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Abstract This paper investigates two transition initiatives at the local level – namely the reconversion of the Porto Marghera and Gela refineries into biorefineries for second-generation biofuels. The study aimed at assessing the extent to which the narrative pressures exerted by local actors influenced the perspectives of key stakeholders involved in these transition processes. To this end, a blended methodology was employed, combining discourse analysis with stakeholder analysis and semi-structured interviews. First, stakeholders were grouped into four categories according to the source (national/global) and channel (formal/informal) of pressure. National/informal actors emerged as the most influential group. The discourse analysis identified three dominant storylines representing complementary trajectories defined by national actors operating through informal channels. Finally, semi-structured interviews with key local actors involved in the Porto Marghera and Gela reconversions were used to assess the impact of these storylines in the reconversion processes. Comparison of the two cases revealed fundamental specificities related to their respective cultural, political and socio-economic contexts. While the Porto Marghera reconversion was presented as a consolidated success story (albeit with a number of drawbacks related to the fact that it was still mainly powered by first-generation feedstocks), the Gela case was viewed as a complex and challenging ongoing process with an uncertain outcome.

Thermal energy storage systems (TES) based on shape-stabilized phase change materials (SSPCM) designed from recycled Tetra Pak (TP) waste, paraffin wax (PW), and expanded graphite (EG) were investigated in this study. This work represents the first study to explore TP waste composed of low-density polyethylene (LDPE)/aluminum (Al) components for energy storage applications. The LDPE part serves as a matrix conserving a material in a compact, solid shape after PW melting; PW acts as an active phase change component contributing to heat absorption/release through a phase change (from a solid to a liquid state, and vice versa) of its crystalline phase. EG serves as a filler that enhances the thermal conductivity and mechanical properties of materials. The focus was put on the optimization of the composition of SSPCM including PW, and EG, to check thermal, mechanical, and rheological properties which influence the future processability of such systems through extrusion, as well as to investigate the synergic effect of graphite and residual Al component on thermal conductivity and leakage of PW. There are two main demands on polymer/PW blends, namely well-separated melting peaks for both components at significantly different temperatures, and good compatibility between polymer and PW. The best performance of SSPCM investigated in this study was found for a mixture having the composition TP/PW/EG = 50/40/10 w/w/w. This mixture shows well-balanced properties, including appropriate heat storage and release parameters, thermal conductivity, thermal diffusivity, toughness and strength, and low leakage of PW from the material. This system can store 116.2 J/g of heat energy and release 93.8 J/g of heat energy. The determination of the heat energy storage and release was performed by the transient guarded hot plate technique. Tensile testing revealed that Young's modulus of the TP/PW/EG = 50/40/10 w/w/w composition was 924 ± 71 MPa and the stress at break was 8.2 ± 1.2 MPa, which are sufficient values from the applicability ...

Abstract The potential of dimethyl ether (DME) and dimethoxymethane (DMM), representatives of the attractive oxymethylene ether (OME) alternative fuel family, are explored here as reactivity enhancers for methane-fueled polygeneration processes. Typically, such processes that can flexibly generate power, heat, or chemicals, operate under fuel-rich conditions in gas turbines or internal combustion engines. To provide a consistent basis for the underlying reaction mechanisms, it is recognized that speciation data for the DME/CH4 fuel combination are available for such conditions while such information for the DMM/CH4 system is largely lacking. In addition, it should be noted that a detailed speciation study in flames, i.e., combustion systems involving chemistry and transport processes over a large temperature range, is still missing in spite of the potential of such systems to provide extended species information. In a systematic approach using speciation with electron ionization molecular-beam mass spectrometry (EI-MBMS), we thus report, as a first step, investigation of six fuel-rich premixed flames of DME and DMM and their blends with methane with special attention on interesting chemicals. Secondly, a comprehensive but compact DME/DMM/CH4 model (PolyMech2.1) is developed based on these data. This model is then examined against available experimental data under conditions from various facilities, focusing preferentially on elevated pressure and fuel-rich conditions. Comparison with existing literature models is also included in this evaluation. Thirdly, an analysis is given on this basis, via the extensively tested PolyMech2.1 model, for assumed polygeneration conditions in a homogeneous charge compression ignition (HCCI) engine environment. The main interest of this model-assisted exploration is to evaluate whether addition of DME or DMM in a polygeneration process can lead to potentially useful conditions for the production of syngas or other chemicals, along with work and heat. The flame results show that high syngas yields, i.e., up to ∼78% for CO and ∼35% for H2, can be obtained in their burnt gases. From the large number of intermediates detected, predominantly acetylene, ethylene, ethane, and formaldehyde show yields of 2.1−4.4% (C2 hydrocarbons) and 3.4−8.7% (CH2O), respectively. Also, methanol and methyl formate show comparably high yields of up to 0.6−6.7% in the flames with DMM, which is 1–2 orders of magnitude higher than in those with DME as the additive. In the modeling-assisted exploration of the engine process, the PolyMech2.1 model is seen to perform at significantly reduced computational costs compared to a recently validated model without sacrificing the prediction performance. Promising conditions for the assumed polygeneration process using fuel combinations in the DME/DMM/CH4 system are identified with attractive syngas yields of up to 77% together with work and heat output at exergetic efficiencies of up to 89% with DME.

A novel protocol for the synthesis of complex framework compounds containing a VCP fragment is presented by means of UV conversion of CP derivatives at r.t., providing high yields of target products in an unprecedented atom economical reversible step.

Abstract A sustainable building design should be compliant with the even more pressing energy saving requirements – as in NZEB – and high levels of Indoor Environmental Quality. Despite it is accepted that different facets of IEQ could have antagonistic effects on building energy demand, relatively few studies are aimed at investigating the mutual interaction among its four components. From this point of view, the hue-heat hypothesis is based on the idea that light and colors can affect the thermal perception. Particularly, spectral power distributions of light shifted to short wavelengths seem to promote a cooler thermal perception and vice-versa. To verify this still debated hypothesis, this paper is focused on a subjective investigation carried out in a special mechanically conditioned test room provided with white-tuning LED sources. 163 volunteers have been exposed to two different lighting scenarios characterized by warm (3000 K) and cool lights (6000 K) at a fixed work-plane illuminance value (300 lx) at two different operative temperature values (20 °C and 25 °C). Obtained results seem to confirm that warm light results in a warmer thermal sensation. Probably due to thermohygrometric conditions relatively close to comfort, no effects on thermal evaluation, and thermal preference were found under both microclimatic scenarios. This was also about the effects of CCT on humidity perception and game performances.