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Abstract Microorganisms used in syngas fermentation require nutrients to grow and convert syngas (CO, H2 and CO2) into various products. Many of the essential nutrients can be provided by biochar. Poultry litter biochar (PLBC) contains minerals and trace metals and has a high pH buffering capacity, making it suitable as a nutrient supplement. The effects of PLBC loadings from 1 to 20 g L−1 on syngas fermentation were determined in 250 ml bottle assays. Results showed that 10 and 20 g L−1 PLBC significantly increased ethanol production compared to standard yeast extract (YE) medium. Fermentations in a 3L continuous stirred tank reactor (CSTR) with 10 g L−1 PLBC with and without 4-morpholineethanesulfonic acid (MES) showed 64% and 36% more ethanol production, respectively, than standard medium. The acetic acid accumulated at the beginning of fermentation was completely converted to ethanol in all media tested in the CSTR. These results demonstrate the feasibility of using PLBC medium without costly MES in the CSTR to enhance ethanol production from syngas for potential use at commercial scale.

Abstract District heating (DH) enables the utilisation and distribution of heating from sources unfeasible for stand-alone applications and combined with cogeneration of heat and power (CHP), has been the cornerstone of Denmark’s realisation of a steady national primary energy supply over the last four decades. However, progressively more energy-efficient houses and a steadily improving heat pump (HP) performance for individual dwellings is straining the competitive advantage of the CHP–DH combination as DH grid losses are growing in relative terms due to decreasing heating demands of buildings and relatively high DH supply temperatures. A main driver for the DH water temperature is the requirements for domestic hot water (DHW) production. This article investigates two alternatives for DHW supply: (a) DH based on central HPs combined with a heat exchanger, and (b) a combination of DH based on central HPs and a small booster HP using DH water as low-temperature source for DHW production. The analyses are conducted using the energyPRO simulation model and are conducted with hourly varying factors; heating demands, DH grid losses, HP coefficient of performance (COP) and spot market prices in order to be able to analyse the relative performance of the two options and their performance over the year. Results are also compared to individual boilers and individual HPs. The results indicate that applying booster HPs enables the DH system to operate at substantially lower temperature levels, improving the COP of central DH HPs while simultaneously lowering DH grid losses significantly. Thus, DH performance is increased significantly. Additionally, performance for the DH HP with booster combination is considerably better than individual boiler or HP solutions.

Abstract This paper presents a novel multi-time-stage input–output-based modeling framework for simulating the dynamics of bioenergy supply chains. One of the key assumptions used in the model is that the production level at the next time-stage of each segment of the energy supply chain adjusts to the output surplus or deficit relative to targets at the current time period. Furthermore, unlike conventional input–output models, the technology matrix in this approach need not be square, and thus can include coefficients denoting flows of environmental goods, such as natural resources or pollutants. Introducing a feedback control term enables the system to regulate the dynamics, thus extending the model further. This is an important feature since the uncontrolled dynamic model exhibits oscillatory or unstable behavior under some conditions; in principle, the control term allows such undesirable characteristics to be suppressed. Numerical simulations of a simple, two-sector case study are given to illustrate dynamic behavior under different scenarios. Although the case study uses only a hypothetical system, preliminary comparisons are made between the simulation results and some broad trends seen in real bioenergy systems. Finally, some of the main policy implications of the model are discussed based on the general dynamic characteristics seen in the case study. In particular, insights from control theory can be used to develop policy interventions to impart desirable dynamic characteristics to nascent or emerging biofuel supply chains. These interventions can be used to guide the growth of bioenergy supplies along final demand trajectories with minimal fluctuation and no instability.

Abstract Reversible carbonation/calcination of CaCO3 is a promising technology for thermochemical energy storage in concentrated solar power plants. However, the major drawback of this technology is the rapid deactivation of CaO due to sintering. In this study, newly developed CaCO3/graphite nanosheets composites were synthesized as the heat storage medium through a one-pot route varying the graphite nanosheets load (3–12 wt%). The impregnation of the composites with H3BO3 solutions enhance the initial weightlessness temperature of graphite nanosheets from 900 °C to 1050 °C in pure CO2 atmosphere, thus upgrading the stability of graphite nanosheets during heat storage/release process. The performances of the synthesized composites were evaluated by thermogravimetric analysis, which simulates the heat storage cycle. The composites showed improved heat storage/output capacity and faster heat input/output rate compared to pure CaCO3. Only 3 wt% of graphite nanosheets was needed to effectively stabilize the heat storage capacity of the material. The heat storage capacity of composites with 3 wt% graphite nanosheets is 1313 kJ/kgcomposite after 50 cycles, corresponding to 2.9 times as much as that of pure CaCO3. This high stability is attributed to the unique synthetic strategy in which the CaCO3 nanoparticles uniformly coated on graphite nanosheets surface, and their sintering and aggregation were prevented. This work brings the development of this technology to a level closer to its industrial application.

Abstract Economically harvesting energy from a microbial fuel cell (MFC), increasing its electrical power production, and developing its role as a practical energy supply, needs a low-cost and high-performance design of the MFC compartments. According to this strategy, a novel monolithic membrane electrode assembly (MEA) was fabricated and evaluated as an air–cathode in a single-chamber MFC (SCMFC). The MEA was made of bacterial cellulose (BC), conductive multi-walled carbon nanotubes (CNT), and nano-zycosil (NZ). BC, as a nano-celluloses with oxygen barrier property, can maintain anaerobic conditions for the anode compartment. Binder-less CNT coating on BC avoids costly binders such as poly-tetra fluoro ethylene (PTFE) and Nafion and decreases the MEA charge transfer resistance. NZ, as a very cheap modifier, not only prevents the anolyte leakage but also provides more MEA’s active sites for the oxygen reduction reaction (ORR). The electrochemical performance of the MEA was compared to a PTFE- based gas diffusion electrode (GDE) in the SCMFC. The MEA cell provided a pulse power density of 1790 mW/m2, roughly twice as high as the pulse power density of GDE (920 mW/m2). SCMFC’s internal resistance decreased from 1.84 KΩ (with GDE) to 0.8 KΩ (with MEA). Also, the cell’s columbic efficiency increased from 4.2% (with GDE) to11.7% (with MEA). Additionally, the capacitance of the MEA (65 mF) was much higher than the value for GDE (0.73 mF). Thus, the MEA compared to the GDE showed higher performance in the SCMFC for electricity generation and wastewater treatment at a lower cost.

Abstract The hybrid pneumatic power system (HPPS) proposed in this research replaces the battery’s electric-chemical energy with flow work and optimizes the management and utilization of the energy. This power system is able to keep the internal-combustion engine working at its optimal condition and turn its waste energy into effective mechanical energy and so enhance the thermal efficiency of the whole system. Using computer simulation software ITI-SIM, this study simulates the overall dynamic characteristics of the system in accordance with the regulated running-vehicle test-mode ECE47, and, with experimental verification and analysis, proves that this system can meet the requirements of the standard running-car mode. As for recycling the waste energy, the experimental results show that this design could offset the shortcomings of the low-density of pneumatic power and so effectively enhance the efficiency of the whole system.