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Earth observation (EO) data are useful tools to analyse geomorphological processes, among which slow-moving landslides triggered by rainfall. EO data are also used to evaluate climate change and to assess its impact on geomorphological processes and geo-hydrological phenomena. The latter is the topic of the Project OT4Clima (Innovative Earth Observation technologies to study Climate Change and its impact on the environment) joined by CNR-IRPI within a consortium that includes other CNR institutes, universities and private companies. The OT4CLIMA project moves from the awareness that the impacts of climate change on the environment need to be better observed, understood, and modelled, especially at a regional scale, in order to put in place appropriate and effective risk mitigation strategies. Within the project, the CNR-IRPI group works on the development of rigorous methods and procedures for evaluating the impact of climate and its change on landslides, in particular on those characterized by a slow cinematic, at a regional scale. The test site is represented by four catchments located in the Basilicata region, southern Italy, namely the basins of the Bradano, Basento, Agri, and Sinni rivers. Long-term rainfall series gathered from 22 rain gauges located in the four catchments are analysed to evaluate the presence of temporal trends. To this aim, non-parametric and statistical tests are applied to the series. Historical landslide information is gathered from the analysis of the IFFI (Inventario dei Fenomeni Franosi in Italia) database, the Idrogeo platform (https://idrogeo.isprambiente.it/app/) and the AVI (Aree Vulnerate in Italia) catalogue. Only some types of landslide movements are considered, namely rotational-translational slides, slow slides/flows, complex movements. Moreover, Copernicus Sentinel-1 images are employed to detect the spatial and temporal distribution of slow earth surface deformations. The obtained results are used for checking the completeness of the landslide inventories. More in detail, the deformation maps of the test site are obtained by means of the application of the SBAS (Small BAseline Subset) technique to three datasets of Sentinel-1 images: t146 ascending orbit and t51 and t124 descending orbits, for the period 2015-2020. Then, a comparative analysis of rainfall data with displacement series is carried out with the aim of identifying clusters of satellite measurements with homogeneous behaviour likely correlated to variations in the rainfall regime. In particular, only the points with a mean velocity in the observation higher than 0.1 cm/year are considered to be moving. Moreover, only the displacement series of points located in areas mapped as landslides - as for the historical inventories - and sited within the influence regions of each rain gauge in the study area are analysed. A 10-km circular buffer centred in the stations are used to define the influence region of each station. The displacement series are analysed and compared to the rainfall series to search for correlations and to evaluate the effects of climate drivers on slow moving landslides.

Why are small islands more vulnerable to the global and major ordeal of climate change? How do they face this huge challenge and what can we learn from their experience? These are among the crucial questions examined by Carola Klöck and Michael Fink in their recently coedited volume entitled Dealing with Climate Change on Small Islands: Toward Effective and Sustainable Adaptation, published by Universitätsverlag Göttingen. Interview by Miriam Périer, CERI.

The aim of the joint activity between CNR ITAE and University of Malta, funded in the framework of a bilateral agreement is the preliminary study of the possible application of thermally-activated technologies for the refrigeration of fish on-board of fishing vessels, with particular attention to the Mediterranean area. In such a context, the two partners, given their expertise in the adsorption and absorption cooling technologies, dedicated the first year of the joint project on several activities needed to define possible integration solutions on-board. The following report is then organized as follows: - Section 3 reports an analysis of the state-of-the-art concerning existing refrigeration systems currently employed in the fishing vessels' application as well as innovative activities recently performed on the possible integration of thermally-driven technologies for the refrigeration. - Section 4 focuses on the definition of possible integration between the waste heat recovered from the engines of the fishing vessel and the sorption technology for refrigeration. This analysis takes into account different possible applications, in terms of refrigeration temperatures as well as capacities. Furthermore, different possible waste heat streams at different temperature levels are investigated. - Section 5 identifies the typical working boundary conditions under which the fishing vessel operates, in terms of cooling demand, also considering different climatic zones (i.e. different geographical areas in which the vessel operates) and vessels' typology. - Section 6 investigates possible working pairs, both for adsorption and absorption technologies, which are promising for the given boundary conditions in Section 5. This activity is needed to set the operational limits that each technology and working pair cannot overcome. - Section 7 reports the calculations performed for each working pair and operating conditions, both taking into account thermodynamic constraints as well as analysing literature results on different prototypes realized and tested. - Section 8 introduces a dynamic model, implemented in TRNSYS environment, of an absorption refrigerator, which was validated and will be used in the following activities to investigate the defined schematics in Section 4. - Section 9 defines the Key Performance Indicators (KPIs) that will be used in the following activities to compare the achievable results of the different configurations.

Esta dissertação explora o modo como a empresa multinacional Unilever tem por objetivo a reconciliação da lógica Comercial e a de Sustentabilidade nas suas principais atividades de negócio, de modo a atingir o hibridismo organizacional. Baseando-se num estudo de caso, demonstra como a Unilever interliga estas duas lógicas através de três fatores distintos: liderança, comunicação e ações. O estudo qualitativo revela que o sucesso desta integração e a sustentação das mesmas não deriva de um único fator em específico, mas sim da interação planeada entre esses três fatores. De acordo com os resultados da minha análise, desenvolvi um modelo que demonstra como as duas lógicas mudam ao longo do tempo, influenciadas por dinâmicas tanto internas como externas. This dissertation explores how the multinational company Unilever aims at reconciling two logics, a Sustainability and a Commercial Logic within its core business activities to achieve organizational hybridity. Based on a case study, it shows that Unilever reconciles the two logics through three distinct drivers: leadership, communication and actions. The qualitative study reveals that there is not a specific single driver that can lead to a successful integration and sustaining of logics, but rather the planned interplay between the three drivers. Resulting from my findings, I developed a model that elucidates how the two logics change over time through both internal and external dynamics.

A recent addition to the anthropogenic sources of underwater noise is offshore wave energy converters. Underwater noise was recorded from the Wavestar wave energy converter located at Hastholm, Denmark (57°7.73´N, 8°37.23´E). The Wavestar is a full-scale test and demonstration converter of the absorber type. During recordings the converter was operating close to maximum power output (nominal capacity of 110 kW). During operation the independently operating absorbers float semi-submerged in the water and wave-generated up-and-down motion is converted into hydraulic pressure by means of pistons connected to the arms of the absorbers. The hydraulic pressure then in turn drives the generator. A 57 minute sequence of noise from the converter was recorded by a Loggerhead datalogger deployed in 7 m deep water 25 m from the converter. This sequence contained recordings of ambient noise, the converter in full operation and start and stop of the converter. Median broad band (10 Hz – 20 kHz) sound pressure level (Leq) was 123 dB re. 1 Pa, irrespective of status of the wave energy converter (stopped, running or starting/stopping). The most pronounced peak in the third-octave spectrum was in the 160 Hz band during start and stop of the converter, attributed to the hydraulic pump responsible for lifting and lowering the absorbers. Less pronounced, but still statistically significant differences were seen in the bands 125, 160, 200 and 250 Hz when operation and ambient were compared. No statistically significant noise above ambient could be detected above the 250 Hz band. The absolute increase in noise above ambient was very small. L50 third-octave levels in the four bands with the converter running were thus only 1-2 dB above ambient L50 levels.The noise recorded 25 m from the wave energy converter was barely detectable above ambient noise and only in the range 125-250 Hz. Harbour seals have good low frequency hearing and third-octave levels of the converter noise are well above their hearing threshold. Harbour seals are thus expected to be able to hear the converter noise, although the elevation in noise levels is so low (1-2 dB) that it is likely to be close to inaudible even at the close range where recordings were obtained. In contrast to seals, harbour porpoises have poor low frequency hearing and it seems unlikely that the converter noise would have been audible to porpoises. Wave energy converters come in different designs and work according to different principles. Other types of converters could be expected to be noisier, perhaps also to generate noise at other frequencies than those reported from the Wavestar. Therefore the conclusion that noise levels from the Wavestar are unlikely to affect seals and porpoises cannot be generalised. Nevertheless, the results clearly demonstrate that it is possible to harvest wave energy in a way which does not add substantially to the increasing levels of anthropogenic noise in the ocean.

The current fashion design, production, and consumption system, known as ‘fast fashion’, is characterized by the manufacturing of low-quality garments in a short period of time carried out in developing countries. In parallel with the deficits in social responsibility and human rights, the prevailing ‘take-make-dispose’ system in the fashion industry is one of the main causes of environmental pollution that concerns the climate change, scarcity of natural resources and health problems for the living beings. Due to these facts, discussions on Circular Design strategies – for waste reduction, components recycling, and materials reuse – became increasingly relevant throughout the globe. This paper’s aspiration is to outline a perspective towards a Circular Fashion. The concept of the Design for Sustainability requires a holistic view throughout de-signing strategies as well as the establishment of cyclical systems for the production site. Notwithstanding, the efficient integration of social and cultural dimensions are vital for Sustainable Fashion’s triumph. This work is supported by FEDER funds through the Competitiveness Factors Operational Programme - COMPETE and by national funds through FCT – Foundation for Science and Technology within the scope of the project POCI-01-0145-FEDER-007136. info:eu-repo/semantics/publishedVersion

The increase of distributed generation (DG) has brought about new challenges in electrical networks electricity markets and in DG units operation and management. Several approaches are being developed to manage the emerging potential of DG, such as Virtual Power Players (VPPs), which aggregate DG plants; and Smart Grids, an approach that views generation and associated loads as a subsystem. This paper presents a multi-level negotiation mechanism for Smart Grids optimal operation and negotiation in the electricity markets, considering the advantages of VPPs’ management. The proposed methodology is implemented and tested in MASCEM – a multiagent electricity market simulator, developed to allow deep studies of the interactions between the players that take part in the electricity market negotiations.

It is widely known that fossil fuels are limited; consequently, the generation of new sources of energy in a clean and environmentally friendly manner is a research priority. Bioethanol appears to be one potential solution, especially second-generation production from renewable biomass.In order to use lignocellulosic feedstock to produce bioethanol, its polysaccharide components, cellulose and hemicellulose, must be hydrolysed into soluble sugars, which can then be converted into ethanol by fermentative microorganisms such as Geobacillus thermoglucosidasius TM242 used by the company ReBio Technologies Ltd.To date, the cost of commercial enzymes used during the hydrolysis process remains a major economic consideration in the production of second-generation bioethanol as an alternative fuel. The research project presented in this thesis aims to improve this rate-limiting step of microbial bioethanol production through an investigation of the different enzymes associated with hemicellulose hydrolysis. Firstly, the TM242 genome sequence revealed a number of genes encoding glycoside-hydrolases. Six of these genes were cloned and expressed in E. coli and the recombinant enzymes characterised; three of them, two β-xylosidases and an α arabinofuranosidase, are relevant to xylan hydrolysis, and were found to be highly active and thermostable. Crystallisation of one of the β-xylosidases permitted the determination of a high-resolution (1.7 Å) structure of the apo-enzyme along with a lower resolution (2.6 Å) structure of the enzyme-substrate complex, resulting in the first reported structure of a GH52 family member (Espina et al., 2014).Secondly, as the TM242 microorganism lacks xylanase enzymes, four genes encoding xylanases from closely-related Geobacillus strains were cloned and expressed in E. coli, with one of them being also successfully cloned and expressed in G. thermoglucosidasius TM242. This heterologous xylanase was secreted in active form representing an enhanced biomass utilisation by TM242.In conclusion, it is felt that the findings presented here have the potential to make a valuable contribution towards second-generation bioethanol production.

Marine mammals accumulate alarming amounts of environmental pollutants and are thus the most contaminated group of animals in the world. Elevated pollutant exposure is of concern to marine mammals because of potential adverse effects on reproduction, endocrine disruption and immunity. In vitro techniques can be used to assess effects on specific health endpoints. To date, however, most studies focus on single compound exposures, rather than realistic complex mixtures, and little has been done to extrapolate molecular effects to higher levels of biological organization. The aim of my PhD was to use a unique combination of approaches, namely statistical meta-analyses, in vitro experimentation, analytical chemistry, and ecological modeling, to gain further insight into pollutant accumulation and effects at molecular and organism levels in North-Atlantic top predators.

This document collects the summaries of the interviews carried out with various stakeholders in the Requena-Utiel region from March to October 2021. The topics covered in these interviews focused on the governance of the aquifer, the creation of the Central Board of Users of the Requena-Utiel Underground Mass and the relationships between the different users, their perception of the quantitative and qualitative state of the aquifer and the future actions to take for sustainable management. The questionnaire written by the team from Bo��azi��i University, Turkey, was taken into account when preparing the interviews. This project is part of the PRIMA Programme supported by the European Union's Horizon 2020 Research and Innovation Programme under Grant Agreement No 1923.