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Abstract Microorganisms used in syngas fermentation require nutrients to grow and convert syngas (CO, H2 and CO2) into various products. Many of the essential nutrients can be provided by biochar. Poultry litter biochar (PLBC) contains minerals and trace metals and has a high pH buffering capacity, making it suitable as a nutrient supplement. The effects of PLBC loadings from 1 to 20 g L−1 on syngas fermentation were determined in 250 ml bottle assays. Results showed that 10 and 20 g L−1 PLBC significantly increased ethanol production compared to standard yeast extract (YE) medium. Fermentations in a 3L continuous stirred tank reactor (CSTR) with 10 g L−1 PLBC with and without 4-morpholineethanesulfonic acid (MES) showed 64% and 36% more ethanol production, respectively, than standard medium. The acetic acid accumulated at the beginning of fermentation was completely converted to ethanol in all media tested in the CSTR. These results demonstrate the feasibility of using PLBC medium without costly MES in the CSTR to enhance ethanol production from syngas for potential use at commercial scale.

Abstract District heating (DH) enables the utilisation and distribution of heating from sources unfeasible for stand-alone applications and combined with cogeneration of heat and power (CHP), has been the cornerstone of Denmark’s realisation of a steady national primary energy supply over the last four decades. However, progressively more energy-efficient houses and a steadily improving heat pump (HP) performance for individual dwellings is straining the competitive advantage of the CHP–DH combination as DH grid losses are growing in relative terms due to decreasing heating demands of buildings and relatively high DH supply temperatures. A main driver for the DH water temperature is the requirements for domestic hot water (DHW) production. This article investigates two alternatives for DHW supply: (a) DH based on central HPs combined with a heat exchanger, and (b) a combination of DH based on central HPs and a small booster HP using DH water as low-temperature source for DHW production. The analyses are conducted using the energyPRO simulation model and are conducted with hourly varying factors; heating demands, DH grid losses, HP coefficient of performance (COP) and spot market prices in order to be able to analyse the relative performance of the two options and their performance over the year. Results are also compared to individual boilers and individual HPs. The results indicate that applying booster HPs enables the DH system to operate at substantially lower temperature levels, improving the COP of central DH HPs while simultaneously lowering DH grid losses significantly. Thus, DH performance is increased significantly. Additionally, performance for the DH HP with booster combination is considerably better than individual boiler or HP solutions.

Abstract This paper presents a novel multi-time-stage input–output-based modeling framework for simulating the dynamics of bioenergy supply chains. One of the key assumptions used in the model is that the production level at the next time-stage of each segment of the energy supply chain adjusts to the output surplus or deficit relative to targets at the current time period. Furthermore, unlike conventional input–output models, the technology matrix in this approach need not be square, and thus can include coefficients denoting flows of environmental goods, such as natural resources or pollutants. Introducing a feedback control term enables the system to regulate the dynamics, thus extending the model further. This is an important feature since the uncontrolled dynamic model exhibits oscillatory or unstable behavior under some conditions; in principle, the control term allows such undesirable characteristics to be suppressed. Numerical simulations of a simple, two-sector case study are given to illustrate dynamic behavior under different scenarios. Although the case study uses only a hypothetical system, preliminary comparisons are made between the simulation results and some broad trends seen in real bioenergy systems. Finally, some of the main policy implications of the model are discussed based on the general dynamic characteristics seen in the case study. In particular, insights from control theory can be used to develop policy interventions to impart desirable dynamic characteristics to nascent or emerging biofuel supply chains. These interventions can be used to guide the growth of bioenergy supplies along final demand trajectories with minimal fluctuation and no instability.

Abstract Economically harvesting energy from a microbial fuel cell (MFC), increasing its electrical power production, and developing its role as a practical energy supply, needs a low-cost and high-performance design of the MFC compartments. According to this strategy, a novel monolithic membrane electrode assembly (MEA) was fabricated and evaluated as an air–cathode in a single-chamber MFC (SCMFC). The MEA was made of bacterial cellulose (BC), conductive multi-walled carbon nanotubes (CNT), and nano-zycosil (NZ). BC, as a nano-celluloses with oxygen barrier property, can maintain anaerobic conditions for the anode compartment. Binder-less CNT coating on BC avoids costly binders such as poly-tetra fluoro ethylene (PTFE) and Nafion and decreases the MEA charge transfer resistance. NZ, as a very cheap modifier, not only prevents the anolyte leakage but also provides more MEA’s active sites for the oxygen reduction reaction (ORR). The electrochemical performance of the MEA was compared to a PTFE- based gas diffusion electrode (GDE) in the SCMFC. The MEA cell provided a pulse power density of 1790 mW/m2, roughly twice as high as the pulse power density of GDE (920 mW/m2). SCMFC’s internal resistance decreased from 1.84 KΩ (with GDE) to 0.8 KΩ (with MEA). Also, the cell’s columbic efficiency increased from 4.2% (with GDE) to11.7% (with MEA). Additionally, the capacitance of the MEA (65 mF) was much higher than the value for GDE (0.73 mF). Thus, the MEA compared to the GDE showed higher performance in the SCMFC for electricity generation and wastewater treatment at a lower cost.

Abstract In an effort to minimise electricity consumption and greenhouse gases emissions, the heating, ventilation and air-conditioning sector has focused its attention on developing alternative solutions to electrically-driven vapour-compression cooling. Liquid desiccant air-conditioning systems represent an energy-efficient and more environmentally friendly alternative technology for dehumidification and cooling, particularly in those cases with high latent loads to maintain indoor air quality and comfort conditions. This technology is considered particularly efficient in hot and humid climates. As a matter of fact, the choice of the desiccant solution influences the overall performance of the system. The current paper reviews the working principle of liquid desiccant systems, focusing on the thermodynamic properties of the desiccant solutions and describes an evaluation of the reference thermodynamic properties of different desiccant solutions to identify which thermodynamic, physical, transport property influences the liquid desiccant process and to what extent. The comparison of these thermodynamic properties for the commonly used desiccants is conducted to estimate which fluid could perform most favourably in the system. The economic factors and the effect of different applications and climatic conditions on the system performance are also described. The paper is intended to be the first step in the evaluation of alternative desiccant fluids able to overcome the problems related to the use of the common desiccant solutions, such as crystallization and corrosion to metals. Ionic liquids seem a promising alternative working fluid in liquid desiccant air-conditioning systems and their characteristics and cost are discussed.

Abstract Urban planners, local authorities, and energy policymakers often develop strategic sustainable energy plans for the urban building stock in order to minimize overall energy consumption and emissions. Planning at such scales could be informed by building stock modeling using existing building data and Geographic Information System-based mapping. However, implementing these processes involves several issues, namely, data availability, data inconsistency, data scalability, data integration, geocoding, and data privacy. This research addresses the aforementioned information challenges by proposing a generalized integrated methodology that implements bottom-up, data-driven, and spatial modeling approaches for multi-scale Geographic Information System mapping of building energy modeling. This study uses the Irish building stock to map building energy performance at multiple scales. The generalized data-driven methodology uses approximately 650,000 Irish Energy Performance Certificates buildings data to predict more than 2 million buildings’ energy performance. In this case, the approach delivers a prediction accuracy of 88% using deep learning algorithms. These prediction results are then used for spatial modeling at multiple scales from the individual building level to a national level. Furthermore, these maps are coupled with available spatial resources (social, economic, or environmental data) for energy planning, analysis, and support decision-making. The modeling results identify clusters of buildings that have a significant potential for energy savings within any specific region. Geographic Information System-based modeling aids stakeholders in identifying priority areas for implementing energy efficiency measures. Furthermore, the stakeholders could target local communities for retrofit campaigns, which would enhance the implementation of sustainable energy policy decisions.

Over the past three decades, Swedish energy policy has evolved in three major stages—oil reduction, phase-out of nuclear energy, renewable energy—each with a different focus. Since 1977, Swedish law has required municipalities to develop an energy plan that addresses the supply, distribution, and use of energy. Whether such plans have contributed to the development of local energy-systems has been a subject for debate. This paper is based on a study of 12 municipal energy-plans that attempted to control and develop local energy-systems in southern Sweden. The analysis examines how municipalities promote oil reduction, efficient energy use, and the use of renewable energy. The plans varied in planning processes, contents, and level of ambition. The results of the study show that the contents of the plans follow the national energy-policies with respect to reduction of oil use, improved energy efficiency, and increased use of renewable energy.

Abstract Advanced combustion engine (ACE) research is typically carried out on single-cylinder research engines. These engines are designed to tightly control fueling and conditions at intake valve closure (IVC) and to precisely measure in-cylinder conditions and emissions. However, to be able to measure and control engine operation so precisely, these research engines typically do not feature intake and exhaust tracts that resemble those in production engines, specifically in regards to turbomachinery, heat exchangers, and exhaust gas recirculation (EGR) systems. For this reason, these research engines are effective for understanding in-cylinder combustion parameters such as heat release rate, burn duration, combustion efficiency, pollutant formation, and exhaust valve opening (EVO) conditions. This paper applies high fidelity simulations to determine the feasibility of achieving a chosen single cylinder engine operating point on a production type homogeneous charge compression ignition (HCCI) engine, using a partial fuel stratification (PFS) strategy. To accomplish this, a Converge 3 dimensional (3D) – computational fluid dynamics (CFD) model of the experimental combustion chamber and intake and exhaust runners was created to simulate the experimental engine. This model was used to simulate an operating point achieved experimentally, as well as to determine the sensitivity of the operating point to variations in intake pressure, intake temperature, injection timing, injected mass, and EGR fraction. The results from these simulations were fed into a 1-dimensional engine simulation created in AVL Boost, featuring production-type intake and exhaust systems, including turbomachinery and heat exchangers necessary to create the required IVC conditions. This full engine simulation was used to assess the cycle efficiency of the engine at the experimental operating condition, and to assess whether changes to this operating point in intake temperature, intake pressure, direct injection timing, or fueling are beneficial to the cycle efficiency and engine-out emissions. In addition, the sensitivity of promising engine operating points to injection timing and injection mass are determined to evaluate the potential stability of these operating points.