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The EU has set out to reduce negative impacts from electricity generation on the environment, human health and towards our dependence on fossil fuels. As the fastest growing renewable source of electricity, photovoltaics plays an important role in the energy transition. The manufacturing of photovoltaic modules requires materials classified as critical, making them prone to supply disruptions. Although these materials are essential to the EU economy, they are not sufficiently recovered at the end of a photovoltaic module’s life. An alternative intermediate solution could be to extend the lifespan of existing modules, to slow down demand for these materials in the future. The aim of this study was to analyse the theoretical options and practical examples of product life extension strategies for photovoltaics. The R-Ladder was used as a guiding framework, which provided examples of life extension strategies. These include Reuse, Repair, Refurbishment, Remanufacture and Repurpose. Aspects for each of these strategies were analysed to find potential benefits and challenges related to four aspects: economics, environment, energy, and materials. The approach of this study includes a literature review to identify the life extension strategies discussed specifically for photovoltaics in the context of the circular economy. This was followed by a multi-case study on practical applications of Reuse, Repair and Repurposing of photovoltaic modules. Findings from literature and the case study were further supplemented with the insights from six experts. These experts had diverse backgrounds in research, manufacturing, and procurement to offer a variety of insights and perspectives on life extension strategies for photovoltaics. Finally, two scenarios were created for possible life extension pathways for used photovoltaic modules to illustrate the potential impacts compared to a commonplace premature replacement scenario. Economics and module performance are key factors in decision-making and acquisition of a photovoltaic ...

The level of advancement in the understanding of the mechanical properties of volcanic rocks is comparatively lower than that of sedimentary rocks. As part of the SUCCEED Project (Synergetic Utilisation of CO2 Storage Coupled with Geothermal Energy Deployment), which aims to investigate the feasibility of injecting captured and produced CO2 into the reservoirs to enhance geothermal production and achieve permanent CO2 storage at the Hellisheiði Geothermal Field in Iceland, this experimental research provides significant insights into the petrophysical and mechanical properties of the volcanic rocks collected from surface outcrops. The subsurface in Hellisheiði is mainly built up of hyaloclastite formations and interglacial basaltic lavas. During a field campaign samples were collected in different outcrops, ensuring that the samples were of high quality and sufficiently diverse to enable comprehensive analysis. Four samples per block and rock type have been prepared from the collected blocks, and they have been subjected to different laboratory tests to evaluate their petrophysical properties, such as porosity, density, and permeability, and their geomechanical behavior, using Unconfined Compression Test (UCS), Active-Source Acoustic Test, and Splitting Tensile Strength Test. Additionally, laboratory experiments have been conducted to investigate the impact of rapid cooling on rock damage due to thermal fracturing. The results show that there are interdependent relationships between porosity, bulk density, ultimate strength, Young's modulus, and wave velocities that can be observed when considering average values per rock. The rocks studied showed a negative correlation between porosity and other parameters and a direct correlation between ultimate strength and Young's Modulus. When examining individual rock samples, no significant correlations were observed between porosity and other parameters, however, those correlations where evident when comparing between different rock types, emphasizing the importance of ...

This paper develops a data-driven model for assessing the availability of flexibility from individual household devices, at house level. The model predicts the potential shift, increase or decrease of the energy consumption of a particular type of device at a given time, in response to a price signal, and for each house separately. Therefore, the location of the flexibility source is known with accuracy. The model has an Auto-Encoder architecture based on Convolution Neural Network. The augmented model demonstrates good performance in terms of predicting the time-shift in load.

Owing to the complexity of the sector, industrial activities are often represented with limited technological resolution in integrated energy system models. In this study, we enriched the technological description of industrial activities in the integrated energy system analysis optimisation (IESA-Opt) model, a peer-reviewed energy system optimisation model that can simultaneously provide optimal capacity planning for the hourly operation of all integrated sectors. We used this enriched model to analyse the industrial decarbonisation of the Netherlands for four key activities: high-value chemicals, hydrocarbons, ammonia, and steel production. The analyses performed comprised 1) exploring optimality in a reference scenario; 2) exploring the feasibility and implications of four extreme industrial cases with different technological archetypes, namely a bio-based industry, a hydrogen-based industry, a fully electrified industry, and retrofitting of current assets into carbon capture utilisation and storage; and 3) performing sensitivity analyses on key topics such as imported biomass, hydrogen, and natural gas prices, carbon storage potentials, technological learning, and the demand for olefins. The results of this study show that it is feasible for the energy system to have a fully bio-based, hydrogen-based, fully electrified, and retrofitted industry to achieve full decarbonisation while allowing for an optimal technological mix to yield at least a 10% cheaper transition. We also show that owing to the high predominance of the fuel component in the levelled cost of industrial products, substantial reductions in overnight investment costs of green technologies have a limited effect on their adoption. Finally, we reveal that based on the current (2022) energy prices, the energy transition is cost-effective, and fossil fuels can be fully displaced from industry and the national mix by 2050.

Abstract Developing countries are growing apart on environmental issues. International environmental negotiations are no longer characterized merely by the North–South conflict. Rising powers have come to divide the Global South and redefine the Common-But-Differentiated Responsibilities principle. This article explains the divergence of China and India at the Kigali Amendment to the Montreal Protocol, one of the first global environmental agreements to differentiate obligations between developing countries. China and India, the world’s two largest hydrofluorocarbon producers, ended decades of collaboration and split the rest of the developing world behind them. I argue that developmental strategy and political institutions shape the preferences and influences of industrial, governmental, and social stakeholders, thereby explaining their negotiation behavior and outcome. This article explains why China moved faster and further than India on negotiations for hydrofluorocarbon regulation. It has important implications for the two rising powers’ implementation of the Kigali Amendment and for their position formulations on other environmental issues.

In view of the growing shares of renewables in the electricity grid in combination with the electrification of hvac (heating, ventilation, air conditioning) systems in residential buildings, the grid intensity (in terms of carbon dioxide emissions per unit of electric energy) becomes increasingly sensitive to weather conditions, and synchronicity between weather and the grid becomes a more critical aspect in building performance assessment. Using building performance simulation techniques to seek robust building designs requires awareness about the uncertainties in circumstantial factors that affect performance. This 2016 – 2022 retrospective study highlights the effects of using low or high temporal resolution grid emissions intensity data on projected operation-induced carbon dioxide emissions for a terraced dwelling in the Netherlands. Building fabric quality, the occupant profile, and systems configurations (i.e., hvac and photovoltaics) are varied to investigate the effects of the applied grid model resolution. This study shows that ignoring high-resolution grid intensity data is getting increasingly problematic; applying low resolution (annual) instead of high-resolution (15-minute) grid intensity data leads to an increasingly unjustified optimistic assessment both for net and gross emissions (either or not allowing for carbon displacement by feeding locally generated electricity into the grid).

We introduce a novel simulation tool capable of calculating the energy yield of a PV system based on its fundamental material properties and using self-consistent models. Thus, our simulation model can operate without measurements of a PV device. It combines wave and ray optics and a dedicated semiconductor simulation to model the optoelectronic PV device properties resulting in the IV-curve. The system surroundings are described via spectrally resolved ray tracing resulting in a cell resolved irradiance distribution, and via the fluid dynamics-based thermal model, in the individual cell temperatures. A lumped-element model is used to calculate the IV-curves of each solar cell for every hour of the year. These are combined factoring in the interconnection to obtain the PV module IV-curves, which connect to the inverter for calculating the AC energy yield. In our case study, we compare two types of 2 terminal perovskite/silicon tandem modules with STC PV module efficiencies of 27.7% and 28.6% with a reference c-Si module with STC PV module efficiency of 20.9%. In four different climates, we show that tandem PV modules operate at 1–1.9 °C lower yearly irradiance weighted average temperatures compared to c-Si. We find that the effect of current mismatch is significantly overestimated in pure optical studies, as they do not account for fill factor gains. The specific yields in kWh/kWp of the tandem PV systems are between −2.7% and +0.4% compared to the reference c-Si system in all four simulated climates. Thus, we find that the lab performance of the simulated tandem PV system translates from the laboratory to outdoors comparable to c-Si systems. Photovoltaic Materials and Devices Electrical Sustainable Energy Energie and Industrie

Using liquid metals confined in capillary porous structures (CPSs) as a plasma-facing component (PFC) could prolong the lifetime of the divertor in the high heat flux area. However, the high atomic number of tin (Sn) limits its acceptable fraction in the main plasma. Therefore, a crucial step in developing this concept is to test it in a tokamak environment, particularly in the diverted plasma region, e.g. ASDEX Upgrade (AUG). In this paper, the design of liquid tin module (LTM) is explained, and the testing in the high heat flux device GLADIS before its use in AUG is presented. The LTM was additively manufactured using selective laser melting, consisting of a 1.5mm porous layer tungsten (W) directly attached to a solid W bulk. The LTM has a plasma-facing area of 16×40mm2 and was filled with 1.54g of Sn. In GLADIS, the module was exposed to power loads between 2 and 8MWm−2 for 1 up to 10s, first unfilled and later filled with Sn. The surface temperature was monitored with infrared imaging and pyrometry. The thermal response was used to compare with simulations in Ansys Mechanical, enabling a determination of the module’s effective thermal properties. Sn droplets could be observed on the infrared camera, until a surface temperature of about a 1000°C was reached. The enhanced wetting of tin on the plasma-facing surface, which was observed by a visible camera, suggests that there is a conditioning of the surface, possibly due to the removal of impurities and oxides. Subsequent examinations of the adjacent tile revealed minor Sn leakages emanating from the module’s edge. Furthermore, the module showed no indication of mechanical failure. Therefore, these results indicated that the LTM qualifies for the heat fluxes expected in ASDEX Upgrade.