that solar radiation does not penetrate the building; therefore it deals neither with the heat transfer problems nor the thermal storage capacity of the building, for the time being. The method does, however, generate relaible kernel data base for future research work on building heat transfer problems. The method is composed of two parts, the second being based on the first. The first part of the method deals with the changes in the sums of the total annual percents of sunlit areas (sunny portion of total exterior walls/total area of exterior walls) of a building at any location, relative to the changes in the orientation. In the second part, the thermal energy of the direct component is added to the variables mentioned above; e.i., location, geometrical design and orientation of the building. Thus, each wall is taken into consideration seperately, with the changes of intensity of solar energy and the percentages of sunlit area on it, due to the changes of the orientation of the building. The method is compiled in ten steps, of which the first five build the primary part, and the last five the secondary. The steps are as follows: 1. Olgyays' bioclimatic chart is adapted to the geographical place. The Overheated and the Underheated periods for selected hours of daytime are marked for selected days. For the selected hours of the selected days 2. percentages of sunlight on the walls of the building of a given orientation are computed, with any shading algorithm of parallel projection. 3. areas of sunlight (mE) on the walls of the building of a given orientation are computed, 4. total percentage of sunlight on the building is computed and grouped under two intensities, e.i. the Overheated and the Underheated. xi5. The annual sums of the total percentages of sunlight for the Overheated and Underheated periods are devided by the number of the Overheated and Underheated daytime hours respectively. 6. Solar thermal energy due to the beam component of hourly radiation is computed for each orientation (KJ/mz.h). 7. Solar thermal energy due to the beam component of hourly radiation is computed for each wall (KJ/h). 8. Total solar thermal energy gain of the building due to the beam component of hourly radiation is computed (KJ/h). 9. Hourly total solar thermal energy gains of the building are grouped under two intensities, the Overheated and the Underheated. 10. The annual sums of total solar thermal energy gains of the building for the Overheated and Underheated groups are devided by the number of Overheated and Underheated daytime hours respectively. application of the first part of the method is done by three blocks of passive apartment houses of the same area and hight, but of different design, for istanbul and Antalya, and for 1., 11., and 21. days of the months. For the second part, however, only the second block is examined for istanbul, and only for 21. days of the months. Hence comparisons of two sets of meteorological data and all the parameters mentioned above may be seen clearly from the graphics relative to the changes in eight orientations, e.i., North, North-East, East, South- East, South, South-West, West, and North-West. A minor modification was made in Olgyay's Overheated period charts in order to eliminate what was believed to be erroneous results by the use of Liu-Jordan equations near the sunrise and sunset hours for the application of the second part of the method. Although percentages of sunlight on the vertical exterior walls are computed with a shading technique based on Conlon's JPCSHAD parallel projection algorithm and the inclusion of the thermal effect mentioned above is done by Liu-Jordan's well known equations, the method is still applicable to other scientists' formulae and shadow analysis models as well. At the last chapter, the method is evaluated and further possible reseach work are pointed out. xiiThe method may be used to generate a wide variety of building blocks. The irradiance load on external surfaces of building blocks of any rectangular design may be evaluated for any orientation, time of day and for different localities. This evidently provides the designer with useful information, guide lines and design aids expanding his ability to manipulate the parameters of form for the control of solar environment and to develop practical indicators and building regulations for planning control. The method may furter be used in a generative process to define alternative proportion of block's sides, configuration of surroundings, street widths, physical characteristics of building surfaces for appropriate solar load criteria. Thus the method may be employed directly in conjunction with other performance criteria for a sythesis of an integrated architectural solution. xiii ÖZET Yapıların, enerji korunumu için yönlendirilmesi ve biçimlendirilmesinde, dış kabuk düşey yüzlerindeki doğrudan güneş ışınımına bağlı, güneşlenme yüzdeleri ve ısıl etkilerin Olgyay konfor bölgelerinde gözlemcinin 2. durumuna göre optimizasyonunun yapıldığı bu metod, iki kademeden meydana gelmektedir: Birinci kademede herhangi bir enlem, boylam ve biçimdeki yapının, düşey dış kabuk elemanları üzerindeki yıllık ortalama toplam güneşlenme yüzdeleri (güneşli alan/toplam alan), güneş ışınımı, bağıl nem, sıcaklık ve hava hareketlerine bağlı Olgyay konfor bölgelerindeki iki şiddet grubu, En Az Sıcak Dönem (EASD) ve En Sıcak Dönem (ESD) altında toplanmakta ve bu değerlerin yönlendirilişe göre değişimi incelenmektedir. Başka bir deyişle, yer, biçim ve yön değişkenlerinin birbirleri üzerindeki etkileri güneşlenme yüzdelerindeki farklılıklar ile belirlenmektedir. ikinci kademede yukarıdaki değişkenlere doğrudan güneş ışınımının düşey yüzeylerdeki ısıl etkileri de eklenmekte ve yapının bütünü ile ilgili, yer, biçim ve yön değişkenlerinin etkileşimine, beher duvarın konumuna ve üzerindeki saatlik güneşlenme yüzdelerine bağlı enerji kazançlarındaki farklılıkların ortalamaları da katılmaktadır. ikinci kademenin uygulamasında Liu- Jordan denklemleri, dünya sathında denenmiş ve kusurları ortaya çıkmış olduğu için, tercih edilmiş; ancak metod diğer araştırıcıların bağıntılarına da açık bırakılmıştır. Yeni metodun gelişimini hazırlayan konular başlıca üç bölüm içinde incelenmiştir. Birinci bölümde enerji korunumlu yapının tanımı pasif sistem metodolojisi içinde verilmekte; aynı bölümde, yapının dış kabuğunu etkileyen iklim elemanları kısaca ve bilgisayarlı ısıl enerji analiz metodları tarihsel gelişim içinde, ikinci bölümde metodun 2. kademesi için önem taşıyan güneş enerjisi verilerinin elde ediliş yolları incelikleri ile açıklanmaktadır, üçüncü bölümde ise yapılarda uygulanan gölge analizi metodları gözlemcinin durumuna göre tanıtılmaktadır. Dördüncü bölümde metod ve inceliklerinin anlaşılabilmesi için bir dizi uygulama sunulmakta, ayrıca birinci kademenin uygulanmasında yararlanılan JPCSHAD gölge algoritması tanıtılmakta ; sonuç bölümünde ise metod değerlendirilmekte ve ileriye dönük araştırmalar için önerilerde bulunulmaktadır. vii 145
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Doctoral thesis 2021Publisher:Fen Bilimleri Enstitüsü Authors: Elagöz, Ayşe;SUMMARY A NEW METHOD FOR THE ORIENTATION AND DESIGN OF A BUILDING OF MINIMAL ENERGY CONSUMPTION Substitution of passive solar systems for the `dirty` combustion of fossil fuels for energy use in buildings to keep the environment biologically clean, can make important contributions to the health, both of individuals and of the global ecosystem, as well as contributing to the energy economy. Local outdoor chemical pollution, with all the damage it causes, can also be reduced with energy-cone ious design. A new method for design and orientation of an energy conservative building is presented for the use of architectural, urban planning, and energy engineering purposes. The precedure of the thesis is explained in five chapters. The concept of the energy conservative building is given in passive systems' methodology in Chapter 1. Also in the same chapter, the climatological effects on the building envelope and a review of current calculation procedures and computer programs with solar heating and cooling system capabilities are included. Successful passive solar architecture integrates energy conservation with passive solar heating, natural cooling and day lighting. The result can be a comfortable and economic building that uses 50%-90% less operating energy than most contemporary buildings. A world wide interest in passive solar architecture has developed since last five years because it provides an alternative to the trend toward an overdependence on lighting, heating, ventilating, and air conditioning equipment to maintain a livable and productive indoor environment in modern building. Building practitioners in many devoloping countries are interested in passive solar methods which may be integrated into the building design using familiar and readily available materials. Passive solar architecture has emphasized heating of residences in temperate climates; however, passive strategies have now spread to nearly all building types and most climates. The process is more complex for institutional and commercial buildings than for residential, but the same concepts always apply. viiiHour-by-hour simulation provides the backbone for design analysis. For smaller or simpler buildings simplified methods are usually based on monthly analysis. For larger or more complex buildings, the trend is to take full advantage of the inceased computing power of the current generation of powerful microcomputers in order to use simulation directly for design. Convenient design tools based on simulation are becoming available. The entire area of design tools appropriate to passive solar architecture needs much additional effort. Rasearch in the software design area, with powerful microcomputers, expert systems, and computer aided design techniques, promises to aid greatly in the spread of passive solar strategies. The second chapter is a review of the methods of estimation of hourly beam, diffuse and reflected solar radiation data for vertical and horizontal surfaces; whereas in this chapter Liu-Jordan's equations have a significant emphasis and are explained in full detail. There is evidence with the increasing emphasis on the use of solar energy in buildings, that much of the past solar radiation data will be rehabiliated and additional data will be collected in the future; however, it is unlikely that the hourly data to be taken will be extended to cover surfaces other than the horizontal for the majority of the stations. Liu and Jordan conducted extensive analyses during the early I960' s on the available solar radiation data and developed several emperical correlations that can be used to estimate the available solar radiation on `average` days for each month of the year and for a larger number of locations in the United States and Canada. Using the correlations, it is possible to take the monthly average daily total radiation on a horizontal surface, divide the daily total into direct and diffuse components, convert each component into hourly values, and then compute the hourly value of either component on a surface of any orientation desired. In the third chapter shadow analysis techniques for window and building energy studies are examined in detail. These techniques are examined under two parallel groups of classification. In the first group, roughly, the methods deal either with the building as a whole or only with the windows. In the second group, however, the methods are classified according to the first or second position of the observer. ixShading and solar influences on a building can be understood from two different observer positions. At the first position the observer stands at the ground or the building element and looks toward the Sun. The entire yearly movements of the Sun and relationship to the modifying intermediate conditions are seen at one time j thus, from the single station point, the observer has a yearly picture of solar movement. The disadavantage of this technique is that every position of the subject surface must be seperately analysed with a a new drawing and accompanying calculations. For a total analysis, a continious three-dimentional site volume must necessarily be broken into discrete representative points each of which is seperately analysed. Without intermediate obstructions any point on a site is equivalent in a solar analysis, since solar rays are parellel. However when the obstruction is large or close, its influence on different station points may be quite varied, such as on an urban. Since the proximity of the obstruction determines the the degree of variation in complex situations, differences may be considerable. Therefore, the movement or location of shadows is impossible to analyze, for only by accident can one determine whether the discrete object point is at a shadow edge. The crucial issue of total overshadowing effects and shadow patterns cannot be seen, nor can the entire building be examined at one time. In the second position, as used in the new method, the observer is located at a spot between the Sun and the building. By considering both the Sun and the entire building at once, all surfaces in any orientation can be observed under solar illumination. In this position, the relationship of of one portion of the site can be understood acting on another portion of the site. It is clearly seen from the examples that in the methods dealing only with the windows, the observer is, generally, in the first position, whereas in the methods which consider the building as a whole, the observer is in the latter position. The method is explained in details and step by step with a set of examples in Chapter 4. The method is an optimisation of the total percent of the sunlit area and the thermal effect due to the beam component of total solar energy on the vertical exterior surfaces of a building of minimal energy consumption, in Olgyay's bioclimatic chart which considers temperature, solar energy, wind, precipitation, relative humidity and vapor pressure. In other words, the method is a new and comprehensive interpretation of Olgyay's well known Overheated period charts. By replacing the secondposition of the observer in hourly simulation by the original gnomonic diagrams based on the first position of the observer, the metod gets closer to the aims of Olgyays' in the interpretation of architectural principles, site selection, sol-air orientation, solar control, environment and building forms, wind effects and air-flow patterns, and finally the thermal effects of materials. The method assumes that solar radiation does not penetrate the building; therefore it deals neither with the heat transfer problems nor the thermal storage capacity of the building, for the time being. The method does, however, generate relaible kernel data base for future research work on building heat transfer problems. The method is composed of two parts, the second being based on the first. The first part of the method deals with the changes in the sums of the total annual percents of sunlit areas (sunny portion of total exterior walls/total area of exterior walls) of a building at any location, relative to the changes in the orientation. In the second part, the thermal energy of the direct component is added to the variables mentioned above; e.i., location, geometrical design and orientation of the building. Thus, each wall is taken into consideration seperately, with the changes of intensity of solar energy and the percentages of sunlit area on it, due to the changes of the orientation of the building. The method is compiled in ten steps, of which the first five build the primary part, and the last five the secondary. The steps are as follows: 1. Olgyays' bioclimatic chart is adapted to the geographical place. The Overheated and the Underheated periods for selected hours of daytime are marked for selected days. For the selected hours of the selected days 2. percentages of sunlight on the walls of the building of a given orientation are computed, with any shading algorithm of parallel projection. 3. areas of sunlight (mE) on the walls of the building of a given orientation are computed, 4. total percentage of sunlight on the building is computed and grouped under two intensities, e.i. the Overheated and the Underheated. xi5. The annual sums of the total percentages of sunlight for the Overheated and Underheated periods are devided by the number of the Overheated and Underheated daytime hours respectively. 6. Solar thermal energy due to the beam component of hourly radiation is computed for each orientation (KJ/mz.h). 7. Solar thermal energy due to the beam component of hourly radiation is computed for each wall (KJ/h). 8. Total solar thermal energy gain of the building due to the beam component of hourly radiation is computed (KJ/h). 9. Hourly total solar thermal energy gains of the building are grouped under two intensities, the Overheated and the Underheated. 10. The annual sums of total solar thermal energy gains of the building for the Overheated and Underheated groups are devided by the number of Overheated and Underheated daytime hours respectively. application of the first part of the method is done by three blocks of passive apartment houses of the same area and hight, but of different design, for istanbul and Antalya, and for 1., 11., and 21. days of the months. For the second part, however, only the second block is examined for istanbul, and only for 21. days of the months. Hence comparisons of two sets of meteorological data and all the parameters mentioned above may be seen clearly from the graphics relative to the changes in eight orientations, e.i., North, North-East, East, South- East, South, South-West, West, and North-West. A minor modification was made in Olgyay's Overheated period charts in order to eliminate what was believed to be erroneous results by the use of Liu-Jordan equations near the sunrise and sunset hours for the application of the second part of the method. Although percentages of sunlight on the vertical exterior walls are computed with a shading technique based on Conlon's JPCSHAD parallel projection algorithm and the inclusion of the thermal effect mentioned above is done by Liu-Jordan's well known equations, the method is still applicable to other scientists' formulae and shadow analysis models as well. At the last chapter, the method is evaluated and further possible reseach work are pointed out. xiiThe method may be used to generate a wide variety of building blocks. The irradiance load on external surfaces of building blocks of any rectangular design may be evaluated for any orientation, time of day and for different localities. This evidently provides the designer with useful information, guide lines and design aids expanding his ability to manipulate the parameters of form for the control of solar environment and to develop practical indicators and building regulations for planning control. The method may furter be used in a generative process to define alternative proportion of block's sides, configuration of surroundings, street widths, physical characteristics of building surfaces for appropriate solar load criteria. Thus the method may be employed directly in conjunction with other performance criteria for a sythesis of an integrated architectural solution. xiii ÖZET Yapıların, enerji korunumu için yönlendirilmesi ve biçimlendirilmesinde, dış kabuk düşey yüzlerindeki doğrudan güneş ışınımına bağlı, güneşlenme yüzdeleri ve ısıl etkilerin Olgyay konfor bölgelerinde gözlemcinin 2. durumuna göre optimizasyonunun yapıldığı bu metod, iki kademeden meydana gelmektedir: Birinci kademede herhangi bir enlem, boylam ve biçimdeki yapının, düşey dış kabuk elemanları üzerindeki yıllık ortalama toplam güneşlenme yüzdeleri (güneşli alan/toplam alan), güneş ışınımı, bağıl nem, sıcaklık ve hava hareketlerine bağlı Olgyay konfor bölgelerindeki iki şiddet grubu, En Az Sıcak Dönem (EASD) ve En Sıcak Dönem (ESD) altında toplanmakta ve bu değerlerin yönlendirilişe göre değişimi incelenmektedir. Başka bir deyişle, yer, biçim ve yön değişkenlerinin birbirleri üzerindeki etkileri güneşlenme yüzdelerindeki farklılıklar ile belirlenmektedir. ikinci kademede yukarıdaki değişkenlere doğrudan güneş ışınımının düşey yüzeylerdeki ısıl etkileri de eklenmekte ve yapının bütünü ile ilgili, yer, biçim ve yön değişkenlerinin etkileşimine, beher duvarın konumuna ve üzerindeki saatlik güneşlenme yüzdelerine bağlı enerji kazançlarındaki farklılıkların ortalamaları da katılmaktadır. ikinci kademenin uygulamasında Liu- Jordan denklemleri, dünya sathında denenmiş ve kusurları ortaya çıkmış olduğu için, tercih edilmiş; ancak metod diğer araştırıcıların bağıntılarına da açık bırakılmıştır. Yeni metodun gelişimini hazırlayan konular başlıca üç bölüm içinde incelenmiştir. Birinci bölümde enerji korunumlu yapının tanımı pasif sistem metodolojisi içinde verilmekte; aynı bölümde, yapının dış kabuğunu etkileyen iklim elemanları kısaca ve bilgisayarlı ısıl enerji analiz metodları tarihsel gelişim içinde, ikinci bölümde metodun 2. kademesi için önem taşıyan güneş enerjisi verilerinin elde ediliş yolları incelikleri ile açıklanmaktadır, üçüncü bölümde ise yapılarda uygulanan gölge analizi metodları gözlemcinin durumuna göre tanıtılmaktadır. Dördüncü bölümde metod ve inceliklerinin anlaşılabilmesi için bir dizi uygulama sunulmakta, ayrıca birinci kademenin uygulanmasında yararlanılan JPCSHAD gölge algoritması tanıtılmakta ; sonuç bölümünde ise metod değerlendirilmekte ve ileriye dönük araştırmalar için önerilerde bulunulmaktadır. vii 145
YÖK Açık Bilim - CoH... arrow_drop_down YÖK Açık Bilim - CoHE Open ScienceDoctoral thesis . 2021License: CC BYData sources: YÖK Açık Bilim - CoHE Open Scienceadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Master thesis 2023 PortugalAuthors: Rodrigues, Jeziel Lima;handle: 10400.22/24037
Esta dissertação oferece contribuições para o campo da energia eólica, e fornece um roteiro claro para a tomada de decisão baseada em dados, bem como orientações práticas para otimizar a operação e manutenção. No contexto atual da transformação digital e crescente demanda energética surge a necessidade de soluções inovadores e sustentáveis em larga escala, como a energia eólica offshore. A energia eólica é uma fonte de energia renovável que tem o potencial de contribuir significativamente para a matriz energética global. A implementação e operação de projetos eólicos offshore são desafiadores devido aos custos elevados e à natureza intrínseca dos riscos no ambiente marítimo, por isso necessitam operar em sua máxima eficiência e desempenho, tendo em vista a viabilidade económica. Este trabalho tem como objetivo a compreensão dos fatores principais que influenciam o desempenho energético dos aerogeradores através dos dados que revelam as interrupções e falhas de sistemas. Os resultados obtidos nesta pesquisa destacam a necessidade de uma abordagem integrada, buscando o conhecimento técnico especializado com a aplicação de tecnologias de monitoramento em tempo real e análise de dados. Ao reconhecer os padrões de falhas e as lacunas de eficiência, os gestores podem direcionar seus esforços para aprimorar a fiabilidade, a disponibilidade e a performance geral dessas unidades geradoras de energia elétrica. Através da implementação das recomendações resultantes deste estudo, espera-se que as instituições possam alcançar uma expressiva rentabilidade e sustentabilidade, alinhando-se de forma eficaz com as demandas atuais, garantindo uma posição sólida no ambiente empresarial e contribuindo para um futuro energético mais equilibrado.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Master thesis 2023 PortugalAuthors: Rodrigues, Jeziel Lima;handle: 10400.22/24037
Esta dissertação oferece contribuições para o campo da energia eólica, e fornece um roteiro claro para a tomada de decisão baseada em dados, bem como orientações práticas para otimizar a operação e manutenção. No contexto atual da transformação digital e crescente demanda energética surge a necessidade de soluções inovadores e sustentáveis em larga escala, como a energia eólica offshore. A energia eólica é uma fonte de energia renovável que tem o potencial de contribuir significativamente para a matriz energética global. A implementação e operação de projetos eólicos offshore são desafiadores devido aos custos elevados e à natureza intrínseca dos riscos no ambiente marítimo, por isso necessitam operar em sua máxima eficiência e desempenho, tendo em vista a viabilidade económica. Este trabalho tem como objetivo a compreensão dos fatores principais que influenciam o desempenho energético dos aerogeradores através dos dados que revelam as interrupções e falhas de sistemas. Os resultados obtidos nesta pesquisa destacam a necessidade de uma abordagem integrada, buscando o conhecimento técnico especializado com a aplicação de tecnologias de monitoramento em tempo real e análise de dados. Ao reconhecer os padrões de falhas e as lacunas de eficiência, os gestores podem direcionar seus esforços para aprimorar a fiabilidade, a disponibilidade e a performance geral dessas unidades geradoras de energia elétrica. Através da implementação das recomendações resultantes deste estudo, espera-se que as instituições possam alcançar uma expressiva rentabilidade e sustentabilidade, alinhando-se de forma eficaz com as demandas atuais, garantindo uma posição sólida no ambiente empresarial e contribuindo para um futuro energético mais equilibrado.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Thesis 2023 United KingdomPublisher:Apollo - University of Cambridge Repository Authors: Gomezgil Yaspik, Vianney;doi: 10.17863/cam.102122
In recent decades, many societal changes have unfolded, including population ageing, reconfigurations of household structures, labour market transformation, and a secular deceleration of economic growth. These shifts pose considerable challenges to preexisting welfare states, particularly to the efficacy of countries’ pension systems. This dissertation examines the context and trajectory of pension reforms in Mexico, the United Kingdom, and the United States. Its contribution is to ascertain the viability and political feasibility of reforms that enhance the financial sustainability of their pension systems, while maintaining adequate income and coverage levels. The dissertation builds on political economy approaches and on the institutionalist literature, which highlight how the role of interest groups and structure of institutions and political systems shape policy outcomes. The frameworks of blame avoidance and credit-claiming are also considered, to provide a comprehensive analysis of the complex dynamics surrounding pension systems and reform efforts. This dissertation uses a mixed-methods approach – including public opinion surveys of 3,000+ individuals, semi-structured elite interviews, historical document analyses, and specialized fiscal and actuarial projections of selected pension reforms in the three selected countries. It addresses three core research questions: 1) What is the current context for pension reform in Mexico, the United Kingdom, and the United States given their histories? 2) Is the necessary (for achieving specific minimum levels of sustainability, adequacy, and coverage) pension reform politically feasible? 3) How do the characteristics of each reform affect its political feasibility? Corollary: The modification of which channel (benefits, contributions, retirement age) is perceived as more politically feasible for diverse stakeholders? The methodology chosen provides a timely picture of the context surrounding potential pension reforms in the three case studies. In Mexico, credit-claiming and the interests of private stakeholders explain the success of recent pension reforms, and partisan politics are the key determinants for future fiscal changes. For the United Kingdom, the institutionalist literature helps explain the reasons for the relatively easier reform avenues; the most politically feasible reforms are those in the private sector, while the housing market is of key importance for pensions. In the United States, the institutionalist literature and the framework of blame avoidance also help explain the current legislative gridlock and the reasons why no major reform has been enacted for decades. For Mexico and the United Kingdom there exist politically feasible reforms, notably a modification of the retirement age channel, that can increase the system’s sustainability while maintaining income adequacy and coverage; whereas based on the current context of extreme polarisation and legislative gridlock, there do not seem to exist politically feasible pension reforms that preserve the structure of Social Security in the United States. The dissertation brings the lens of political feasibility to bear on a previously technical literature on the structure of the pension systems in the three countries, and thus on the feasibility of reform to deliver financial sustainability, adequacy of retirement incomes, and adequate coverage of the old age population. It identifies the feasible routes for reform in Mexico and the United Kingdom, but concludes that the political economy context the United States has reached rules out feasible reforms of its current pension structures.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Thesis 2023 United KingdomPublisher:Apollo - University of Cambridge Repository Authors: Gomezgil Yaspik, Vianney;doi: 10.17863/cam.102122
In recent decades, many societal changes have unfolded, including population ageing, reconfigurations of household structures, labour market transformation, and a secular deceleration of economic growth. These shifts pose considerable challenges to preexisting welfare states, particularly to the efficacy of countries’ pension systems. This dissertation examines the context and trajectory of pension reforms in Mexico, the United Kingdom, and the United States. Its contribution is to ascertain the viability and political feasibility of reforms that enhance the financial sustainability of their pension systems, while maintaining adequate income and coverage levels. The dissertation builds on political economy approaches and on the institutionalist literature, which highlight how the role of interest groups and structure of institutions and political systems shape policy outcomes. The frameworks of blame avoidance and credit-claiming are also considered, to provide a comprehensive analysis of the complex dynamics surrounding pension systems and reform efforts. This dissertation uses a mixed-methods approach – including public opinion surveys of 3,000+ individuals, semi-structured elite interviews, historical document analyses, and specialized fiscal and actuarial projections of selected pension reforms in the three selected countries. It addresses three core research questions: 1) What is the current context for pension reform in Mexico, the United Kingdom, and the United States given their histories? 2) Is the necessary (for achieving specific minimum levels of sustainability, adequacy, and coverage) pension reform politically feasible? 3) How do the characteristics of each reform affect its political feasibility? Corollary: The modification of which channel (benefits, contributions, retirement age) is perceived as more politically feasible for diverse stakeholders? The methodology chosen provides a timely picture of the context surrounding potential pension reforms in the three case studies. In Mexico, credit-claiming and the interests of private stakeholders explain the success of recent pension reforms, and partisan politics are the key determinants for future fiscal changes. For the United Kingdom, the institutionalist literature helps explain the reasons for the relatively easier reform avenues; the most politically feasible reforms are those in the private sector, while the housing market is of key importance for pensions. In the United States, the institutionalist literature and the framework of blame avoidance also help explain the current legislative gridlock and the reasons why no major reform has been enacted for decades. For Mexico and the United Kingdom there exist politically feasible reforms, notably a modification of the retirement age channel, that can increase the system’s sustainability while maintaining income adequacy and coverage; whereas based on the current context of extreme polarisation and legislative gridlock, there do not seem to exist politically feasible pension reforms that preserve the structure of Social Security in the United States. The dissertation brings the lens of political feasibility to bear on a previously technical literature on the structure of the pension systems in the three countries, and thus on the feasibility of reform to deliver financial sustainability, adequacy of retirement incomes, and adequate coverage of the old age population. It identifies the feasible routes for reform in Mexico and the United Kingdom, but concludes that the political economy context the United States has reached rules out feasible reforms of its current pension structures.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2022 TurkeyPublisher:Elsevier BV handle: 20.500.12511/8719
According to the second law of thermodynamics, all human activities cause exergy destructions, adding to additional root causes for carbon dioxide emissions responsibility. It means that current carbon dioxide concentrations are accurately observed, but the root causes and their potential solutions against global warming fall short of achieving the goals of the Paris agreement by almost 45% in terms of decarbonization efforts, as shown in this paper. This result applies to all activities, including the green facility concept. In this respect, the primary aim of this paper is to raise awareness about the essence of the Second Law of Thermodynamics in expanding the green facility concept to reach more effective and sustainable rating methodologies concerning the climate crisis. A new evaluating and rating model with a set of exergy-based green building metrics that relate additional carbon dioxide emissions to irreversible exergy destructions has been developed. Examples about apparently green buildings according to the First Law of Thermodynamics are given by showing that these buildings are not green due to additional carbon dioxide emissions responsibility due to exergy destructions. An airport terminal building case is elaborated. It has been shown that although part of the electricity comes from a third-party wind energy provider, it ends up with carbon dioxide emissions responsibility because it is not entirely used in exergy-rational demand points and compares less favorably with an on-site cogeneration system using natural gas by about 30% more emissions responsibility. The results and derivations of new metrics are discussed, which shed light on adding new criteria to existing green building certification programs.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 13 citations 13 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article 2022 TurkeyPublisher:Elsevier BV handle: 20.500.12511/8719
According to the second law of thermodynamics, all human activities cause exergy destructions, adding to additional root causes for carbon dioxide emissions responsibility. It means that current carbon dioxide concentrations are accurately observed, but the root causes and their potential solutions against global warming fall short of achieving the goals of the Paris agreement by almost 45% in terms of decarbonization efforts, as shown in this paper. This result applies to all activities, including the green facility concept. In this respect, the primary aim of this paper is to raise awareness about the essence of the Second Law of Thermodynamics in expanding the green facility concept to reach more effective and sustainable rating methodologies concerning the climate crisis. A new evaluating and rating model with a set of exergy-based green building metrics that relate additional carbon dioxide emissions to irreversible exergy destructions has been developed. Examples about apparently green buildings according to the First Law of Thermodynamics are given by showing that these buildings are not green due to additional carbon dioxide emissions responsibility due to exergy destructions. An airport terminal building case is elaborated. It has been shown that although part of the electricity comes from a third-party wind energy provider, it ends up with carbon dioxide emissions responsibility because it is not entirely used in exergy-rational demand points and compares less favorably with an on-site cogeneration system using natural gas by about 30% more emissions responsibility. The results and derivations of new metrics are discussed, which shed light on adding new criteria to existing green building certification programs.
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 13 citations 13 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Thesis 2023Embargo end date: 14 Jul 2023 United KingdomPublisher:Apollo - University of Cambridge Repository doi: 10.17863/cam.99818
The aggravating global problems of energy crisis, rising atmospheric greenhouse gas concentrations and accumulation of persistent waste have attracted the attention of scientists, policy-makers and global organisations to come up with effective and expeditious solutions to address these challenges. In this context, the development of sustainable technologies driven by renewable energy sources for the production of clean fuels and commodity chemicals from diverse waste feedstocks is an appealing approach towards creating a circular economy. Over the years, semiconductor photocatalysts based on TiO₂, CdS, carbon-nitrides (CNx) and carbon dots (CDs) have been widely used for the photocatalytic reforming (PC reforming) of pre-treated waste substrates to organic products, accompanied with clean hydrogen (H₂) generation. However, these conventional solar-driven processes suffer from major drawbacks such as low production rates, poor product selectivity, CO₂ release, challenging process and catalyst optimisation, and harsh waste pre-treatment conditions, which limit their commercial applicability. These challenges are tackled in this thesis with the introduction of new and efficient photoelectrochemical (PEC) and chemoenzymatic processes for reforming a diverse range of waste feedstocks to sustainable fuels. Solar-driven PEC reforming based on halide perovskite light-absorber is first developed as an attractive alternative to PC reforming. The PEC systems consist of a perovskite|Pt photocathode for clean H₂ production and a Cu-Pd alloy anode for reforming diverse waste streams, including pre-treated cellulosic biomass, polyethylene terephthalate (PET) plastics, and industrial by-product glycerol into industrially-relevant, value-added chemicals (gluconic acid, glycolic acid and glyceric acid) without any externally applied bias or voltage. Additionally, the single light-absorber PEC systems can also convert the airborne waste stream and greenhouse gas CO₂ to diverse products with the simultaneous reforming of PET plastics with no applied voltage. The perovskite-based photocathode enables the integration of different CO₂ reduction catalysts such as a molecular cobalt porphyrin, a Cu-In alloy and formate dehydrogenase enzyme, which produce CO, syngas and formate, respectively. The versatile PEC systems, which can be assembled in either a ‘two-compartment’ or standalone ‘artificial leaf’ configurations achieve 60‒90% oxidation product selectivity (with no over-oxidation) and >100 µmol cm‾² h‾¹ product formation rates, corresponding to 10²‒10⁴ times higher activity than conventional PC reforming systems. In addition to developing PEC platforms, this thesis also explores avenues for circumventing the harsh alkaline pre-treatment strategies (pH >13, 60‒80 ºC) adopted for photoreforming waste substrates. For this purpose, a chemoenzymatic pathway is introduced whereby PET and polycaprolactone plastics were deconstructed using functional enzymes under benign conditions (pH 6‒8, 37‒65 ºC), followed by PC reforming using Pt loaded TiO₂ (TiO₂|Pt) or Ni₂P loaded carbon-nitride (CNx|Ni₂P) photocatalysts. The chemoenzymatic reforming process demonstrates versatility in upcycling polyester films and nanoplastics for H₂ production at high yields reaching ∼10³‒10⁴ µmol gsub‾¹ and activities at >500 µmol gcat‾¹ h‾¹. The utilisation of enzyme pre-treated plastics also allowed the coupling of plastic reforming with photocatalytic CO₂-to-syngas conversion using a phosphonated cobalt bis(terpyridine) co-catalyst immobilised on TiO₂ (TiO₂|CotpyP). Finally, moving beyond solar-driven systems, a bio-electrocatalytic flow process is demonstrated for the conversion of microbe pre-treated food waste to ethylene (an important feedstock in the chemical industry) on graphitic carbon electrodes via succinic acid as the central intermediate. In conclusion, with its focus on improving efficiencies, achieving selective product formation, building versatile platforms, diversifying substrate and product scope, and reducing carbon footprint and economic strain, this thesis aims to bring sustainable waste-to-fuel technologies a step closer to commercial implementation.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.17863/cam.99818&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Thesis 2023Embargo end date: 14 Jul 2023 United KingdomPublisher:Apollo - University of Cambridge Repository doi: 10.17863/cam.99818
The aggravating global problems of energy crisis, rising atmospheric greenhouse gas concentrations and accumulation of persistent waste have attracted the attention of scientists, policy-makers and global organisations to come up with effective and expeditious solutions to address these challenges. In this context, the development of sustainable technologies driven by renewable energy sources for the production of clean fuels and commodity chemicals from diverse waste feedstocks is an appealing approach towards creating a circular economy. Over the years, semiconductor photocatalysts based on TiO₂, CdS, carbon-nitrides (CNx) and carbon dots (CDs) have been widely used for the photocatalytic reforming (PC reforming) of pre-treated waste substrates to organic products, accompanied with clean hydrogen (H₂) generation. However, these conventional solar-driven processes suffer from major drawbacks such as low production rates, poor product selectivity, CO₂ release, challenging process and catalyst optimisation, and harsh waste pre-treatment conditions, which limit their commercial applicability. These challenges are tackled in this thesis with the introduction of new and efficient photoelectrochemical (PEC) and chemoenzymatic processes for reforming a diverse range of waste feedstocks to sustainable fuels. Solar-driven PEC reforming based on halide perovskite light-absorber is first developed as an attractive alternative to PC reforming. The PEC systems consist of a perovskite|Pt photocathode for clean H₂ production and a Cu-Pd alloy anode for reforming diverse waste streams, including pre-treated cellulosic biomass, polyethylene terephthalate (PET) plastics, and industrial by-product glycerol into industrially-relevant, value-added chemicals (gluconic acid, glycolic acid and glyceric acid) without any externally applied bias or voltage. Additionally, the single light-absorber PEC systems can also convert the airborne waste stream and greenhouse gas CO₂ to diverse products with the simultaneous reforming of PET plastics with no applied voltage. The perovskite-based photocathode enables the integration of different CO₂ reduction catalysts such as a molecular cobalt porphyrin, a Cu-In alloy and formate dehydrogenase enzyme, which produce CO, syngas and formate, respectively. The versatile PEC systems, which can be assembled in either a ‘two-compartment’ or standalone ‘artificial leaf’ configurations achieve 60‒90% oxidation product selectivity (with no over-oxidation) and >100 µmol cm‾² h‾¹ product formation rates, corresponding to 10²‒10⁴ times higher activity than conventional PC reforming systems. In addition to developing PEC platforms, this thesis also explores avenues for circumventing the harsh alkaline pre-treatment strategies (pH >13, 60‒80 ºC) adopted for photoreforming waste substrates. For this purpose, a chemoenzymatic pathway is introduced whereby PET and polycaprolactone plastics were deconstructed using functional enzymes under benign conditions (pH 6‒8, 37‒65 ºC), followed by PC reforming using Pt loaded TiO₂ (TiO₂|Pt) or Ni₂P loaded carbon-nitride (CNx|Ni₂P) photocatalysts. The chemoenzymatic reforming process demonstrates versatility in upcycling polyester films and nanoplastics for H₂ production at high yields reaching ∼10³‒10⁴ µmol gsub‾¹ and activities at >500 µmol gcat‾¹ h‾¹. The utilisation of enzyme pre-treated plastics also allowed the coupling of plastic reforming with photocatalytic CO₂-to-syngas conversion using a phosphonated cobalt bis(terpyridine) co-catalyst immobilised on TiO₂ (TiO₂|CotpyP). Finally, moving beyond solar-driven systems, a bio-electrocatalytic flow process is demonstrated for the conversion of microbe pre-treated food waste to ethylene (an important feedstock in the chemical industry) on graphitic carbon electrodes via succinic acid as the central intermediate. In conclusion, with its focus on improving efficiencies, achieving selective product formation, building versatile platforms, diversifying substrate and product scope, and reducing carbon footprint and economic strain, this thesis aims to bring sustainable waste-to-fuel technologies a step closer to commercial implementation.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
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You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2019 TurkeyPublisher:Elsevier BV Authors: Çetinkaya, Afşin Yusuf; Yetilmezsoy, Kaan;Abstract The present analysis was conducted as the first study to investigate the biochemical methane potential of four different agro-industrial wastewaters originating from chocolate, slaughterhouse, gum, and beet sugar industries under the same anaerobic fermentation conditions. To the best of our knowledge, no previous study has specifically attempted to pinpoint a hybrid programming strategy for making a quantitative description of the anaerobic biodegradability of these waste streams. Thus, considering the scarcity of the literature in this field, a comprehensive study was conducted to evaluate the amount of bio-methane obtainable from the investigated organic wastes and to predict their kinetics using three different sigmoidal microbial growth curve models (modified Gompertz equation, transference function (reaction curve-type model), and logistic function) within the framework an original MATLAB®-based coding scheme. The results showed that methane productions started immediately after 4 h of incubation for all substrates and reached their maximum rates of 118, 116, 108, 34 mL CH4/g VS/day, respectively, for wastewaters from chocolate, slaughterhouse, gum, and beet sugar industries. The corrected mean steady state methane contents were 61.7%, 73.4%, 62.8%, and 62.1% in the respective order. The highest methane yield (943 mL CH4/g VS) was obtained from the slaughterhouse wastewater, and this value was 1.32, 1.58, and 4.56 times higher than those obtained in the anaerobic digestion of chocolate, gum, and beet sugar wastewaters, respectively. Among the three kinetic models tested, the logistic function best explained the behavior of the observed data of all substrates using a Quasi-Newton cubic line search procedure (R2 = 0.987–0.996) with minimum number of non-linear iterations and function counts. Deviations between the measured and the outputs of the best-fit kinetic model were less than 4.3% in prediction of methane production potentials, suggesting that the proposed computational methodology could be used as a well-suited and robust approach for modeling and optimization of a highly non-linear biosystem.
Aksaray University I... arrow_drop_down Aksaray University Institutional RepositoryArticle . 2019Data sources: Aksaray University Institutional RepositoryJournal of Cleaner ProductionArticle . 2019 . Peer-reviewedLicense: Elsevier TDMData sources: CrossrefYildiz Technical University - AVESISArticle . 2019Data sources: Yildiz Technical University - AVESISadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.jclepro.2019.117921&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 28 citations 28 popularity Top 10% influence Top 10% impulse Top 10% Powered by BIP!
more_vert Aksaray University I... arrow_drop_down Aksaray University Institutional RepositoryArticle . 2019Data sources: Aksaray University Institutional RepositoryJournal of Cleaner ProductionArticle . 2019 . Peer-reviewedLicense: Elsevier TDMData sources: CrossrefYildiz Technical University - AVESISArticle . 2019Data sources: Yildiz Technical University - AVESISadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.jclepro.2019.117921&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Journal 2019 TurkeyPublisher:Elsevier BV Authors: Çetinkaya, Afşin Yusuf; Yetilmezsoy, Kaan;Abstract The present analysis was conducted as the first study to investigate the biochemical methane potential of four different agro-industrial wastewaters originating from chocolate, slaughterhouse, gum, and beet sugar industries under the same anaerobic fermentation conditions. To the best of our knowledge, no previous study has specifically attempted to pinpoint a hybrid programming strategy for making a quantitative description of the anaerobic biodegradability of these waste streams. Thus, considering the scarcity of the literature in this field, a comprehensive study was conducted to evaluate the amount of bio-methane obtainable from the investigated organic wastes and to predict their kinetics using three different sigmoidal microbial growth curve models (modified Gompertz equation, transference function (reaction curve-type model), and logistic function) within the framework an original MATLAB®-based coding scheme. The results showed that methane productions started immediately after 4 h of incubation for all substrates and reached their maximum rates of 118, 116, 108, 34 mL CH4/g VS/day, respectively, for wastewaters from chocolate, slaughterhouse, gum, and beet sugar industries. The corrected mean steady state methane contents were 61.7%, 73.4%, 62.8%, and 62.1% in the respective order. The highest methane yield (943 mL CH4/g VS) was obtained from the slaughterhouse wastewater, and this value was 1.32, 1.58, and 4.56 times higher than those obtained in the anaerobic digestion of chocolate, gum, and beet sugar wastewaters, respectively. Among the three kinetic models tested, the logistic function best explained the behavior of the observed data of all substrates using a Quasi-Newton cubic line search procedure (R2 = 0.987–0.996) with minimum number of non-linear iterations and function counts. Deviations between the measured and the outputs of the best-fit kinetic model were less than 4.3% in prediction of methane production potentials, suggesting that the proposed computational methodology could be used as a well-suited and robust approach for modeling and optimization of a highly non-linear biosystem.
Aksaray University I... arrow_drop_down Aksaray University Institutional RepositoryArticle . 2019Data sources: Aksaray University Institutional RepositoryJournal of Cleaner ProductionArticle . 2019 . Peer-reviewedLicense: Elsevier TDMData sources: CrossrefYildiz Technical University - AVESISArticle . 2019Data sources: Yildiz Technical University - AVESISadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1016/j.jclepro.2019.117921&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 28 citations 28 popularity Top 10% influence Top 10% impulse Top 10% Powered by BIP!
more_vert Aksaray University I... arrow_drop_down Aksaray University Institutional RepositoryArticle . 2019Data sources: Aksaray University Institutional RepositoryJournal of Cleaner ProductionArticle . 2019 . Peer-reviewedLicense: Elsevier TDMData sources: CrossrefYildiz Technical University - AVESISArticle . 2019Data sources: Yildiz Technical University - AVESISadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Master thesis 2023 PortugalAuthors: Santos, Rafael de Matos Ferreira da Mota;handle: 10400.22/24114
A indústria petrolífera, que tem como um dos produtos o plástico, e a do ferro e aço são das maiores emissoras mundiais de Gases com Efeito de Estufa (GEE). Assim, atualmente, com as crescentes preocupações ambientas da população, torna-se urgente estudar o impacte ambiental das fábricas produtoras de embalagens de plástico e metal. Desse modo, a presente dissertação foi realizada na Colep Packaging Portugal e teve como objetivo calcular a pegada de carbono da fábrica referente ao ano de 2022. A avaliação da pegada de carbono foi realizada tendo como linhas orientadoras a metodologia Greenhouse Gas Protocol e sempre que possível, foram utilizados os fatores de emissão de origem primária. A pegada de carbono é dividida em três âmbitos: o primeiro é referente às emissões diretas da empresa relatora; o segundo são emissões indiretas para a produção de energia; o terceiro refere-se a emissões que ocorrem como consequência da atividade da empresa relatora. É possível afirmar que este mesmo objetivo foi atingido, obtendo-se como resultado 7 408,235 t CO2 eq de âmbito 1 (7,03%), 2 846,705 t CO2 eq de âmbito 2 (2,70%) e 95 075,239 t CO2 eq de âmbito 3 (90,27%). Globalmente, o valor calculado foi 105 330,179 t CO2 eq. As categorias que mais contribuíram para este valor da pegada de carbono são os bens e serviços adquiridos, o fim de vida dos produtos vendidos e o consumo de gás natural. Estas três categorias emitiram, em 2022, 87 732,707 t CO2 eq, o que corresponde a 83,29% das emissões totais da Colep Packaging Portugal. Para calcular a pegada de carbono foi necessário realizar um inventário, em primeiro lugar, aos tipos de energia consumida. Nestes parâmetros estão incluídos o gás natural, propano, gasóleo, gasolina e líquidos refrigerantes para o âmbito 1 e a eletricidade para o âmbito 2. Foi também realizado um inventário para o âmbito 3 a todas as matérias-primas, serviços e bens capitais adquiridos, ao transporte a montante (de matérias-primas) e a jusante (de produtos vendidos), aos resíduos gerados no processo produtivo, às viagens de negócios e diárias dos colaboradores, aos bens alugados a montante (veículos de leasing e paletes) e a jusante (edifícios), ao processamento dos produtos vendidos e ao fim de vida destes. Também se analisou o uso dos produtos vendidos, os franchises da empresa e os investimentos, porém, estas categorias não registaram valores. De maneira a reduzir o valor da pegada de carbono sugere-se a realização de algumas medidas. Ao todo são 16 de onde se destacam a substituição dos veículos a combustão por elétricos, a utilização de camiões elétricos, a utilização de energia 100% renovável, a utilização de comboios para transporte superior a 250 km, a instalação de painéis solares, o aumento da eficiência energética e a incorporação de reciclado nas embalagens metálicas. Ao serem implementadas, as 16 medidas permitem reduzir em 54 262,702 t CO2 eq, o que corresponde a 51,52% do atual valor global.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
visibility 16visibility views 16 download downloads 4 Powered bymore_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Master thesis 2023 PortugalAuthors: Santos, Rafael de Matos Ferreira da Mota;handle: 10400.22/24114
A indústria petrolífera, que tem como um dos produtos o plástico, e a do ferro e aço são das maiores emissoras mundiais de Gases com Efeito de Estufa (GEE). Assim, atualmente, com as crescentes preocupações ambientas da população, torna-se urgente estudar o impacte ambiental das fábricas produtoras de embalagens de plástico e metal. Desse modo, a presente dissertação foi realizada na Colep Packaging Portugal e teve como objetivo calcular a pegada de carbono da fábrica referente ao ano de 2022. A avaliação da pegada de carbono foi realizada tendo como linhas orientadoras a metodologia Greenhouse Gas Protocol e sempre que possível, foram utilizados os fatores de emissão de origem primária. A pegada de carbono é dividida em três âmbitos: o primeiro é referente às emissões diretas da empresa relatora; o segundo são emissões indiretas para a produção de energia; o terceiro refere-se a emissões que ocorrem como consequência da atividade da empresa relatora. É possível afirmar que este mesmo objetivo foi atingido, obtendo-se como resultado 7 408,235 t CO2 eq de âmbito 1 (7,03%), 2 846,705 t CO2 eq de âmbito 2 (2,70%) e 95 075,239 t CO2 eq de âmbito 3 (90,27%). Globalmente, o valor calculado foi 105 330,179 t CO2 eq. As categorias que mais contribuíram para este valor da pegada de carbono são os bens e serviços adquiridos, o fim de vida dos produtos vendidos e o consumo de gás natural. Estas três categorias emitiram, em 2022, 87 732,707 t CO2 eq, o que corresponde a 83,29% das emissões totais da Colep Packaging Portugal. Para calcular a pegada de carbono foi necessário realizar um inventário, em primeiro lugar, aos tipos de energia consumida. Nestes parâmetros estão incluídos o gás natural, propano, gasóleo, gasolina e líquidos refrigerantes para o âmbito 1 e a eletricidade para o âmbito 2. Foi também realizado um inventário para o âmbito 3 a todas as matérias-primas, serviços e bens capitais adquiridos, ao transporte a montante (de matérias-primas) e a jusante (de produtos vendidos), aos resíduos gerados no processo produtivo, às viagens de negócios e diárias dos colaboradores, aos bens alugados a montante (veículos de leasing e paletes) e a jusante (edifícios), ao processamento dos produtos vendidos e ao fim de vida destes. Também se analisou o uso dos produtos vendidos, os franchises da empresa e os investimentos, porém, estas categorias não registaram valores. De maneira a reduzir o valor da pegada de carbono sugere-se a realização de algumas medidas. Ao todo são 16 de onde se destacam a substituição dos veículos a combustão por elétricos, a utilização de camiões elétricos, a utilização de energia 100% renovável, a utilização de comboios para transporte superior a 250 km, a instalação de painéis solares, o aumento da eficiência energética e a incorporação de reciclado nas embalagens metálicas. Ao serem implementadas, as 16 medidas permitem reduzir em 54 262,702 t CO2 eq, o que corresponde a 51,52% do atual valor global.
add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=od______2595::67eb2cca17dacea22b5d7426c394f961&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 0 citations 0 popularity Average influence Average impulse Average Powered by BIP!
visibility 16visibility views 16 download downloads 4 Powered bymore_vert add ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
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For further information contact us at helpdesk@openaire.eu