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Abstract In recent years, distributed energy systems (DESs) have been recognized as a promising option for sustainable development of future energy systems, and their application has increased rapidly with supportive policies and financial incentives. With growing concerns on global warming and depletion of fossil fuels, design optimization of DESs through economic assessments for short-run benefits only is not sufficient, while application of exergy principles can improve the efficiency in energy resource use for long-run sustainability of energy supply. The innovation of this paper is to investigate exergy in DES design to attain rational use of energy resources including renewables by considering energy qualities of supply and demand. By using low-temperature sources for low-quality thermal demand, the waste of high-quality energy can be reduced, and the overall exergy efficiency can be increased. The goal of the design optimization problem is to determine types, numbers and sizes of energy devices in DESs to reduce the total annual cost and increase the overall exergy efficiency. Based on a pre-established DES superstructure with multiple energy devices such as combined heat and power and PV, a multi-objective linear problem is formulated. In modeling of energy devices, the novelty is that the entire available size ranges and the variation of their efficiencies, capital and operation and maintenance costs with sizes are considered. The operation of energy devices is modeled based on previous work on DES operation optimization. By minimizing a weighted sum of the total annual cost and primary exergy input, the problem is solved by branch-and-cut. Numerical results show that the Pareto frontier provides good balancing solutions for planners based on economic and sustainability priorities. The total annual cost and primary exergy input of DESs with optimized configurations are reduced by 21–36% as compared with conventional energy supply systems, where grid power is used for the electricity demand, and gas-fired boilers and electric chillers fed by grid power for thermal demand. A sensitivity analysis is also carried out to analyze the influence of energy prices and energy demand variation on the optimized DES configurations.

Thermal energy storage systems (TES) based on shape-stabilized phase change materials (SSPCM) designed from recycled Tetra Pak (TP) waste, paraffin wax (PW), and expanded graphite (EG) were investigated in this study. This work represents the first study to explore TP waste composed of low-density polyethylene (LDPE)/aluminum (Al) components for energy storage applications. The LDPE part serves as a matrix conserving a material in a compact, solid shape after PW melting; PW acts as an active phase change component contributing to heat absorption/release through a phase change (from a solid to a liquid state, and vice versa) of its crystalline phase. EG serves as a filler that enhances the thermal conductivity and mechanical properties of materials. The focus was put on the optimization of the composition of SSPCM including PW, and EG, to check thermal, mechanical, and rheological properties which influence the future processability of such systems through extrusion, as well as to investigate the synergic effect of graphite and residual Al component on thermal conductivity and leakage of PW. There are two main demands on polymer/PW blends, namely well-separated melting peaks for both components at significantly different temperatures, and good compatibility between polymer and PW. The best performance of SSPCM investigated in this study was found for a mixture having the composition TP/PW/EG = 50/40/10 w/w/w. This mixture shows well-balanced properties, including appropriate heat storage and release parameters, thermal conductivity, thermal diffusivity, toughness and strength, and low leakage of PW from the material. This system can store 116.2 J/g of heat energy and release 93.8 J/g of heat energy. The determination of the heat energy storage and release was performed by the transient guarded hot plate technique. Tensile testing revealed that Young's modulus of the TP/PW/EG = 50/40/10 w/w/w composition was 924 ± 71 MPa and the stress at break was 8.2 ± 1.2 MPa, which are sufficient values from the applicability ...

Abstract This paper assesses the effects of a global emissions trading scheme (GETS) for international aviation and shipping as a way of reducing emissions of both greenhouse gases (GHG) and other atmospheric emissions that lead to air pollution. A prior assessment of such integration requires the coupling of energy–environment–economy (E3) global modelling of mitigation policies with the atmospheric modelling of pollution sources, mixing and deposition. We report the methodology and results of coupling of the E3MG model and the global atmospheric model, p-TOMCAT. We assess the effects of GETS on the concentrations of atmospheric gases and on the radiative forcing, comparing a GETS scenario to a reference BASE scenario with higher use of fossil fuels. The paper assesses the outcome of GETS for atmospheric composition and radiative forcing for 2050. GETS on international shipping and aviation reduces their CO 2 and non-CO 2 emissions up to 65%. As a consequence atmospheric concentrations are modified and the radiative forcing due to international transport is reduced by different amounts as a function of the pollutant studied (15% for CO 2 , 35% for methane and up to 50% for ozone).

PurposeValue chain analysis (VCA) can expose strategic and operational misalignments within chains, and the consequential misallocation of resources, and hence opportunities for improvements which create value and economic sustainability. This paper's purpose is to argue why and how VCA needs to integrate the social and environmental aspects of sustainability in pursuit of sustainable competitive advantage.Design/methodology/approachBased on a review of existing methods and case studies, the paper proposes three dimensions of VCA, which illustrate the flaws in narrow tools, and the need to broaden the boundaries of VCA, the interpretation of “value” and relationships along the chain in order to highlight opportunities for creating sustainable value chains.FindingsTo date VCA has largely focused on economic sustainability and paid inadequate attention to social and environment consequences of firm behaviour and the (re) allocation of resources within and between firms in the chain. This risks producing recommendations which either ignore the competitive advantage offered from improving environmental management and social welfare, or have such detrimental external consequences as to render any proposals unsustainable when exposed to government or broader (public) scrutiny.Research limitations/implicationsVCA variants need to be developed which incorporate all three pillars of sustainability. Some initial experiences are presented and ideas for future research and applications proposed.Practical implicationsThe development of sustainable VCA tools should identify business opportunities consistent with Porter and Kramer's imperative for value chains to create shared value between business and society.Originality/valueAdopting the broader dimensions identified will allow VCA to become more widely applicable, and more relevant in business scenarios where there is a growing imperative to include social and environmental impacts into “mainstream” business strategies.

Abstract Predicting heat transfer is a primary task in the design of open-cell foams. When a Local Thermal Non Equilibrium (LTNE) model is employed, convection heat transfer between the solid and fluid phases is considered, and a volumetric heat transfer coefficient needs to be defined. Some recent studies pointed out that the effects of developing convection heat transfer between the fluid and the solid in a foam are to be taken into account. The developing thermal flow of air through an open-cell foam, with a uniform heat flux solid/fluid boundary condition, is investigated numerically in this paper. The geometry is modeled with reference to Kelvin's tetrakaidecahedron foam model. A correlation among the porosity, the cell diameter and the ratio of heat transfer surface to volume is derived. Three regions are identified along the flow direction: an impingement region, a thermally developing region and a thermally developed region. Dimensional and dimensionless convection heat transfer coefficients have been predicted numerically as a function of the axial coordinate of the foam, for different values of the Reynolds number and the porosity. A correlation is presented among the predicted values of the volumetric Nusselt number, the porosity, and the Reynolds number in the thermally developed region, which is in good agreement with experimental data and numerical predictions by other authors. Finally, the analysis of the convection heat transfer through a single foam cell, at a local pore-scale, is presented.

We censused primate populations at three non-hunted ‘terra firme’ forests of south-eastern Colombian Amazonia. The aggregate biomass densities of diurnal primates at all sites were amongst the lowest recorded for any non-hunted forest in western Amazonia and elsewhere in the Neotropics. Densities of red howler monkeys were low, as is typical in Amazonian terra firme forests far removed from white-water rivers, and densities of woolly monkeys were 1.5–3.5 times lower than those estimated for this species in central-western Brazilian Amazonia. Densities of small to mid-sized primates except for brown capuchins (Cebus apella) and white-faced capuchins (Cebus albifrons) were similar to those of other oligotrophic Amazonian forest sites. Our results are in agreement with other studies showing that terra firme forests of lowland Amazonia typically sustain a low biomass density of primates and other mid-sized to large vertebrates. Large reserves are therefore required to assure the viability of primate populations in oligotrophic systems. Given the escalating negative impacts of human habitat disturbance and hunting in Colombian Amazonia, we urge that a baseline sampling protocol to quantify the abundance and distribution of the harvest-sensitive vertebrate fauna be established within protected areas and the large indigenous reserves so that conservation efforts can be defined and implemented.

This paper is a further study of ion binding to protein surfaces and builds on the studies of the binding of [Cr(CN)6]3− and [Fe(edta)(H2O)]− previously reported [Williams et al. (1982) FEBS Lett. 15, 293–299; Eley et al. (1982) Eur. J. Biochem. 124, 295–303]. In the present paper the binding of polyaminocarboxylate complexes of gadolinium have been studied. Eight ion‐binding sites have been identified on the surface of cytochrome c. These exhibit different binding specificities which, in some cases, are not fully understood. However it is clear that simple outer‐sphere interactions are not the sole determining factor for the association of metal ion complexes with proteins. The NMR paramagnetic difference spectrum method has been shown to be good at locating binding sites and revealing qualitative differences in their relative affinities for a range of complex types. However the use of relaxation probes is not a good method for the quantitative determination of binding constants; for this, isostructural shift probes must be sought.

Fusarium poae is one of the Fusarium species commonly detected in wheat kernels affected by Fusarium Head Blight. Fusarium poae produces a wide range of mycotoxins including nivalenol (NIV). The effect of temperature on colony growth and NIV production was investigated in vitro at 5-40 °C with 5 °C intervals. When the data were fit to a Beta equation (R2 ≥ 0.97), the optimal temperature was estimated to be 24.7 °C for colony growth and 27.5 °C for NIV production. The effects of temperature on infection incidence, fungal biomass, and NIV contamination were investigated by inoculating potted durum wheat plants at full anthesis; inoculated heads were kept at 10-40 °C with 5 °C intervals for 3 days and then at ambient temperature until ripening. Temperature significantly affected the incidence of floret infection and fungal biomass (as indicated by DNA amount) in the affected heads but did not affect NIV content in the head tissue. Inoculation of potted plants with F. poae did not reduce yield.