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Abstract In this work, earth-abundant CZTSSe thin film solar cells were fabricated by sulfo-selenization of the Mo/Zn/Cu/Sn/Cu metallic precursors. The influences of morphological and compositional properties of the absorbers on performance of solar cells were investigated by tuning Cu content in the films. The Raman analysis showed that absorbers consist of a kesterite CZTSSe phase with ZnSe as a minor secondary phase. X-ray photoelectron spectroscopy (XPS) analyses revealed that the surfaces are Cu depleted and Zn enriched compared with the bulk composition of the absorbers. The results indicate that during sulfo-selenization the Cu diffused into the film and the Zn towards the film surface. The performance of the solar cells initially improved with the increasing of the Cu content and then decreased. By tuning the Cu content in the absorbers, the minority-carrier life time improved from 0.8 to 1.6 ns. The power conversion efficiency increased from 5.1 to 8.03% with fine controlling of Cu composition of the CZTSSe absorbers. The diode-ideality factors are higher than 2, suggesting an increased interfacial recombination in the devices. The high ideality-factors A and low minority carrier life times may originate from surface and bulk related defects, which in turn limits the Voc and the achievable high conversion efficiency for the CZTSSe thin film solar cells.

Abstract In this work, earth-abundant CZTSSe thin film solar cells were fabricated by sulfo-selenization of the Mo/Zn/Cu/Sn/Cu metallic precursors. The influences of morphological and compositional properties of the absorbers on performance of solar cells were investigated by tuning Cu content in the films. The Raman analysis showed that absorbers consist of a kesterite CZTSSe phase with ZnSe as a minor secondary phase. X-ray photoelectron spectroscopy (XPS) analyses revealed that the surfaces are Cu depleted and Zn enriched compared with the bulk composition of the absorbers. The results indicate that during sulfo-selenization the Cu diffused into the film and the Zn towards the film surface. The performance of the solar cells initially improved with the increasing of the Cu content and then decreased. By tuning the Cu content in the absorbers, the minority-carrier life time improved from 0.8 to 1.6 ns. The power conversion efficiency increased from 5.1 to 8.03% with fine controlling of Cu composition of the CZTSSe absorbers. The diode-ideality factors are higher than 2, suggesting an increased interfacial recombination in the devices. The high ideality-factors A and low minority carrier life times may originate from surface and bulk related defects, which in turn limits the Voc and the achievable high conversion efficiency for the CZTSSe thin film solar cells.

Abstract Methane dry reforming with CO2 using FeO powder in molten salt has been investigated at various flow rates of CH4/CO2 mixed gases (CH4/CO2=1) between 50 and 400 ml/min at 1223 K in an infrared furnace. This work is carried out to determine the usefulness of this method for the chemical storage of solar energy. The CH4/CO2 mixed gases passing through the molten salt (Na2CO3/K2CO3=1) containing the FeO powder were catalytically decomposed into CO, H2 and H2O. The product gas mole ratios, CO/H2/H2O, were shown to be 3:1:1 for a high flow rate of 200 ml/min and to be CO/H2=2:1 for a low flow rate of 50 ml/min. The results were explained in terms of the kinetics of the CH4-reforming reaction and the thermodynamics of the redox process of FeO powder mixed in the molten salt; CH 4 +2FeO⇒2Fe+H 2 +CO+H 2 O Fe+CO 2 ⇒FeO+CO for a high flow rate, and FeO+CH 4 ⇒Fe+2H 2 +CO Fe+CO 2 ⇒FeO+CO for a low flow rate.