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Digital Annex for the following thesis: Vila-Viçosa, C. (2023). Natural History, Biogeography and Evolution of the Iberian white oak syngameon (Quercus L. Sect. Quercus). Ph.D. Thesis, Faculdade de Ciências da Universidade do Porto, Portugal Abstract: The genus Quercus L. is one of the most diverse and important group of woody plants, particularly when considering that they are the trees that rule the Northern Hemisphere forests. Oaks have an intricate Biogeography that criss-crosses diverse climatic and edaphic gradients, encompassing a huge ambiguity in terms of species delimitation. Frequently, the taxonomic proposals brought by traditional Linnaean Botany are either insufficient or rather inflate the number of species and nomenclatural assignments, which are further diluted into inconsistent taxonomic ranks, varying from species to subspecies and varieties. The supremacy given to morphological characters that are inherently fragile and plastic, spread across the distribution areas of distinct lineages, may carry ambiguity on the identification and proper species delimitation. From the oaks that are distributed across the Western Palearctic region, the ones that are deciduous or brevi-deciduous present higher levels of ambiguity in terms of species number and their delimitation. This ambiguity is particularly strong in the circummediterranean region and in the transitional areas between the two major biogeographic Regions of the western Palearctic region, the Euro-Siberian and Mediterranean. This degree of uncertainty, which increases towards the Southern European Peninsulas, is amplified by the ease that the different species of oaks tend to hybridize among them. The present work provides a holistic framework that covers multiple areas, from the taxonomic and evolutive study of this genus, to biogeography and molecular characterization. Its major objective was to resolve the species delimitation of the Iberian deciduous and marcescent oaks and putative introgression among them, enhancing the available knowledge about species diversity, which can foster suitable species and forest conservation. A specific objective was to cross-reference the natural history revision and the different taxonomic treatments brought by distinct authors, with personal observations. These data were then incorporated into ecological modelling and molecular characterization, which in the end fed a newly updated taxonomic proposal. In Section A we obtained results from extensive field, herbaria, and literature review, updating the nomenclature of the Portuguese and western Mediterranean oaks. Section B was supported by Section A’s in-depth review and enabled finer species distribution models, nurturing both hindcast (since ca. 20 Kyr) and forecast (2070-2100) exercises of the range dynamics of Mediterranean oaks species. The study of past and future range shifts solved important pending biogeographic questions, especially related to past range-shifts. Such past-range shifts improved our knowledge on species responses to climate dynamics and allowed a better anticipation of future responses of range shifts driven by climate change. Section C encompassed the molecular characterization of Iberian white oak species and their hybrids, whose delimitation is often faltering when one intends to infer about species rank, or hypothesize about the participation of parent taxon in natural hybrid swarms. This work allowed us to solve the phylogenetic backbone of western Palearctic white oaks, suggesting a significant segregation of the Iberian pedunculate oaks and unveiling two subsections inside Section Quercus. These subsections are biogeographically well-segregated and present diverse levels of introgression among species. Results demonstrated the efficiency of RADSeq for rebuilding the reticulate phylogeny of the Eurasian white oaks, showcasing the significance of the Iberian Peninsula as a major hotspot for oak diversity. We implemented a circular approach to these methods, which retro-fed themselves in terms of insight generation, enabling a powerful strategy to solve the evolutionary history of this difficult groups of plants. We estimate that the reticulate historical biogeography of the western Palearctic white oaks deserves further scrutiny by adding vicariant oak populations from northern Africa, the Near East and southern European Peninsulas. Methods should again follow this similar additive and sequential process of adjoining deep Natural History examination, with extensive fieldwork in type populations and genome-wide molecular surveys, in order to solve this group of plants. With the present work, we were able to significantly improve on the depiction of the basic unit of Biodiversity (the Species), in the complex Quercus genus. We provided tools to enable further efforts for the conservation of the Mediterranean oak forests, which overwhelm one of the most important (and one of the most threatened) Biomes for plant conservation at the global scale.

<h3>Project Overview</h3> <p>Jurisdictional boundaries of governmental agencies often do not align with the geographic or social boundaries of the policy issues they are tasked with addressing. This spatial mismatch is especially common in relation to natural resources and the environment. Where it occurs, achievement of policy goals may require coordination across jurisdictions, which can lead to mutual benefits. Yet, governmental agencies may view coordination as costly or as leading to a loss of autonomy. This project examined coordination decisions made by local level governmental agencies in California, as they formed Groundwater Sustainability Agencies (GSAs) and subsequently coordinated development of their first groundwater sustainability plans (GSPs) under California's Sustainable Groundwater Management Act (SGMA). The project addresses the question of how agencies make decisions and manage interactions when under a coordination mandate that allots agencies the discretion to decide how to coordinate. More specifically, it investigates:<ol><li>What factors influence decisions regarding the geographic extent of and parties involved in development of new formal agencies for groundwater management,</li><li>How do concerns about the potential risks of coordination affect the choice of coordination mechanisms,</li><li>How does the structure of agency interactions affect their achievement of the objectives of the coordination mandate, and</li><li>How do agencies make sense of a coordination mandate and how does that sense-making process influence the decisions agencies make when deciding how to respond to the mandate?</li></ol></p> <h3>Data Collection Overview</h3> <p>Data were collected between January 2018 and May 2020. The methods for data collection varied by data type.<ul><li>Secondary data on the physical, social, and institutional characteristics of groundwater basins were collected from California Department of Water Resources datasets, the American Community Survey, and the National Land Use Database.</li><li>Data on GSA formation and copies of GSPs and Coordination Agreements were obtained from the California’s SGMA Portal Website (https://sgma.water.ca.gov/portal/)</li><li>Meeting minutes and other documentation were obtained from the respective websites of local-level agencies that formed GSAs.</li><li>Interviews were conducted with representatives from 67 groundwater sustainability agencies. Interviewees spanned 17 of the 19 basins and 38 of the 44 groundwater sustainability plans produced. Interviewees were identified based on formal GSA contact information and selected based on formal notices to produce a GSP. Recruitment sought to interview representatives from least one GSA from each GSP group.</li><li>Participant observation was undertaken of more than 58 public meetings (in person, virtually, or reviewing recordings).</li></ul></p> <h3>Shared Data Organization</h3> <p>The shared data is organized into three folders. A GIS folder contains 16 relevant data files. An interview transcripts folder contains 52 de-identified transcripts from the interviews that were recorded and transcribed. Some interviewees did not agree to recording and transcription of the interviews, thus data from those interviews are not available. A tabular data folder contains 3 spreadsheet workbooks. These include a spreadsheet documenting coordination concerns at the basin-level; a spreadsheet documenting organizational forms and institutions adopted at the basin-level; and a spreadsheet documenting coordination outcomes at the basin-level. Each spreadsheet includes a copy of the codebook used in analyzing the data. This data project also includes 6 documentation files: a GIS metadata workbook, an interview catalog, an interview consent form, a redaction protocol, this data narrative, and an administrative README file.</p> <h3>Data Overview</h3> <p>The research involved a mixed-methods approach that combines information on agencies; the physical, social, and institutional characteristics of groundwater basins and the agencies located within them; formal filings; agreements; and plans developed by agencies; meeting minutes; interview data; and data from participant observation.</p>

The world, society and education are constantly evolving, and to respond to these changes, the main governmental institutions have been proposing different global strategies to focus efforts in the same direction. Currently, the United Nations and its 17 Sustainable Development Goals (SDG) have presented a series of indicators that could help to minimise the environmental, economic and social instability we are experiencing. In this sense, Education for Sustainable Development (ESD) has been described as a fundamental factor. Specifically, in previous work, we argued that physical education (PE) could be a good tool to contribute to SDGs. Based on this, no research analysing the voices of Physical Education Teachers (PET) on how this contribution could be made has been identified in previous literature. Therefore, the objectives of this research are: (1) to analyse the voices and opinions of active PETs in terms of the knowledge they have about Sustainable Development (SD); (2) to determine their opinions about the contribution that PE could make to SDGs; and finally, (3) to identify the challenges and limitations of pedagogical action of SD in PE. For this purpose, a qualitative analysis through a semi-structured interview with 41 active PETs was carried out. The main findings will be presented and discussed around four themes: (a) agreement on the concept of sustainability; (b) PE can contribute to the achievement of SDGs; (c) ambiguity in applying SDGs to PE lessons; and (d) teachers’ constraints on how to implement SDGs in PE. It seems to indicate that PETs do not have a multidimensional vision of sustainable development. While they recognise the potential of PE to contribute to SDGs through awareness raising and student learning, they point to its pedagogical and formative constraints as the main barriers to being able to contribute. They pointed to a lack of knowledge on how to do so, guidelines on how to integrate ESD, lack of involvement, shortage of time or resources in school physical education.

The olive oil mill wastewater (OMW) is a by-product (with a high organic load) derived from the production of the olive oil. The OMW steam reforming (OMWSR) process was studied herein, aiming to decrease the environmental damage of such effluents; simultaneously, the waste is economically and energetically valorized with the H-2 production. Several Ni-containing catalysts were prepared and tested to compare their performances for the OMWSR using a synthetic OMW effluent; still, stability tests were also carried out. The materials were extensively characterized: thermogravimetric analysis, temperature programmed oxidation/reduction, temperature-programmed desorption of CO2/NH3, chemisorption of H-2, inductively coupled plasma optical emission spectrometry and physical adsorption-desorption of N-2 at-196 & DEG;C. Amongst the materials tested, the Ni-Ru/SiO2 sample stood out, exhibiting high catalytic performance: at 400 & DEG;C, the H-2 yield (> 8 mol(H2)& BULL;mol(OMW)(-1)) and conversion of total organic carbon (asymptotic to 75%) were high during all the 24 h of the long-term test, with only a small deactivation being noticed.

Abstract The Mediterranean region is one of the most vulnerable regions to climate change. The majority of climate models forecast a rise in temperatures and less rainfall, which have been observed in recent decades. These changes will affect several vegetation properties, especially phenological dynamics and traits, by increasing drought intensity and recurrence. In this climate change context, the present study aims to assess the evolution of vegetation state and its relation with the climate dynamics in the Mediterranean forest region of northeast Tunisia using Land Surface Phenology (LSP) metrics and the vegetation index (NDVI) analysis from 2000 to 2017. To conduct this work, we used precipitation and temperature data from the two closest weather stations and 16-day NDVI composite images from the MODIS satellite source, with 250-m spatial resolution. Three phenological metrics— start of season (SOS), end of season (EOS), and length of season (LOS) — were obtained and compared for different vegetation types. The LSP variation in response to climatic metrics was also analyzed. The results showed that the LSP in our study area changed significantly during the 2000–2017 period, which includes an average 7.8 days delay in the SOS, an average advance in the EOS by 5 days, and LOS shortened by an average 12.8 days. Autumn (Pr_9) and spring (Pr_3 and P3_4) precipitations, as well as maximum temperature (Tx9+10), represent the best climate parameters to explain the changes in LSP. Both the NDVI and SPEI showed a significant high correlation (p

Abstract Concrete is identified in the literature as a suitable material for thermal energy storage applications, with even innovative application potentials such as storage media in concentrating solar power plants. To ensure a suitable heat transfer among concrete components, the binder material of concrete (cement paste) require further research and understanding to this aim. In particular, the thermal stability of cement paste under temperature cycled conditions arises as a research gap. In this study, ordinary Portland and calcium aluminate cement types were selected using a low water-cement ratio. Thermo-mechanical properties were studied before and after 1, 10, and 25 or 50 thermal cycles at 200 °C, 400 °C, 600 °C, and 800 °C. Although ordinary Portland cement paste showed micro-cracking propagation after 25 thermal cycles from ambient temperature to 200 °C and 400 °C, both cement pastes preserved their integrity, being compressive strength higher in ordinary Portland cement. On the contrary, after 25 or 50 thermal cycles at 600 °C and 800 °C, only calcium aluminate cement preserved its integrity, while ordinary Portland cement revealed a fragmentation status. Despite the compressive strength decrease in calcium aluminate paste at 600 °C and 800 °C, as a result of porosity increase, the properties were maintained after 10 thermal cycles. However, thermal conductivity in calcium aluminate paste was reduced nearly 50% after the first cycle at temperatures higher than 200 °C.

In the recent years, some experimental forms of housing (cohousing and social housing) have developed in Italy, which also take on the features of real energy communities. These initiatives have been planned and implemented thanks to the active participation and investments of the people involved in the project. Their primary aim is to implement new form of shared housing, but by adopting renewable generation systems and sharing both energy production and consumption, they are contributing to foster the energy transition process. In this research, we studied the management of the energy resource and the social interactions among the cohousers. Moreover, we analysed the social impacts on the surrounding territory in order to know as they can widespread the clean energy technologies and social innovation processes. To do this, we compared two experiences of collaborative housing: the first one, active since some years in Northern Italy, is a bottom-up initiative set up by the voluntary action of some families and individuals. Its goal is to share common spaces and activities, but also to produce and use renewable energy with a view to economic and environmental sustainability. The second one is a social cohousing, established in Messina (Southern Italy) and implemented by the Fondazione di Comunità di Messina. The project involves people who live in socio-economic difficulties. Through the ESCO Solidarity & Energy, the Fondazione has designed and applied energy systems to allow the tenants to become prosumers and prosumagers.

In recent years, the biomass as a renewable feedstock has been gaining utmost importance in order to meet the global need for fuels and chemicals from sustainability perspectives [1,2]. Principal components of biomass are cellulosic and triglycerides derivatives. The triglyceride part is principally used to obtain biodiesel and liquid alkanes, as alternative fuels [3]. Biomass derived from the lignocellulose part is rich in carbohydrates and furan derivatives, and the presence of oxygen in their structure makes them suitable for further utilization to obtain added-value products. As concern the sustainability of the chemical processes, efforts are being made to turn them into "green" processes, working on the procedures (favorable reagent ratio, catalyst amount and green solvents) and exploiting heterogeneous catalysis. The use of solid catalyst is indeed very favorable from a sustainable point of view, due to its simple separation, regeneration and recycling of the material [4,5]. This implies a high efficiency of the catalysts accompanied by a decrease in the processing cost. This presentation will focus on different types of functionalized silica or titania based materials applied to the biomass exploitation, both to the synthesis of biodiesel and its additives and for the obtainment of added-value products such as GVL, diols or HMF. Biomass can use also for the production of new materials applied in the abatement of aqueous pollutants