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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Baldwin, John Derouet Couper;

    The need for an improved control strategy for the operation of a wind-powered refrigeration system for the storage of apples was investigated. The results are applicable to other systems which employ intermittently available power sources, battery and thermal storage, and an auxiliary, direct current power supply. Tests were conducted on the wind-powered refrigeration system at the Virginia Polytechnic Institute and State University Horticulture Research Farm in Blacksburg, Virginia. Tests were conducted on the individual components of the system. In situ windmill performance were also conducted. The results of these tests have been presented. An improved control strategy was developed to improve the utilization of available wind energy and to reduce the need for electrical energy from an external source while maintaining an adequate apple storage environment. Ph. D.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ VTechWorksarrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    VTechWorks
    Doctoral thesis . 1979
    Data sources: VTechWorks
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ VTechWorksarrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      VTechWorks
      Doctoral thesis . 1979
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Baldwin, John Derouet Couper;

    The need for an improved control strategy for the operation of a wind-powered refrigeration system for the storage of apples was investigated. The results are applicable to other systems which employ intermittently available power sources, battery and thermal storage, and an auxiliary, direct current power supply. Tests were conducted on the wind-powered refrigeration system at the Virginia Polytechnic Institute and State University Horticulture Research Farm in Blacksburg, Virginia. Tests were conducted on the individual components of the system. In situ windmill performance were also conducted. The results of these tests have been presented. An improved control strategy was developed to improve the utilization of available wind energy and to reduce the need for electrical energy from an external source while maintaining an adequate apple storage environment. Ph. D.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ VTechWorksarrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    VTechWorks
    Doctoral thesis . 1979
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ VTechWorksarrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      Doctoral thesis . 1979
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  • Authors: Ding, Yang; Wang, Chunhua; Pei, Lang; Mao, Qinan; +7 Authors

    Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions, Mn4+ ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode (W-LED), plant cultivation LED, and temperature thermometer. Up to now, Mn4+ has been widely introduced into the lattices of various inorganic hosts for brightly red-emitting phosphors. However, how to correlate the structure-activity relationship between host framework, luminescence property, and photoelectric device is urgently demanded. In this review, we thoroughly summarize the recent advances of Mn4+ doped phosphors. Meanwhile, several strategies like co-doping and defect passivation for improving Mn4+ emission are also discussed. Most importantly, the relationship between the protocols for tailoring the structures of Mn4+ doped phosphors, increased luminescence performance, and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated. Finally, the challenges and perspectives of Mn4+ doped phosphors for practical applications are anticipated. We cordially anticipate that this review can deliver a deep comprehension of not only Mn4+ luminescence mechanism but also the crystal structure tailoring strategy of phosphors, so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.

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  • Authors: Ding, Yang; Wang, Chunhua; Pei, Lang; Mao, Qinan; +7 Authors

    Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions, Mn4+ ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode (W-LED), plant cultivation LED, and temperature thermometer. Up to now, Mn4+ has been widely introduced into the lattices of various inorganic hosts for brightly red-emitting phosphors. However, how to correlate the structure-activity relationship between host framework, luminescence property, and photoelectric device is urgently demanded. In this review, we thoroughly summarize the recent advances of Mn4+ doped phosphors. Meanwhile, several strategies like co-doping and defect passivation for improving Mn4+ emission are also discussed. Most importantly, the relationship between the protocols for tailoring the structures of Mn4+ doped phosphors, increased luminescence performance, and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated. Finally, the challenges and perspectives of Mn4+ doped phosphors for practical applications are anticipated. We cordially anticipate that this review can deliver a deep comprehension of not only Mn4+ luminescence mechanism but also the crystal structure tailoring strategy of phosphors, so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.

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  • Authors: M.C. Lobo; Antonio Plaza; I. Bautista; Pedro V. Mauri; +1 Authors

    The objective of the study was to evaluate the effect of two types of treated sewage sludge as soil amendment, composted with pruning wastes (CP) and thermally dried (ST) on the production of ten woody perennials species for energy purposes. The species used were: Paulownia tomentosa (princess tree), Populus x euramericana (Canadian poplar), Ulmus minor (field elm, tree clones), Ulmus laevis (European white elm), Prunus x amygdalo-persica (adafuel), Tamarix gallica (tamarisk), Salix alba (white willow) and Platanus x hispanica (plane tree). The increase in plant growth three years after amendment application is evaluated with the aim to analyze the long term effect of the treated sewage sludges application on plant production. In general, the plants developed in the soils treated with ST sludge present the highest values of growth (diameter, height and width), which can be due to the faster supply of nitrogen from this material. However, the growth rate was higher in the CP treatment for the most of the species due to a continuous release of nutrients from the CP degradation. In this sense, the effect of CP treatment on plant production would be observed at the longer time than the ST one. Proceedings of the 26th European Biomass Conference and Exhibition, 14-17 May 2018, Copenhagen, Denmark, pp. 369-373

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  • Authors: M.C. Lobo; Antonio Plaza; I. Bautista; Pedro V. Mauri; +1 Authors

    The objective of the study was to evaluate the effect of two types of treated sewage sludge as soil amendment, composted with pruning wastes (CP) and thermally dried (ST) on the production of ten woody perennials species for energy purposes. The species used were: Paulownia tomentosa (princess tree), Populus x euramericana (Canadian poplar), Ulmus minor (field elm, tree clones), Ulmus laevis (European white elm), Prunus x amygdalo-persica (adafuel), Tamarix gallica (tamarisk), Salix alba (white willow) and Platanus x hispanica (plane tree). The increase in plant growth three years after amendment application is evaluated with the aim to analyze the long term effect of the treated sewage sludges application on plant production. In general, the plants developed in the soils treated with ST sludge present the highest values of growth (diameter, height and width), which can be due to the faster supply of nitrogen from this material. However, the growth rate was higher in the CP treatment for the most of the species due to a continuous release of nutrients from the CP degradation. In this sense, the effect of CP treatment on plant production would be observed at the longer time than the ST one. Proceedings of the 26th European Biomass Conference and Exhibition, 14-17 May 2018, Copenhagen, Denmark, pp. 369-373

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  • Authors: M.L. Savouré; A. Besnard; F. Labalette; Brigitte Chabbert; +6 Authors

    The climatic, energetic and political context promotes the development of bioenergies. However we have a lack of knowledge to find out the best energy crops, depending on the soil, the climate and the end­use. This work aimed at studying the adaptation and the biomass and biofuel yield, of several energy crops grown in France in different soil and climate conditions. The biomass yields were very variable between the different experimental sites and no differences were observed on the median biomass yield between crops. Moreover, there was no evidence of a highly productive crop in all the conditions of soil and climate. Because of little differences of the lower heating value between crops, no differences were observed on the primary energy yield. The ethanol yield per hectare was higher for miscanthus, switchgrass and fiber sorghum because of higher cellulose content in these crops. The nitrogen removed at harvest by miscanthus and switchgrass were significantly lower than the other crops witch could lead to reduced fertilizer­N requirements. Further research are needed to clarify the effect of limiting factors on the biomass yield of the different energy crops and to consider other parameters such as the environmental impacts to give rules to choose the most suitable crop in a given region. Proceedings of the 18th European Biomass Conference and Exhibition, 3-7 May 2010, Lyon, France, pp. 269-272

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  • Authors: M.L. Savouré; A. Besnard; F. Labalette; Brigitte Chabbert; +6 Authors

    The climatic, energetic and political context promotes the development of bioenergies. However we have a lack of knowledge to find out the best energy crops, depending on the soil, the climate and the end­use. This work aimed at studying the adaptation and the biomass and biofuel yield, of several energy crops grown in France in different soil and climate conditions. The biomass yields were very variable between the different experimental sites and no differences were observed on the median biomass yield between crops. Moreover, there was no evidence of a highly productive crop in all the conditions of soil and climate. Because of little differences of the lower heating value between crops, no differences were observed on the primary energy yield. The ethanol yield per hectare was higher for miscanthus, switchgrass and fiber sorghum because of higher cellulose content in these crops. The nitrogen removed at harvest by miscanthus and switchgrass were significantly lower than the other crops witch could lead to reduced fertilizer­N requirements. Further research are needed to clarify the effect of limiting factors on the biomass yield of the different energy crops and to consider other parameters such as the environmental impacts to give rules to choose the most suitable crop in a given region. Proceedings of the 18th European Biomass Conference and Exhibition, 3-7 May 2010, Lyon, France, pp. 269-272

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: EMIL DINGA; CORNEL IONESCU; CAMELIA BALTARETU;

    The paper aims to achieve a definition of the concept of sustainability and of sustainable system from a logical perspective. In this respect, it introduces and defines (through the sufficiency predicates) the concept of logically vivid system and, on this basis, are discussed a logical concept of sustainability, respectively of a sustainable system in general are discussed and built up. Sustainability is considered in light of identity preservation of the systems, as a static anchor, on one hand, and of the concept of automatic stabilizers as a dynamic anchor on the other side. Finally, the two sufficiency conditions for a logically vivid system be sustainable are identified: the presence of hyper-cycles, respectively the absence of positive feed-back.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Challenges of the Kn...arrow_drop_down
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: EMIL DINGA; CORNEL IONESCU; CAMELIA BALTARETU;

    The paper aims to achieve a definition of the concept of sustainability and of sustainable system from a logical perspective. In this respect, it introduces and defines (through the sufficiency predicates) the concept of logically vivid system and, on this basis, are discussed a logical concept of sustainability, respectively of a sustainable system in general are discussed and built up. Sustainability is considered in light of identity preservation of the systems, as a static anchor, on one hand, and of the concept of automatic stabilizers as a dynamic anchor on the other side. Finally, the two sufficiency conditions for a logically vivid system be sustainable are identified: the presence of hyper-cycles, respectively the absence of positive feed-back.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Challenges of the Kn...arrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Challenges of the Kn...arrow_drop_down
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/

    Optimization of all numerical codes ported in the infrastructure and used for supercapacitors, PV and batteries. The scope of deliverable D3.2 is to report the new advances in the field of materials for energy that comes from the search of new methodologies and models that could be more efficient on the new generation of computer hardware for exascale. In this respect, deliverable D3.2 is a transversal deliverable that report the new advances related to activities described in task T3.2, T3.3 and T3.4. H2020

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ ZENODOarrow_drop_down
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    Other literature type . 2017
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    Optimization of all numerical codes ported in the infrastructure and used for supercapacitors, PV and batteries. The scope of deliverable D3.2 is to report the new advances in the field of materials for energy that comes from the search of new methodologies and models that could be more efficient on the new generation of computer hardware for exascale. In this respect, deliverable D3.2 is a transversal deliverable that report the new advances related to activities described in task T3.2, T3.3 and T3.4. H2020

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ ZENODOarrow_drop_down
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  • Authors: Ziman, H.; Hillier, G.; Donegan, S.;

    There is increasing commercial interest in the pyrolysis of biomass and wastes to form pyrolysis oil, a dark liquid that is sometimes colloquially referred to as bio-crude oil. However, it is not compatible with crude oil or the refining processes used to produce hydrocarbons (including fuels) and petrochemicals. Currently pyrolysis oils are mostly used as a low grade fuel to generate heat and power.Current processes for the production of biofuels for blending into transport fuels have focused on the use of plant oils or starches as raw materials.These have the potential to compete with food for agricultural capacity. Some technologies have used wastes of varying types ranging from mixed wastes through to plastics and tyres.The development of processes that use lignocellulosic biomass (e.g. wood, straw) would enable waste biomass and forestry materials to be used in this way. Such sources of biomass can be used to produce pyrolysis oil.Laboratory work has shown that pyrolysis oils produced from a range of feedstocks have the potential to be upgraded into vehicle fuels.There is also the potential to extract commercially useful materials from pyrolysis oils providing a renewable alternative to petrochemicals

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  • Authors: Ziman, H.; Hillier, G.; Donegan, S.;

    There is increasing commercial interest in the pyrolysis of biomass and wastes to form pyrolysis oil, a dark liquid that is sometimes colloquially referred to as bio-crude oil. However, it is not compatible with crude oil or the refining processes used to produce hydrocarbons (including fuels) and petrochemicals. Currently pyrolysis oils are mostly used as a low grade fuel to generate heat and power.Current processes for the production of biofuels for blending into transport fuels have focused on the use of plant oils or starches as raw materials.These have the potential to compete with food for agricultural capacity. Some technologies have used wastes of varying types ranging from mixed wastes through to plastics and tyres.The development of processes that use lignocellulosic biomass (e.g. wood, straw) would enable waste biomass and forestry materials to be used in this way. Such sources of biomass can be used to produce pyrolysis oil.Laboratory work has shown that pyrolysis oils produced from a range of feedstocks have the potential to be upgraded into vehicle fuels.There is also the potential to extract commercially useful materials from pyrolysis oils providing a renewable alternative to petrochemicals

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  • Authors: Ekaterina Sermyagina; Esa Vakkilainen; Marcelo Cardoso; F.J. Borges Gomes; +2 Authors

    Renewable energy (mainly hydroelectric power plants) has a significant share in energy generation sector in Brazil. Recent climate changes, however, resulted in lower rainfall indexes and acted as a driving factor for the increasing interest in biomass applications. Therefore, having the land available for forest planting and a critical need for a new source of renewable energy, Brazil has the potential to further increase the energy generation from biomass. Due to the diverse nature of biomass materials, their properties range widely and exhibit different behaviors in thermal processes. To choose the most efficient way for production of energy, it is required to know the energy potential of the biomass samples. This study focuses on the physical-chemical characterization of nine lignocellulosic biomasses widely available in Brazil: five types of eucalyptus wood chips, sugarcane bagasse, elephant grass, bamboo, and coconut husk. Some characteristics regarded as important to thermochemical conversion are evaluated, such as: biomass chemical composition - polisacharides (glucans, xylans, galactans, mannans, arabinans), total uronic acids, acetyl groups, lignin, chloride, elementary analysis of the ash (Cu, Fe, Ca, Mn, Mg and K), silica and extractives, heating value, ultimate and proximate analyses. Moreover, the studied samples were investigated by thermogravimetric analysis (TG and DTG). The evaluation of these characteristics is important for understanding the processes of the thermochemical conversion of biomasses. Proceedings of the 23rd European Biomass Conference and Exhibition, 1-4 June 2015, Vienna, Austria, pp. 294-298

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  • Authors: Ekaterina Sermyagina; Esa Vakkilainen; Marcelo Cardoso; F.J. Borges Gomes; +2 Authors

    Renewable energy (mainly hydroelectric power plants) has a significant share in energy generation sector in Brazil. Recent climate changes, however, resulted in lower rainfall indexes and acted as a driving factor for the increasing interest in biomass applications. Therefore, having the land available for forest planting and a critical need for a new source of renewable energy, Brazil has the potential to further increase the energy generation from biomass. Due to the diverse nature of biomass materials, their properties range widely and exhibit different behaviors in thermal processes. To choose the most efficient way for production of energy, it is required to know the energy potential of the biomass samples. This study focuses on the physical-chemical characterization of nine lignocellulosic biomasses widely available in Brazil: five types of eucalyptus wood chips, sugarcane bagasse, elephant grass, bamboo, and coconut husk. Some characteristics regarded as important to thermochemical conversion are evaluated, such as: biomass chemical composition - polisacharides (glucans, xylans, galactans, mannans, arabinans), total uronic acids, acetyl groups, lignin, chloride, elementary analysis of the ash (Cu, Fe, Ca, Mn, Mg and K), silica and extractives, heating value, ultimate and proximate analyses. Moreover, the studied samples were investigated by thermogravimetric analysis (TG and DTG). The evaluation of these characteristics is important for understanding the processes of the thermochemical conversion of biomasses. Proceedings of the 23rd European Biomass Conference and Exhibition, 1-4 June 2015, Vienna, Austria, pp. 294-298

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  • Authors: Floriana Craciun (1); Francesco Cordero (1); Carmen Galassi (2);

    Dielectric and anelastic spectroscopies are complementary techniques and their combination allows valuable information to be obtained in the field of multifunctional materials. Whereas the dielectric spectroscopy measures the dielectric susceptibility ?(?,T) and it is sensitive to fluctuations of electric dipoles, the anelastic spectroscopy measures the elastic compliance or elastic susceptibility s(?,T) and it is sensitive to fluctuations of elastic dipoles. Both susceptibilities are complex, their immaginary part being due to the delayed response of the mobile defects coupled to the electric field/stress. The great advantage of using a combination of both techniques is that the anelastic measurements are insensitive to free charges, therefore it is possible to measure the dynamics of ions also in the presence of free charges. Two main types of investigations have been pursued by the combination of these techniques: the study of structural phase transitions and the study of microscopic mechanisms associated with the presence of defects, both important for the knowledge and development of multifunctional materials. We have applied this approach for different functional materials with perovskite framework: multiferroic, ferroelectric and relaxor ferroelectric ceramics, and organic-inorganic perovskite photovoltaics. Thanks to the combination of the two spectroscopies, it has been possible to probe more accurately the structural transitions involving the antiferrodisortive tilt modes of the octahedra in PZT [1] and NBT-BT [2]. It was also possible to evidence incipient phase separation in lead titanate-based multiferroics [3]. Moreover, since the elastic response is insensitive to free charges, it has been used to probe the piezoelectric response even in unpoled ceramics [4] and for the study of coexisting ferroelectric and metallic states [5]. The combination of the two techniques allowed also new features to be revealed on the reorientation dynamics of the organic molecules in MAPbI3 photovoltaic organic-inorganic perovskites and the hindrance of their ferroelectric order by coupling with the tilt modes [6]. 1. F. Cordero, F. Trequattrini, F. Craciun, C. Galassi, Phys. Rev. B, 87 (2013) 094108 2. F. Cordero, F. Craciun, F. Trequattrini, et al., Phys. Rev. B, 81 (2010) 144124 3. F. Craciun, F. Cordero, B. Vasile, et al., Phys. Chem. Chem. Phys., 20 (2018) 14652 4. F. Cordero, F. Craciun, F. Trequattrini, C. Galassi, Phys. Rev. B, 93 (2016) 174111 5. F. Cordero, F. Trequattrini, F. Craciun, et al., Phys. Rev. B, 99 (2019) 064106 6. F. Cordero, F. Craciun, F. Trequattrini, et al., J. Phys. Chem. Lett., 9 (2018) 4401

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  • Authors: Floriana Craciun (1); Francesco Cordero (1); Carmen Galassi (2);

    Dielectric and anelastic spectroscopies are complementary techniques and their combination allows valuable information to be obtained in the field of multifunctional materials. Whereas the dielectric spectroscopy measures the dielectric susceptibility ?(?,T) and it is sensitive to fluctuations of electric dipoles, the anelastic spectroscopy measures the elastic compliance or elastic susceptibility s(?,T) and it is sensitive to fluctuations of elastic dipoles. Both susceptibilities are complex, their immaginary part being due to the delayed response of the mobile defects coupled to the electric field/stress. The great advantage of using a combination of both techniques is that the anelastic measurements are insensitive to free charges, therefore it is possible to measure the dynamics of ions also in the presence of free charges. Two main types of investigations have been pursued by the combination of these techniques: the study of structural phase transitions and the study of microscopic mechanisms associated with the presence of defects, both important for the knowledge and development of multifunctional materials. We have applied this approach for different functional materials with perovskite framework: multiferroic, ferroelectric and relaxor ferroelectric ceramics, and organic-inorganic perovskite photovoltaics. Thanks to the combination of the two spectroscopies, it has been possible to probe more accurately the structural transitions involving the antiferrodisortive tilt modes of the octahedra in PZT [1] and NBT-BT [2]. It was also possible to evidence incipient phase separation in lead titanate-based multiferroics [3]. Moreover, since the elastic response is insensitive to free charges, it has been used to probe the piezoelectric response even in unpoled ceramics [4] and for the study of coexisting ferroelectric and metallic states [5]. The combination of the two techniques allowed also new features to be revealed on the reorientation dynamics of the organic molecules in MAPbI3 photovoltaic organic-inorganic perovskites and the hindrance of their ferroelectric order by coupling with the tilt modes [6]. 1. F. Cordero, F. Trequattrini, F. Craciun, C. Galassi, Phys. Rev. B, 87 (2013) 094108 2. F. Cordero, F. Craciun, F. Trequattrini, et al., Phys. Rev. B, 81 (2010) 144124 3. F. Craciun, F. Cordero, B. Vasile, et al., Phys. Chem. Chem. Phys., 20 (2018) 14652 4. F. Cordero, F. Craciun, F. Trequattrini, C. Galassi, Phys. Rev. B, 93 (2016) 174111 5. F. Cordero, F. Trequattrini, F. Craciun, et al., Phys. Rev. B, 99 (2019) 064106 6. F. Cordero, F. Craciun, F. Trequattrini, et al., J. Phys. Chem. Lett., 9 (2018) 4401

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  • Authors: Rasch, F.A.; Ebaid, R.; Najjar, M.;

    This research investigates the positive role developers and private investors play in preservation and restoration of historical buildings and important sites to national identity in Malta. The research also investigates the positive experience of energy conservation and its contribution to the environment. The role of foreign investors through direct investments, made a significant contribution to the restoration, preservation, and improvements to the tourism sector of the Maltese economy. Findings shows that this is the golden age in construction technology, whereby firms are experimenting with varying technologies, that includes 3D printing, VR, and other digitalized technologies that uses data to make better informed decisions regarding restoration and preservation of heritage buildings, as is the case with Sadeen Group, which showed that innovative practices were facilitated by the education arm of Sadeen, and affection of turning historical ruins into educational institution can make a significant difference to the local community. Proceedings of the 30th European Biomass Conference and Exhibition, 9-12 May 2022, Online, pp. 351-355

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  • Authors: Rasch, F.A.; Ebaid, R.; Najjar, M.;

    This research investigates the positive role developers and private investors play in preservation and restoration of historical buildings and important sites to national identity in Malta. The research also investigates the positive experience of energy conservation and its contribution to the environment. The role of foreign investors through direct investments, made a significant contribution to the restoration, preservation, and improvements to the tourism sector of the Maltese economy. Findings shows that this is the golden age in construction technology, whereby firms are experimenting with varying technologies, that includes 3D printing, VR, and other digitalized technologies that uses data to make better informed decisions regarding restoration and preservation of heritage buildings, as is the case with Sadeen Group, which showed that innovative practices were facilitated by the education arm of Sadeen, and affection of turning historical ruins into educational institution can make a significant difference to the local community. Proceedings of the 30th European Biomass Conference and Exhibition, 9-12 May 2022, Online, pp. 351-355

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Baldwin, John Derouet Couper;

    The need for an improved control strategy for the operation of a wind-powered refrigeration system for the storage of apples was investigated. The results are applicable to other systems which employ intermittently available power sources, battery and thermal storage, and an auxiliary, direct current power supply. Tests were conducted on the wind-powered refrigeration system at the Virginia Polytechnic Institute and State University Horticulture Research Farm in Blacksburg, Virginia. Tests were conducted on the individual components of the system. In situ windmill performance were also conducted. The results of these tests have been presented. An improved control strategy was developed to improve the utilization of available wind energy and to reduce the need for electrical energy from an external source while maintaining an adequate apple storage environment. Ph. D.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ VTechWorksarrow_drop_down
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    VTechWorks
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Baldwin, John Derouet Couper;

    The need for an improved control strategy for the operation of a wind-powered refrigeration system for the storage of apples was investigated. The results are applicable to other systems which employ intermittently available power sources, battery and thermal storage, and an auxiliary, direct current power supply. Tests were conducted on the wind-powered refrigeration system at the Virginia Polytechnic Institute and State University Horticulture Research Farm in Blacksburg, Virginia. Tests were conducted on the individual components of the system. In situ windmill performance were also conducted. The results of these tests have been presented. An improved control strategy was developed to improve the utilization of available wind energy and to reduce the need for electrical energy from an external source while maintaining an adequate apple storage environment. Ph. D.

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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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  • Authors: Ding, Yang; Wang, Chunhua; Pei, Lang; Mao, Qinan; +7 Authors

    Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions, Mn4+ ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode (W-LED), plant cultivation LED, and temperature thermometer. Up to now, Mn4+ has been widely introduced into the lattices of various inorganic hosts for brightly red-emitting phosphors. However, how to correlate the structure-activity relationship between host framework, luminescence property, and photoelectric device is urgently demanded. In this review, we thoroughly summarize the recent advances of Mn4+ doped phosphors. Meanwhile, several strategies like co-doping and defect passivation for improving Mn4+ emission are also discussed. Most importantly, the relationship between the protocols for tailoring the structures of Mn4+ doped phosphors, increased luminescence performance, and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated. Finally, the challenges and perspectives of Mn4+ doped phosphors for practical applications are anticipated. We cordially anticipate that this review can deliver a deep comprehension of not only Mn4+ luminescence mechanism but also the crystal structure tailoring strategy of phosphors, so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.

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  • Authors: Ding, Yang; Wang, Chunhua; Pei, Lang; Mao, Qinan; +7 Authors

    Owing to their high luminous efficiency and tunable emission in both red light and far-red light regions, Mn4+ ion-activated phosphors have appealed significant interest in photoelectric and energy conversion devices such as white light emitting diode (W-LED), plant cultivation LED, and temperature thermometer. Up to now, Mn4+ has been widely introduced into the lattices of various inorganic hosts for brightly red-emitting phosphors. However, how to correlate the structure-activity relationship between host framework, luminescence property, and photoelectric device is urgently demanded. In this review, we thoroughly summarize the recent advances of Mn4+ doped phosphors. Meanwhile, several strategies like co-doping and defect passivation for improving Mn4+ emission are also discussed. Most importantly, the relationship between the protocols for tailoring the structures of Mn4+ doped phosphors, increased luminescence performance, and the targeted devices with efficient photoelectric and energy conversion efficiency is deeply correlated. Finally, the challenges and perspectives of Mn4+ doped phosphors for practical applications are anticipated. We cordially anticipate that this review can deliver a deep comprehension of not only Mn4+ luminescence mechanism but also the crystal structure tailoring strategy of phosphors, so as to spur innovative thoughts in designing advanced phosphors and deepening the applications.

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  • Authors: M.C. Lobo; Antonio Plaza; I. Bautista; Pedro V. Mauri; +1 Authors

    The objective of the study was to evaluate the effect of two types of treated sewage sludge as soil amendment, composted with pruning wastes (CP) and thermally dried (ST) on the production of ten woody perennials species for energy purposes. The species used were: Paulownia tomentosa (princess tree), Populus x euramericana (Canadian poplar), Ulmus minor (field elm, tree clones), Ulmus laevis (European white elm), Prunus x amygdalo-persica (adafuel), Tamarix gallica (tamarisk), Salix alba (white willow) and Platanus x hispanica (plane tree). The increase in plant growth three years after amendment application is evaluated with the aim to analyze the long term effect of the treated sewage sludges application on plant production. In general, the plants developed in the soils treated with ST sludge present the highest values of growth (diameter, height and width), which can be due to the faster supply of nitrogen from this material. However, the growth rate was higher in the CP treatment for the most of the species due to a continuous release of nutrients from the CP degradation. In this sense, the effect of CP treatment on plant production would be observed at the longer time than the ST one. Proceedings of the 26th European Biomass Conference and Exhibition, 14-17 May 2018, Copenhagen, Denmark, pp. 369-373

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  • Authors: M.C. Lobo; Antonio Plaza; I. Bautista; Pedro V. Mauri; +1 Authors

    The objective of the study was to evaluate the effect of two types of treated sewage sludge as soil amendment, composted with pruning wastes (CP) and thermally dried (ST) on the production of ten woody perennials species for energy purposes. The species used were: Paulownia tomentosa (princess tree), Populus x euramericana (Canadian poplar), Ulmus minor (field elm, tree clones), Ulmus laevis (European white elm), Prunus x amygdalo-persica (adafuel), Tamarix gallica (tamarisk), Salix alba (white willow) and Platanus x hispanica (plane tree). The increase in plant growth three years after amendment application is evaluated with the aim to analyze the long term effect of the treated sewage sludges application on plant production. In general, the plants developed in the soils treated with ST sludge present the highest values of growth (diameter, height and width), which can be due to the faster supply of nitrogen from this material. However, the growth rate was higher in the CP treatment for the most of the species due to a continuous release of nutrients from the CP degradation. In this sense, the effect of CP treatment on plant production would be observed at the longer time than the ST one. Proceedings of the 26th European Biomass Conference and Exhibition, 14-17 May 2018, Copenhagen, Denmark, pp. 369-373

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  • Authors: M.L. Savouré; A. Besnard; F. Labalette; Brigitte Chabbert; +6 Authors

    The climatic, energetic and political context promotes the development of bioenergies. However we have a lack of knowledge to find out the best energy crops, depending on the soil, the climate and the end­use. This work aimed at studying the adaptation and the biomass and biofuel yield, of several energy crops grown in France in different soil and climate conditions. The biomass yields were very variable between the different experimental sites and no differences were observed on the median biomass yield between crops. Moreover, there was no evidence of a highly productive crop in all the conditions of soil and climate. Because of little differences of the lower heating value between crops, no differences were observed on the primary energy yield. The ethanol yield per hectare was higher for miscanthus, switchgrass and fiber sorghum because of higher cellulose content in these crops. The nitrogen removed at harvest by miscanthus and switchgrass were significantly lower than the other crops witch could lead to reduced fertilizer­N requirements. Further research are needed to clarify the effect of limiting factors on the biomass yield of the different energy crops and to consider other parameters such as the environmental impacts to give rules to choose the most suitable crop in a given region. Proceedings of the 18th European Biomass Conference and Exhibition, 3-7 May 2010, Lyon, France, pp. 269-272

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  • Authors: M.L. Savouré; A. Besnard; F. Labalette; Brigitte Chabbert; +6 Authors

    The climatic, energetic and political context promotes the development of bioenergies. However we have a lack of knowledge to find out the best energy crops, depending on the soil, the climate and the end­use. This work aimed at studying the adaptation and the biomass and biofuel yield, of several energy crops grown in France in different soil and climate conditions. The biomass yields were very variable between the different experimental sites and no differences were observed on the median biomass yield between crops. Moreover, there was no evidence of a highly productive crop in all the conditions of soil and climate. Because of little differences of the lower heating value between crops, no differences were observed on the primary energy yield. The ethanol yield per hectare was higher for miscanthus, switchgrass and fiber sorghum because of higher cellulose content in these crops. The nitrogen removed at harvest by miscanthus and switchgrass were significantly lower than the other crops witch could lead to reduced fertilizer­N requirements. Further research are needed to clarify the effect of limiting factors on the biomass yield of the different energy crops and to consider other parameters such as the environmental impacts to give rules to choose the most suitable crop in a given region. Proceedings of the 18th European Biomass Conference and Exhibition, 3-7 May 2010, Lyon, France, pp. 269-272

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    Authors: EMIL DINGA; CORNEL IONESCU; CAMELIA BALTARETU;

    The paper aims to achieve a definition of the concept of sustainability and of sustainable system from a logical perspective. In this respect, it introduces and defines (through the sufficiency predicates) the concept of logically vivid system and, on this basis, are discussed a logical concept of sustainability, respectively of a sustainable system in general are discussed and built up. Sustainability is considered in light of identity preservation of the systems, as a static anchor, on one hand, and of the concept of automatic stabilizers as a dynamic anchor on the other side. Finally, the two sufficiency conditions for a logically vivid system be sustainable are identified: the presence of hyper-cycles, respectively the absence of positive feed-back.

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    Authors: EMIL DINGA; CORNEL IONESCU; CAMELIA BALTARETU;

    The paper aims to achieve a definition of the concept of sustainability and of sustainable system from a logical perspective. In this respect, it introduces and defines (through the sufficiency predicates) the concept of logically vivid system and, on this basis, are discussed a logical concept of sustainability, respectively of a sustainable system in general are discussed and built up. Sustainability is considered in light of identity preservation of the systems, as a static anchor, on one hand, and of the concept of automatic stabilizers as a dynamic anchor on the other side. Finally, the two sufficiency conditions for a logically vivid system be sustainable are identified: the presence of hyper-cycles, respectively the absence of positive feed-back.

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    Optimization of all numerical codes ported in the infrastructure and used for supercapacitors, PV and batteries. The scope of deliverable D3.2 is to report the new advances in the field of materials for energy that comes from the search of new methodologies and models that could be more efficient on the new generation of computer hardware for exascale. In this respect, deliverable D3.2 is a transversal deliverable that report the new advances related to activities described in task T3.2, T3.3 and T3.4. H2020

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    Optimization of all numerical codes ported in the infrastructure and used for supercapacitors, PV and batteries. The scope of deliverable D3.2 is to report the new advances in the field of materials for energy that comes from the search of new methodologies and models that could be more efficient on the new generation of computer hardware for exascale. In this respect, deliverable D3.2 is a transversal deliverable that report the new advances related to activities described in task T3.2, T3.3 and T3.4. H2020

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  • Authors: Ziman, H.; Hillier, G.; Donegan, S.;

    There is increasing commercial interest in the pyrolysis of biomass and wastes to form pyrolysis oil, a dark liquid that is sometimes colloquially referred to as bio-crude oil. However, it is not compatible with crude oil or the refining processes used to produce hydrocarbons (including fuels) and petrochemicals. Currently pyrolysis oils are mostly used as a low grade fuel to generate heat and power.Current processes for the production of biofuels for blending into transport fuels have focused on the use of plant oils or starches as raw materials.These have the potential to compete with food for agricultural capacity. Some technologies have used wastes of varying types ranging from mixed wastes through to plastics and tyres.The development of processes that use lignocellulosic biomass (e.g. wood, straw) would enable waste biomass and forestry materials to be used in this way. Such sources of biomass can be used to produce pyrolysis oil.Laboratory work has shown that pyrolysis oils produced from a range of feedstocks have the potential to be upgraded into vehicle fuels.There is also the potential to extract commercially useful materials from pyrolysis oils providing a renewable alternative to petrochemicals

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  • Authors: Ziman, H.; Hillier, G.; Donegan, S.;

    There is increasing commercial interest in the pyrolysis of biomass and wastes to form pyrolysis oil, a dark liquid that is sometimes colloquially referred to as bio-crude oil. However, it is not compatible with crude oil or the refining processes used to produce hydrocarbons (including fuels) and petrochemicals. Currently pyrolysis oils are mostly used as a low grade fuel to generate heat and power.Current processes for the production of biofuels for blending into transport fuels have focused on the use of plant oils or starches as raw materials.These have the potential to compete with food for agricultural capacity. Some technologies have used wastes of varying types ranging from mixed wastes through to plastics and tyres.The development of processes that use lignocellulosic biomass (e.g. wood, straw) would enable waste biomass and forestry materials to be used in this way. Such sources of biomass can be used to produce pyrolysis oil.Laboratory work has shown that pyrolysis oils produced from a range of feedstocks have the potential to be upgraded into vehicle fuels.There is also the potential to extract commercially useful materials from pyrolysis oils providing a renewable alternative to petrochemicals

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  • Authors: Ekaterina Sermyagina; Esa Vakkilainen; Marcelo Cardoso; F.J. Borges Gomes; +2 Authors

    Renewable energy (mainly hydroelectric power plants) has a significant share in energy generation sector in Brazil. Recent climate changes, however, resulted in lower rainfall indexes and acted as a driving factor for the increasing interest in biomass applications. Therefore, having the land available for forest planting and a critical need for a new source of renewable energy, Brazil has the potential to further increase the energy generation from biomass. Due to the diverse nature of biomass materials, their properties range widely and exhibit different behaviors in thermal processes. To choose the most efficient way for production of energy, it is required to know the energy potential of the biomass samples. This study focuses on the physical-chemical characterization of nine lignocellulosic biomasses widely available in Brazil: five types of eucalyptus wood chips, sugarcane bagasse, elephant grass, bamboo, and coconut husk. Some characteristics regarded as important to thermochemical conversion are evaluated, such as: biomass chemical composition - polisacharides (glucans, xylans, galactans, mannans, arabinans), total uronic acids, acetyl groups, lignin, chloride, elementary analysis of the ash (Cu, Fe, Ca, Mn, Mg and K), silica and extractives, heating value, ultimate and proximate analyses. Moreover, the studied samples were investigated by thermogravimetric analysis (TG and DTG). The evaluation of these characteristics is important for understanding the processes of the thermochemical conversion of biomasses. Proceedings of the 23rd European Biomass Conference and Exhibition, 1-4 June 2015, Vienna, Austria, pp. 294-298

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  • Authors: Ekaterina Sermyagina; Esa Vakkilainen; Marcelo Cardoso; F.J. Borges Gomes; +2 Authors

    Renewable energy (mainly hydroelectric power plants) has a significant share in energy generation sector in Brazil. Recent climate changes, however, resulted in lower rainfall indexes and acted as a driving factor for the increasing interest in biomass applications. Therefore, having the land available for forest planting and a critical need for a new source of renewable energy, Brazil has the potential to further increase the energy generation from biomass. Due to the diverse nature of biomass materials, their properties range widely and exhibit different behaviors in thermal processes. To choose the most efficient way for production of energy, it is required to know the energy potential of the biomass samples. This study focuses on the physical-chemical characterization of nine lignocellulosic biomasses widely available in Brazil: five types of eucalyptus wood chips, sugarcane bagasse, elephant grass, bamboo, and coconut husk. Some characteristics regarded as important to thermochemical conversion are evaluated, such as: biomass chemical composition - polisacharides (glucans, xylans, galactans, mannans, arabinans), total uronic acids, acetyl groups, lignin, chloride, elementary analysis of the ash (Cu, Fe, Ca, Mn, Mg and K), silica and extractives, heating value, ultimate and proximate analyses. Moreover, the studied samples were investigated by thermogravimetric analysis (TG and DTG). The evaluation of these characteristics is important for understanding the processes of the thermochemical conversion of biomasses. Proceedings of the 23rd European Biomass Conference and Exhibition, 1-4 June 2015, Vienna, Austria, pp. 294-298

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  • Authors: Floriana Craciun (1); Francesco Cordero (1); Carmen Galassi (2);

    Dielectric and anelastic spectroscopies are complementary techniques and their combination allows valuable information to be obtained in the field of multifunctional materials. Whereas the dielectric spectroscopy measures the dielectric susceptibility ?(?,T) and it is sensitive to fluctuations of electric dipoles, the anelastic spectroscopy measures the elastic compliance or elastic susceptibility s(?,T) and it is sensitive to fluctuations of elastic dipoles. Both susceptibilities are complex, their immaginary part being due to the delayed response of the mobile defects coupled to the electric field/stress. The great advantage of using a combination of both techniques is that the anelastic measurements are insensitive to free charges, therefore it is possible to measure the dynamics of ions also in the presence of free charges. Two main types of investigations have been pursued by the combination of these techniques: the study of structural phase transitions and the study of microscopic mechanisms associated with the presence of defects, both important for the knowledge and development of multifunctional materials. We have applied this approach for different functional materials with perovskite framework: multiferroic, ferroelectric and relaxor ferroelectric ceramics, and organic-inorganic perovskite photovoltaics. Thanks to the combination of the two spectroscopies, it has been possible to probe more accurately the structural transitions involving the antiferrodisortive tilt modes of the octahedra in PZT [1] and NBT-BT [2]. It was also possible to evidence incipient phase separation in lead titanate-based multiferroics [3]. Moreover, since the elastic response is insensitive to free charges, it has been used to probe the piezoelectric response even in unpoled ceramics [4] and for the study of coexisting ferroelectric and metallic states [5]. The combination of the two techniques allowed also new features to be revealed on the reorientation dynamics of the organic molecules in MAPbI3 photovoltaic organic-inorganic perovskites and the hindrance of their ferroelectric order by coupling with the tilt modes [6]. 1. F. Cordero, F. Trequattrini, F. Craciun, C. Galassi, Phys. Rev. B, 87 (2013) 094108 2. F. Cordero, F. Craciun, F. Trequattrini, et al., Phys. Rev. B, 81 (2010) 144124 3. F. Craciun, F. Cordero, B. Vasile, et al., Phys. Chem. Chem. Phys., 20 (2018) 14652 4. F. Cordero, F. Craciun, F. Trequattrini, C. Galassi, Phys. Rev. B, 93 (2016) 174111 5. F. Cordero, F. Trequattrini, F. Craciun, et al., Phys. Rev. B, 99 (2019) 064106 6. F. Cordero, F. Craciun, F. Trequattrini, et al., J. Phys. Chem. Lett., 9 (2018) 4401

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  • Authors: Floriana Craciun (1); Francesco Cordero (1); Carmen Galassi (2);

    Dielectric and anelastic spectroscopies are complementary techniques and their combination allows valuable information to be obtained in the field of multifunctional materials. Whereas the dielectric spectroscopy measures the dielectric susceptibility ?(?,T) and it is sensitive to fluctuations of electric dipoles, the anelastic spectroscopy measures the elastic compliance or elastic susceptibility s(?,T) and it is sensitive to fluctuations of elastic dipoles. Both susceptibilities are complex, their immaginary part being due to the delayed response of the mobile defects coupled to the electric field/stress. The great advantage of using a combination of both techniques is that the anelastic measurements are insensitive to free charges, therefore it is possible to measure the dynamics of ions also in the presence of free charges. Two main types of investigations have been pursued by the combination of these techniques: the study of structural phase transitions and the study of microscopic mechanisms associated with the presence of defects, both important for the knowledge and development of multifunctional materials. We have applied this approach for different functional materials with perovskite framework: multiferroic, ferroelectric and relaxor ferroelectric ceramics, and organic-inorganic perovskite photovoltaics. Thanks to the combination of the two spectroscopies, it has been possible to probe more accurately the structural transitions involving the antiferrodisortive tilt modes of the octahedra in PZT [1] and NBT-BT [2]. It was also possible to evidence incipient phase separation in lead titanate-based multiferroics [3]. Moreover, since the elastic response is insensitive to free charges, it has been used to probe the piezoelectric response even in unpoled ceramics [4] and for the study of coexisting ferroelectric and metallic states [5]. The combination of the two techniques allowed also new features to be revealed on the reorientation dynamics of the organic molecules in MAPbI3 photovoltaic organic-inorganic perovskites and the hindrance of their ferroelectric order by coupling with the tilt modes [6]. 1. F. Cordero, F. Trequattrini, F. Craciun, C. Galassi, Phys. Rev. B, 87 (2013) 094108 2. F. Cordero, F. Craciun, F. Trequattrini, et al., Phys. Rev. B, 81 (2010) 144124 3. F. Craciun, F. Cordero, B. Vasile, et al., Phys. Chem. Chem. Phys., 20 (2018) 14652 4. F. Cordero, F. Craciun, F. Trequattrini, C. Galassi, Phys. Rev. B, 93 (2016) 174111 5. F. Cordero, F. Trequattrini, F. Craciun, et al., Phys. Rev. B, 99 (2019) 064106 6. F. Cordero, F. Craciun, F. Trequattrini, et al., J. Phys. Chem. Lett., 9 (2018) 4401

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  • Authors: Rasch, F.A.; Ebaid, R.; Najjar, M.;

    This research investigates the positive role developers and private investors play in preservation and restoration of historical buildings and important sites to national identity in Malta. The research also investigates the positive experience of energy conservation and its contribution to the environment. The role of foreign investors through direct investments, made a significant contribution to the restoration, preservation, and improvements to the tourism sector of the Maltese economy. Findings shows that this is the golden age in construction technology, whereby firms are experimenting with varying technologies, that includes 3D printing, VR, and other digitalized technologies that uses data to make better informed decisions regarding restoration and preservation of heritage buildings, as is the case with Sadeen Group, which showed that innovative practices were facilitated by the education arm of Sadeen, and affection of turning historical ruins into educational institution can make a significant difference to the local community. Proceedings of the 30th European Biomass Conference and Exhibition, 9-12 May 2022, Online, pp. 351-355

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  • Authors: Rasch, F.A.; Ebaid, R.; Najjar, M.;

    This research investigates the positive role developers and private investors play in preservation and restoration of historical buildings and important sites to national identity in Malta. The research also investigates the positive experience of energy conservation and its contribution to the environment. The role of foreign investors through direct investments, made a significant contribution to the restoration, preservation, and improvements to the tourism sector of the Maltese economy. Findings shows that this is the golden age in construction technology, whereby firms are experimenting with varying technologies, that includes 3D printing, VR, and other digitalized technologies that uses data to make better informed decisions regarding restoration and preservation of heritage buildings, as is the case with Sadeen Group, which showed that innovative practices were facilitated by the education arm of Sadeen, and affection of turning historical ruins into educational institution can make a significant difference to the local community. Proceedings of the 30th European Biomass Conference and Exhibition, 9-12 May 2022, Online, pp. 351-355

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