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Abstract The Biofuels Directive sets reference values for the quantity of biofuels and other renewable fuels to be placed on the transport market. Biogas from agricultural crops can be used to meet this directive. This paper investigates biogas production for three crop rotations: wheat, barley and sugar beet; wheat, wheat and sugar beet; wheat only. A technical and economic analysis for each crop rotation was carried out. It was found that wheat produces significantly more biogas than either barley or sugar beet, when examined on a weight basis. However sugar beet produces more biogas and subsequently more energy when examined on an area basis. When producing biofuels, land is the limiting factor to the quantity of energy that may be produced. Thus if optimising land then a crop rotation of wheat, wheat and sugar beet should be utilised, as this scenario produced the greatest quantity of energy. This scenario has a production cost of €0.90/mN3, therefore, this scenario is competitive with petrol when the price of petrol is at least €1.09/l (VAT is charged at 21%). If optimising the production costs then a crop rotation of wheat only should be utilised when the cost of grain is less than €132/ton. This scenario has the least production cost at €0.83/mN3, therefore, this scenario is competitive with petrol when the price of petrol is at least €1.00/l. But as this scenario produces the least quantity of biogas, it also produces the least quantity of energy. In comparing with other works by the authors it is shown that a biomethane system produces more energy from the same crops at a cheaper cost than an ethanol system.

Abstract Bioproducts from biomass feedstocks and organic wastes have shown great potential to address challenges across food-energy-water systems. However, bioproducts production is at an early, nascent stage that requires new inventions and cost-reducing approaches to meet market needs. Biochar, a byproduct of the pyrolysis process, derived from nutrient-rich biomass feedstocks (e.g., cattle manure and poultry litter) is one of these bioproducts that has numerous applications, such as improving soil fertility and crop productivity. This study investigates the market opportunity and sustainability benefits of converting manure to biochar on-site, using a portable refinery unit. Techno-economic and environmental impact assessments are conducted on a real case study in Twin Falls, Idaho, USA. The techno-economic analysis includes a stochastic optimization model to calculate the total cost of biochar production and distribution. The environmental study employs a life cycle assessment method to evaluate the global warming potential of manure-to-biochar production and distribution network. The total cost of biochar production from cattle manure near the feedlots is approximately $237 per metric ton, and total emission is 951 kg CO2 eq. per metric ton. The on-site operation and manure moisture content are two key parameters that can reduce biochar unit price and carbon footprint of manure management. It is concluded that converting cattle manure, using the presented strategy and process near the collection sites can address upstream and midstream sustainability challenges and stimulate the biochar industry.

Effectively analyzing and then treating energy-related air pollution requires examining every factor, from the pollution source to the end of treatment. This paper applies index decomposition analysis and a whole process treatment perspective to identify the factors facilitating air pollution reduction across three stages: source prevention, process control, and end-of-pipe treatment. Empirical research using data from China’s Jiangsu Province and its 13 cities reveals differences in local approaches to pollution prevention. At the provincial level, end-of-pipe treatment remains the primary approach to control air pollution emissions, indicating that the pattern of “pollute first, govern later” has not yet been fundamentally reversed. At the city level, 13 cities can be divided into four types, based on their approach to air pollution treatment: the leading type, process-dependent type, end-dependent type, and lagging type. Of these, 7 cities are using multiple control approaches, reflecting the comprehensive effect of whole process treatment. The Jiangsu Province should consider further strengthening effective whole process air pollution treatment models, by transitioning to pollution control, adjusting industrial structure, promoting technological progress, and consuming clean energy.

This study presents an investigation on the influence of hydrothermally treated municipal solid waste (MSW) on the co-combustion characteristics with different rank coals, i.e. Indian, Indonesian and Australian coals. MSW blends of 10%, 20%, 30% and 50% (wt.%) with different rank coals were tested in a thermogravimetric analyser (TGA) in the temperature range from ambient to 700 °C under the heating rate of 10 °C/min. Combustion characteristics such as volatile release, ignition and burnout were studied for the blend fuel. Different ignition behavior was observed depending on the blends composition and the coal rank. The result of this work indicates that the blending of MSW improves devolatization properties of coal. But it was found that the co-combustion characteristics of MSW and coal blend cannot be predicted only from the pyrolytic and or devolatization phenomena as the other factors such as the coal quality also plays a vital role in deciding the blends co-combustion characteristics. The TGA combustion profiles showed that the combustion characteristics of blends followed those of parent fuels in both an additive and non-additive manners. These experimental results help to understand and predict the behavior of coal and MSW blends in practical applications.

Carbon emission reduction is a long-term strategy for China to promote its economic and social development. However, emission reduction often involves a huge amount of technological investment, which could vary substantially across different provinces due to their discrepancy in economic and technological development levels. Emission trading as a useful policy instrument may help different provinces achieve their emission reduction targets cost-effectively. This paper models the economic performance of an interprovincial emission reduction quota trading scheme in China. The marginal abatement cost curve of each province in China is first estimated. A nonlinear programming model is further developed to evaluate the economic performance of interprovincial emission reduction quota trading. Five equity criteria are used to conduct the initial allocation of emission reduction targets between different provinces. Our modeling results show that China’s total emission abatement cost could decrease by over 40% through implementing such an interprovincial emission reduction quota trading scheme. Of the five alternative criteria, the CO2 emissions and population criteria look fairer and are recommended for use in the initial allocation of CO2 emission reduction targets.

Abstract A novel magnesia-stabilized carbide slag (MSCS) was synthesized with carbide slag, magnesium nitrate hydrate and by-product of biodiesel by combustion, which was used as a CO 2 sorbent during the calcium looping process. The effects of preparation condition (combustion temperature, combustion duration, by-product of biodiesel addition and magnesia addition) and CO 2 capture condition (carbonation and calcination atmosphere) on CO 2 capture capacity of MSCS were investigated during the calcium looping cycles. The main compositions of MSCS are CaO and MgO. The addition of by-product of biodiesel in the preparation of the sorbent leads to the uniform mix of MgO and CaO grains in MSCS, which shows an obviously positive effect on its CO 2 capture capacity. Only on the condition of the addition of by-product of biodiesel, MgO derived from magnesium nitrate hydrate improves the cyclic CO 2 capture capacity and durability of MSCS during the multiple cycles. MSCS with a mass ratio of CaO to MgO of 80:20 combusted at 850 °C for 60 min exhibits higher CO 2 capture capacity and greater durability. The CO 2 capture capacity of MSCS can retain 0.42 g/g after 20 cycles, which is 60% higher than that of carbide slag. MSCS calcined under the high concentration of steam displays much higher CO 2 capture capacity and better sintering resistance during the cycles, compared to MSCS calcined under the high concentration of CO 2 . The addition of steam in the carbonation enhances CO 2 capture capacities of MSCS and carbide slag. MSCS consists of CaO–MgO grain groups and the support of MgO sustains the high sintering resistance of the sorbent. MSCS remains much larger surface area and pore volume than carbide slag during the cycles, compared to carbide slag. MSCS appears promising as an effective and low-cost CO 2 sorbent during the calcium looping.

Abstract In this study, batch tests were performed to evaluate the effects of different thermal pretreatment temperatures (55–160 °C) and durations (15–120 min) on the anaerobic digestion of kitchen waste (KW). Two commonly used approaches, namely the modified Gompertz model and the approach developed by Koch and Drewes, were applied to assess the effects of the different pretreatment parameters on the biomethane yield, lag time and hydrolysis rate constant via data fitting. The subsequent anaerobic digestion of KW pretreated at 55–120 °C presented greater efficiency, and longer treatment durations resulted in increased methane production and higher hydrolysis rate constants. These findings were obtained due to the lower nutrient loss observed in KW treated at lower temperature treatments compared with that found with higher temperature treatments. In general, the effects of thermal pretreatment on the lag phase and hydrolysis rate differed depending on the treatment parameters leading to the variations in the KW compositions. The soundness of the two model results was evaluated, and higher statistical indicators (R2) were found with the modified Gompertz model than with the approach developed by Koch and Drewes.

Biomass gasification is considered a key technology in reaching targets for renewable energy and CO2 emissions reduction. This study evaluates policy instruments affecting the profitability of biom ...

Abstract One of the strategies to improve environmentally friendly energy harvesting can be realized by using biomass as a primary energy source for generating electricity and H2. In addition, high energy efficiency can be achieved by minimizing exergy loss through process integration and exergy recovery. As an implementation, this study proposes a cogeneration system for black liquor (BL) to co-produce electricity and H2. The system primarily comprises BL drying, circulating fluidized bed gasification, syngas chemical looping (SCL), and power generation. The Aspen Plus V8.8 software package is used for modeling and performing calculations of the proposed integrated system. Furthermore, thermodynamic analysis of gasification is performed by employing Gibbs energy minimization. The effects of target solid content on the required total work and compressor outlet pressure during drying and gasification with different steam-to-fuel ratios are evaluated. Moreover, the SCL process adopts three reactors, namely, the reducer, oxidizer, and combustor. Compared to conventional processes, the integrated drying-gasification-SCL processes are significantly cleaner and more energy efficient. The proposed integrated system can achieve a net energy efficiency of about 70% with almost 100% carbon capture.