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In this study, air concentrations of BaP in two different seasons (winter 2015 and summer 2016) and BaP levels in ground vegetation from Tarragona County were used as control simulations performed with the WRF-CHIMERE air quality modelling system, in order to reproduce the incidence of that hazardous chemical in air and soils. The CTM was validated for the present climatology, showing a good ability to represent air and soil concentrations of BaP over the target domain (petrochemical, chemical, urban and background sites), particularly in the winter. Then, the variation of the BaP concentrations in air and soils were simulated for the time series 1996-2015 and for the climate change scenario RCP8.5 (2031-2050). While an increase is projected for the levels in air, particularly in chemical and remote sites where the variation can go up to 10%, in terms of soil deposition the findings are the opposite, with an evident decrease in soil BaP concentrations, particularly for background sites. Finally, a potential health effect of BaP for the local population (lung cancer) was assessed. Although according to the projections the EU threshold for BaP atmospheric incidence (1 ng m-3) will not be reached by 2050, there will be an increase in the life-time risk of lung cancer, particularly in the most populated areas within the simulation domain.

Using recycled rubber crumbs as drainage layer in extensive green roofs have high potential to reduce the heating and cooling loads in buildings over traditional materials used as drainage layer, such as pozzolana gravel. However, the environmental impact due to the life cycle should be analyzed to assess its environmental benefit. This paper evaluates the environmental performance of green roofs in which the drainage layer is made of rubber crumbs, a recycled material the use of which is still experimental for this purpose. In this paper Life Cycle Assessment (LCA) is applied to compare the environmental impact of four constructive systems, two extensive green roofs without insulation layer and with different drainage materials, e a recycled material, rubber crumbs, and a conventional one, pozzolana gravel -, in front of two conventional flat roofs, with and without thermal insulation (polyurethane), built in an experimental set-up consisting of four monitored house-like cubicles, located in Mediterranean continental climate (Lleida, Spain). The LCA considered the production, construction, operational, and disposal phases of the roofs, according to UNE-EN 15643-2. The operational phase was carried out using data measured in the experimental set-up, considering heating and cooling energy consumptions in the winter and summer period, respectively.

Abstract An exergy analysis, which only considers the unavoidable exergy destruction, is conducted for single, double, triple and half effect Water–Lithium bromide absorption cycles. Thus, the obtained performances represent the maximum achievable performance under the given operation conditions. The coefficient of performance (COP), the exergetic efficiencies and the exergy destruction rates are determined and the effect of the heat source temperature is evaluated. As expected, the COP increases significantly from double lift to triple effect cycles. The exergetic efficiency varies less among the different configurations. In all cycles the effect of the heat source temperature on the exergy destruction rates is similar for the same type of components, while the quantitative contributions depend on cycle type and flow configuration. Largest exergy destruction occurs in the absorbers and generators, especially at higher heat source temperatures.

This paper provides a review of the literature that applies the life cycle assessment (LCA) methodology to the assessment of the environmental performance of the life cycle of construction and demolition waste (CDW) management systems. This article is focused on generating a general mapping of the literature and on identifying the best practices in compliance with LCA framework and proposing directions for future LCA studies in this field. The temporal evolution of the research in this field and the aim of the studies have grown in parallel with the legal framework related to waste and energy efficiency of buildings. Most studies have been published in Europe, followed by USA. Asia and Australia, being at an incipient application stage to the rest of the world. Topics related to "LCA of buildings, including their EoL" and "LCA of general CDW management strategies" are the most frequently analysed, followed by "LCA of EoL of construction elements" and "LCA of natural material vs recycled material". Regarding the strategies, recycling off-site and incineration, both combined with landfill for the rejected fractions, are the most commonly applied. Re-use or recycling on-site is the strategy least applied. The key aspect when LCA is applied to evaluate CDW management systems is the need to normalise which processes to include in the system boundary and the functional unit, the use of inventory data adapted to the context of the case study and the definition of a common set of appropriate impact assessment categories. Also, it is important to obtain results disaggregated by unit processes. This will allow the comparison between case studies.

Abstract Life Cycle Assessment (LCA) has been conducted for seven experimental cubicles located in Puigverd de Lleida (Spain). The objective of this experimental set-up is to test different constructive solutions in order to point out the most sustainable solution with lower energy demand during the operational phase. Therefore, different building, insulation and Phase Change Materials (PCMs) have been tested under controlled temperature conditions to examine the thermal performance of the whole system. Although some of these materials are able to reduce the energy demand and consequently the environmental impact during the operational phase, they still have high embodied energy that can cause high environmental impact during the manufacturing phase. Therefore the LCA study in this paper focuses on assessing the impact of the embodied energy needed during the manufacturing and disposal phase by highlighting and comparing the effect of using different building materials, insulating materials, and phase change materials.

Abstract This paper presents the experimental characterization and modeling of a scroll expander. The expander used here is a scroll compressor modified to work as an expander. It is characterized in two experimental setups using air and ammonia as working fluids. The paper studies how the main operating variables (supply pressure and temperature, pressure ratio, rotational speed and lubrication) influence the performance of the scroll expander. A semi-empirical model is proposed to determine the scroll expander performance. This model uses some semi-empirical parameters (such as built-in volume ratio, leakage area and mechanical losses), obtained through experimentation, to calculate the mechanical power, supply mass flow rate and exhaust temperature. Using this semi-empirical model, the deviations in the calculated mechanical power, exhaust temperature and supply mass flow rate are ±9%, ±4 K and ±5% Hz.

Central solar heating plants with seasonal storage (CSHPSS) are among the most promising technologies to save energy in the industrial and residential-commercial building sectors. This work introduces a systematic approach to optimize these systems according to economic and environmental criteria. Our method, which combines the TRNSYS 17 simulation software with life cycle assessment and multi-objective optimization, identifies optimal CSHPSS designs for any climatic condition and heating demand profile considering economic and environmental criteria simultaneously. The capabilities of this approach are illustrated through its application to a case study of a CSHPSS located in Barcelona (Spain), which satisfies a heating demand for a neighborhood of 1120 dwellings. Numerical results show that the CSHPSS plant leads to significant environmental and economic improvements compared to the use of a conventional natural gas heating system. Our tool can guide engineers and architects in the transition towards a more sustainable residential sector.

The main target of this paper is to numerically study a multi-source (air/sun/ground) heat pump with the implementation of a thermal energy storage, using either water or PCM, for residential space heating. The system was modelled considering several sub-models for each of the components (compressor, solar panels, storage tank, heat exchangers etc.). A control strategy has been established to decide which operating mode of the system provides the highest coefficient of performance (COP). A multi-objective optimization through genetic algorithm of several decisional variables of the system was carried out, in different configurations and climate conditions, by considering different scenarios in terms of total investment and energy consumption costs, to optimize seasonal performances and investment cost of the entire system. Results show that solar thermal and solar photovoltaic collectors coupled with water storage tank give higher seasonal energy performance, especially in warmer climates, whereas the exploitation of the ground source can be more advantageous for colder climates. From the optimization analysis, it results that optimal non-dominated solutions characterized by a SCOP increase between 50% and 250% are characterized by higher investment costs between 215% and 730%, depending on the climate conditions. None of the solutions employing a PCM storage tank results economically feasible, due to a slight effect on system performance, and a much higher effect on investment costs. Finally, several cost scenarios in terms of incentives on investment costs and increased energy prices were analysed, for which the employment of scenarios with higher capital investment can be more advantageous in terms of lower total costs. This work was partially funded by Ministerio de Ciencia, Innovación y Universidades - Agencia Estatal de Investigación (AEI) (PID2021-123511OB-C31 - MCIN/AEI/10.13039/501100011033/FEDER, UE and RED2018-102431-T - MCIU/AEI). This work is partially supported by ICREA under the ICREA Academia programme. The authors form University of Lleida would like to thank the Catalan Government for the quality accreditation given to their research group (2017 SGR 1537). GREiA is certified agent TECNIO in the category of technology developers from the Government of Catalonia.