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Syngas (CO, CO2, and H2) has attracted special attention due to the double benefit of syngas fermentation for carbon sequestration (pollution reduction), while generating energy. Syngas can be either produced by gasification of biomasses or as a by-product of industrial processes. Only few microorganisms, mainly clostridia, were identified as capable of using syngas as a substrate to produce medium chain acids, or alcohols (such as butyric acid, butanol, hexanoic acid, and hexanol). Since CO plays a critical role in the availability of reducing equivalents and carbon conversion, this work assessed the effects of constant CO partial pressure (PCO), ranging from 0.5 to 2.5 atm, on cell growth, acid production, and solvent production, using Clostridium carboxidivorans. Moreover, this work focused on the effect of the liquid to gas volume ratio (VL/VG) on fermentation performances; in particular, two VL/VG were considered (0.28 and 0.92). The main results included—(a) PCO affected the growth kinetics of the microorganism; indeed, C. carboxidivorans growth rate was characterized by CO inhibition within the investigated range of CO concentration, and the optimal PCO was 1.1 atm (corresponding to a dissolved CO concentration of about 25 mg/L) for both VL/VG used; (b) growth differences were observed when the gas-to-liquid volume ratio changed; mass transport phenomena did not control the CO uptake for VL/VG = 0.28; on the contrary, the experimental CO depletion rate was about equal to the transport rate in the case of VL/VG = 0.92.

Recently, the marketable value of ω-3 fatty acid, particularly eicosapentaenoic acid (EPA), increased considering their health effects for human consumption. Microalgae are considered a valuable and “green” source of EPA alternative to fish oils, but considerable efforts are necessary for their exploitation at an industrial level. Due to the high operation costs of photoautotrophic microalgae cultivation, heterotrophic growth represents a promising economic solution. Marine diatoms are the major ecological producers of ω-3 fatty acids. Few species of diatoms are capable to grow in the dark using organic carbon sources. The marine diatom Cyclotella cryptica was cultivated for 14 days under photoautotrophic and heterotrophic conditions to define the effects on growth parameters, lipid production, total fatty acids and EPA content. Photoautotrophic conditions led to a total EPA production of 1.6% of dry weight, 12.2 mg L−1 culture and productivity of 0.9 mg L−1 day−1. The heterotrophy cultures reported a total EPA production of 2.7% of dry cell weight, 18 mg L−1 culture, a productivity of 1.3 mg L−1 day−1, which are promising values in the prospective of improving culture parameters for the biotechnological exploitation of dark cultivation. C. cryptica could be a potential candidate for the heterotrophic production of EPA, also considering its robustness, capacity to resist to bacterial contaminations and plasticity of lipid metabolism.

Fluidized bed gasification is a promising process technology to manage the growing amount of sewage sludge (SS) requiring disposal. Two samples of SS, produced in different seasons of the year by a municipal wastewater treatment plant, were subjected to gasification at 850 °C in a bench-scale fluidized bed reactor using, as a gasification agent, a nitrogen/air mixture at different values of oxygen/fuel equivalence ratio (ER = 0.1-0.2). The starting materials and the output streams (syngas, tar, and solid residues) were thoroughly characterized. The fate of specific SS constituents and the characteristics of bottom ashes were addressed, so contributing to the problem of a proper SS management approach in the context of the circular economy. Computer-aided simulations were also performed, which allowed us to predict the composition of the syngas from SS gasification under operating conditions different from those experimentally investigated (i.e., reactor temperature and ER).

The post-treatment of biomass from phytoremediation is not yet a well-established practice due to the risk induced by the presence of Potentially Toxic Elements (PTEs). Pyrolysis is a thermochemical treatment that reduces the volume and weight of contaminated matter producing a combustible vapor phase and a solid residue (char). A key factor enhancing the economic and the environmental sustainability of biomass valorization through pyrolysis is the production of a market value char. A proper choice of the pyrolysis operating conditions should take into account the effect of final temperature on PTEs release, on the char physicochemical properties as well as on the mobility of retained PTEs. In particular, in this work the influence of both the temperature and the plant parts is discussed (branches and leaves of Populus Nigra L. and rhizomes and culms of Arundo donax L.) on the release of Cd, Pb, Cu, and Zn in the temperature range 653-873 K under steam assisted slow pyrolysis conditions. The mobility of the heavy metals retained in the chars was also studied as well as the product yields, the gas composition and char porosity. The results suggested that in presence of Cd it is necessary to operate at low-temperature (lower than 703 K) to obtain a heavy metals free vapor phase fuel, whereas in presence of one or more metals among Pb, Cu, and Zn, it is possible to conduct a pyrolytic treatment at higher temperatures, thus obtaining a char with high BET surface area and lower metals mobility.

In this study, the sustainability of low-temperature geothermal field exploitation in a carbonate reservoir near Mondragone (CE), Southern Italy, is analyzed. The Mondragone geothermal field has been extensively studied through the research project VIGOR (Valutazione del potenzIale Geotermico delle RegiOni della convergenza). From seismic, geo-electric, hydro-chemical and groundwater data, obtained through the experimental campaigns carried out, physiochemical features of the aquifers and characteristics of the reservoir have been determined. Within this project, a well-doublet open-loop district heating plant has been designed to feed two public schools in Mondragone town. The sustainability of this geothermal application is analyzed in this study. A new exploration well (about 300 m deep) is considered to obtain further stratigraphic and structural information about the reservoir. Using the derived hydrogeological model of the area, a numerical analysis of geothermal exploitation was carried out to assess the thermal perturbation of the reservoir and the sustainability of its exploitation. The effect of extraction and reinjection of fluids on the reservoir was evaluated for 60 years of the plant activity. The results are fundamental to develop a sustainable geothermal heat plant and represent a real case study for the exploitation of similar carbonate reservoir geothermal resources.

The influence of two strains of Trichoderma (T. harzianum strain T22 and T. atroviride strain P1) on the growth of lettuce plants (Lactuca sativa L.) irrigated with As-contaminated water, and their effect on the uptake and accumulation of the contaminant in the plant roots and leaves, were studied. Accumulation of this non-essential element occurred mainly into the root system and reduced both biomass development and net photosynthesis rate (while altering the plant P status). Plant growth-promoting fungi (PGPF) of both Trichoderma species alleviated, at least in part, the phytotoxicity of As, essentially by decreasing its accumulation in the tissues and enhancing plant growth, P status and net photosynthesis rate. Our results indicate that inoculation of lettuce with selected Trichoderma strains may be helpful, beside the classical biocontrol application, in alleviating abiotic stresses such as that caused by irrigation with As-contaminated water, and in reducing the concentration of this metalloid in the edible part of the plant.

Abstract. The mountain cryosphere of mainland Europe is recognized to have important impacts on a range of environmental processes. In this paper, we provide an overview on the current knowledge on snow, glacier, and permafrost processes, as well as their past, current, and future evolution. We additionally provide an assessment of current cryosphere research in Europe and point to the different domains requiring further research. Emphasis is given to our understanding of climate–cryosphere interactions, cryosphere controls on physical and biological mountain systems, and related impacts. By the end of the century, Europe's mountain cryosphere will have changed to an extent that will impact the landscape, the hydrological regimes, the water resources, and the infrastructure. The impacts will not remain confined to the mountain area but also affect the downstream lowlands, entailing a wide range of socioeconomical consequences. European mountains will have a completely different visual appearance, in which low- and mid-range-altitude glaciers will have disappeared and even large valley glaciers will have experienced significant retreat and mass loss. Due to increased air temperatures and related shifts from solid to liquid precipitation, seasonal snow lines will be found at much higher altitudes, and the snow season will be much shorter than today. These changes in snow and ice melt will cause a shift in the timing of discharge maxima, as well as a transition of runoff regimes from glacial to nival and from nival to pluvial. This will entail significant impacts on the seasonality of high-altitude water availability, with consequences for water storage and management in reservoirs for drinking water, irrigation, and hydropower production. Whereas an upward shift of the tree line and expansion of vegetation can be expected into current periglacial areas, the disappearance of permafrost at lower altitudes and its warming at higher elevations will likely result in mass movements and process chains beyond historical experience. Future cryospheric research has the responsibility not only to foster awareness of these expected changes and to develop targeted strategies to precisely quantify their magnitude and rate of occurrence but also to help in the development of approaches to adapt to these changes and to mitigate their consequences. Major joint efforts are required in the domain of cryospheric monitoring, which will require coordination in terms of data availability and quality. In particular, we recognize the quantification of high-altitude precipitation as a key source of uncertainty in projections of future changes. Improvements in numerical modeling and a better understanding of process chains affecting high-altitude mass movements are the two further fields that – in our view – future cryospheric research should focus on.