• Energy Research
• Geosciences close

Shales are the most abundant class of sedimentary rocks, distinguished by being very fine-grained, clayey, and compressible. Their physical and chemical properties are important in widely different enterprises such as civil engineering, ceramics, and petroleum exploration. One characteristic, which is studied here, is a systematic reduction of porosity with depth of burial. This is due increases in grain-to-grain stress and temperature. Vertical stress in sediments is given by the overburden less the pore fluid pressure, σ, divided by the fraction of the horizontal area which is the supporting matrix, (1−φ), where φ is the porosity. It is proposed that the fractional reduction of this ratio, Λ, with time is given by the product of φ4m/3, (1−φ)4n/3, and one or more Arrhenius functions Aexp(−E/RT) with m and n close to 1. This proposal is tested for shale sections in six wells from around the world for which porosity-depth data are available. Good agreement is obtained above 30–40 °C and fractional porosities less than 0.5. Single activation energies for each well are obtained in the range 15–33 kJ/mole, close to the approximate pressure solution of quartz, 24 kJ/mol. Values of m and n are in the range 1 to 0.8, indicating nearly fractal water-wet pore-to-matrix interfaces at pressure solution locations. Results are independent of over- or under-pressure of pore water. This model attempts to explain shale compaction quantitatively. For the petoleum industry, given porosity-depth data for uneroded sections and accurate activation energy, E, paleo-geothermal-gradient can be inferred and from that organic maturity, indicating better drilling prospects.

Niobium and tantalum are mainly produced from columbite–tantalite ores, and 60% of their production is nowadays located in the Democratic Republic of Congo and Rwanda. The concentration of supply, the scarcity, the wide range of use in all electronic devices, and the expected future demand boosted by the clean and digital transition means that Nb and Ta have high supply risks. In this context, extraction from rich Ta and Nb tailings from abandoned mines could partly offset such risks. This study analyzes the energy cost that the reprocessing of both elements from tailings would have. To that end, we simulate with HSC Chemistry software the different processes needed to beneficiate and refine both metals from zinc tailings as a function of Nb and Ta concentration. At current energy and metal prices, tantalum recovery from rich Ta-Nb tailings would be cost-effective if ore-handling costs were allocated to a paying metal. By way of contrast, niobium recovery would not be favored unless market prices increase.

The volcanic-hydrothermal geo-diversity of the Basse-Terre Island of Guadeloupe archipelago (Eastern Caribbean, France) is a major asset of the Caribbean bio-geoheritage. In this paper, we use Guadeloupe as a representative of many small island developing states (SIDS), to show that the volcanic-hydrothermal geodiversity is a major resource and strategic thread for resilience and sustainability. These latter are related to the specific richness of Guadeloupe’s volcanic-geothermal diversity, which is de facto inalienable even in the wake of climate change and natural risks that are responsible for this diversity, i.e., volcanic eruptions. We propose the interweaving the specificity of volcanic-geothermal diversity into planning initiatives for resilience and sustainability. Among these initiatives research and development programs focused on the knowledge of geodiversity, biodiversity and related resources and risks are central for the long-term management of the water resource, lato sensu. Such a management should include a comprehensive scientific observatory for the characterization, exploration, and sustainable exploitation of the volcanic-hydrothermal geodiversity alongside planning for and mitigating geophysical risks related to sudden volcanic-induced phenomena and long-term systemic drifts due to climate change. The results of this exercise for Guadeloupe could typify innovative paths for similar SIDS around their own volcanic-hydrothermal geodiversity.

This article reviews the current status of tropical glaciers in the South American Andes, East Africa, and Australasia by shedding light on past, present, and future glacier coverage in the tropics, the influence of global and regional climates on the tropical glaciers, the regional importance of these glaciers, and challenges of ongoing glacier recessions. While tropical glaciers have predominantly receded since the Little Ice Age, the rate of shrinkage has accelerated since the late 1970s as a result of climate changes. As a result, socio-ecological implications occur around ecosystem health, natural hazards, freshwater resources, agriculture, hydropower, mining, human and animal health, traditions and spirituality, and peace.

Previous land surface modeling efforts to predict and understand water budgets in the U.S. Southeast for soil water management have struggled to characterize parts of the region due to an extensive presence of fragipan soils for which current calibration approaches are not adept at handling. This study presents a physically based approach for calibrating fragipan-dominated regions based on the “effective” soil moisture capacity concept, which accounts for the dynamic perched saturation zone effects created by the low hydraulic capacities of the fragipan layers. The approach is applied to the Variable Infiltration Capacity model to develop a hydrologic model of the Obion River Watershed (ORW), TN, which has extensive fragipan coverage. Model calibration was performed using observed streamflow data, as well as evapotranspiration and soil moisture data, to ensure correct partitioning of surface and subsurface fluxes. Estimated Nash-Sutcliffe coefficients for the various sub-drainage areas within ORW were all greater than 0.65, indicating good model performance. The model results suggest that ORW has a high responsivity and high resilience. Despite forecasted temperature increases, the simulation results suggest that water budget trends in the ORW are unlikely to change significantly in the near future up to 2050 due to sufficient precipitation amounts.

Climate change is expected to reduce water security in arid mountain regions around the world. Vulnerable water supplies in semi-arid zones, such as the Dry Andes, are projected to be further stressed through changes in air temperature, precipitation patterns, sublimation, and evapotranspiration. Together with glacier recession this will negatively impact water availability. While glacier hydrology has been the focus of scientific research for a long time, relatively little is known about the hydrology of mountain permafrost. In contrast to glaciers, where ice is at the surface and directly affected by atmospheric conditions, the behaviour of permafrost and ground ice is more complex, as other factors, such as variable surficial sediments, vegetation cover, or shallow groundwater flow, influence heat transfer and time scales over which changes occur. The effects of permafrost on water flow paths have been studied in lowland areas, with limited research in the mountains. An understanding of how permafrost degradation and associated melt of ground ice (where present) contribute to streamflow in mountain regions is still lacking. Mountain permafrost, particularly rock glaciers, is often conceptualized as a (frozen) water reservoir; however, rates of permafrost ground ice melt and the contribution to water budgets are rarely considered. Additionally, ground ice and permafrost are not directly visible at the surface; hence, uncertainties related to their three-dimensional extent are orders of magnitude higher than those for glaciers. Ground ice volume within permafrost must always be approximated, further complicating estimations of its response to climate change. This review summarizes current understanding of mountain permafrost hydrology, discusses challenges and limitations, and provides suggestions for areas of future research, using the Dry Andes as a basis.

In this paper, we describe recent studies for the geophysical and geomechanical characterization of soils in Hispaniola (Greater Antilles), an island threatened by the eventual rupture of major seismogenic fault systems. The investigations were performed for four different cities settled on complex geological formations in Haiti (Cap-Haïtien, Port-au-Prince) and the Dominican Republic (Santo Domingo, Santiago de los Caballeros). We present the complete methodology we implemented for mapping zones of homogeneous seismic response and for microzonation studies, but each main stage of investigation is described as it was conducted in one or two cities. Therefore, first we present our site-characterization technique applied to Santo Domingo and Santiago de los Caballeros, which is based on geotechnical data, geophysical multichannel analysis of surface waves, and ambient-noise recordings. Then we present the site-response analysis through numerical analysis with nonlinear soil models that we performed for the city of Cap-Haïtien. Finally, we describe the amplification factors for site-specific response spectra that we derived for the microzonation of Port-au-Prince. We argue for the implementation of a multidisciplinary approach built upon complementary field geological, geophysical, and geotechnical data rather than solely depending on geophysical measures for the characterization of VS30. In addition, we explore the compatibility of the soil classes recommended by the International Building Code (IBC) in the context of local seismic amplification.

Changes induced by climate change in salt weathering of built cultural heritage are estimated in different ways, but generally as a function of phase changes phenomena of two common salts, sodium chloride and sodium sulfate. We propose to use not only these salts, but also other common salts as calcium sulfate, or mixtures of chlorides, sulfates, and nitrates of sodium, calcium, magnesium, and potassium. Comparisons between the predicted changes in salt weathering obtained for single salts and for combinations of different salts are presented. We applied the proposed methodology to 41 locations uniformly distributed in France. The results show that estimations of actual and evolution of future weathering depend on the selected salt or combination of salts. According to our results, when using a combination of different salts, weathering evolution is less favorable (more damage in the future) than when using a single salt.